EP0662117B1 - Schwachalkalische geschirreinigungsmittel - Google Patents

Schwachalkalische geschirreinigungsmittel Download PDF

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Publication number
EP0662117B1
EP0662117B1 EP93920745A EP93920745A EP0662117B1 EP 0662117 B1 EP0662117 B1 EP 0662117B1 EP 93920745 A EP93920745 A EP 93920745A EP 93920745 A EP93920745 A EP 93920745A EP 0662117 B1 EP0662117 B1 EP 0662117B1
Authority
EP
European Patent Office
Prior art keywords
weight
sodium
detergent
alkali metal
citrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP93920745A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0662117A1 (de
Inventor
Birgit Burg
Jürgen Härer
Peter Jeschke
Willi Buchmeier
Helmut Blum
Christian Nitsch
Heinz-Jürgen VÖLKEL
Horst-Dieter Speckmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0662117A1 publication Critical patent/EP0662117A1/de
Application granted granted Critical
Publication of EP0662117B1 publication Critical patent/EP0662117B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609—Protease or amylase in solid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds

Definitions

  • Weakly alkaline agents for machine dishwashing are on known. They essentially contain peroxy compounds as Bleaching agents, enzymes as cleaning enhancers, pentaalkali metal phosphates and alkali silicates as builders, nonionic surfactants and alkali carbonates as a buffer substance. Your pH is at Application below 11, but can also be 7 (see FR 1 544 393, US 4 162 289, EP 135 226, EP 135 227). So far one is from im Principle of alkaline reacting compounds by means of suitable combinations and additives, the pH value until then usually more than 11 lowered accordingly.
  • the present invention relates to a weakly alkaline phosphate-free agent for the mechanical cleaning of dishes, which is characterized is that it is polymer-free and more than 30 to 60% by weight sodium citrate, 5 to 50% by weight Contains alkali hydrogen carbonate and a pH of 8 in 1% by weight solution to less than 10.
  • Trisodium citrate dihydrate can be used as a fine or coarse crystalline powder.
  • the content of trisodium citrate dihydrate is more than 30 to 60, preferably more than 30 to 50% by weight; it can more than partially, i.e. up to 50 wt .-% by occurring in nature Hydroxycarboxylic acids such as e.g. Mono-, dihydroxysuccinic acid, ⁇ -hydroxypropionic acid and glucose acid are replaced.
  • the alkali bicarbonate is preferably sodium bicarbonate.
  • the Sodium bicarbonate should preferably be in a coarse compact form a grain size in the main fraction between 0.4 and 1.0 mm be used. Its proportion in the composition is 5 to 50, preferably 25 to 40% by weight.
  • HGSM cleaning agents for household dishwashers
  • cleaning agents for household dishwashers primarily include sodium perborate mono- and tetrahydrate as well as sodium percarbonate. Because of the bulk density increase is compacted sodium perborate monohydrate prefers. But also the use of boron compounds, for example stabilized sodium percarbonate (German Offenlegungsschrift 33-21 082) has advantages because it is particularly cheap affects the corrosion behavior of glasses. Because active oxygen its full effect only at elevated temperatures are unfolded to activate them at approx. 60 ° C, the approximate Temperatures of the cleaning process in the HGSM, so-called bleach activators used.
  • TAED are preferably used as bleach activators (Tetraacetylethylenediamine), PAG (pentaacetylglucose), DADHT (1,5-diacety] -2,2-dioxo-hexahydro-1,3,5-triazine) and ISA (isatoic anhydride).
  • bleach activators Tetraacetylethylenediamine
  • PAG penentaacetylglucose
  • DADHT 1,5-diacety] -2,2-dioxo-hexahydro-1,3,5-triazine
  • ISA isatoic anhydride
  • Bleach stabilizers such as phosphonates, borates or metaborates and metasilicates may be useful.
  • the proportion of bleaching agent in the total is 2 to 20, preferably 5 to 10% by weight of that of the bleach activator 1 to 8, preferably 2 to 6 wt .-%.
  • Enzymes such as proteases, amylases, lipases and cellulases can be used to better remove protein or starch-containing food residues, for example proteases such as BLAP (R) 140 from Henkel; Optimase (R) -M-440, Optimase (R) -M-330, Opticlean (R) -M-375, Opticlean (R) -M-250 from Solvay Enzymes; Maxacal (R) CX 450,000, Maxapem (R) from Ibis, Savinase (R) 4.0 T 6.0 T 8.0 T from Novo or Experase (R) 1 from Ibis and amylases such as Termamyl (R) 60 T, 90 T from Novo; Amylase-LT (R) from Solvay Enzymes or Maxamyl (R) P 5000, CXT 5000 or CXT 2900 from Ibis, lipases such as Lipolase (R) 30 T from Novo, cellulases
  • alkali carbonates as alkali carriers to the agents according to the invention. If the cleaners are to remain label-free, you must adhere to the EC preparation guidelines for detergents and cleaning agents.
  • the amount which can be used is from 0 to about 20, preferably from 7 to 12,% by weight. If naturally occurring Na 2 CO 3 xNaHCO 3 (Trona / Solvay) is used, the amount used may have to be doubled.
  • the pH of the 1% cleaner formulation increases over the desired weakly alkaline range of 9.0 to 9.5.
  • substitution of sodium hydrogen carbonate against citric acid in amounts from 0 to 15 % By weight, preferably from 0 to 8% by weight.
  • nonionic surfactants can also be added to the agents according to the invention, which serve to better detach fatty food residues, as wetting agents and as granulating aids. Their amount is then 0 to 4, preferably 1 to 2% by weight. Extremely low-foam connections are usually used. These preferably include C 12 -C 18 alkyl polyethylene glycol polypropylene glycol ethers, each with up to 8 moles of ethylene oxide and propylene oxide units in the molecule.
  • nonionic surfactants known to be low-foaming such as, for example, C 12 -C 18 -alkylpolyethylene glycol-polybutylene glycol ether, each with up to 8 moles of ethylene oxide and butylene oxide units in the molecule, end-capped alkylpolyalkylene glycol mixed ethers and the foaming but ecologically attractive C 8 -C 10 alkyl polyglucosides and / or C 12 -C 14 alkyl polyethylene glycols with 3 - 8 ethylene oxide units in the molecule with a degree of polymerization of about 1 - 4, these then together with 0 to 1, preferably 0 to 0.5% by weight, based on the finished cleaning agent, defoaming agents such as silicone oils, mixtures of silicone oil and hydrophobized silica, paraffin oil / Guerbet alcohols, bisstearyl acid diamide, hydrophobized silica and other other known commercially available defoamers.
  • defoaming agents such
  • the agents according to the invention can optionally the sodium salts of homo- or copolymeric (meth) acrylic acids (as Polymer) with sodium carbonate and sodium bicarbonate in any Mixer, for example placed in a ploughshare mixer and then adding liquids such as water, a non-ionic surfactant or liquid poly (meth) acrylate agglomerating granulated, the granules thus obtained optionally in a second granulation level set to an even grain distribution, it dried in motion in a warm air stream, fine and Coarse fractions sieved and then with a bleach and optionally a bleach activator, a bleach stabilizer, Fragrance, enzymes, nonionic surfactants, trisodium citrate dihydrate and / or dyes are mixed.
  • any Mixer for example placed in a ploughshare mixer and then adding liquids such as water, a non-ionic surfactant or liquid poly (meth) acrylate agglomerating granulated, the granules thus
  • the trisodium citrate dihydrate can also be used in the first granulation stage be added.
  • the drying must be carried out so that the bicarbonate decays of sodium bicarbonate to sodium carbonate if possible is low (or at least as constant as possible). An additional through the drying sodium carbonate portion would have to the formulation of the granulate recipe must be taken into account.
  • Low Drying temperatures do not only affect sodium bicarbonate decay opposed, but also increase the solubility of the granular detergent when using. It is advantageous therefore when drying a supply air temperature, on the one hand to avoid bicarbonate decay should be as low as possible and, on the other hand, must be as high as necessary to use a product to get good storage properties. Drying is preferred an inlet air temperature of approx. 80 ° C.
  • the manufacturing process is the disintegration of sodium bicarbonate at the later use in the cleaning process in the dishwasher quite desirable, because this makes the alkalinity of the fleet and thus increased their cleaning performance.
  • the in situ formation of sodium carbonate (irritating to eyes and skin irritating) from sodium hydrogen carbonate (non-irritating) mitigates dangers for the consumer, e.g. in the event of improper use by children.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
EP93920745A 1992-09-25 1993-09-16 Schwachalkalische geschirreinigungsmittel Expired - Lifetime EP0662117B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4232170A DE4232170C2 (de) 1992-09-25 1992-09-25 Schwachalkalische Geschirreinigungsmittel
DE4232170 1992-09-25
PCT/EP1993/002510 WO1994007981A1 (de) 1992-09-25 1993-09-16 Schwachalkalische geschirreinigungsmittel

Publications (2)

Publication Number Publication Date
EP0662117A1 EP0662117A1 (de) 1995-07-12
EP0662117B1 true EP0662117B1 (de) 2000-06-21

Family

ID=6468844

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93920745A Expired - Lifetime EP0662117B1 (de) 1992-09-25 1993-09-16 Schwachalkalische geschirreinigungsmittel

Country Status (10)

Country Link
EP (1) EP0662117B1 (da)
JP (1) JPH08501598A (da)
AT (1) ATE194012T1 (da)
CA (1) CA2145663A1 (da)
DE (2) DE4232170C2 (da)
DK (1) DK0662117T3 (da)
ES (1) ES2148239T3 (da)
GR (1) GR3033851T3 (da)
PT (1) PT662117E (da)
WO (1) WO1994007981A1 (da)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007006628A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007006627A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007006630A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007006629A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007044418A1 (de) 2007-09-17 2009-03-19 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007044417A1 (de) 2007-09-17 2009-03-19 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007059677A1 (de) 2007-12-10 2009-06-25 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102008060470A1 (de) 2008-12-05 2010-06-10 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102008063801A1 (de) 2008-12-19 2010-06-24 Henkel Ag & Co. Kgaa Maschinelles Geschirrspülmittel
WO2011032868A1 (de) 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschinelles geschirrspülmittel
DE102009029636A1 (de) 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschine Geschirrspülmittel
WO2011032869A1 (de) 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschinelles geschirrspülmittel
WO2011051419A1 (de) 2009-10-30 2011-05-05 Henkel Ag & Co. Kgaa Maschinelles geschirrspülmittel
DE102011007695A1 (de) 2011-04-19 2012-10-25 Henkel Ag & Co. Kgaa Phosphatfreies Geschirrspülmittel
WO2014200656A1 (en) 2013-06-13 2014-12-18 Danisco Us Inc. Alpha-amylase from streptomyces umbrinus
WO2014200658A1 (en) 2013-06-13 2014-12-18 Danisco Us Inc. Alpha-amylase from promicromonospora vindobonensis
WO2014200657A1 (en) 2013-06-13 2014-12-18 Danisco Us Inc. Alpha-amylase from streptomyces xiamenensis
WO2014204596A1 (en) 2013-06-17 2014-12-24 Danisco Us Inc. Alpha-amylase from bacillaceae family member
WO2015050724A1 (en) 2013-10-03 2015-04-09 Danisco Us Inc. Alpha-amylases from a subset of exiguobacterium, and methods of use, thereof
WO2015050723A1 (en) 2013-10-03 2015-04-09 Danisco Us Inc. Alpha-amylases from exiguobacterium, and methods of use, thereof
WO2015077126A1 (en) 2013-11-20 2015-05-28 Danisco Us Inc. Variant alpha-amylases having reduced susceptibility to protease cleavage, and methods of use, thereof
WO2017173190A2 (en) 2016-04-01 2017-10-05 Danisco Us Inc. Alpha-amylases, compositions & methods
WO2017173324A2 (en) 2016-04-01 2017-10-05 Danisco Us Inc. Alpha-amylases, compositions & methods
WO2018007298A1 (de) 2016-07-05 2018-01-11 Henkel Ag & Co. Kgaa Geschirrspülmittel enthaltend zuckersäure und aminocarbonsäure
EP3431575A1 (de) 2017-07-21 2019-01-23 Henkel AG & Co. KGaA Geschirrspülmittel enthaltend citratdihydrat und -anhydrat
WO2024129938A1 (en) * 2022-12-14 2024-06-20 Colgate-Palmolive Company Home care compositions

Families Citing this family (16)

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Publication number Priority date Publication date Assignee Title
EP0697036B1 (de) * 1993-05-08 1999-07-28 Henkel Kommanditgesellschaft auf Aktien Silberkorrosionsschutzmittel ii
US5389303A (en) * 1993-09-10 1995-02-14 Srchem Incorporated Mixtures of polyamino acids and citrate
DE69413055T2 (de) * 1993-11-03 1999-05-06 The Procter & Gamble Co., Cincinnati, Ohio Kalziumkarbonatabsetzungskontrolle in geschirrspuelmaschinen
ATE189696T1 (de) * 1995-08-25 2000-02-15 Henkel Kgaa Verwendung von lipasen in niederalkalischen mitteln zum maschinellen geschirrspülen
DE19532304A1 (de) * 1995-09-01 1997-03-06 Henkel Kgaa Verfahren zur Herstellung granularer Vorprodukte niederalkalischer Reinigungsmittel
DE19540086A1 (de) * 1995-10-27 1997-04-30 Henkel Kgaa Verwendung von polymeren Aminodicarbonsäuren in Waschmitteln
DE19603760A1 (de) * 1996-02-02 1997-08-07 Henkel Kgaa Feste Reinigungsmittelzubereitungen
DE19606765A1 (de) * 1996-02-23 1997-08-28 Henkel Kgaa Verfahren zur Herstellung von Geschirrspülmitteltabletten
DE19649375A1 (de) 1996-11-29 1998-06-04 Henkel Kgaa Acetonitril-Derivate als Bleichaktivatoren in Reinigungsmitteln
DE19752601C1 (de) * 1997-11-28 1998-12-10 Henkel Kgaa Verfahren zur Herstellung von Geschirrspülmitteltabletten
DE19908051A1 (de) 1999-02-25 2000-08-31 Henkel Kgaa Verfahren zur Herstellung compoundierter Acetonitril-Derivate
US6447717B1 (en) * 1999-06-04 2002-09-10 Donlar Corporation Composition and method for inhibition of metal corrosion
GB2353800A (en) * 1999-09-02 2001-03-07 Procter & Gamble Antibacterial detergent compositions
JP2004269843A (ja) * 2003-02-19 2004-09-30 Kumano Yushi Kk 自動食器洗い機用洗浄剤
US7271138B2 (en) * 2003-10-16 2007-09-18 The Procter & Gamble Company Compositions for protecting glassware from surface corrosion in automatic dishwashing appliances
EP3257929B1 (en) 2016-06-17 2022-03-09 The Procter & Gamble Company Automatic dishwashing detergent composition

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FR1544393A (fr) * 1966-11-14 1968-10-31 Unilever Nv Compositions détergentes
JPH01146998A (ja) * 1987-12-04 1989-06-08 Matsushita Electric Ind Co Ltd 食器洗い機用洗剤
EP0414197A2 (de) * 1989-08-22 1991-02-27 Joh. A. Benckiser GmbH Maschinengeschirrspülmittel
WO1992009680A1 (en) * 1990-11-14 1992-06-11 The Procter & Gamble Company Nonphosphated dishwashing compositions with oxygen bleach systems
WO1993018129A1 (en) * 1992-03-12 1993-09-16 The Procter & Gamble Company Low-dosage automatic dishwashing detergent with monopersulfate and enzymes
WO1994005762A1 (de) * 1992-08-29 1994-03-17 Henkel Kommanditgesellschaft Auf Aktien Geschirrspülmittel mit ausgewähltem builder-system

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DE4110510A1 (de) * 1991-03-30 1992-10-01 Henkel Kgaa Niederalkalische, chlor- und phosphatfreie maschinengeschirrspuelmittel in form von schwerpulvern und -granulaten
DE4112075A1 (de) * 1991-04-12 1992-10-15 Henkel Kgaa Verfahren zur herstellung stabiler, bifunktioneller, phospat- und metasilikatfreier niederalkalischer reinigungsmitteltabletten fuer das maschinelle geschirrspuelen
DE4121307A1 (de) * 1991-06-27 1993-01-07 Henkel Kgaa Verfahren zur herstellung stabiler, bifunktioneller, phosphat- und metasilikatfreier niederalkalischer reinigungsmitteltabletten fuer das maschinelle geschirrspuelen
DE59208478D1 (de) * 1991-08-29 1997-06-19 Benckiser Gmbh Joh A Neutrales maschinelles Geschirrspülmittel
WO1993017089A1 (de) * 1992-02-20 1993-09-02 Henkel Kommanditgesellschaft Auf Aktien Verfahren zur herstellung niederalkalischer, aktivchlor-, silikat-, und phosphatfreier maschinengeschirrspülmittel in form von schwergranulaten
DE4205071A1 (de) * 1992-02-20 1993-08-26 Henkel Kgaa Verfahren zur herstellung niederalkalischer, aktivchlor-, silikat- und phosphatfreier maschinengeschirrspuelmittel in form von schwergranulaten

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FR1544393A (fr) * 1966-11-14 1968-10-31 Unilever Nv Compositions détergentes
JPH01146998A (ja) * 1987-12-04 1989-06-08 Matsushita Electric Ind Co Ltd 食器洗い機用洗剤
EP0414197A2 (de) * 1989-08-22 1991-02-27 Joh. A. Benckiser GmbH Maschinengeschirrspülmittel
WO1992009680A1 (en) * 1990-11-14 1992-06-11 The Procter & Gamble Company Nonphosphated dishwashing compositions with oxygen bleach systems
WO1993018129A1 (en) * 1992-03-12 1993-09-16 The Procter & Gamble Company Low-dosage automatic dishwashing detergent with monopersulfate and enzymes
WO1994005762A1 (de) * 1992-08-29 1994-03-17 Henkel Kommanditgesellschaft Auf Aktien Geschirrspülmittel mit ausgewähltem builder-system

Cited By (41)

* Cited by examiner, † Cited by third party
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US9752100B2 (en) 2007-02-06 2017-09-05 Henkel Ag & Co. Kgaa Detergents
US7879154B2 (en) 2007-02-06 2011-02-01 Henkel Ag & Co. Kgaa Phosphate-free dishwashing detergents comprising builder, bleaching agent, nonionic surfactant, copolymer and a phosphonate
DE102007006630A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007006629A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007006628A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
US8303721B2 (en) 2007-02-06 2012-11-06 Henkel Ag & Co. Kgaa Detergent comprising a builder, a bleaching agent, and a copolymer
DE102007006627A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE202007019720U1 (de) 2007-02-06 2017-06-07 Henkel Ag & Co. Kgaa Reinigungsmittel
WO2009037013A2 (de) 2007-09-17 2009-03-26 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007044417A1 (de) 2007-09-17 2009-03-19 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007044418A1 (de) 2007-09-17 2009-03-19 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007059677A1 (de) 2007-12-10 2009-06-25 Henkel Ag & Co. Kgaa Reinigungsmittel
US8242068B2 (en) 2008-12-05 2012-08-14 Henkel Ag & Co. Kgaa Cleaning agents
DE102008060470A1 (de) 2008-12-05 2010-06-10 Henkel Ag & Co. Kgaa Reinigungsmittel
US8268768B2 (en) 2008-12-19 2012-09-18 Henkel Ag & Co. Kgaa Automatic dishwashing agent
DE102008063801A1 (de) 2008-12-19 2010-06-24 Henkel Ag & Co. Kgaa Maschinelles Geschirrspülmittel
WO2011032868A1 (de) 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschinelles geschirrspülmittel
DE102009029635A1 (de) 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschinelles Geschirrspülmittel
WO2011032870A1 (de) 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschinelles geschirrspülmittel
DE102009029637A1 (de) 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschinelles Geschirrspülmittel
WO2011032869A1 (de) 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschinelles geschirrspülmittel
DE102009029636A1 (de) 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschine Geschirrspülmittel
US8551930B2 (en) 2009-09-21 2013-10-08 Henkel Ag & Co. Kgaa Dishwasher detergent
WO2011051419A1 (de) 2009-10-30 2011-05-05 Henkel Ag & Co. Kgaa Maschinelles geschirrspülmittel
DE102009046216A1 (de) 2009-10-30 2011-05-12 Henkel Ag & Co. Kgaa Maschinelles Geschirrspülmittel
DE102011007695A1 (de) 2011-04-19 2012-10-25 Henkel Ag & Co. Kgaa Phosphatfreies Geschirrspülmittel
WO2012143315A1 (de) 2011-04-19 2012-10-26 Henkel Ag & Co. Kgaa Phosphatfreies geschirrspülmittel
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WO2014200658A1 (en) 2013-06-13 2014-12-18 Danisco Us Inc. Alpha-amylase from promicromonospora vindobonensis
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WO2015077126A1 (en) 2013-11-20 2015-05-28 Danisco Us Inc. Variant alpha-amylases having reduced susceptibility to protease cleavage, and methods of use, thereof
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WO2017173324A2 (en) 2016-04-01 2017-10-05 Danisco Us Inc. Alpha-amylases, compositions & methods
WO2018007298A1 (de) 2016-07-05 2018-01-11 Henkel Ag & Co. Kgaa Geschirrspülmittel enthaltend zuckersäure und aminocarbonsäure
DE102016212248A1 (de) 2016-07-05 2018-01-11 Henkel Ag & Co. Kgaa Geschirrspülmittel enthaltend Zuckersäure und Aminocarbonsäure
EP3431575A1 (de) 2017-07-21 2019-01-23 Henkel AG & Co. KGaA Geschirrspülmittel enthaltend citratdihydrat und -anhydrat
DE102017212561A1 (de) 2017-07-21 2019-01-24 Henkel Ag & Co. Kgaa Geschirrspülmittel enthaltend Citratdihydrat und -anhydrat
WO2024129938A1 (en) * 2022-12-14 2024-06-20 Colgate-Palmolive Company Home care compositions

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ES2148239T3 (es) 2000-10-16
GR3033851T3 (en) 2000-10-31
DE59310064D1 (de) 2000-07-27
EP0662117A1 (de) 1995-07-12
PT662117E (pt) 2000-12-29
DK0662117T3 (da) 2000-10-23
DE4232170A1 (de) 1994-03-31
ATE194012T1 (de) 2000-07-15
DE4232170C2 (de) 1999-09-16
CA2145663A1 (en) 1994-04-14
JPH08501598A (ja) 1996-02-20
WO1994007981A1 (de) 1994-04-14

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