EP0715820A2 - Spender für einen flüssigen oder partösen Produkt - Google Patents
Spender für einen flüssigen oder partösen Produkt Download PDFInfo
- Publication number
- EP0715820A2 EP0715820A2 EP95402528A EP95402528A EP0715820A2 EP 0715820 A2 EP0715820 A2 EP 0715820A2 EP 95402528 A EP95402528 A EP 95402528A EP 95402528 A EP95402528 A EP 95402528A EP 0715820 A2 EP0715820 A2 EP 0715820A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- product
- end piece
- piece according
- dispensing
- application surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/26—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
- A45D40/262—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball using a brush or the like
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/02—Casings wherein movement of the lipstick or like solid is a sliding movement
- A45D40/04—Casings wherein movement of the lipstick or like solid is a sliding movement effected by a screw
Definitions
- the present invention relates to a nozzle for applying a product, of liquid to pasty consistency on a support, as well as to a dispenser provided with this application nozzle.
- This dispenser is intended, in particular, for applying a cosmetic product to the skin or the mucous membranes, but it is also usable for dispensing a viscous product in other fields of technology, for example an adhesive.
- the invention relates to the distribution and application of a composition of red or lip balm of creamy consistency or of a skin treatment cream.
- the invention aims, in particular, the conservation of this composition in good conditions, without risk of deterioration thereof by ambient air.
- such a dispenser comprises a reservoir for the product to be applied and a member for applying said product.
- an applicator for liquid products comprising a cylindrical reservoir separated into two compartments by a partition, a front compartment and a rear compartment.
- the first compartment, or front compartment contains the liquid product and a piston.
- the rear compartment includes means for driving the piston, in order to cause the expulsion of the product.
- This applicator further comprises a dispensing orifice which ends in a hollow application brush.
- this type of brush applicator does not allow precise makeup of the lips, due to the flexibility of the bristles. brush. This results in a feeling of discomfort for the user. Furthermore, with a brush-shaped applicator, it is not possible to apply compositions having a high viscosity. In addition, when a colored make-up cream is applied to the lips using a brush, the intensity of the pigments contained in the composition is blurred and a matte and low-covering make-up is thus obtained.
- a liquid lipstick applicator provided with a flexible tip.
- This applicator has the following drawbacks: on the one hand, when the product to be applied is very fluid, it may run off and thus contaminate the environment, especially when the applicator is in a horizontal position or upside down , for example during transport or storage, on the other hand, when the product is sensitive to oxidation or to microbial contamination, the ambient air coming into contact with the product risks damaging the latter.
- the Applicant has sought to avoid the drawbacks of previous distributors and to ensure, in particular, a metered distribution of a product of creamy consistency, in particular of a product for the lips.
- the Applicant has sought, in particular to create an applicator having great application comfort with good product spreading properties, while allowing precise makeup of the lips.
- this product can be stored in good conditions without risk of leakage and at shelter from ambient air without risking contaminating or degrading the product, in particular in the case of a product sensitive to oxidation or microbial contamination.
- the invention relates to an application nozzle for dispensing and applying a product of liquid to pasty consistency, comprising an application surface provided with at least one dispensing orifice, characterized in that 'it includes a unidirectional closing system allowing the distribution of the product and preventing ambient air from coming into contact with the product.
- product of liquid to pasty consistency means any composition capable of flowing under the action of a distribution means exerting a push on this product, capable of causing the expulsion of the product through the dispensing orifice.
- the viscosity of this product varies between 0.6 and 17 Pa ⁇ s.
- the dispensing orifice communicates with a supply channel completely passing through the endpiece and in communication with the product contained in a tank.
- this unidirectional closure system is constituted by a valve capable of closing the passage and opening under the thrust of the product during the dispensing thereof, and preventing ambient air from entering the reservoir when the dispensing ceases , stopping the flow of the product instantly after dispensing.
- this valve is located near the orifice and more particularly at the end of the supply channel.
- the valve is part of the nozzle, the nozzle and the valve thus being made in one piece. This valve can be in elastic abutment against a seat formed by a rigid part, for example an attached part, provided with said passage for supplying the product.
- the application surface of the end piece comprises at least one cavity or at least one groove, the orifice being located in this cavity or in this groove.
- the cavity or the groove into which the orifice opens is extended, parallel to the application surface, by passages so as to create spreading channels for the product when it is applied to the support.
- This surface can be flat, concave or convex.
- parallel is understood to mean passages dug in the application surface at a substantially constant depth.
- the application surface can be constituted by a grid.
- This application surface may advantageously include two series of woven threads, the threads of one series being crossed with those of another series, in particular in two orthogonal directions.
- the application surface thus comprises a multitude of dispensing orifices. When a multitude of such orifices is produced, their section can be variable and of different shape.
- the application surface may comprise a multitude of pins, separated by a multitude of cavities communicating with each other, at least part of the cavities being provided, in their bottom, with at least one dispensing orifice intended to communicate with a reservoir containing the product to be dispensed.
- the application tip may be provided with an application surface comprising roughness regularly distributed over all or part of the surface thereof.
- the channels arranged in the application surface can be straight or curvilinear and in particular form closed curves.
- the end piece can be made, advantageously, from a flexible material, for example from an elastomeric material chosen from the group of elastomers of polyethylene, polyurethane, polyester; polyether block amides; polyvinyls; ter-polymers of ethylene, propylene and a diene (EPDM); block styrene-butadiene polymers (SEBS-SIS), silicones, nitrile rubbers, latexes, etc.
- a flexible material for example from an elastomeric material chosen from the group of elastomers of polyethylene, polyurethane, polyester; polyether block amides; polyvinyls; ter-polymers of ethylene, propylene and a diene (EPDM); block styrene-butadiene polymers (SEBS-SIS), silicones, nitrile rubbers, latexes, etc.
- SEBS-SIS block styrene-butadiene polymers
- silicones
- the application nozzle which has just been described is intended, more particularly for the application of a product for the lips.
- the application tip is shaped substantially in the shape of a warhead provided with a flat or slightly curved application surface, located obliquely on the side of the warhead, fitted with at least one dispensing orifice, so as to imitate the shape of conventional lipsticks, with solid grapes, before any application.
- the advantage of a non-deformable semi-rigid tip compared to a deformable grape is to keep its shape until the tube of lipstick or lip balm is exhausted and therefore ensure precise and homogeneous makeup until the end.
- the invention also relates to a dispenser for dispensing and applying a product of liquid to pasty consistency
- a dispenser for dispensing and applying a product of liquid to pasty consistency comprising a reservoir for the product to be dispensed, an applicator tip conforming to that which has just been described, mounted on the reservoir and comprising an application surface provided with at least one dispensing orifice, and means capable of causing the expulsion of the product through the dispensing orifice
- the application surface of the nozzle may include at least one cavity or at least one groove, the orifice being located at the bottom of this cavity or this groove.
- This dispenser may include, if necessary, a removable protective cover.
- the application tip advantageously comprises an annular sealing bead, on which is placed, with friction, the protective cover.
- this dispenser comprises a reservoir of generally cylindrical shape equipped with means capable of causing the expulsion of the product, for example of a piston mounted sliding in this reservoir and drives in translation by a suitable mechanism.
- the product can be packaged in a conventional tube, the dispensing orifice of which is surmounted by an application nozzle according to the invention, the dispensing of the product being carried out by simple pressure on the tube.
- a dispenser equipped with the applicator tip of the invention is more particularly suitable for dispensing a cosmetic composition, in particular a composition for lips of liquid to pasty consistency, for example a product of red or balm to lips, giving the application a great softness comfort and having good properties of spreading and smoothing the product on the lips, while being capable of absorbing the possible surplus of product.
- a cosmetic composition in particular a composition for lips of liquid to pasty consistency, for example a product of red or balm to lips, giving the application a great softness comfort and having good properties of spreading and smoothing the product on the lips, while being capable of absorbing the possible surplus of product.
- the makeup obtained is precise and shiny.
- Figure 1 is a longitudinal sectional view of a dispenser, provided with an application nozzle according to the invention.
- FIG. 2 is an axial section of another variant of a valve application nozzle which can be fitted to the distribution assembly of FIG. 1.
- Figure 3 is a longitudinal sectional view of an alternative embodiment of the nozzle of Figure 2, comprising a unidirectional distribution valve.
- Figure 4 is a longitudinal sectional view of another variant of the nozzle of Figure 2, comprising a unidirectional distribution valve.
- FIGS. 5 to 12 show, in perspective, different alternative embodiments of the dispensing nozzle which can be fitted to the dispenser of FIG. 1.
- a dispenser for dispensing a product P of liquid to pasty consistency such as a lipstick composition
- This dispenser comprises a reservoir 3 of generally cylindrical shape containing the product P.
- the reservoir 3 has at its upper part a shoulder 31, surmounted by a cylindrical neck 32.
- an application nozzle 2 advantageously made in one flexible elastomeric materials mentioned above.
- This nozzle 2 is shaped substantially in a warhead, having a flat application surface 5, located at an angle on the side of the warhead.
- This surface 5 has a dispensing orifice 61.
- the end piece 2 has a supply chimney 2a for placing the orifice 61 in communication with the reservoir 3.
- the end piece 2 has an internal annular groove 2b cooperating with a fixing bead annular 33 with which the neck 32 is provided.
- the reservoir 3 has a circular bottom 34 provided with a central hole 35 traversed by a threaded control rod 50.
- This rod 50 is part of means M capable of causing the expulsion of the product P.
- These means M further comprise, a piston 13 having an internally threaded passage 14 through which the threaded rod 50 passes, this piston being capable of sliding in translation inside the reservoir 3 under the action of the control rod 50.
- These means also include a control wheel 51, mounted freely in rotation on a cylindrical skirt carried by the bottom 34.
- the wheel 51 comprises a central chimney 52 of cylindrical shape, in which is fixed a free end 50a of the rod 50.
- the wheel 51 also comprises a cylindrical skirt 53 surrounding the skirt 36 carried by the bottom 34.
- the skirts 36, 53 are provided with a latching system constituted by a pair of annular rib 54 / annular bead 37 cooperating with each other, so te that the wheel 51 remains free to rotate.
- the end piece 2 further comprises an annular attachment cord 2c, capable of retaining, by friction, a protective cover 6.
- the cover 6 is mounted on the end piece 2 in a sealed manner, which is in particular useful to prevent the evaporation of volatile components contained, if necessary, in the product P.
- the application surface 5 has a cutout so as to form a unidirectional valve 62b, in abutment, in the rest position of the dispensing assembly, against a rigid insert 62a, and deviating under the product push during distribution (position 62b).
- this valve is an elastic lip capable of returning to its rest position when the dispensing ceases. Thanks to this lip, the product keeps without deterioration for an extended period. There is no need to associate a protective cover.
- the means capable of causing the expulsion of the product can be constituted by a ratchet mechanism, as described, for example in document FR-A-2 588 733, according to which a push button located at the bottom of the applicator, causes the piston to advance towards the dispensing orifice and thus the dispensing of a dose of product.
- the means capable of causing the expulsion of the product in the form of a cartridge (not shown), possibly interchangeable, containing the product to be dispensed, this cartridge being provided with a dispensing pump, the outlet rod of which and connected to an application tip according to the invention. In this case, to dispense a dose of product, the user presses on the bottom of the cartridge, at its end opposite the valve.
- this dispenser is as follows.
- the user by turning the dial 51, causes the piston 13 to advance.
- a suitable quantity of product P for example a lipstick composition, is then expelled through the orifice 61.
- the surface of application thus preloaded with product on the lips, the user proceeds to make up the lips.
- the product is diffused in the throat 7.
- the user feels a great comfort and a great softness of application, and obtains, in a precise manner, a layer of product perfectly spread.
- FIG. 2 represents, in longitudinal section, a flexible application end piece 21, the application surface 5 of which is convex and has a plurality of orifices 61.
- the application surface 5 also comprises a spike shutter 66, shutter, in the rest position, the neck 3 of the reservoir, lifting under the pressure of the product P and stopping the distribution instantaneously, when the distribution ceases.
- a nozzle 22 comprises a concave application surface 5 provided with a rigid or semi-rigid insert 40 provided with a channel 43 for the product, this insert being in intimate contact with the internal wall of the application surface 5.
- This insert 40 has an annular groove 45 connecting the dispensing orifices 4.
- a tube 44 separates the annular groove 45 from the channel 43.
- the insert 40 also comprises a peripheral recess 42 cooperating with an internal bead 41 of the application nozzle 28. In the rest position, the channel 43 is closed by a central needle 5b secured to a portion 5a of the application surface.
- this portion 5a is capable of lifting under the thrust of the product, and of closing the channel 43 instantly and tightly, when the dispensing stops, to prevent ambient air to come into contact with the product.
- product P is protected against soiling and oxidation.
- the end piece 22 also serves as a protective cover.
- FIG. 4 represents an application end piece 23 made of polyethylene elastomer and comprising a variant of distribution valve 64, 65, 72.
- a nozzle 60 of generally cylindrical shape, comprising a circular plate 62 provided with a central passage 63.
- this plate 62 On the side facing the neck, this plate 62 has a cylindrical sealing skirt 61 which is forced into the neck 32.
- the plate 62 On the side opposite the neck 32, the plate 62 has a central dome 64 located in the extension of the passage 63 and forming a blind hole.
- the dome 64 has one or more radial orifices 65.
- the plate 62 is also provided with a cylindrical skirt 66 whose free end is cut in a slope.
- This skirt 66 comprises an annular bead 33 able to cooperate with a complementary annular groove 68 which is provided with the internal cylindrical wall 70 of the application nozzle 29.
- This nozzle 29 has a slightly convex application surface 5 on which there is distribution orifices 4 arranged in a circle.
- the application surface 5 comprises, on the side facing the plate 62 a sealing skirt 73 which is applied in a sealed manner in the skirt 66 carried by the plate 62.
- the application surface 5 is slightly convex.
- a central glove finger 71 secured to the application surface 5 extends in the direction of the plate 62 so as to completely surround the dome 64.
- This glove finger 71 comprises an elastic cylindrical skirt 72 covering the orifices 65, capable of moving away from these orifices under the thrust of the product and returning to the closed position instantly, when dispensing ceases.
- This skirt 72 constitutes the one-way valve according to the invention.
- Figures 5 to 12 show several embodiments of the application nozzle, according to the invention, on which the same constituent elements or the elements playing a similar role, bear the reference numbers of Figure 1.
- the one-way valve has been omitted in these figures
- this valve can be formed by a single valve (or lip) common in accordance with Figures 3 and 4, or else be formed by individual valves (one valve per port).
- FIG. 5 represents an application nozzle 27 comprising an application surface provided with an oval groove 15 and an elongated cavity 16, disposed along the major axis of the oval groove, defining an oval section 17.
- FIG. 6 represents an application nozzle 28 similar to that of FIG. 3, provided with a unidirectional distribution valve 5b, 44 and comprising a concave application surface 5 provided with four distribution orifices 4.
- FIG. 7 shows, in perspective, an application nozzle 29, the application surface 5 of which comprises a grid 10, the interstices of which, in square shape, form cavities or grooves 7 at the bottom of which the dispensing orifices are formed 4 bringing the product P.
- FIG. 8 represents a variant 30 of the nozzle of FIG. 7, in which the cavities 7 are of the same nature as those of the nozzle 21 of FIG. 2, but arranged differently.
- FIG. 9 shows an end piece 31, the application surface 5 of which comprises two series of parallel bars, the bars 8 of a first series forming a substantially right angle with those 9 of a second series and are located at a different level. These bars thus define an application grid. Optionally, these bars can be arranged in a fabric (alternating overlapping of two series of bars 8, 9).
- FIG. 10 shows a nozzle 24 comprising an application surface 5 provided with a central distribution orifice 4 surrounded by a multitude of pins 11.
- cavities 7, communicating with each other, are formed between the pins 11 of shape cylindrical.
- the inter-pin spaces define channels 7.
- FIG. 11 shows an application nozzle 25, the application surface 5 of which includes pins 12 of square section, arranged alternately with cavities 7 of square section, at the bottom of which are dispensing orifices 4.
- a passage exists between a cavity and the neighboring cavities, along the diagonal of the sections of the cavities 7, defining channels for the product.
- the application nozzle 26, according to FIG. 12, comprises an application surface 5 formed by two concentric rings 14a, 14b, at the bottom of which are arranged radial bars 7a, 7b, the interstices between these bars constituting orifices distribution 4 of the product.
- the surface 5 can comprise at least one zone provided with asperities, so as to obtain a granite surface, facilitating the spreading of the product.
- the area provided with asperities can be, for example, the oval section 17 of FIG. 5.
Landscapes
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Closures For Containers (AREA)
- Coating Apparatus (AREA)
- Nozzles (AREA)
- Jellies, Jams, And Syrups (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9414652A FR2727608B1 (fr) | 1994-12-06 | 1994-12-06 | Distributeur pour un produit de consistance liquide a pateuse |
FR9414652 | 1994-12-06 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0715820A2 true EP0715820A2 (de) | 1996-06-12 |
EP0715820A3 EP0715820A3 (de) | 2001-07-18 |
EP0715820B1 EP0715820B1 (de) | 2004-03-24 |
Family
ID=9469520
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95402528A Expired - Lifetime EP0715820B1 (de) | 1994-12-06 | 1995-11-10 | Spender für ein flüssiges oder pastoses Produkt |
Country Status (8)
Country | Link |
---|---|
US (1) | US5772347A (de) |
EP (1) | EP0715820B1 (de) |
JP (1) | JP2885675B2 (de) |
AT (1) | ATE262294T1 (de) |
CA (1) | CA2164380C (de) |
DE (1) | DE69532743T2 (de) |
ES (1) | ES2217275T3 (de) |
FR (1) | FR2727608B1 (de) |
Cited By (6)
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FR2752608A1 (fr) * | 1996-08-20 | 1998-02-27 | Kerplas Snc | Clapet anti-retour pour organe de distribution de produit, capuchon-poussoir pour recipient de distribution equipe d'un tel clapet et procede de fabrication correspondant |
EP0998209A1 (de) * | 1997-07-02 | 2000-05-10 | Henlopen Manufacturing Co., Inc. | Auftragsvorrichtung für flüssigkeiten |
WO2006049283A1 (ja) | 2004-11-08 | 2006-05-11 | Mitsubishi Pencil Co., Ltd. | 液体塗布具 |
WO2007080266A1 (fr) * | 2005-12-16 | 2007-07-19 | Cebal Sas | Distributeur applicateur de produits faiblement visqueux |
WO2009124049A1 (en) * | 2008-03-31 | 2009-10-08 | The Procter & Gamble Company | Package for dispensing a personal care product |
WO2015177706A1 (en) | 2014-05-20 | 2015-11-26 | L'oreal | Device for packaging and applying a cosmetic or dermatological product |
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US6357945B1 (en) | 1998-01-21 | 2002-03-19 | Colgate Palmolive Company | Cosmetic dispenser |
US6336763B1 (en) | 1998-10-07 | 2002-01-08 | Colgate-Palmolive Company | Applicator for flowable substances |
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US2442503A (en) | 1946-02-27 | 1948-06-01 | Melnikoff Zachary | Lip rouge applicator |
FR2588733A1 (fr) | 1985-10-17 | 1987-04-24 | Oreal | Applicateur pour produits liquides, notamment cosmetiques |
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CA514281A (en) * | 1955-07-05 | Mendelevitch Pierre | Distributing stoppers for liquid containers | |
FR667224A (fr) * | 1928-01-10 | 1929-10-14 | étui pour rouge à lèvres | |
US1968686A (en) * | 1931-09-11 | 1934-07-31 | A J & K Company Inc | Cream dispenser |
US2069442A (en) * | 1935-04-18 | 1937-02-02 | Heseltine Ambrose | Dispensing device |
FR813194A (fr) * | 1935-11-08 | 1937-05-27 | Distributeur de colle ou d'autres produits | |
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US2232140A (en) * | 1938-08-22 | 1941-02-18 | Raymond C Rupp | Combined container and applicator |
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- 1994-12-06 FR FR9414652A patent/FR2727608B1/fr not_active Expired - Fee Related
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1995
- 1995-11-10 EP EP95402528A patent/EP0715820B1/de not_active Expired - Lifetime
- 1995-11-10 DE DE69532743T patent/DE69532743T2/de not_active Expired - Fee Related
- 1995-11-10 ES ES95402528T patent/ES2217275T3/es not_active Expired - Lifetime
- 1995-11-10 AT AT95402528T patent/ATE262294T1/de not_active IP Right Cessation
- 1995-12-04 CA CA002164380A patent/CA2164380C/fr not_active Expired - Fee Related
- 1995-12-05 JP JP7316807A patent/JP2885675B2/ja not_active Expired - Fee Related
- 1995-12-06 US US08/568,324 patent/US5772347A/en not_active Expired - Fee Related
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US2442503A (en) | 1946-02-27 | 1948-06-01 | Melnikoff Zachary | Lip rouge applicator |
FR2588733A1 (fr) | 1985-10-17 | 1987-04-24 | Oreal | Applicateur pour produits liquides, notamment cosmetiques |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2752608A1 (fr) * | 1996-08-20 | 1998-02-27 | Kerplas Snc | Clapet anti-retour pour organe de distribution de produit, capuchon-poussoir pour recipient de distribution equipe d'un tel clapet et procede de fabrication correspondant |
EP0998209A1 (de) * | 1997-07-02 | 2000-05-10 | Henlopen Manufacturing Co., Inc. | Auftragsvorrichtung für flüssigkeiten |
WO2006049283A1 (ja) | 2004-11-08 | 2006-05-11 | Mitsubishi Pencil Co., Ltd. | 液体塗布具 |
EP1810712A1 (de) * | 2004-11-08 | 2007-07-25 | Mitsubishi Pencil Co., Ltd. | Flüssigkeitsapplikator |
EP1810712A4 (de) * | 2004-11-08 | 2009-11-04 | Mitsubishi Pencil Co | Flüssigkeitsapplikator |
US7980778B2 (en) | 2004-11-08 | 2011-07-19 | Mitsubishi Pencil Co., Ltd. | Liquid applicator |
WO2007080266A1 (fr) * | 2005-12-16 | 2007-07-19 | Cebal Sas | Distributeur applicateur de produits faiblement visqueux |
WO2009124049A1 (en) * | 2008-03-31 | 2009-10-08 | The Procter & Gamble Company | Package for dispensing a personal care product |
WO2015177706A1 (en) | 2014-05-20 | 2015-11-26 | L'oreal | Device for packaging and applying a cosmetic or dermatological product |
FR3021194A1 (fr) * | 2014-05-20 | 2015-11-27 | Oreal | Dispositif de conditionnement et d'application de produit cosmetique ou dermatologique. |
Also Published As
Publication number | Publication date |
---|---|
ES2217275T3 (es) | 2004-11-01 |
DE69532743D1 (de) | 2004-04-29 |
CA2164380C (fr) | 2000-11-28 |
JP2885675B2 (ja) | 1999-04-26 |
EP0715820A3 (de) | 2001-07-18 |
JPH08229461A (ja) | 1996-09-10 |
EP0715820B1 (de) | 2004-03-24 |
US5772347A (en) | 1998-06-30 |
CA2164380A1 (fr) | 1996-06-07 |
DE69532743T2 (de) | 2005-03-17 |
ATE262294T1 (de) | 2004-04-15 |
FR2727608B1 (fr) | 1997-01-10 |
FR2727608A1 (fr) | 1996-06-07 |
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