EP0849350B1 - Procédé de transformation d'une coupe gazole pour produire un carburant à haut indice de cétane, désaromatisé et désulfuré - Google Patents
Procédé de transformation d'une coupe gazole pour produire un carburant à haut indice de cétane, désaromatisé et désulfuré Download PDFInfo
- Publication number
- EP0849350B1 EP0849350B1 EP97402996A EP97402996A EP0849350B1 EP 0849350 B1 EP0849350 B1 EP 0849350B1 EP 97402996 A EP97402996 A EP 97402996A EP 97402996 A EP97402996 A EP 97402996A EP 0849350 B1 EP0849350 B1 EP 0849350B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- metal
- weight
- catalyst
- support
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 29
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 title claims description 14
- 239000003921 oil Substances 0.000 title 1
- 230000009466 transformation Effects 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims description 60
- 229910052751 metal Inorganic materials 0.000 claims description 49
- 239000002184 metal Substances 0.000 claims description 49
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 27
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 26
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 24
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 20
- 239000000446 fuel Substances 0.000 claims description 16
- 229910052759 nickel Inorganic materials 0.000 claims description 15
- 150000002736 metal compounds Chemical class 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- -1 silica-aluminas Substances 0.000 claims description 12
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 11
- 229910052750 molybdenum Inorganic materials 0.000 claims description 11
- 229910000510 noble metal Inorganic materials 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 150000002367 halogens Chemical class 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052796 boron Inorganic materials 0.000 claims description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 9
- 239000011707 mineral Substances 0.000 claims description 9
- 239000011733 molybdenum Substances 0.000 claims description 9
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 7
- 150000001491 aromatic compounds Chemical class 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 7
- 239000011737 fluorine Substances 0.000 claims description 7
- 239000007789 gas Substances 0.000 claims description 7
- 238000004064 recycling Methods 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001639 boron compounds Chemical class 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 230000001131 transforming effect Effects 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 239000005078 molybdenum compound Substances 0.000 claims description 2
- 150000002752 molybdenum compounds Chemical class 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims 1
- 229910052810 boron oxide Inorganic materials 0.000 claims 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- 150000003018 phosphorus compounds Chemical class 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 description 21
- 239000011593 sulfur Substances 0.000 description 21
- 239000000047 product Substances 0.000 description 17
- 239000002283 diesel fuel Substances 0.000 description 13
- 229910052698 phosphorus Inorganic materials 0.000 description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000011574 phosphorus Substances 0.000 description 7
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 241000287107 Passer Species 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 229940082150 encore Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
- C10G65/08—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a hydrogenation of the aromatic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
Definitions
- the catalyst support can be selected from the group formed by alumina, silica, silica-aluminas, zeolites, titanium oxide, magnesia, zirconia, clays and mixtures of two or more of these compounds minerals.
- Alumina is very commonly used.
- the catalyst of these steps a), a1), a2) comprise, deposited on the support, at least one metal or a compound of metal, advantageously chosen from the group formed by molybdenum and tungsten and at least one metal or a metal compound advantageously selected in the group formed by nickel, cobalt and iron.
- this catalyst includes molybdenum or a molybdenum compound and at least one metal or compound of metal selected from the group consisting of nickel and cobalt.
- a catalyst containing Ni, Mo, P is preferably used, the proportions of these elements previously described, or better Ni, Mo, P, B.
- a particularly advantageous catalyst is that described in patent EP-297,949 whose teaching is included in this description.
- This catalyst comprises: a) a support comprising a porous mineral matrix, boron or a boron compound and phosphorus or a phosphorus compound, and b) at least one metal or group VIB metal compound of the periodic table of elements and at least one metal or group VIII metal compound of said classification, wherein the sum of the amounts of boron and phosphorus, expressed respectively by weight of boron trioxide (B 2 O 3 ) and phosphorus pentoxide (P 2 O 5 ) relative to the weight of the support is about 5 to 15%, preferably about 6 to 12% and preferably about 8 to 11.5%, the atomic ratio boron on phosphorus (B / P) is about 1.05: 1, 2: 1 and preferably about 1.1: 1 to 1.8: 1.
- at least 40% and preferably at least 50% of the total pore volume of the finished catalyst is contained in pores with an average diameter greater than 13 nanometers.
- the amount by weight of the metals contained in the finished catalyst expressed by weight of metal over the weight of the finished catalyst is usually, for the metal or the Group VIB metals of about 2 to 30% and preferably about 5 to 25%, and for the metal or Group VIII metals from about 0.1 to 15% and more particularly from about 0.1 to 5% and preferably from about 0.15 to 3% in the case of metals group VIII (Pt, Pd, Ru, Rh, Os, Ir) and about 0.5 to 15% and preferably from 1 to 10% in the case of non noble metals of group VIII (Fe, Co, Ni).
- Halogen is usually introduced onto the support from the acid halides corresponding and the noble metal, preferably platinum or palladium, from example of aqueous solutions of their salts or compounds such as for example the acid hexachloroplatinic in the case of platinum.
- the noble metal preferably platinum or palladium
- Another suitable catalyst is that described in US Pat. No. 4,225,461. he comprises a noble metal and a halogen and has been prepared in a particular way.
- the first step is carried out in a pilot hydrotreatment unit.
- This includes two reactors in series that can hold up to 20 l. fixed bed catalyst.
- the unit includes a hydrogen recycling compressor. Fluid flow is down in each of the reactors.
- the unit has an online column of steam stripping which allows to stripper the effluent of the reaction which is thus completely free of H2S and NH3 formed during the reaction.
- the effluent is stored for second-stage pilot tests.
- the second step is carried out in a smaller pilot unit with a reactor of 1 l. with upward flow of fluids.
- the unit does not have any recycling compressor.
- the effluent is stored for second-stage pilot tests.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9615929 | 1996-12-20 | ||
| FR9615929A FR2757532B1 (fr) | 1996-12-20 | 1996-12-20 | Procede de transformation d'une coupe gazole pour produire un carburant a haute indice de cetane, desaromatise et desulfure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0849350A1 EP0849350A1 (fr) | 1998-06-24 |
| EP0849350B1 true EP0849350B1 (fr) | 2005-04-13 |
Family
ID=9499065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP97402996A Expired - Lifetime EP0849350B1 (fr) | 1996-12-20 | 1997-12-10 | Procédé de transformation d'une coupe gazole pour produire un carburant à haut indice de cétane, désaromatisé et désulfuré |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US6042716A (enExample) |
| EP (1) | EP0849350B1 (enExample) |
| JP (1) | JP4134345B2 (enExample) |
| KR (1) | KR100536016B1 (enExample) |
| CN (1) | CN1134529C (enExample) |
| BR (1) | BR9706404A (enExample) |
| DE (1) | DE69732998T2 (enExample) |
| ES (1) | ES2242209T3 (enExample) |
| FR (1) | FR2757532B1 (enExample) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2757532B1 (fr) * | 1996-12-20 | 1999-02-19 | Inst Francais Du Petrole | Procede de transformation d'une coupe gazole pour produire un carburant a haute indice de cetane, desaromatise et desulfure |
| AU756565B2 (en) * | 1998-12-08 | 2003-01-16 | Exxonmobil Research And Engineering Company | Production of low sulfur/low aromatics distillates |
| FR2795420B1 (fr) * | 1999-06-25 | 2001-08-03 | Inst Francais Du Petrole | Procede d'hydrotraitement d'un distillat moyen dans deux zones successives comprenant une zone intermediaire de stripage de l'effluent de la premiere zone avec condensation des produits lourds sortant en tete du strippeur |
| US6821412B1 (en) | 1999-08-30 | 2004-11-23 | Cosmo Oil Co., Ltd. | Catalyst for hydrotreating of gas oil and method for hydrotreating of gas oil |
| US6676829B1 (en) * | 1999-12-08 | 2004-01-13 | Mobil Oil Corporation | Process for removing sulfur from a hydrocarbon feed |
| EP1120454A3 (en) * | 2000-01-25 | 2002-01-30 | Haldor Topsoe A/S | Process for reducting content of sulphur compounds and poly-aromatic hydrocarbons in hydrocarbon feed |
| FR2804967B1 (fr) | 2000-02-11 | 2005-03-25 | Inst Francais Du Petrole | Procede et installation utilisant plusieurs lits catalytiques en serie pour la production de gazoles a faible teneur en soufre |
| FR2804966B1 (fr) * | 2000-02-11 | 2005-03-25 | Inst Francais Du Petrole | Procede et installation utilisant plusieurs lits catalytiques en serie pour la production de gazoles a faible teneur en souffre |
| WO2001074973A1 (en) * | 2000-03-30 | 2001-10-11 | Japan Energy Corporation | Process for hydrodesulfurization of light oil fraction |
| EP1409612A4 (en) * | 2000-04-20 | 2004-06-16 | Exxonmobil Res & Eng Co | Production of low sulfur/low aromatics distillates |
| CA2405019C (en) * | 2000-04-20 | 2010-06-22 | Exxonmobil Research And Engineering Company | Production of low sulfur distillates |
| FR2823216B1 (fr) * | 2001-04-09 | 2007-03-09 | Inst Francais Du Petrole | Procede et installation utilisant plusieurs lits catalytiques en serie pour la production de gazoles a faible teneur en soufre |
| ES2292537T3 (es) * | 2001-11-22 | 2008-03-16 | Institut Francais Du Petrole | Procedimiento de hidrotratamiento de destilados medios en dos etapas que comprende dos bucles de reciclado de hidrogeno. |
| US8158843B2 (en) * | 2002-02-12 | 2012-04-17 | The Penn State Research Foundation | Deep desulfurization of hydrocarbon fuels |
| JP4575646B2 (ja) * | 2003-03-07 | 2010-11-04 | Ｊｘ日鉱日石エネルギー株式会社 | 軽油組成物 |
| JP4567947B2 (ja) * | 2003-03-07 | 2010-10-27 | Ｊｘ日鉱日石エネルギー株式会社 | 軽油組成物 |
| JP4567948B2 (ja) * | 2003-03-07 | 2010-10-27 | Ｊｘ日鉱日石エネルギー株式会社 | 軽油組成物およびその製造方法 |
| JP4576333B2 (ja) * | 2003-03-07 | 2010-11-04 | Ｊｘ日鉱日石エネルギー株式会社 | 軽油留分の水素化処理方法 |
| JP2004269685A (ja) * | 2003-03-07 | 2004-09-30 | Nippon Oil Corp | 軽油組成物及びその製造方法 |
| CN1313573C (zh) * | 2003-09-15 | 2007-05-02 | 中国石油化工股份有限公司 | 一种柴油馏分油深度脱硫的方法 |
| FR2867988B1 (fr) * | 2004-03-23 | 2007-06-22 | Inst Francais Du Petrole | Catalyseur supporte dope de forme spherique et procede d'hydrotraitement et d'hydroconversion de fractions petrolieres contenant des metaux |
| CN1294241C (zh) * | 2004-07-06 | 2007-01-10 | 中国石油化工股份有限公司 | 一种劣质汽油的加氢改质方法 |
| EP1832645A4 (en) * | 2004-12-28 | 2012-01-11 | Japan Energy Corp | METHOD FOR PRODUCING A GAS OIL BASED MATERIAL WITH SUPER LOW SULFUR CONTENT OR GAS OIL COMPOSITION WITH SUPER LOW SULFUR CONTENT AND GAS OIL COMPOSITION WITH SUPER LOW SULFUR CONTENT |
| KR101156370B1 (ko) * | 2005-02-17 | 2012-06-13 | 에스케이에너지 주식회사 | 저방향족 및 초저유황 경유를 제조하는 방법 |
| EP1779929A1 (en) * | 2005-10-27 | 2007-05-02 | Süd-Chemie Ag | A catalyst composition for hydrocracking and process of mild hydrocracking and ring opening |
| US7906013B2 (en) | 2006-12-29 | 2011-03-15 | Uop Llc | Hydrocarbon conversion process |
| JP4589940B2 (ja) * | 2007-05-15 | 2010-12-01 | 株式会社ジョモテクニカルリサーチセンター | 高出力軽油組成物 |
| US7790020B2 (en) * | 2007-10-15 | 2010-09-07 | Uop Llc | Hydrocarbon conversion process to improve cetane number |
| KR100934331B1 (ko) * | 2008-06-17 | 2009-12-29 | 에스케이루브리컨츠 주식회사 | 고급 나프텐계 베이스 오일의 제조방법 |
| US8008534B2 (en) * | 2008-06-30 | 2011-08-30 | Uop Llc | Liquid phase hydroprocessing with temperature management |
| US8999141B2 (en) * | 2008-06-30 | 2015-04-07 | Uop Llc | Three-phase hydroprocessing without a recycle gas compressor |
| US9279087B2 (en) * | 2008-06-30 | 2016-03-08 | Uop Llc | Multi-staged hydroprocessing process and system |
| US8518241B2 (en) * | 2009-06-30 | 2013-08-27 | Uop Llc | Method for multi-staged hydroprocessing |
| US8221706B2 (en) * | 2009-06-30 | 2012-07-17 | Uop Llc | Apparatus for multi-staged hydroprocessing |
| CN101691496B (zh) * | 2009-09-17 | 2012-01-25 | 湖南长岭石化科技开发有限公司 | 一种催化汽油改质降烯烃的方法 |
| CN102746894B (zh) * | 2011-04-22 | 2014-11-19 | 中国石油天然气股份有限公司 | 一种芳烃选择性开环反应方法 |
| JP6273202B2 (ja) * | 2011-07-29 | 2018-01-31 | サウジ アラビアン オイル カンパニー | 段間スチームストリッピングを伴う水素化分解法 |
| US11072751B1 (en) | 2020-04-17 | 2021-07-27 | Saudi Arabian Oil Company | Integrated hydrotreating and deep hydrogenation of heavy oils including demetallized oil as feed for olefin production |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3356608A (en) * | 1967-12-05 | Hydrotreating process with hzs removal from the effluent | ||
| US3236764A (en) * | 1964-11-27 | 1966-02-22 | Standard Oil Co | Jet fuel manufacture |
| FR2197967B1 (enExample) * | 1972-09-01 | 1975-01-03 | Inst Francais Du Petrole | |
| FR2413127A1 (fr) * | 1978-01-02 | 1979-07-27 | Inst Francais Du Petrole | Procede de preparation d'un catalyseur de metal noble du groupe viii presentant une resistance amelioree au soufre, catalyseur obtenu et son utilisation pour l'hydrogenation d'hydrocarbures aromatiques |
| US4427534A (en) * | 1982-06-04 | 1984-01-24 | Gulf Research & Development Company | Production of jet and diesel fuels from highly aromatic oils |
| FR2617412B1 (fr) * | 1987-07-01 | 1993-05-14 | Inst Francais Du Petrole | Catalyseur comprenant un support mineral, du phosphore et du bore, methodes de preparation et utilisation en hydroraffinage de coupes petrolieres |
| US4828675A (en) * | 1987-12-04 | 1989-05-09 | Exxon Research And Engineering Company | Process for the production of ultra high octane gasoline, and other fuels from aromatic distillates |
| US4875992A (en) * | 1987-12-18 | 1989-10-24 | Exxon Research And Engineering Company | Process for the production of high density jet fuel from fused multi-ring aromatics and hydroaromatics |
| US5110444A (en) * | 1990-08-03 | 1992-05-05 | Uop | Multi-stage hydrodesulfurization and hydrogenation process for distillate hydrocarbons |
| US5114562A (en) * | 1990-08-03 | 1992-05-19 | Uop | Two-stage hydrodesulfurization and hydrogenation process for distillate hydrocarbons |
| US5462651A (en) * | 1994-08-09 | 1995-10-31 | Texaco Inc. | Hydrodearomatization of hydrocarbon oils using novel "phosphorus treated carbon" supported metal sulfide catalysts |
| FR2757532B1 (fr) * | 1996-12-20 | 1999-02-19 | Inst Francais Du Petrole | Procede de transformation d'une coupe gazole pour produire un carburant a haute indice de cetane, desaromatise et desulfure |
-
1996
- 1996-12-20 FR FR9615929A patent/FR2757532B1/fr not_active Expired - Lifetime
-
1997
- 1997-12-10 ES ES97402996T patent/ES2242209T3/es not_active Expired - Lifetime
- 1997-12-10 DE DE69732998T patent/DE69732998T2/de not_active Expired - Lifetime
- 1997-12-10 EP EP97402996A patent/EP0849350B1/fr not_active Expired - Lifetime
- 1997-12-18 BR BR9706404A patent/BR9706404A/pt not_active IP Right Cessation
- 1997-12-18 US US08/992,486 patent/US6042716A/en not_active Expired - Lifetime
- 1997-12-19 KR KR1019970070486A patent/KR100536016B1/ko not_active Expired - Fee Related
- 1997-12-19 JP JP35061197A patent/JP4134345B2/ja not_active Expired - Fee Related
- 1997-12-20 CN CNB971297231A patent/CN1134529C/zh not_active Expired - Fee Related
-
2000
- 2000-01-10 US US09/480,628 patent/US6221239B1/en not_active Expired - Lifetime
-
2001
- 2001-03-22 US US09/813,946 patent/US6451198B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2242209T3 (es) | 2005-11-01 |
| US6221239B1 (en) | 2001-04-24 |
| BR9706404A (pt) | 1999-06-08 |
| JP4134345B2 (ja) | 2008-08-20 |
| MX9710346A (es) | 1998-08-30 |
| JPH10183144A (ja) | 1998-07-14 |
| CN1189526A (zh) | 1998-08-05 |
| DE69732998T2 (de) | 2005-09-01 |
| DE69732998D1 (de) | 2005-05-19 |
| KR19980064338A (ko) | 1998-10-07 |
| US20010013485A1 (en) | 2001-08-16 |
| FR2757532A1 (fr) | 1998-06-26 |
| FR2757532B1 (fr) | 1999-02-19 |
| KR100536016B1 (ko) | 2006-04-20 |
| CN1134529C (zh) | 2004-01-14 |
| US6451198B2 (en) | 2002-09-17 |
| US6042716A (en) | 2000-03-28 |
| EP0849350A1 (fr) | 1998-06-24 |
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