EP0779375B1 - Acier pour la fabrication de pièces de mécanique sécables et pièce obtenue - Google Patents
Acier pour la fabrication de pièces de mécanique sécables et pièce obtenue Download PDFInfo
- Publication number
- EP0779375B1 EP0779375B1 EP96402534A EP96402534A EP0779375B1 EP 0779375 B1 EP0779375 B1 EP 0779375B1 EP 96402534 A EP96402534 A EP 96402534A EP 96402534 A EP96402534 A EP 96402534A EP 0779375 B1 EP0779375 B1 EP 0779375B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel
- chemical composition
- mpa
- steel according
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title claims description 52
- 239000010959 steel Substances 0.000 title claims description 52
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 239000000126 substance Substances 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- 229910052804 chromium Inorganic materials 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 claims description 4
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052711 selenium Inorganic materials 0.000 claims description 3
- 239000011669 selenium Substances 0.000 claims description 3
- 229910052714 tellurium Inorganic materials 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 238000003723 Smelting Methods 0.000 claims 1
- 229910001562 pearlite Inorganic materials 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 22
- 229910000859 α-Fe Inorganic materials 0.000 description 19
- 238000005242 forging Methods 0.000 description 16
- 239000011651 chromium Substances 0.000 description 15
- 239000010949 copper Substances 0.000 description 15
- 239000011572 manganese Substances 0.000 description 13
- 238000001816 cooling Methods 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- 230000002349 favourable effect Effects 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 229910052720 vanadium Inorganic materials 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 235000001508 sulfur Nutrition 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- 240000008042 Zea mays Species 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- -1 iron carbides Chemical class 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 241001080024 Telles Species 0.000 description 1
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- VCTOKJRTAUILIH-UHFFFAOYSA-N manganese(2+);sulfide Chemical class [S-2].[Mn+2] VCTOKJRTAUILIH-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
Definitions
- the present invention relates to a steel for manufacturing a part of breakable mechanics, and in particular for the manufacture of a connecting rod for internal combustion engine.
- connection rods internal combustion engine consist of at least two elements separable assembled by fixing means such as screws.
- These parts can be cast iron, sintered and forged metal powder, or forged steel.
- the invention relates to parts, and in particular connecting rods, in forged steel.
- the steel constituting the forged steel connecting rods must be forgeable, easily machinable and have mechanical characteristics allowing to ensure good service life of the connecting rods. Characteristics mechanical properties generally required are a hardness of between 210 HB and 360 HB and a breaking strength of between 650 MPa and 1200 MPa. to obtain sufficient resistance to fatigue, and an elastic limit included between 300 MPa and 800 MPa in order to avoid deformation by exceeding the elastic limit.
- the precise choice of characteristics required for a particular connecting rod intended for a particular engine depends on the design of the rod and the nature of the engine in which it is incorporated.
- the steel which constitutes it is chosen in function of these mechanical characteristics and the manufacturing process which includes, after forging, a controlled cooling intended to obtain a ferrito-pearlitic structure which has mechanical characteristics required and satisfactory machinability.
- the steels used are, in general carbon steels like XC42 or low alloy steels like 45M5, 30MSV6, 38MVS5 (according to French standard).
- the carbon content is chosen mainly according to the level of hardness required, and the elements of alloy are added either to increase the hardenability of the steel so increase the proportion of perlite, which is favorable for machinability, i.e. to harden ferrite and improve the yield strength to strength ratio rupture.
- the separation of the different parts of the connecting rod does not can only be done by machining which requires a complex machining range and expensive.
- Impurities taken among P, Si, Ni, V, Cu, Cr and Mo having individual contents preferably such as: Ni ⁇ 0.2%, Mo ⁇ 0.02%, Cr ⁇ 0.1%, Cu ⁇ 0.15% V ⁇ 0.035% 0.15% ⁇ If ⁇ 0.35%, and P ⁇ 0.03%.
- this steel which is of the XC70 type (according to the French standard), has the disadvantage of having an irregular behavior during the fragile rupture operation, in particular because, it is practically impossible to control industrially the proportion of proeutectoid phase, this can vary from 0% to 15% depending on the exact chemical analysis of the steel and the means of manufacture used, which makes it difficult to use industrially, moreover, it only makes it possible to obtain the characteristics specific to the XC70 which limits its use to parts for which these characteristics are suitable.
- the object of the present invention is to remedy these drawbacks by offering a steel which makes it possible to obtain the mechanical characteristics required for a wide range of applications, particularly in the field connecting rods, and good machinability, while allowing the operation to be carried out brittle failure under satisfactory industrial conditions.
- the invention relates to a steel for the manufacture of a breakable mechanical part whose chemical composition comprises, by weight: 0.25% ⁇ C ⁇ 0.75%, 0.2% ⁇ If ⁇ 1.5%, 0.1% ⁇ Mn ⁇ 2%, 0% ⁇ Ni ⁇ 1%, 0% ⁇ Cr ⁇ 1%, 0% ⁇ Mo ⁇ 1%, 0% ⁇ Cu ⁇ 1%, 0% ⁇ V ⁇ 0.2%, 0.02% ⁇ S ⁇ 0.35%, 0.04% ⁇ P ⁇ 0.2%, 0% ⁇ Al ⁇ 0.005%, 0.005% ⁇ N ⁇ 0.02%, possibly at minus one element taken from lead, tellurium and selenium in contents less than 0.1%, the remainder being iron and impurities resulting from elaboration, the steel possibly being treated with calcium.
- the chemical composition of the steel satisfies at least one of the following relationships: 0.06% ⁇ P ⁇ 0.12%, 0.8% ⁇ If ⁇ 1.2%, 0.05% ⁇ V ⁇ 0.15%.
- the chemical composition of the steel can be such that: 0.65% ⁇ C ⁇ 0.75%, 0.25% ⁇ Mn ⁇ 1%, Ni ⁇ 0.15%, Cr ⁇ 0.15%, Mo ⁇ 0.05%, Cu ⁇ 0.35%
- the chemical composition of the steel can also be such that: 0.25% ⁇ C ⁇ 0.5%, Ni ⁇ 0.15%, Cr ⁇ 0.15%, Mo ⁇ 0.05%, Cu ⁇ 0.35%, preferably with 0.25% ⁇ Mn ⁇ 1.3%.
- the invention also relates to the use of a steel according to the invention for the manufacture of a mechanical part comprising at least two elements obtained by fragile rupture of a blank of said part, as well as said piece.
- This part can be, in particular, a connecting rod for a motor internal combustion consisting for example of a steel whose hardness is between 210 HB and 360 HB, the breaking strength is between 650 MPa and 1200 MPa, with a majority of relatively large grains, of which the ASTM size index of the austenitic grains is less than 5, having, preferably, a structure comprising at least 70% perlite.
- a steel close to the eutectoid comprising from 0.65% to 0.75% of carbon, less than 1% silicon, 0.25% to 1% manganese, less than 0.15% nickel, less than 0.15% chromium, less than 0.05% molybdenum, less than 0.35% copper and less than 0.005% aluminum.
- This steel can be carbon steel, at which case it contains less than 0.5% manganese. But it can be also a steel weakly alloyed with manganese, silicon, or possibly with vanadium. It can then contain between 1% and 2% of manganese, and / or between 0.5% and 1.5% of silicon, and / or between 0.5% and 0.2% of vanadium.
- the blanks were then machined and then separated in half elements by fragile rupture. This separation by fragile rupture was made without difficulty whatever the ferrite content.
- the blanks were then machined and then separated in half elements by fragile rupture. This separation by fragile rupture was made without difficulty whatever the ferrite content.
- the blanks were then machined and then separated in half elements by fragile rupture. This separation by fragile rupture was made without difficulty whatever the ferrite content.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9514833A FR2742448B1 (fr) | 1995-12-14 | 1995-12-14 | Acier pour la fabrication de pieces de mecanique secables et piece obtenue |
FR9514833 | 1995-12-14 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0779375A1 EP0779375A1 (fr) | 1997-06-18 |
EP0779375B1 true EP0779375B1 (fr) | 2000-06-07 |
Family
ID=9485504
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96402534A Expired - Lifetime EP0779375B1 (fr) | 1995-12-14 | 1996-11-26 | Acier pour la fabrication de pièces de mécanique sécables et pièce obtenue |
Country Status (17)
Country | Link |
---|---|
US (1) | US5769970A (ko) |
EP (1) | EP0779375B1 (ko) |
JP (1) | JPH09176796A (ko) |
KR (1) | KR970043238A (ko) |
CN (1) | CN1158908A (ko) |
AR (1) | AR004375A1 (ko) |
AT (1) | ATE193733T1 (ko) |
BR (1) | BR9606002A (ko) |
CA (1) | CA2192509A1 (ko) |
DE (1) | DE69608773T2 (ko) |
DK (1) | DK0779375T3 (ko) |
ES (1) | ES2148705T3 (ko) |
FR (1) | FR2742448B1 (ko) |
GR (1) | GR3034003T3 (ko) |
NO (1) | NO965318L (ko) |
PL (1) | PL192823B1 (ko) |
PT (1) | PT779375E (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008028447A1 (de) | 2006-09-01 | 2008-03-13 | Georgsmarienhütte Gmbh | Stahl und verarbeitungsverfahren für die herstellung von höherfesten bruchtrennbaren maschinenbauteilen |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0856590B2 (en) * | 1997-02-04 | 2005-12-28 | Daido Tokushuko Kabushiki Kaisha | High strength non-thermal refining steel for hot forging |
JP3445478B2 (ja) * | 1997-11-18 | 2003-09-08 | いすゞ自動車株式会社 | 機械構造用鋼及びそれを用いた破断分割機械部品 |
FR2774098B1 (fr) * | 1998-01-28 | 2001-08-03 | Ascometal Sa | Acier et procede pour la fabrication de pieces de mecanique secables |
GB2335200A (en) * | 1998-03-10 | 1999-09-15 | British Steel Plc | Steel composition |
JP3671688B2 (ja) * | 1998-08-28 | 2005-07-13 | 株式会社神戸製鋼所 | 破断分断性に優れた破断分割型コンロッド用熱間鍛造用非調質鋼 |
FR2800670B1 (fr) * | 1999-11-05 | 2003-04-18 | Fag Oem & Handel Ag | Bandage de roues ou roue monobloc pour des jeux de roues de vehicules ferroviaires |
US6395109B1 (en) * | 2000-02-15 | 2002-05-28 | Cargill, Incorporated | Bar product, cylinder rods, hydraulic cylinders, and method for manufacturing |
JP3893889B2 (ja) * | 2001-03-21 | 2007-03-14 | 大同特殊鋼株式会社 | 破断による分離が容易な熱間鍛造用非調質鋼 |
US7819794B2 (en) * | 2002-10-21 | 2010-10-26 | Becker Paul F | Method and apparatus for the treatment of physical and mental disorders with low frequency, low flux density magnetic fields |
US6899667B2 (en) * | 2002-10-21 | 2005-05-31 | Paul F. Becker | Method and apparatus for the treatment of physical and mental disorders with low frequency, low flux density magnetic fields |
JP4346404B2 (ja) * | 2002-11-20 | 2009-10-21 | 本田技研工業株式会社 | 低温での破断分離用非調質鋼及びこの非調質鋼からなる勘合部材 |
JP2005308189A (ja) * | 2004-04-26 | 2005-11-04 | Honda Motor Co Ltd | コネクティングロッド及びその製造方法 |
JP4763551B2 (ja) * | 2006-08-24 | 2011-08-31 | 住友金属工業株式会社 | 破断分離性と加工性に優れた機械構造用鋼およびその製造方法 |
US8382912B2 (en) * | 2007-11-28 | 2013-02-26 | Kao Corporation | Biofilm-removing agent |
JP4264460B1 (ja) * | 2007-12-03 | 2009-05-20 | 株式会社神戸製鋼所 | 破断分割性および被削性に優れた破断分割型コネクティングロッド用鋼 |
CN102061995A (zh) * | 2010-11-26 | 2011-05-18 | 杭州汽轮铸锻有限公司 | 一种燃气轮机进气缸及制作工艺 |
FR3064282B1 (fr) * | 2017-03-23 | 2021-12-31 | Asco Ind | Acier, procede pour la fabrication de pieces mecaniques en cet acier, et pieces ainsi fabriquees |
CN109234626B (zh) * | 2018-07-18 | 2020-11-24 | 石家庄钢铁有限责任公司 | 一种易切削重载汽车轮毂轴承用钢及制造方法 |
CN114645208B (zh) * | 2022-03-23 | 2023-04-25 | 青海西钢特殊钢科技开发有限公司 | 一种采用碲处理的非调质胀断连杆用钢及其生产方法 |
CN114959501B (zh) * | 2022-06-29 | 2023-04-07 | 马鞍山钢铁股份有限公司 | 一种Te微合金化高碳胀断连杆用钢及制造方法和应用 |
CN115029640B (zh) * | 2022-06-29 | 2023-04-07 | 马鞍山钢铁股份有限公司 | 一种Te微合金化中碳胀断连杆用钢及制造方法和应用 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2182758A (en) * | 1938-05-14 | 1939-12-05 | Inland Steel Co | Steel |
US2182759A (en) * | 1938-08-15 | 1939-12-05 | Inland Steel Co | Steel |
US2402862A (en) * | 1943-03-25 | 1946-06-25 | Nat Tube Co | Well casing |
US4168159A (en) * | 1978-02-28 | 1979-09-18 | Latrobe Steel Company | High speed steels with phosphorus for improved cutting performance |
US4786466A (en) * | 1987-02-19 | 1988-11-22 | Frema, Inc. | Low-sulfur, lead-free free machining steel alloy |
US5055253A (en) * | 1990-07-17 | 1991-10-08 | Nelson & Associates Research, Inc. | Metallic composition |
US5135587A (en) * | 1991-04-01 | 1992-08-04 | Ford Motor Company | Machinable, strong, but crackable low ductility steel forging |
-
1995
- 1995-12-14 FR FR9514833A patent/FR2742448B1/fr not_active Expired - Fee Related
-
1996
- 1996-11-26 ES ES96402534T patent/ES2148705T3/es not_active Expired - Lifetime
- 1996-11-26 DE DE69608773T patent/DE69608773T2/de not_active Expired - Lifetime
- 1996-11-26 AT AT96402534T patent/ATE193733T1/de not_active IP Right Cessation
- 1996-11-26 EP EP96402534A patent/EP0779375B1/fr not_active Expired - Lifetime
- 1996-11-26 DK DK96402534T patent/DK0779375T3/da active
- 1996-11-26 PT PT96402534T patent/PT779375E/pt unknown
- 1996-12-10 CA CA002192509A patent/CA2192509A1/fr not_active Abandoned
- 1996-12-10 KR KR1019960063848A patent/KR970043238A/ko not_active Application Discontinuation
- 1996-12-11 AR ARP960105626A patent/AR004375A1/es unknown
- 1996-12-12 PL PL317455A patent/PL192823B1/pl unknown
- 1996-12-12 NO NO965318A patent/NO965318L/no unknown
- 1996-12-13 BR BR9606002A patent/BR9606002A/pt not_active IP Right Cessation
- 1996-12-13 CN CN96119789A patent/CN1158908A/zh active Pending
- 1996-12-13 JP JP8352891A patent/JPH09176796A/ja active Pending
- 1996-12-16 US US08/767,430 patent/US5769970A/en not_active Expired - Lifetime
-
2000
- 2000-07-24 GR GR20000401689T patent/GR3034003T3/el not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008028447A1 (de) | 2006-09-01 | 2008-03-13 | Georgsmarienhütte Gmbh | Stahl und verarbeitungsverfahren für die herstellung von höherfesten bruchtrennbaren maschinenbauteilen |
EP2057298A1 (de) | 2006-09-01 | 2009-05-13 | Georgsmarienhütte GmbH | Stahl und verarbeitungsverfahren für die herstellung von höherfesten bruchtrennbaren maschinenbauteilen |
Also Published As
Publication number | Publication date |
---|---|
PL192823B1 (pl) | 2006-12-29 |
PT779375E (pt) | 2000-10-31 |
CA2192509A1 (fr) | 1997-06-15 |
NO965318D0 (no) | 1996-12-12 |
DK0779375T3 (da) | 2000-10-16 |
JPH09176796A (ja) | 1997-07-08 |
CN1158908A (zh) | 1997-09-10 |
DE69608773T2 (de) | 2001-02-01 |
US5769970A (en) | 1998-06-23 |
FR2742448A1 (fr) | 1997-06-20 |
GR3034003T3 (en) | 2000-11-30 |
KR970043238A (ko) | 1997-07-26 |
EP0779375A1 (fr) | 1997-06-18 |
AR004375A1 (es) | 1998-11-04 |
MX9606392A (es) | 1997-10-31 |
FR2742448B1 (fr) | 1998-01-16 |
ATE193733T1 (de) | 2000-06-15 |
ES2148705T3 (es) | 2000-10-16 |
PL317455A1 (en) | 1997-06-23 |
DE69608773D1 (de) | 2000-07-13 |
BR9606002A (pt) | 1998-09-01 |
NO965318L (no) | 1997-06-16 |
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