EP0797932B1 - Procédé de fabrication d'un entoilage thermocollant - Google Patents
Procédé de fabrication d'un entoilage thermocollant Download PDFInfo
- Publication number
- EP0797932B1 EP0797932B1 EP97400402A EP97400402A EP0797932B1 EP 0797932 B1 EP0797932 B1 EP 0797932B1 EP 97400402 A EP97400402 A EP 97400402A EP 97400402 A EP97400402 A EP 97400402A EP 0797932 B1 EP0797932 B1 EP 0797932B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- screen printer
- points
- process according
- transfer roller
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 18
- 239000004753 textile Substances 0.000 claims description 46
- 229920000642 polymer Polymers 0.000 claims description 16
- 230000008018 melting Effects 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 11
- 239000004744 fabric Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000000151 deposition Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- -1 polyethylenes Polymers 0.000 claims description 4
- 229920001169 thermoplastic Polymers 0.000 claims description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001634 Copolyester Polymers 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 230000002093 peripheral effect Effects 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 1
- 230000005670 electromagnetic radiation Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 59
- 238000007650 screen-printing Methods 0.000 description 14
- 239000012943 hotmelt Substances 0.000 description 11
- 239000000853 adhesive Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 230000008021 deposition Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000012790 adhesive layer Substances 0.000 description 3
- 239000002998 adhesive polymer Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 229920003180 amino resin Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 206010029216 Nervousness Diseases 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C1/00—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
- B05C1/04—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
- B05C1/08—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
- B05C1/10—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line the liquid or other fluent material being supplied from inside the roller
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D27/00—Details of garments or of their making
- A41D27/02—Linings
- A41D27/06—Stiffening-pieces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C9/00—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
- B05C9/04—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material to opposite sides of the work
Definitions
- the invention relates to a method of manufacturing a fusible interfacing.
- linings are specifically intended to be laminated to another textile, for example a drapery, so as to constitute a complex whose physical properties, behavior, nervousness, flexibility, touch, volume, hand, ... can be controlled.
- thermo-adhesive layer These properties of the complex result from the nature of the drapery, the nature of the textile support, and also, the nature of the composition and the method of application of the thermo-adhesive layer.
- the fusible interfacing After being made, the fusible interfacing must be able to withstand storage at room temperature. It is then necessary that the different layers of this product, usually stored in rolls, does not adhere to each other. Iron-on interfacing should not have a tacky effect and adhesive properties to room temperature (“tack").
- the fusible interfacing is later laminated on the draperies so as to obtain the complex sought.
- this lamination is carried out at using a press operating at temperatures between 100 ° C and 180 ° C, under pressures of a few decibars at a few bars, for a while relatively short, on the order of 10 to 30 seconds.
- thermo-adhesive polymers of the stabilizer must at least partially regain their adhesion properties.
- thermo-adhesive polymers prevent these thermo-adhesive polymers from piercing the drapery or do produce returns, i.e. pierce the textile support of the interlining.
- Document FR-A-2 177 038 thus proposed to interlining by successively depositing two adhesive layers on a textile support.
- the first one layer is applied by coating with a dispersion viscous (paste) containing high viscosity polymers and / or high melting point directly on the support textile by means of a screen printing frame.
- paste dispersion viscous
- the second layer is applied by dusting a powder of fusible polymers of viscosity and / or melting points lower than those of the first layer.
- thermo-adhesive material dispersed as a fine powder over the coated textile support is deposited by gravity on the whole of the support, but adheres more firmly to the dough point.
- thermo-adhesive layer having a higher melting point than those of the thermo-adhesive layer thus form a screen; the adhesive does not flow theoretically not through the textile support when the interlining is then laminated to a drapery.
- the points of the underlay being spherical or ellipsoidal shape
- the material particles thermo-adhesive stick on the whole surface of the point of dough, especially at the point of contact between the dough point and the textile support; with the consequence that the thermo-adhesive material present at the point of contact through the textile support without the underlay being able to screen when laminating, crossings then appearing.
- the underlay penetrates more or less in the textile support during coating, due to its irregular surface.
- the adhesive surface of the underlay is thus variable, and therefore, the amount of particles also, with harmful consequences on the adhesion forces between the interlining and the drapery, and particularly on the inhomogeneity of these forces of membership.
- top layer of adhesive must adhere to the bottom layer. This is why, according to this process, most often a sintering is carried out which allows the top layer to adhere to the bottom layer.
- the state of the art can also be represented by document FR-A-2 576 191 which describes a interlining comprising a first hot-melt layer applied to the front side of a support and a second layer with a higher melting temperature than the first and applied to the back side of said support.
- a first object of the present invention is to propose a process for manufacturing a stabilizer which fuses the limitations or disadvantages of those known to the state of technical.
- an object of this invention is to provide such a method by which the thermo-adhesive material does not flow through the support textile when laminating the interlining on the drapery.
- the textile thus coated is subjected to radiation electromagnetic, and / or electronic bombardment, and / or heat treatment.
- the invention also relates to a fusible interlining characterized in that it is obtained by implementing a process in accordance with present invention.
- FIG. 1 is a schematic view of a device illustrating the manufacturing process of a stabilizer fusible according to the invention.
- the fusible interlining 1 includes a textile support 2 coated on each of its faces 3, 4 of a layer 5, 7 of hot-melt polymers.
- the textile support 2 is in itself known. It is of the same nature as those conventionally used in the area of interlining.
- It can be a woven or knitted fabric or of a nonwoven. Most often these textiles are processed and then subjected to finishing operations before to be used as a coating support.
- the textile support 2 has a first layer 5 hot-melt applied to the front side 3 of the support textile 2 and a second layer 7 applied to the face back 4 of the textile backing 2.
- the first layer 5 is hot melt while the second layer 7 has a melting temperature higher than the first 5.
- hot melt means a layer that allows the hot lamination, which is solid at temperature ambient and has no adhesive power, but which is plastic at high temperature therefore partially pasty, flowing but adhesive. So the first layer 5 has thermoplastic creep superior to creep second layer thermoplastic 7.
- the fusible interlining 1 is like the second layer 7 constitutes a barrier or a screen vis-à-vis the first layer 5, i.e. prevents the phenomenon of return as defined above.
- the interlining manufacturing process fusible 1 is such that it is deposited simultaneously on each side 3, 4 of the textile support 2 a layer 5, 7 of hot melt polymers.
- the first layer 5 hot-melt is placed directly on the front side 3 of the textile support 2 while the second layer 7 is deposited by transfer on the back side 4 of the support textile 2.
- the deposits of the first hot-melt layer 5 and of the second layer 7 are made by means of the frames serigraphic 9 and 10 respectively.
- These rotating frames 9 and 10 in themselves known, cooperate respectively with a doctor blade 9a, 10a on the one hand and on the other hand, both with the transfer cylinder 11.
- the transfer cylinder 11 serves as a counter cylinder for the first screen printing frame 9, while the latter serves as a counter-cylinder for the transfer cylinder 11.
- the first screen frame 9, the second screen frame 10 and the transfer cylinder 11 are superimposed, their axes of rotation being in a same plane and perpendicular to the direction of travel of the textile support 2.
- the screen printing frames 9, 10 allow the setting implementing wet coating processes in which very fine polymer powders, in dispersion aqueous, are applied respectively to the support textile 2 and the transfer cylinder 11 by a doctor blade 9a, 10a hollow installed inside the rotary cylinder which has a thin perforated wall.
- the doctor blades 9a, 10a produce the passage of the dough respectively constituting the layers 5 and 7 through the perforations of the frames screen prints 9 and 10.
- first 9 and second 10 serigraphic frames have the same diameter and have the same reticular network of perforations.
- the composition of the first layer 5 hot-melt, deposited on the front side 3 of the support textile 2 is based on at least one polymer or at least a thermoplastic copolymer, for example, a polyethylene, a copolyethylene, a polyamide, a polyester, a copolyester in the form of a dispersion / solution of these compounds. It can also be a mixture of these compounds.
- composition of the second layer 7, deposited on the reverse side 4 of the textile support 2 is variable according to applications. It can for example include a non-stick which can be a silicone product.
- the second layer 7 comprises polymers crosslinkable or not, and the melting point of which is superior to that of polymers in the hot-melt layer 5.
- materials are used finely ground with a melting point above that of the material used for the first layer 5, such than polyethylenes.
- reactive materials chosen so that their are also superior to those of the material used for the first layer 5. So the mixtures aminoplasts, acrylic resins, aminoplasts and polyurethanes, epoxy and acrylic-urethanes particularly suitable.
- This paste is then deposited on the cylinder of transfer 11 by the second screen printing frame 10 and by means 11 'then undergoes transformations aimed at evaporate the solvent in whole or in part, and / or to react the polymers thereof and / or to melt the finely ground polymer particles.
- the next step is to transfer the network from points 8 of the second layer 7 on the reverse side 4 of the textile support 2.
- the support textile 2 is pressed between the transfer cylinder 11 and the first screen printing frame 9.
- the first screen printing frame 9 and the transfer cylinder 11 are tangent at a point 13, the textile support 2 scrolling between the first frame screen printing 9 and the transfer cylinder 11 being also tangent to each of these at point 13.
- the perforations of the first screen printing frame 9 correspond with the points 8 of the second layer 7 at less at the point of tangency or contact 13 of the support textile 2 with the first screen printing frame 9 and the transfer cylinder 11.
- the points 8 of the second layer 7 as well transferred have a flat surface and a small thickness and are arranged on the surface of the textile support 2.
- the deposition of the second layer 7 on the cylinder of transfer 11 by the second screen printing frame 10 is done therefore prior to the deposition of the first layer 5 directly on the front side 3 of the textile support 2 by the first screen frame 9.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Details Of Garments (AREA)
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatment Of Fiber Materials (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Decoration By Transfer Pictures (AREA)
- Printing Methods (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9603693A FR2746264B1 (fr) | 1996-03-25 | 1996-03-25 | Procede de fabrication d'un entoilage thermocollant et entoilage thermocollant ainsi obtenu |
FR9603693 | 1996-03-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0797932A1 EP0797932A1 (fr) | 1997-10-01 |
EP0797932B1 true EP0797932B1 (fr) | 2000-05-10 |
Family
ID=9490513
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97400402A Expired - Lifetime EP0797932B1 (fr) | 1996-03-25 | 1997-02-24 | Procédé de fabrication d'un entoilage thermocollant |
Country Status (23)
Country | Link |
---|---|
US (1) | US5827579A (ru) |
EP (1) | EP0797932B1 (ru) |
JP (1) | JPH101809A (ru) |
CN (1) | CN1189111C (ru) |
AR (1) | AR006383A1 (ru) |
AT (1) | ATE192628T1 (ru) |
AU (1) | AU710521B2 (ru) |
BR (1) | BR9701445A (ru) |
CA (1) | CA2198995A1 (ru) |
CZ (1) | CZ292040B6 (ru) |
DE (1) | DE69701915T2 (ru) |
ES (1) | ES2146962T3 (ru) |
FR (1) | FR2746264B1 (ru) |
HK (1) | HK1002445A1 (ru) |
HU (1) | HUP9700638A3 (ru) |
MY (1) | MY129780A (ru) |
NO (1) | NO309009B1 (ru) |
PL (1) | PL184624B1 (ru) |
RU (1) | RU2172758C2 (ru) |
SK (1) | SK284226B6 (ru) |
TR (1) | TR199700217A1 (ru) |
UA (1) | UA45978C2 (ru) |
ZA (1) | ZA972407B (ru) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1057541A1 (de) * | 1999-06-04 | 2000-12-06 | Solipat Ag | Vorrichtung und Verfahren zum partiellen Auftragen einer Oberflächenbeschichtung und Warenbahn mit einer partiellen Oberflächenbeschichtung |
US6875710B2 (en) * | 2001-11-05 | 2005-04-05 | 3M Innovative Properties Company | Composite webs with reinforcing polymeric regions and elastic polymeric regions |
US7037457B2 (en) * | 2001-11-05 | 2006-05-02 | 3M Innovative Properties Company | Systems and methods for composite webs with structured discrete polymeric regions |
US6942894B2 (en) | 2001-11-05 | 2005-09-13 | 3M Innovative Properties Company | Methods for producing composite webs with reinforcing discrete polymeric regions |
FR2870433B1 (fr) | 2004-05-24 | 2007-08-24 | Lainiere De Picardie Bc Soc Pa | Procede de fabrication d'un entoilage thermocollant et entoilage thermocollant obtenu |
US7534481B2 (en) | 2006-08-08 | 2009-05-19 | 3M Innovative Properties Company | Shaped elastic tab laminates |
JP5069896B2 (ja) † | 2006-10-23 | 2012-11-07 | 株式会社小森コーポレーション | 液体供給装置 |
CA2760294C (en) * | 2009-04-27 | 2017-05-16 | Avery Dennison Corporation | Systems, methods and materials for delivery and debonding on demand |
EP2909270A1 (en) | 2012-10-22 | 2015-08-26 | Avery Dennison Corporation | Hybrid material of crosslinked microgel particles dispersed in an adhesive |
CN102972889B (zh) * | 2012-12-17 | 2014-06-04 | 浙江金三发粘合衬有限公司 | 粘合衬布生产线 |
CN105921362B (zh) * | 2016-06-06 | 2018-09-07 | 中山松德新材料装备有限公司 | 一种涂布机正反面涂布对位系统 |
CN110665740B (zh) * | 2019-09-26 | 2021-03-02 | 烽火通信科技股份有限公司 | 用于制造光纤带的涂覆轮、涂覆装置、系统及方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2214236C3 (de) * | 1972-03-23 | 1983-11-10 | Kufner Textilwerke KG, 8000 München | Rasterförmige Beschichtung aus Heißsiegelklebern auf Flächengebilden |
US4198446A (en) * | 1978-02-14 | 1980-04-15 | Ncr Corporation | Apparatus for the manufacture of a dual coated manifold sheet with pressure-rupturable materials |
DE2914617C2 (de) * | 1979-04-11 | 1982-06-03 | Fa. Carl Freudenberg, 6940 Weinheim | Verfahren und Vorrichtung zum gleichzeitigen, kontinuierlichen Aufbringen von Pasten auf einander gegenüberliegende Oberflächenzonen der Vorder- und Rückseite eines flexiblen, porösen Flächengebildes |
FI66448C (fi) * | 1980-10-08 | 1984-10-10 | Waertsilae Oy Ab | Belaeggningsanordning foer bana |
FR2576191B1 (fr) * | 1985-01-23 | 1990-11-23 | Picardie Lainiere | Produit nouveau destine a etre colle a chaud par pression sur des articles plats et procede de fabrication d'un tel produit |
SE465709B (sv) * | 1990-04-03 | 1991-10-21 | Btg Kaelle Inventing Ab | Foerfarande foer tvaasidig bestrykning av en loepande bana medelst tvaa motstaellda oeverfoeringsvalsar |
WO1992000187A1 (en) * | 1990-06-18 | 1992-01-09 | Harder Robert L | Improved fusible bonding tape and method of manufacture thereof |
FR2685171B1 (fr) * | 1991-12-20 | 1994-03-11 | Picardie Lainiere | Entoilage thermocollant et son procede de fabrication. |
EP0675183B1 (de) * | 1994-03-30 | 1997-08-27 | KUFNER TEXTILWERKE GmbH | Verfahren zum rasterförmigen Beschichten von Flächengebilden mit Schmelzklebern |
-
1996
- 1996-03-25 FR FR9603693A patent/FR2746264B1/fr not_active Expired - Fee Related
-
1997
- 1997-02-24 DE DE69701915T patent/DE69701915T2/de not_active Expired - Fee Related
- 1997-02-24 ES ES97400402T patent/ES2146962T3/es not_active Expired - Lifetime
- 1997-02-24 EP EP97400402A patent/EP0797932B1/fr not_active Expired - Lifetime
- 1997-02-24 AT AT97400402T patent/ATE192628T1/de not_active IP Right Cessation
- 1997-02-26 AU AU14949/97A patent/AU710521B2/en not_active Ceased
- 1997-02-27 CZ CZ1997618A patent/CZ292040B6/cs not_active IP Right Cessation
- 1997-02-27 MY MYPI97000753A patent/MY129780A/en unknown
- 1997-03-03 CA CA002198995A patent/CA2198995A1/en not_active Abandoned
- 1997-03-11 UA UA97031092A patent/UA45978C2/uk unknown
- 1997-03-11 US US08/815,167 patent/US5827579A/en not_active Expired - Fee Related
- 1997-03-19 ZA ZA9702407A patent/ZA972407B/xx unknown
- 1997-03-19 SK SK359-97A patent/SK284226B6/sk unknown
- 1997-03-20 CN CNB971033358A patent/CN1189111C/zh not_active Expired - Fee Related
- 1997-03-20 TR TR97/00217A patent/TR199700217A1/xx unknown
- 1997-03-21 RU RU97104182/04A patent/RU2172758C2/ru not_active IP Right Cessation
- 1997-03-21 PL PL97319088A patent/PL184624B1/pl not_active IP Right Cessation
- 1997-03-24 NO NO971380A patent/NO309009B1/no not_active IP Right Cessation
- 1997-03-24 BR BR9701445A patent/BR9701445A/pt not_active Application Discontinuation
- 1997-03-24 HU HU9700638A patent/HUP9700638A3/hu unknown
- 1997-03-24 JP JP9070165A patent/JPH101809A/ja active Pending
- 1997-03-25 AR ARP970101192A patent/AR006383A1/es active IP Right Grant
-
1998
- 1998-02-17 HK HK98101206A patent/HK1002445A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ATE192628T1 (de) | 2000-05-15 |
CZ292040B6 (cs) | 2003-07-16 |
HK1002445A1 (en) | 1998-08-28 |
SK35997A3 (en) | 1997-10-08 |
HUP9700638A2 (hu) | 1998-03-02 |
JPH101809A (ja) | 1998-01-06 |
RU2172758C2 (ru) | 2001-08-27 |
TR199700217A1 (xx) | 1997-10-21 |
FR2746264B1 (fr) | 1998-05-22 |
CZ61897A3 (en) | 1997-10-15 |
CN1189111C (zh) | 2005-02-16 |
AU1494997A (en) | 1997-10-09 |
HU9700638D0 (en) | 1997-05-28 |
BR9701445A (pt) | 1998-11-03 |
ES2146962T3 (es) | 2000-08-16 |
MY129780A (en) | 2007-04-30 |
DE69701915D1 (de) | 2000-06-15 |
NO309009B1 (no) | 2000-11-27 |
NO971380D0 (no) | 1997-03-24 |
AU710521B2 (en) | 1999-09-23 |
AR006383A1 (es) | 1999-08-25 |
CN1164369A (zh) | 1997-11-12 |
PL184624B1 (pl) | 2002-11-29 |
MX9702098A (es) | 1997-09-30 |
UA45978C2 (uk) | 2002-05-15 |
HUP9700638A3 (en) | 1998-03-30 |
NO971380L (no) | 1997-09-26 |
CA2198995A1 (en) | 1997-09-25 |
DE69701915T2 (de) | 2000-12-07 |
EP0797932A1 (fr) | 1997-10-01 |
ZA972407B (en) | 1997-09-25 |
FR2746264A1 (fr) | 1997-09-26 |
SK284226B6 (en) | 2004-11-03 |
US5827579A (en) | 1998-10-27 |
PL319088A1 (en) | 1997-09-29 |
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