EP0753568A2 - Adjuvant sous forme de granulé pour les compositions détergentes - Google Patents

Adjuvant sous forme de granulé pour les compositions détergentes Download PDF

Info

Publication number
EP0753568A2
EP0753568A2 EP96109246A EP96109246A EP0753568A2 EP 0753568 A2 EP0753568 A2 EP 0753568A2 EP 96109246 A EP96109246 A EP 96109246A EP 96109246 A EP96109246 A EP 96109246A EP 0753568 A2 EP0753568 A2 EP 0753568A2
Authority
EP
European Patent Office
Prior art keywords
sodium
detergent
granular detergent
detergent builder
granular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96109246A
Other languages
German (de)
English (en)
Other versions
EP0753568A3 (fr
EP0753568B1 (fr
Inventor
Günther Dr. Schimmel
Alexander Dr. Tapper
Volker Thewes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Hoechst AG
Clariant GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Clariant GmbH filed Critical Hoechst AG
Publication of EP0753568A2 publication Critical patent/EP0753568A2/fr
Publication of EP0753568A3 publication Critical patent/EP0753568A3/fr
Application granted granted Critical
Publication of EP0753568B1 publication Critical patent/EP0753568B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/1253Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates

Definitions

  • the present invention relates to a granular detergent builder in the form of a cogranulate from a mixture of sodium hydrogen carbonate and crystalline phyllosilicates of the general formula NaMSi x O 2x + 1 * yH 2 O, where M means sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20, a process for its preparation and its use.
  • alkali metal tripolyphosphates such as sodium tripolyphosphate
  • new builder systems which generally consist of a synthetic, crystalline aluminosilicate (for example zeolite A), an alkali source (for example soda) and at least one Cobuilder exist.
  • Nitrilotriacetic acid or its salts, phosphonates and also polycarboxylates, in particular those based on acrylic and / or maleic acid, are usually used as cobuilders individually or in combination with one another or in combination with other substances.
  • EP-0 425 428 B1 discloses a process for the production of crystalline sodium silicates with a layered structure, in which amorphous sodium silicate with a water content of 15 to 23% by weight in a rotary kiln at temperatures of 500 to 850 ° C. calcined, the calcine after crushing and grinding is fed to a roller compactor and then the school pen obtained after pre-crushing and sieving are processed into granules with a bulk density of 700 to 1000 g / l.
  • DE-A-43 30 868 describes a process for the production of compacted, granular sodium silicates, in which the sodium silicate with an average grain diameter of ⁇ 500 ⁇ m is first mixed with a material which increases its hardness before it is compacted, crushed and sieved transferred to a press granulate with grain sizes of 0.1 to 5 mm.
  • EP-A-0 164 514 describes the use of crystalline sodium silicates for the softening of water which contains calcium and / or magnesium ions.
  • EP-A-0 563 631 discloses water-disintegrating cogranulates with a high bulk density made of aluminosilicates and crystalline sodium silicates with a layer structure, a process for their preparation and their use.
  • a disadvantage of all detergent formulations containing aluminosilicate is the water-insolubility of the aluminosilicates, which among other things causes an increased sewage sludge load. It is also disadvantageous that larger agglomerates can form during the processing of aluminosilicates or in the course of their use, so that the use of cobuilders is necessary in order to break up the aluminosilicates into a suspension of fine primary particles, since agglomerates of aluminosilicates - especially zeolite A - have no tendency to disintegrate into the primary particles.
  • Detergent formulations such as those described in PCT / WO 92/18594, have a pH value of 10 to 11 in 1% strength solution in distilled water at 20 ° C.
  • Detergent builder formulations which include sodium carbonate (soda) as an alkali source contain, inherently have a pH of> 10.
  • Alkali-reduced detergents on the other hand, require other builders or builder combinations in which it would be desirable for the builder formulations to have an intrinsic pH in the range of ⁇ 10. A low pH value contributes significantly to protecting delicate fabrics during the washing process.
  • the granular detergent builder preferably has a bulk density of ⁇ 900 g / l.
  • the degree of reaction between crystalline layered silicate and sodium hydrogen carbonate is preferably between 5 and 60%.
  • the sodium silicates in the granular detergent builder according to the invention preferably have an SiO 2 / Na 2 O ratio of (1.9 to 2.1): 1.
  • the present object is also achieved by a process for producing a granular detergent builder in the form of a cogranulate from a mixture of sodium hydrogen carbonate and crystalline phyllosilicates of the general formula NaMSi x O 2x + 1 * yH 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20, which is characterized in that sodium hydrogen carbonate and sodium silicate are mixed together in powder form; that the mixture is fed to a zone in which it is compacted under pressure between two rollers rotating in opposite directions to form a solid (Schulpen); that you crush the solid; and that the desired grain sizes are finally separated from the oversize and undersize.
  • the pressure of the rolls preferably corresponds to a line pressure Kratt> 20 kN / cm at 200 mm roll diameter.
  • the Schulpen preferably have a temperature of ⁇ 70 ° C.
  • the crystalline sodium disilicate with a layer structure contained in the cogranulates according to the invention ( ⁇ -sodium disilicate is commercially available from Hoechst AG, Federal Republic of Germany, under the name SKS-6®) is slowly water-soluble, as a result of which sludge relief in the sewage treatment plants is achieved.
  • the component soda can optionally be completely omitted in the detergent or cleaning agent formulation, since the crystalline sodium disilicate is a source of alkali.
  • the invention also relates to the use of the granular detergent builder according to the invention in detergents and cleaning agents.
  • the above-mentioned detergents and cleaning agents preferably contain 3 to 60% by weight of the granular detergent builder.
  • the detergents and cleaning agents can additionally contain other detergent builders and other detergent auxiliaries.
  • the other detergent builders are preferably sodium tripolyphosphate, zeolite A, zeolite P, amorphous silicates, water glass and / or alkali metal carbonates.
  • the other detergent ingredients are preferably surfactants, bleaches, bleach activators, bleach stabilizers, enzymes, polycarboxylates and / or carboxyl-containing cobuilders.
  • the analysis data of the cogranulates according to the invention were determined using the following test methods.
  • the particle size distribution is determined on the basis of a 50 gram sample by sieve analysis (apparatus used: RETSCH VIBRATONIC) and the mean particle diameter is determined from this by means of a graphic evaluation.
  • the granules to be examined are sieved in the sample preparation via a sieve (710 ⁇ m).
  • the undersize is used to determine the kinetics of decay in water (18 ° dH) with a MICROTRAC Series 9200 (Leeds & Nothrup GmbH).
  • the pH value is measured in a 1% solution in distilled water at 20 ° C with a digital pH meter CG 840 from SCHOTT.
  • the degree of preservation provides information about what percentage of the starting components are present side by side in an unreacted form.
  • the temperature increase is determined which is achieved by the amount of heat released and the corresponding heat of solution when 25 grams of the cogranulate sample to be measured are added to 100 grams of distilled water.
  • the degree of maintenance is related to the temperature increase of the zero value, which is achieved if instead of the cogranulate, only a corresponding physical mixture of the starting components is used in the determination.
  • the filtrate must be made strongly acidic (pH ⁇ 2.5) due to possible reprecipitation with HCl, so that the excess carbonate in the form of CO 2 can be removed from the filtrate by stirring.
  • the calcium remaining in the filtrate is then determined complexometrically.
  • the calcium binding capacity generally referred to as the KBV value, was calculated by forming the difference with the original calcium content.
  • the result is a solution with 3 ° dH.
  • the solution is kept in a water bath thermostat (ERWEKA) with stirring at 20 ° C. and 1 gram of the cogranulate sample to be measured is added.
  • ERWEKA water bath thermostat
  • the sample is then filtered through a folded filter (Ederol 12). If the sample to be examined contains carbonate, the filtrate must be made strongly acidic (pH ⁇ 2.5) due to possible precipitation with HCl, so that the excess carbonate in the form of CO 2 can be removed from the filtrate by stirring.
  • the magnesium remaining in the filtrate is then determined complexometrically. The magnesium binding capacity was calculated by forming the difference with the original magnesium content.
  • SKS-6® sodium disilicate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
EP96109246A 1995-07-11 1996-06-10 Adjuvant sous forme de granulé pour les compositions détergentes Expired - Lifetime EP0753568B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19525197A DE19525197A1 (de) 1995-07-11 1995-07-11 Granularer Waschmittelbuilder
DE19525197 1995-07-11

Publications (3)

Publication Number Publication Date
EP0753568A2 true EP0753568A2 (fr) 1997-01-15
EP0753568A3 EP0753568A3 (fr) 1998-01-28
EP0753568B1 EP0753568B1 (fr) 2002-09-25

Family

ID=7766525

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96109246A Expired - Lifetime EP0753568B1 (fr) 1995-07-11 1996-06-10 Adjuvant sous forme de granulé pour les compositions détergentes

Country Status (8)

Country Link
US (1) US5874397A (fr)
EP (1) EP0753568B1 (fr)
JP (1) JPH0931491A (fr)
KR (1) KR970006469A (fr)
CN (1) CN1146484A (fr)
CA (1) CA2180926A1 (fr)
DE (2) DE19525197A1 (fr)
TW (1) TW352393B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999050382A1 (fr) * 1998-03-30 1999-10-07 The Procter & Gamble Company Compositions detergentes

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW370561B (en) * 1996-03-15 1999-09-21 Kao Corp High-density granular detergent composition for clothes washing
US6723693B1 (en) * 1999-07-08 2004-04-20 The Procter & Gamble Company Method for dispensing a detergent comprising an amionic/silicate agglomerate
US7210383B2 (en) * 2000-08-14 2007-05-01 Sd3, Llc Detection system for power equipment
US6723335B1 (en) * 2000-04-07 2004-04-20 Jeffrey William Moehlenbruck Methods and compositions for treating intervertebral disc degeneration
KR100420104B1 (ko) * 2002-01-23 2004-03-02 주식회사 크렌비 소듐세스퀴카보네이트와 층상실리케이트로 구성된 분말을제조하는 방법
KR100420105B1 (ko) * 2002-05-14 2004-03-02 주식회사 크렌비 세탁용 세제 조성물
WO2005007791A1 (fr) * 2003-07-22 2005-01-27 Clenvi Co., Ltd. Composition de detergent a lessive
US20060281659A1 (en) * 2003-07-22 2006-12-14 Clenvi Co., Ltd. Process for producing a powder consisting of sodiumsesquicarbonate and layered silicate
US8021493B2 (en) * 2007-05-04 2011-09-20 Ecolab Usa Inc. Method of reducing corrosion using a warewashing composition

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416366A2 (fr) * 1989-09-08 1991-03-13 Hoechst Aktiengesellschaft Agent pour le lavage de la vaisselle comprenant des silicates en couche
WO1992018594A1 (fr) * 1991-04-23 1992-10-29 The Procter & Gamble Company Compositions de detergents particulaires
EP0578986A1 (fr) * 1992-07-17 1994-01-19 Hoechst Aktiengesellschaft Procédé de préparation de silicates de sodium de structure en couches et leur utilisation
EP0614965A2 (fr) * 1993-03-11 1994-09-14 Hoechst Aktiengesellschaft Détergent pour lavage doux
DE4329392A1 (de) * 1993-09-01 1995-03-02 Henkel Kgaa Gerüststoffkomponente für Wasch- oder Reinigungsmittel
DE4329394A1 (de) * 1993-09-01 1995-03-02 Henkel Kgaa Gerüststoffkomponente für Wasch- oder Reinigungsmittel

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3413571A1 (de) * 1984-04-11 1985-10-24 Hoechst Ag, 6230 Frankfurt Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung
US4891148A (en) * 1985-08-05 1990-01-02 Colgate-Palmolive Company Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent comopsition and method of use
GB8710291D0 (en) * 1987-04-30 1987-06-03 Unilever Plc Preparation of granular detergent composition
US4996001A (en) * 1989-01-23 1991-02-26 Capital City Products Company Puffed borax as an agglomerating aid
US5236682A (en) * 1989-10-25 1993-08-17 Hoechst Aktiengesellschaft Process for producing crystalline sodium silicates having a layered structure
CA2024966C (fr) * 1989-10-25 1995-07-18 Gunther Schimmel Procede de production de silicates de sodium
US5229095A (en) * 1989-10-25 1993-07-20 Hoechst Aktiengesellschaft Process for producing amorphous sodium silicate
US5540855A (en) * 1991-04-23 1996-07-30 The Procter & Gamble Company Particulate detergent compositions
US5256886A (en) * 1991-04-30 1993-10-26 E. I. Du Pont De Nemours And Company Apparatus for optically detecting contamination in particles of low optical-loss material
EP0550077A1 (fr) * 1992-01-03 1993-07-07 The Procter & Gamble Company Composition de blanchiment granulaire pour le lavage du linge
US5300250A (en) * 1992-01-14 1994-04-05 The Procter & Gamble Company Granular laundry compositions having improved solubility
DE4210253A1 (de) * 1992-03-28 1993-09-30 Hoechst Ag Aus Alumosilicaten und Natriumsilicaten bestehende Cogranulate, ein Verfahren zu ihrer Herstellung und ihre Verwendung
DE4306665A1 (de) * 1993-03-03 1994-09-08 Sued Chemie Ag Waschmittelzusatz für gewebeweichmachende Waschmittel
DE4330868A1 (de) * 1993-09-11 1995-03-16 Hoechst Ag Verfahren zur Herstellung körniger Natriumsilikate
US5658867A (en) * 1995-05-31 1997-08-19 The Procter & Gamble Company Cleaning compositions containing a crystalline builder material in selected particle size ranges for improved performance

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416366A2 (fr) * 1989-09-08 1991-03-13 Hoechst Aktiengesellschaft Agent pour le lavage de la vaisselle comprenant des silicates en couche
WO1992018594A1 (fr) * 1991-04-23 1992-10-29 The Procter & Gamble Company Compositions de detergents particulaires
EP0578986A1 (fr) * 1992-07-17 1994-01-19 Hoechst Aktiengesellschaft Procédé de préparation de silicates de sodium de structure en couches et leur utilisation
EP0614965A2 (fr) * 1993-03-11 1994-09-14 Hoechst Aktiengesellschaft Détergent pour lavage doux
DE4329392A1 (de) * 1993-09-01 1995-03-02 Henkel Kgaa Gerüststoffkomponente für Wasch- oder Reinigungsmittel
DE4329394A1 (de) * 1993-09-01 1995-03-02 Henkel Kgaa Gerüststoffkomponente für Wasch- oder Reinigungsmittel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999050382A1 (fr) * 1998-03-30 1999-10-07 The Procter & Gamble Company Compositions detergentes

Also Published As

Publication number Publication date
TW352393B (en) 1999-02-11
EP0753568A3 (fr) 1998-01-28
CN1146484A (zh) 1997-04-02
EP0753568B1 (fr) 2002-09-25
DE59609711D1 (de) 2002-10-31
JPH0931491A (ja) 1997-02-04
DE19525197A1 (de) 1997-01-16
KR970006469A (ko) 1997-02-21
CA2180926A1 (fr) 1997-01-12
US5874397A (en) 1999-02-23

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