EP0716684B1 - Adjuvant de lavage pour produits de lavage ou de nettoyage - Google Patents
Adjuvant de lavage pour produits de lavage ou de nettoyage Download PDFInfo
- Publication number
- EP0716684B1 EP0716684B1 EP94926862A EP94926862A EP0716684B1 EP 0716684 B1 EP0716684 B1 EP 0716684B1 EP 94926862 A EP94926862 A EP 94926862A EP 94926862 A EP94926862 A EP 94926862A EP 0716684 B1 EP0716684 B1 EP 0716684B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- quantities
- sodium
- additives
- roll
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004140 cleaning Methods 0.000 title claims 5
- 238000005406 washing Methods 0.000 title abstract description 11
- 150000004760 silicates Chemical class 0.000 claims abstract description 18
- 239000011734 sodium Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 14
- 239000004615 ingredient Substances 0.000 claims abstract description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
- 239000001257 hydrogen Substances 0.000 claims abstract description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 20
- 239000008187 granular material Substances 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 239000000654 additive Substances 0.000 claims description 14
- 239000003599 detergent Substances 0.000 claims description 12
- 239000002736 nonionic surfactant Substances 0.000 claims description 12
- 150000007524 organic acids Chemical class 0.000 claims description 9
- 235000005985 organic acids Nutrition 0.000 claims description 9
- 239000003945 anionic surfactant Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 150000007519 polyprotic acids Polymers 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 239000001509 sodium citrate Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims 4
- 238000009826 distribution Methods 0.000 claims 2
- 239000011362 coarse particle Substances 0.000 claims 1
- 239000010419 fine particle Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims 1
- 239000012459 cleaning agent Substances 0.000 abstract description 16
- 239000004115 Sodium Silicate Substances 0.000 abstract description 3
- 235000019351 sodium silicates Nutrition 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000009490 roller compaction Methods 0.000 description 7
- 229910052615 phyllosilicate Inorganic materials 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 238000003825 pressing Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000004753 textile Substances 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- -1 optical brighteners Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000011182 sodium carbonates Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
Definitions
- the invention relates to a builder component with a very high bulk density and to detergents or cleaning agents which contain this component.
- Such crystalline layered silicates are described, for example, in European patent application EP-A-0 164 514.
- Preferred crystalline layered silicates are those in which M is sodium and x is 2 or 3.
- both ⁇ - and ⁇ -sodium disilicate Na 2 Si 2 O 5 .yH 2 O are preferred, wherein ⁇ -sodium disilicate can be obtained, for example, by the method described in international patent application WO-A-91/08171.
- ⁇ -sodium disilicate is commercially available under the name SKS 7 (R)
- ⁇ -sodium disilicate is available under the name SKS 6 (R) (commercial products from Hoechst AG, Federal Republic of Germany).
- SKS 7 (R) commercial products from Hoechst AG, Federal Republic of Germany.
- crystalline layered silicates according to the disclosure of the international patent application WO-A-92/18594 spray-drying detergent-containing slurries suffer losses in their washing action caused by the destruction of their physical structure, they should preferably be used by other process methods in washing or cleaning agents can be incorporated. However, due to their high proportion of fine grains and thus their dusty structure, these powders are also unsuitable for use as an admixing component with other granular components of detergents or cleaning agents. In addition, since crystalline layered silicates such as crystalline disilicates have a lower dissolution rate in water than amorphous silicates, local deposits on the textiles can lead to an increase in the pH value to values above 12, which can damage the textile fibers.
- the crystalline layered silicates are used in the form of a granular builders component which contains at least 10% by weight of crystalline layered silicates and 5 to 90% by weight in water Form of ions of organic acids and / or inorganic or organic salts present, the material used should not, however, exceed an average size of 300 ⁇ m, and optionally contain further binders, surfactants and other common ingredients of detergents or cleaning agents.
- a preferred way of producing this builder component is roller compaction, in which a pressure of 10 to 50 kN / cm roller length and preferably around 25 kN / cm roller length is used.
- Such builders components still have high pH values in 1% aqueous solution; however, since these components have a higher dissolution rate than the powder, the risk of local deposits on textiles and thus damage to textile fibers is reduced.
- this invention is limited to builder components which contain a maximum of 95% by weight of crystalline layered silicates.
- the object of the invention was to further develop methods of roller compacting builders components containing crystalline phyllosilicates in such a way that, on the one hand, the most effective, i.e. concentrated builders components are obtained and on the other hand an improvement in the dissolving behavior of builders components which contain crystalline phyllosilicates above 95% by weight is achieved.
- the builders components should therefore contain as little as possible of additives.
- the invention accordingly relates to a process for the preparation of a builder component which contains crystalline phyllosilicates of the formula NaMSi x O 2x + 1 .yH 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number of 0 to 20, by roller compacting at pressures up to 50 kN / cm roller length, the crystalline layered silicates in amounts of more than 95% by weight to 99.8% by weight and customary solid ingredients of detergents or cleaning agents as additives in Amounts of 0.2 to less than 5 wt .-% are used.
- Disilicates particularly ⁇ -sodium disilicates and ⁇ -sodium disilicate, are used as particularly preferred crystalline sheet silicates.
- Which conventional solid ingredients of washing or cleaning agents can in principle be used can be found, for example, in international patent application WO-A-92/18594.
- the invention particularly includes a method for roller compaction, in which 96 to 99% by weight of crystalline phyllosilicates are compacted in a mixture with additives, which are either organic acids, preferably polybasic organic acids, and / or salts of inorganic and / or organic acids, preferably polybasic acids. It was particularly surprising that even small amounts of these preferred additives are sufficient to bring about a significantly improved dissolving behavior of the builders components compared to a 100% by weight roll-compacted crystalline layered silicate granulate.
- additives which are either organic acids, preferably polybasic organic acids, and / or salts of inorganic and / or organic acids, preferably polybasic acids.
- additives are sulfates, in particular sodium sulfate and carbonates
- the preferred organic additives include citric acid, tartaric acid, succinic acid, glutaric acid, adipic acid and sugar acids and their salts. These additives can be used alone or in a mixture with each other.
- sulfate and / or citrate can be used with preference for their sodium salts or combinations of two or three with polybasic organic acids with preference for citric acid. Due to the small amount of additives that is used in total, in most cases only one selected compound or a maximum of two selected compounds will be compacted in a mixture with the crystalline layered silicates.
- the roller pressing itself can be carried out without or with a pre-compression of the premixed powdery material.
- the pair of rollers can be arranged in any spatial direction, in particular thus vertically or horizontally to one another.
- the mixture to be compacted or the sole powder of crystalline layered silicate is then fed to the roll gap either by gravity filling or by means of a suitable device, for example by means of a stuffing screw.
- the material to be compacted is then pressed through the gap of a pair two rollers running in opposite directions at approximately the same circumferential speed and thereby compacted into a plate-like or band-shaped material to be pressed, which is also referred to as a sliver belt.
- Preferred press pressures are between 7 and 30 kN / cm roll length and in particular press presses between 10 and 25 kN / cm roll length. Press pressures between 12 and 20 kN / cm roll length are particularly advantageous.
- the shoulder strap is then subjected to a comminution process.
- This comminution or grinding can take place, for example, in a mill.
- the comminuted material is then expediently subjected to a screening process, coarse material being separated off and returned to the comminution device, while material which is too fine is added again to the batch of the powdery mixture or the powdered layered silicate and is again fed to the compacting in the nip.
- the sliver belt is preferably made by conventional grinding into granules with a particle size range of 0.05 mm to 2 mm, preferably with a particle size range that consists of at least 70% by weight of granules with a particle diameter between 0.1 and 1.6 mm , is set, while fine-grain fractions with granule diameters below 0.05 mm are returned to the compacting and coarse-grained fractions with granule diameters above 2 mm are returned to the grinding.
- a granular builder component is obtained which has a bulk density between 800 and 1100 g / l.
- the granular builder components obtained are selected in a subsequent step with further ingredients of washing or cleaning agents, preferably with impregnating agents, from the group of ethoxylated nonionic surfactants, mixtures of nonionic and anionic surfactants, pasty aqueous nonionic and / or anionic surfactants, the water possibly being subsequently dried off, and the silicone oils and paraffin oils, in particular with nonionic surfactants.
- the builders components can then additionally with powdery solids, be powdered in particular with powdered crystalline layered silicates.
- the invention relates to a washing or cleaning agent which contains the builders components according to the invention.
- these agents preferably contain the builder components according to the invention in amounts of 10 to 70% by weight and in particular in amounts of 20 to 60% by weight.
- the washing or cleaning agents contain other customary inorganic and / or organic builders, contents of 25 to 50% by weight of the builders components according to the invention are particularly advantageous.
- the washing or cleaning agents can contain all the usual ingredients such as anionic, nonionic, amphoteric, cationic and / or zwitterionic surfactants, other builders such as zeolite and / or phosphates, phyllosilicates such as bentonites, polycarboxylates such as citrates etc., polymeric polycarboxylates such as salts of homo- or copolymers of acrylic acid, bleaching agents and bleach activators, graying inhibitors such as cellulose ether or polyvinylpyrrolidone, optical brighteners, dyes and fragrances, and enzymes and enzyme stabilizers. Foam inhibitors can also be included.
- other builders such as zeolite and / or phosphates, phyllosilicates such as bentonites, polycarboxylates such as citrates etc., polymeric polycarboxylates such as salts of homo- or copolymers of acrylic acid, bleaching agents and bleach activators, graying inhibitors such as cellulose
- the agents can consist of a base granulate or of a multicomponent mixture, whereby multicomponent mixtures can be advantageous.
- enzyme granules and, for example, bleach activator granules, but also foam inhibitor granules or individual constituents such as sodium carbonate, sodium silicate or polycarboxylate are subsequently mixed in.
- the individual components can be made by spray drying, granulation, extrusion or other conventional techniques.
- the agents have a bulk density above 650 g / l, preferably above 700 g / l.
- detergents or cleaning agents with bulk densities above 800 g / l can also be produced without these agents tending to separate.
- These agents are also suitable for concentrates with high surfactant contents.
- a high anionic surfactant content can be achieved by admixing a highly concentrated anionic surfactant compound, for example by spray drying, spray neutralization or by granulation and simultaneous drying in a fluidized bed was obtained, and a high nonionic surfactant content can be achieved by admixing the builder components according to the invention with high nonionic surfactant contents. Washing or cleaning agents with 15 to 40% by weight, in particular with 18 or 20 to 35% by weight, anionic and nonionic surfactants are preferred.
- roller-compacted granules produced according to the invention are mixed into extruded granules which may contain highly concentrated anionic surfactant compounds and are preferably low in nonionic to nonionic in particular.
- Crystalline layered silicates of the type SKS 6 (R) ( ⁇ -sodium disilicate, commercial product from Hoechst AG, Germany) and the inorganic or organic salts of polybasic acids specified below were pressed at a pressure of 17 kN / cm on a roller press of the type WR 50 N / 75 (Alexanderwerk AG, Germany) at 20 ° C to form crusts of approx. 1 mm thickness. After comminution into granules with an average particle size range of 0.1 to 1.6 mm, products with the bulk densities specified below were obtained. The dissolving speeds given in the table were determined for the sieve fraction 0.6 to 0.8 mm according to the following test:
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Detergent Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Claims (12)
- Procédé de production de composant builder, qui contient des silicates feuilletés cristallins de formule NaMSiXO2X+1·yH2O, où M représente le sodium ou l'hydrogène, x un nombre de 1,9 à 4 et y un nombre de 0 à 20, par compactage par cylindres à des pressions de compression pouvant atteindre 50 kN/cm de longueur de cylindre,
caractérisé en ce qu'
on utilise les silicates feuilletés cristallins en des quantités supérieures à 95 % en poids jusqu'à 99,8 % en poids et les autres composants usuels solides des produits de lavage et de nettoyage comme additifs en des quantités de 0,2 à moins de 5 % en poids. - Procédé selon la revendication 1,
caractérisé en ce qu'
on utilise les silicates feuilletés en des quantités de 96 à 99 % en poids et, comme additifs des acides organiques, de préférence des polyacides, et/ou des sels d'acides minéraux et/ou organiques et/ou des polyacides. - Procédé selon la revendication 1 ou 2,
caractérisé en ce qu'
on réalise le compactage par cylindres à des pressions de compression comprises entre 7 et 30 kN/cm de longueur de cylindre, de préférence à des pressions de compression comprises entre 10 et 25 kN/cm de longueur de cylindre et notamment entre 12 et 20 kN/cm de longueur de cylindre. - Procédé selon l'une des revendications 1 à 3,
caractérisé en ce qu'
on utilise comme silicates feuilletés cristallins des disilicates et notamment du B-disilicate de sodium et/ou du δ-disilicate de sodium. - Procédé selon l'une des revendications 1 à 4,
caractérisé en ce qu'
on utilise comme additifs un ou plusieurs acides organiques du groupe de l'acide citrique, l'acide tartrique, les acides succiniques, l'acide glutarique, l'acide adipique et les acides sacchariques, surtout l'acide citrique. - Procédé selon l'une des revendications 1 à 5,
caractérisé en ce qu'
on utilise comme additifs des sels minéraux et/ou organiques de polyacides, de sulfate et/ou de citrate, de préférence de sulfate de sodium et/ou de citrate de sodium. - Procédé selon l'une des revendications 1 à 6,
caractérisé en ce qu'
on transforme la bande comprimée par broyage habituel en granulés avec une répartition de grains de 0,05 mm à 2 mm, de préférence avec une répartition de grains de 0,05 mm à 2 mm, de préférence avec une répartition de grains qui est constituée d'au moins 70 % en poids de granulés compris entre 0,1 et 1,6 mm et on retourne au compactage les fractions de grains fins ayant des diamètres de granulés inférieurs à 0,05 mm et on recycle au broyage les fractions de grains grossier avec des diamètres de granulés supérieurs à 2 mm. - Procédé selon l'une des revendications 1 à 7,
caractérisé en ce qu'
on produit un composant builder granulé avec une densité apparente comprise entre 800 et 1100 g/l. - Procédé selon l'une des revendications 1 à 8,
caractérisé en ce qu'
on charge les composants builders granulés obtenus lors d'une étape consécutive avec d'autres composants de produits de lavage ou de nettoyage, notamment avec des tensioactifs non ioniques. - Procédé selon l'une des revendications 1 à 9,
caractérisé en ce qu'
on ajoute par mélange les granulés obtenus par compactage sur cylindres, chargés de préférence de tensioactifs non ioniques à des granulés extrudés qui contiennent le cas échéant des mélanges de tensioactifs anioniques très concentrés et qui ont peu ou pas de tensioactifs non ioniques. - Produit de lavage ou de nettoyage contenant des composants builders préparés selon le procédé de l'une des revendications 1 à 10.
- Produit de lavage ou de nettoyage selon la revendication 11,
caractérisé en ce qu'
il contient les composants builders en des quantités de 10 à 70 % en poids, de préférence en des quantités de 20 à 60 % en poids et notamment en des quantités de 25 à 50 % en poids ainsi que le cas échéant d'autres substances builders usuelles minérales et/ou organiques.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4329392A DE4329392A1 (de) | 1993-09-01 | 1993-09-01 | Gerüststoffkomponente für Wasch- oder Reinigungsmittel |
DE4329392 | 1993-09-01 | ||
PCT/EP1994/002777 WO1995006707A1 (fr) | 1993-09-01 | 1994-08-22 | Adjuvant de lavage pour produits de lavage ou de nettoyage |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0716684A1 EP0716684A1 (fr) | 1996-06-19 |
EP0716684B1 true EP0716684B1 (fr) | 1997-04-09 |
Family
ID=6496502
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94926862A Expired - Lifetime EP0716684B1 (fr) | 1993-09-01 | 1994-08-22 | Adjuvant de lavage pour produits de lavage ou de nettoyage |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0716684B1 (fr) |
JP (1) | JPH09501978A (fr) |
KR (1) | KR960705018A (fr) |
AT (1) | ATE151453T1 (fr) |
DE (2) | DE4329392A1 (fr) |
ES (1) | ES2100742T3 (fr) |
WO (1) | WO1995006707A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19525197A1 (de) * | 1995-07-11 | 1997-01-16 | Hoechst Ag | Granularer Waschmittelbuilder |
DE19756696A1 (de) | 1997-12-19 | 1999-07-01 | Clariant Gmbh | Schichtsilikathaltige Wasch- und Reinigungsmittelkomponente |
GB2339194A (en) * | 1998-07-08 | 2000-01-19 | Procter & Gamble | Layered crystalline silicate as detergent builder component |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3624336A1 (de) * | 1986-07-18 | 1988-01-28 | Henkel Kgaa | Verfahren zur herstellung von rieselfaehigen alkalischen reinigungsmitteln durch kompaktierende granulation |
DE3633519A1 (de) * | 1986-10-02 | 1988-04-14 | Henkel Kgaa | Verfahren zur herstellung von rieselfaehigen, stabilen schauminhibitor-konzentraten durch kompaktierende granulation |
GB9108639D0 (en) * | 1991-04-23 | 1991-06-12 | Procter & Gamble | Particulate detergent compositions |
-
1993
- 1993-09-01 DE DE4329392A patent/DE4329392A1/de not_active Withdrawn
-
1994
- 1994-08-22 WO PCT/EP1994/002777 patent/WO1995006707A1/fr active IP Right Grant
- 1994-08-22 ES ES94926862T patent/ES2100742T3/es not_active Expired - Lifetime
- 1994-08-22 KR KR1019960701018A patent/KR960705018A/ko not_active Application Discontinuation
- 1994-08-22 EP EP94926862A patent/EP0716684B1/fr not_active Expired - Lifetime
- 1994-08-22 JP JP7507914A patent/JPH09501978A/ja active Pending
- 1994-08-22 AT AT94926862T patent/ATE151453T1/de not_active IP Right Cessation
- 1994-08-22 DE DE59402397T patent/DE59402397D1/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE4329392A1 (de) | 1995-03-02 |
KR960705018A (ko) | 1996-10-09 |
ATE151453T1 (de) | 1997-04-15 |
JPH09501978A (ja) | 1997-02-25 |
WO1995006707A1 (fr) | 1995-03-09 |
DE59402397D1 (de) | 1997-05-15 |
ES2100742T3 (es) | 1997-06-16 |
EP0716684A1 (fr) | 1996-06-19 |
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