EP0629411B1 - Absorbierende Zusammensetzung und Wegwerfwindel mit dieser Zusammensetzung - Google Patents

Absorbierende Zusammensetzung und Wegwerfwindel mit dieser Zusammensetzung Download PDF

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Publication number
EP0629411B1
EP0629411B1 EP94108880A EP94108880A EP0629411B1 EP 0629411 B1 EP0629411 B1 EP 0629411B1 EP 94108880 A EP94108880 A EP 94108880A EP 94108880 A EP94108880 A EP 94108880A EP 0629411 B1 EP0629411 B1 EP 0629411B1
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EP
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Prior art keywords
weight
absorbent composition
particles
absorbing resin
water absorbing
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French (fr)
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EP0629411A1 (de
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Takashi Sumiya
Masashi Date
Kenji Tanaka
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Sanyo Chemical Industries Ltd
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Sanyo Chemical Industries Ltd
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/18—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica

Definitions

  • the present invention relates to a powdery or particulate absorbent composition which is suitably used for disposable diapers. More particularly, it relates to an absorbent composition having an excellent absorbing capacity as well as an excellent elasticity modulus after shearing of the gel and a moderate absorption rate, whereby excellent performance can be maintained for a long time.
  • the invention also relates to the use of the absorbent composition in a disposable diaper and to disposable diapers comprising the said absorbent composition and a fibrous material.
  • water absorbing resins powdery or particulate water swellable crosslinked polymers referred to as water absorbing resins have been used as absorbents for disposable diapers.
  • the water absorbing resin include crosslinked copolymers of starch-acrylic acid salts, crosslinked polyacrylic acid salts, saponified products of crosslinked acrylic estervinyl acetate copolymers, crosslinked copolymers of maleic anhydride, and denaturated cellulose derivatives.
  • crosslinked copolymers of starch-acrylic acid salts or crosslinked polyacrylic salts have been used for disposable diapers, heretofore.
  • the amount of the water absorbing resin used in a conventional disposable diaper is small (e.g. about 15 to 25 % by weight) based on the total weight of fibrous material such as pulp and water absorbing resin.
  • the absorbing capacity of the disposable diaper can be satisfied to some extent in a conventional disposable diaper, however, there is a problem that it is inferior in repeated absorbing capacity of urine because of low elasticity modulus after shearing of the absorbing gel, and diffusion property of urine is inferior and leakage is occuring because of unsuitable absorption rate.
  • the conventional disposable diaper is not designed for a thin type disposable diaper having a large ratio of the water absorbing resin to the fibrous material, balance between absorbency under load and elasticity modulus of the gel, shear-stability of the absorbing gel and diffusion property of urine are not actually taken into consideration.
  • performance of the disposable diaper depends largely on performance of the water absorbing resin in the disposable diaper wherein a ratio of the water absorbing resin to the fibrous material is large.
  • JP-A-62-54751 U.S. Patent No. 4,654,039 suggests a non-grafted absorbent having a gel volume with respect to synthetic urine of at least 20 g/g, a shear modulus of the hydrogel of at least 2.10 -4 N/mm 2 (2,000 dyne/cm 2 ) and an equilibrium extractable polymer content of not more than 17 % by weight.
  • Some effect can be expected regarding items (2) and (3) among the above mentioned five functions because attention is paid only to the absorbing capacity under pressure-free state and the gel-strength as performances of the absorbent.
  • JP-A-1-132802 (U.S. Patent No. 5,061,259) suggests a slightly-crosslinked absorbable gelatinizer having an equilibrium gel volume with respect to synthetic urine of at least 20 g/g and a mass median particle size of 400 to 1680 ⁇ m.
  • Some effect can be expected regarding item (4) among the above mentioned five functions because attention is paid only to the absorbing capacity under pressure-free state and the particle size as performances of the absorbent.
  • the absorbable gelatinizer satisfies the other four functions sufficiently.
  • JP-A-60-185804 and 60-185805 suggest an absorbent polymer having an absorbency of physiologic saline of 40 to 90 g/g, an absorption rate of 8 ml/0.3 g polymer or more and a gel-strength on saturation/swelling of deionized water of 33 to 200 g/cm 2 .
  • Some effect can be expected regarding the items (2) and (5) among the above mentioned five functions because attention is paid only to the absorbing capacity under pressure-free state, the absorption rate and the gel-strength to water as performances of the absorbent.
  • the absorbent polymer satisfies the other three functions sufficiently.
  • the absorbent composition should possess large absorbency under load with respect to urine and an excellent initial absorbency under load, whereby urine is sufficiently absorbed even in a state in which the user's weight is applied to the composition.
  • a shear force e.g. crawling, shifting of hip, turning-over, etc.
  • a further object of the present invention is to provide an absorbent composition wherein no dusting occurs and fluidity of powders is excellent, which results in excellent workability.
  • a still further object of the present invention is to provide an absorbent composition for disposable diaper, which does not escape from the fibrous material, whereby productivity during production of disposable diapers is improved (production loss is reduced).
  • the objective absorbent can be obtained by mixing a hydrophilic silicon dioxide powder having a specific property into carboxylic group-containing water absorbing resin particles having a specific multi-crosslinked structure and further controlling a particle size distribution.
  • the present invention relates to a powdery or particulate absorbent composition suitable for disposable diapers which is used with a fibrous material, comprising a mixture of 100 parts by weight of water absorbing resin particles (A) and 0.05 to 5 parts by weight of a hydrophilic silicon dioxide fine powder (B), said composition having a particle size distribution such that the amount of particles having a particle size of larger than 850 ⁇ m is not more than 10 % by weight and the amount of particles having a particle size of smaller than 150 ⁇ m is not more than 10 % by weight;
  • the present invention furthermore relates to the use of the above mentioned absorbent composition in a disposable diaper.
  • the present invention relates to a disposable diaper comprising the above mentioned absorbent composition and a fibrous material.
  • examples of the salt of acrylic acid include alkali metal salts (e.g. sodium salt, potassium salt and lithium salt), ammonium salts and amine salts (e.g. alkylamine salts with an alkyl group having 1 to 12 carbon atoms such as methylamine and trimethylamine salts; alkanolamine salts with an alkanol group having 2 to 12 carbon atoms such as triethanolamine and diethanolamine).
  • alkali metal salts e.g. sodium salt, potassium salt and lithium salt
  • ammonium salts and amine salts e.g. alkylamine salts with an alkyl group having 1 to 12 carbon atoms such as methylamine and trimethylamine salts
  • alkanolamine salts with an alkanol group having 2 to 12 carbon atoms such as triethanolamine and diethanolamine
  • the preferable salts are alkali metal salts, and more preferable salts are sodium or potassium salts.
  • a molar ratio of the acrylic acid to the acrylic acid salt is normally (10 to 40) : (60 to 90), preferably (20 to 35) : (80 to 65).
  • the resulting water absorbing resin becomes alkaline.
  • the resulting water absorbing resin becomes acidic. Both cases are not preferred in view of safety to the skin of the human body and, therefore, these polymers are not suitable for a constituent component of the absorbent composition for disposable diaper.
  • the acrylic acid When using the acrylic acid as the monomer, it is normal to partially neutralize carboxylic groups in the polymer with an alkaline substance after the completion of polymerization.
  • alkaline substance used for neutralization include alkali metal compounds (e.g. sodium hydroxide and potassium hydroxide), alkali metal carbonates (e.g. sodium carbonate and sodium bicarbonate), ammonia, amine compounds (e.g. alkylamines with an alkyl group having 1 to 12 carbon atoms such as methylamine and trimethylamine ; alkanolamines with an alkanol group having 2 to 12 carbon atoms such as triethanolamine and diethanolamine) and a mixture thereof.
  • alkali metal compounds e.g. sodium hydroxide and potassium hydroxide
  • alkali metal carbonates e.g. sodium carbonate and sodium bicarbonate
  • ammonia amine compounds (e.g. alkylamines with an alkyl group having 1 to 12 carbon atoms such as methylamine and trimethyl
  • the neutralization degree is usually 60 to 90 mol %, preferably 65 to 80 mol %.
  • the neutralization degree is less than 60 mol %, the resulting water absorbing resin becomes acidic.
  • the resulting water absorbing resin becomes alkaline. Both cases are not preferred in view of safety to the skin of the human body and, therefore, these polymers are not suitable for a constituent component of the absorbent composition for disposable diaper.
  • examples of the first crosslinking agent (a) having at least two double bonds capable of copolymerizing with the monomer are as follows.
  • preferable crosslinking agents (a) are bis(meth)acrylamide (1), diester or polyester of polyols and unsaturated monocarboxylic or polycarboxylic acid (2), di(meth)allyl or poly(meth)allyl ethers of polyols (5) and polyallyloxyalkanes (8). More preferable crosslinking agents are N,N' -methylenebisacrylamide, ethylene glycol diacrylate, trimethylolpropane triacrylate, tetraallyloxyethane and pentaerythritol triallyl ether.
  • crosslinking agents are tetraallyloxyethane and pentaerythritol triallyl ether because they contain no functional group which is liable to be hydrolyzed (e.g. amide group or ester group) in the molecule.
  • the amount of the crosslinking agent (a) is normally 0.01 to 5 % by weight, preferably 0.05 to 3 % by weight, more preferably 0.1 to 1 % by weight, based on the total weight of the polymerizable monomers.
  • the amount of (a) is less than 0.01 % by weight, the resulting water absorbent resin is inferior in the elasticity modulus after shearing of the gel even if it is further crosslinked with a second crosslinking agent (b).
  • it exceeds 5 % the initial elasticity modulus becomes too large to be brittle, which results in decrease of the elasticity modulus after shearing as well as absorbency under load.
  • the water absorbing resin is further crosslinked with a second crosslinking agent (b) having at least two functional groups capable of covalently binding to a carboxylic group.
  • the crosslinking agent (b) include polyglycidyl ether compounds (e.g. ethylene glycol diglycidyl ether, glycerin-1,3-diglycidyl ether, glycerin triglycidyl ether and polyethylene glycol diglycidyl ether); polyol compounds (e.g. glycerin, ethylene glycol and polyethylene glycol); and polyamine compounds (e.g.
  • crosslinking agents (b) are polyglycidyl ether compounds, polyol compounds and polyamine compounds.
  • crosslinking agents (b) are ethylene glycol diglycidyl ether, glycerin-1,3-diglycidyl ether, polyamide polyamine epichlorohydrin resin and polyamine epichlorohydrin resin because they form a strong covalent bond together with the carboxylic group to give a water absorbing resin having an excellent elasticity modulus after shearing, and they can undergo a crosslinking reaction at a comparatively low temperature.
  • Crosslinking agents which form an ionic bond together with the carboxylic group e.g.
  • crosslinking agent (b) zinc acetate, calcium acetate, barium acetate, strontium acetate, aluminum hydroxide, zirconium lactate and titanium lactate
  • a positive ion is sometimes dissociated on absorption of urine and, therefore, good elasticity modulus after shearing of the gel can not be obtained.
  • the amount of the crosslinking agent (b) is normally 0.001 to 3 % by weight, preferably 0.005 to 2 % by weight, more preferably 0.01 to 1 % by weight, based on the total weight of the monomers.
  • the amount of (b) is less than 0.001 % by weight, the initial elasticity modulus of the resulting water absorbing resin becomes low and the elasticity modulus after shearing of the gel is also decreased.
  • the gel becomes too hard to be brittle, which results in decrease of the elasticity modulus after shearing as well as absorbency under load and absorption rate.
  • the monomer of the acrylic acid salt and/or acrylic acid can be used in combination with other hydrophilic monomers.
  • hydrophilic monomer examples include unsaturated monocarboxylic or polycarboxylic acids [e.g. methacrylic acid, crotonic acid, maleic acid, itaconic acid and maleic anhydride]; monomers containing a sulfonic group [e.g.
  • vinyl sulfonic acids such as vinyl sulfonic acid, allyl sulfonic acid, vinyl toluenesulfonic acid and styrene sulfonic acid, (meth)acryl sulfonic acids such as sulfoethyl (meth)acrylate and sulfopropyl (meth)acrylate, and (meth)acrylamide sulfonic acids such as 2-acrylamide-2-methylpropanesulfonic acid]; polymerizable monomers containing a phosphoric group [e.g. 2-hydroxyethyl (meth)acryloyl phosphate and phenyl-2-acryloyloxyethyl phosphate]; (meth)acrylamides and derivatives thereof; and vinyl acetate.
  • a phosphoric group e.g. 2-hydroxyethyl (meth)acryloyl phosphate and phenyl-2-acryloyloxyethyl phosphate
  • the amount of the other hydrophilic monomer is normally 0 to 30 % by weight, preferably 0 to 10 % by weight, based on the total weight of the monomers. When the amount of the other hydrophilic monomer exceeds 30 % by weight, the absorbency under load of the resulting water absorbing resin is reduced.
  • (meth)acrylic- means “acrylic-” or “methacrylic-”.
  • a known method may be employed, for example, a method of subjecting a polymerizable monomer and a crosslinking agent (a) to aqueous solution polymerization, a method of reverse phased suspension polymerization, a method of polymerizing by irradiation of radiation, electron ray or ultraviolet ray.
  • the polymerization conditions e.g. polymerization concentration, kind or amount of polymerization solvent and polymerization temperature
  • conventional known conditions may be employed.
  • the water absorbing resin is further crosslinked with a second crosslinking agent (b) having at least two functional groups capable of covalently binding with a carboxylic group after polymerization.
  • This polymerization method is not limited to a specific one, and examples thereof include a method (1) comprising adding/kneading a crosslinking agent (b), which is optionally in the form of an aqueous solution, to a hydrogel polymer of the water absorbent resin, if necessary, partially neutralized with an alkali substance after polymerization and heat crosslinking (the hydrogel polymer may be dried and crosslinked, simultaneously); a method (2) comprising adding or spraying a crosslinking agent (b), which is optionally in the form of an aqueous solution, to the resulting powdered polymer obtained by drying/pulverizing the hydrogel polymer which is obtained by polymerization and is optionally adjusted to a desired particle size, and further crosslinking the polymer by a heat treatment; and a method (3)
  • the heat-crosslinking temperature of the hydrogel polymer or powdery or particulate mixture thereof which the crosslinking agent (b) has been added/kneaded is usually 80 to 220 °C, preferably 100 to 190 °C.
  • the temperature is less than 80 °C, it takes a long time to heat and is not economical and a crosslinking reaction sometimes does not proceed sufficiently to obtain the effect of the present invention by depending on the kinds or addition amount of (b).
  • the temperature exceeds 220 °C coloring of the water absorbing resin and decrease in absorbency under load due to heat crosslinking may occur.
  • An apparatus for crosslinking may be any one which has hitherto been known.
  • an apparatus for kneading the crosslinking agent (b) with the hydrogel polymer for example there can be used a kneader, universal mixer, single or double-screw extruder or meat chopper.
  • an apparatus for heat crosslinking or drying for example, there can be used a hot-air drier, drum drier, belt type drier or vacuum dryer.
  • a screw blender for example, there can be used a screw blender, turbulizer, Nauta blender, V-shaped rotating mixer, ribbon mixer, double arm type kneader, fluidized bed mixer or air blender.
  • a hot-air drier for example, there can be used a hot-air drier, airborne drier, fluidized bed drier, belt type drier, Nauta type heater, paddle drier or infrared drier.
  • the shape of the water absorbing resin particles (A) of the present invention may be any one which is powdery or particulate, for example, particle, granular, agglomerated, lamellar, lumpy or pearly shape.
  • the hydrophilic silicon dioxide fine powder (B) used in the present invention is dry silica produced by hydrolyzing silicon tetrachloride in a flame obtained by high temperature combustion of oxygen and hydrogen, which is normally referred to as "Fumed Silica". Accordingly, the hydrophilic silicon dioxide fine power (B) used in the present invention is normally non-porous silica.
  • it is a hydrophilic silicon dioxide having a specific surface area of 50 to 450 m 2 /g and a water affinity of not less than 70 %.
  • it is a hydrophilic silicon dioxide having a specific surface area of 100 to 400 m 2 /g and a water affinity of not less than 75 %.
  • the specific surface area is less than 50 m 2 /g, the suitable absorption rate which is an object of the present invention is not accomplished, and the initial absorbency under load (absorbency under load after 5 minutes) is reduced. Further, the elasticity after shearing of the gel is also not improved. On the other hand, no change is observed in performances of the absorbent composition even if the specific surface area exceeds 450 m 2 /g.
  • hydrophobic nature of the silicon dioxide becomes strong. Therefore, when the silicon dioxide is mixed into the water absorbing resin having a small content of fine powder as well as a narrow particle size distribution of the invention, the absorption rate of the resulting absorbent composition becomes low and the initial absorbency under load is also reduced. Furthermore, a hydrophobic silica has an inferior compatibility with the hydrophilic water absorbing resin and, therefore, it is not tightly adhered on the surface of the water absorbing resin (A), sometimes. When (B) is not tightly adhered on the surface of (A), dusting is liable to happen.
  • the silicon dioxide fine powder having a water affinity of less than 70 % is normally referred to as a hydrophobic silica which is obtained by further reacting a silanol group at the surface of the hydrophilic silicon dioxide fine powder in the present invention with e.g. monomethyltrichlorosilane, dimethyldichlorosilane or trimethylchlorosilane to introduce an alkyl group. It is not suitable for the present invention by the above mentioned reason.
  • the hydrophobic silica can be used in combination in an amount at which the resulting water affinity is within the defined range of the present invention.
  • specific surface area means a value measured by Brunauer, Emmett and Teller's method.
  • the particle size of the silicon dioxide fine powder may be not particularly limited if the specific surface area and water affinity satisfy the range of the present invention. Normally, it is said that the silicon dioxide fine powder has an initial particle size of 5 to 50 nm; see Ullmann's Encyclopedia of Industrial Chemistry, 5 th Ed., Vol A23, 1993, pp. 635-638. However, enlarged particles by aggregation of initial particles are present in a normal state.
  • the particle size is normally 0.07 to 1 ⁇ m, preferably 0.1 to 0.8 ⁇ m.
  • the mixing ratio of the water absorbing resin (A) to the hydrophilic silicon dioxide fine powder (B) is 100 parts by weight (A): 0.05 to 5 parts by weight (B), preferably 0.1 to 2 parts by weight.
  • amount of (B) is less than 0.05 parts by weight, sufficient elasticity modulus after shearing of the gel can not be obtained.
  • amount of (B) exceeds 5 parts by weight, the effect corresponding to the amount can not be obtained, and it is not economical.
  • fine powders (B) which are not tightly adhered on the particle surface of (A), cause dusting and frictional resistance is increased. Therefore, workability in case of treatment of the absorbent composition is reduced and constant amount-feeding property becomes inferior.
  • An apparatus for mixing (A) with (B) may be a usual powder mixing apparatus, for example, a conical blender, Nauta blender, V-type blender, air-blending type mixer, turbulizer, screw type line blender or static mixer.
  • the amount of particles having a particle size of larger than 850 ⁇ m is not more than 10 % by weight, and the amount of particles having a particle size of smaller than 150 ⁇ m is not more than 10 % by weight.
  • the amount of particles having a particle size of larger than 850 ⁇ m is not more than 5 % by weight, and the amount of particles having a particle size of smaller than 150 ⁇ m is not more than 5 % by weight. More preferably, the amount of particles having a particle size of larger than 710 ⁇ m is not more than 5 % by weight, and the amount of particles having a particle size of smaller than 150 ⁇ m is not more than 5 % by weight.
  • the amount of particles having a particle size of larger than 600 ⁇ m is not more than 5 % by weight, and the amount of particles having a particle size of smaller than 150 ⁇ m is not more than 5 % by weight.
  • the amount of particles having a particle size of larger than 850 ⁇ m exceeds 10 % by weight, the absorption rate of the resulting absorbent composition becomes too low to cause leakage of urine, sometimes, in case of application for a disposable diaper.
  • the amount of particles having a particle size of smaller than 150 ⁇ m exceeds 10 % by weight, gel-blocking is liable to occur in case of contacting with urine, and leakage of urine sometimes happensbecause the elasticity modulus after shearing is reduced.
  • fine powders cause dusting and aggregation is caused by moisture absorption and, further, resin particles are liable to escape from the fibrous material, the workability in case of application for the disposable diaper becomes inferior.
  • the particle size of "850 ⁇ m" corresponds to 18 mesh according to JIS (Japanese Industrial Standard), 710 ⁇ m corresponds to 22 mesh, 600 ⁇ m corresponds to 28 mesh and 150 ⁇ m corresponds to 100 mesh, respectively.
  • the particle size distribution can be adjusted by a method which has been hitherto known. For example, a method of controlling the amount of particles having a particle size of larger than 850 ⁇ m and particles having a particle size of smaller than 150 ⁇ m by passing an absorbent composition through a sieve is convenient. In addition to this method, there can be used a method of granulating fine particles (if necessary, a binder may be used) to obtain the objective particle size distribution, or a method of optimizing pulverization conditions to obtain the objective particle size distribution without screening. When using the reverse phased suspension polymerization method, the objective particle size distribution can also be obtained by selecting kind and amount of a dispersion stabilizer and optimizing the structure of a reaction tank and the stirring conditions, as is known to those skilled in the art.
  • the particle size distribution can also be adjusted at the stage of (A) alone. In this case, some fine powders can be sometimes produced by a mechanical shear force according to the apparatus used for mixing (A) with (B). Therefore, it is preferred to set the amount of particles having a particle size of smaller than 150 ⁇ m below the above range.
  • absorbency under load with respect to artificial urine i.e. aqueous solution containing 0.8 % sodium chloride, 2 % urea, 0.08 % magnesium sulfate and 0.03 % calcium chloride
  • absorbency under load with respect to artificial urine is 20 to 50 g/g
  • the elasticity modulus after shearing of artificial urine absorbing gel is not less than 4 ⁇ 10 -3 N/mm 2 (40,000 dyne/cm 2 ) and the absorption rate is 10 to 90 seconds.
  • artificial urine is to be understood as a solution similar in composition and chemical behaviour to natural urine.
  • the absorbency under load with respect to artificial urine is 25 to 50 g/g
  • the elasticity modulus after shearing of the artificial urine absorbing gel is not less than 4,5.10 -3 N/mm 2 (45,000 dyne/cm 2 ) and the absorption rate is 15 to 75 seconds.
  • a disposable diaper having good dry feeling and no leakage of urine after use for a long time can be realized.
  • the ratio of the absorbent to the fibrous material is large (e.g. a weight ratio of the absorbent to the fibrous material exceeds 30:70).
  • the fibrous material for example, there can be used cellulose fibers, modified cellulose fibers, organic synthetic fibers and a mixture thereof.
  • the cellulose fiber examples include natural fibers such as fluff pulp and cellulose type chemical fibers such as viscose rayon and acetate rayon.
  • the organic synthetic fiber examples include polypropylene fiber, polyethylene fiber, polyamide fiber, polyacrylonitrile fiber, polyester fiber, polyvinyl alcohol fiber and heat adherent bicomponent fiber (e.g. bicomponent fiber wherein at least one sort of the above fiber is formed into sheath & core type, eccentric core-sheath type or side-by-side type, bicomponent fiber wherein at least two sorts of the above fibers are blended and bicomponent fiber wherein the surface layer of the above fiber is modified).
  • bicomponent fiber wherein at least one sort of the above fiber is formed into sheath & core type, eccentric core-sheath type or side-by-side type, bicomponent fiber wherein at least two sorts of the above fibers are blended and bicomponent fiber wherein the surface layer of the above fiber is modified).
  • preferred fibrous materials are cellulose type natural fiber, polypropylene fiber, polyethylene fiber, polyester fiber, heat adherent bicomponent fiber and a mixture thereof. More preferable fibrous materials are fluff pulp, heat adherent bicomponent fiber formed into sheath & core type, eccentric core-sheath type or side-by-side type and a mixture thereof because they are superior in shape retention after the disposable diaper absorbed urine.
  • the above organic synthetic fiber is usually subjected to a hydrophilization treatment using a hydrophilizing agent such as a surfactant to apply for the disposable diaper, and it is suitable for the present invention.
  • a hydrophilizing agent such as a surfactant
  • Length and thickness of the above fibrous material is not specifically limited, and those having a length of 1 to 200 mm and a thickness of 0.1 to 100 denier can be suitably used.
  • the shape may be anyone which is fiber-shaped. and examples thereof include web, thin cylinder, cut split yarn, staple and filament shape.
  • the amount of the absorbent composition is usually 20 to 80 % by weight, preferably 30 to 70 % by weight, more preferably 35 to 65 % by weight based on the total weight of the fibrous material and the absorbent composition.
  • the amount of the absorbent composition is less than 20% by weight, a conventional water absorbing resin can be satisfactorily used and the effect of using the absorbent composition of the present invention is little.
  • the amount exceeds 80 % by weight it becomes difficult to fix the absorbent composition to the fibrous material.
  • the using methods of the absorbent composition may be those which have hitherto been known, for example, a method of mixing with the fibrous material, and a method of sandwiching between two-layers of fibrous materials, a method of dispersing between layers of a laminated fibrous material having at least three layers.
  • the absorbent composition of the present invention can be used in combination with a conventional water absorbing resin, or it can be separately used at a separate part.
  • an absorber wherein the absorbent composition has been applied in the fibrous material by the above method is further laminated with an absorbent paper or a fibrous material and a liquid permeable top sheet is provided on the top and a liquid non-permeable back sheet is provided on the bottom and, further, leg gathers, waist gathers and a fastening tape are provided to give a disposable diaper.
  • a suitable amount of bulking agents and additives such as organic powders (e.g. pulp powder, cellulose derivative and natural polysaccharides), inorganic powders (e.g. zeolite, super micronized hydrophobic silica and activated carbon), antiseptic agents, disinfectants, coloring agents, perfumes and surfactants can be added in the absorbent composition of the present invention unless the object and effect of the present invention is damaged.
  • organic powders e.g. pulp powder, cellulose derivative and natural polysaccharides
  • inorganic powders e.g. zeolite, super micronized hydrophobic silica and activated carbon
  • antiseptic agents e.g. zeolite, super micronized hydrophobic silica and activated carbon
  • An absorbent composition (1 g) was charged into a tea bag made from 250-mesh nylon net, which was then dipped in excess artificial urine for 30 minutes and then taken out and left for water removal for 15 minutes. Then, the weight increase was measured as absorbency under pressure-free state.
  • F the stress (g) after compression at 20 times
  • 980 is the acceleration of gravity (cm/second 2 )
  • S sectional area (cm 2 ) of gel after compression at 20 times.
  • the resulting value was designated as elasticity modulus after shearing of the gel.
  • model disposable diaper On a polyethylene sheet cut into a rectangular piece of 14 cm ⁇ 36 cm in size, a tissue paper having the same size and a fluff pulp having a weight of 200 g/m 2 are laminated. Then, 7.5 g of a water absorbing resin is uniformly spreaded on the fluff pulp and, further, a fluff pulp having a weight of 100 g/m 2 , a tissue paper and a non-woven fabric are laminated in this order. The resulting laminate was pressed at a pressure of 5 kg/cm 2 for 90 seconds to prepare a model disposable diaper.
  • the particle size was adjusted such that the proportion of particles of 850 to 150 ⁇ m (containing 4 % of particles having a particle size of larger than 850 ⁇ m and 2 % of particles having a particle size of smaller than 150 ⁇ m) becomes 94 % to obtain water absorbing resin particles (R-1).
  • the hydrogel polymer (I) obtained in Production Example 1 was subjected to hot-air drying at 130 to 150 °C and pulverized. Then, the particle size was adjusted such that the proportion of particles of 850 to 150 ⁇ m (containing 4 % of particles having a particle size of larger than 850 ⁇ m and 2 % of particles having a particle size of smaller than 150 ⁇ m) becomes 94 % to obtain crosslinked polymer particles (II).
  • 3 g of a 10 % aqueous solution of ethylene glycol diglycidyl ether was sprayed uniformly to 100 g of the crosslinked polymer particles (II) with stirring at high speed, followed by heat treatment at about 140 °C for 30 minutes to obtain water absorbing resin particles (R-2).
  • the particle size distribution of (R-2) was almost the same as that of (II).
  • the hydrogel polymer (III) obtained in Production Example 3 was dried with a drum drier the surface temperature of which is 180 °C and pulverized. Then the particle size was adjusted such that the proportion of particles of 850 to 150 ⁇ m (containing 2 % of particles having a particle size of larger than 850 ⁇ m and 4 % of particles having a particle size of smaller than 150 ⁇ m) becomes 94 % to obtain crosslinked polymer particles (IV). 4 g of a 10 % aqueous solution of polyamide polyamine epichlorohydrin resin was sprayed uniformly to 100 g of the crosslinked polymer particles (IV) with stirring at high speed, followed by heat treatment at about 140 °C for 30 minutes to obtain water absorbing resin particles (R-4). The particle size distribution of (R-4) was almost the same as that of (IV).
  • Crosslinked polymer particles (II) obtained in Production Example 2 and crosslinked by only the crosslinking agent (a) were designated as comparative water absorbing resin particles (R-7), and crosslinked polymer particles (IV) obtained in Production Example 4 and crosslinked by only the crosslinking agent (a) were designated as comparative water absorbing resin particles (R-8).
  • the absorbent composition of the present invention has the following advantageous effects.
  • the disposable diaper wherein the absorbent composition obtained by the process of the present invention is used in the fibrous material has the following characteristics.
  • the absorbent composition obtained by the process of the present invention is useful for disposable diapers (e.g. disposable diapers for infants or adults). Particularly, it is suitable for thin type disposable diapers wherein the ratio of the absorbent to the fibrous material is large.
  • the absorbent composition can be used suitably for other water-absorptive pads and sanitary materials (e.g. sanitary napkin, incontinence pad, mother's milk pad, under pad for operation, pet sheet, etc.)
  • sanitary materials e.g. sanitary napkin, incontinence pad, mother's milk pad, under pad for operation, pet sheet, etc.

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  • Health & Medical Sciences (AREA)
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Claims (14)

  1. Pulverförmige oder aus Teilchen bestehende absorbierende Zusammensetzung umfassend ein Gemisch aus 100 Gewichtsteilen wasserabsorbierender Harzteilchen (A) und 0,05 bis 5 Gewichtsteilen hydrophilen, feinkörnigen Siliciumdioxidpulvers (B), wobei die Zusammensetzung eine derartige Teilchengrößenverteilung aufweist, daß die Menge an Teilchen mit einer Teilchengröße von größer als 850 µm höchstens 10 Gew.-% ist und daß die Menge an Teilchen mit einer Teilchengröße von kleiner als 150 µm höchstens 10 Gew.-% ist;
    wobei die wasserabsorbierenden Harzteilchen (A) ein Acrylsäuresalz und/oder eine Acrylsäure als ein Hauptmonomer des erhaltenen Polymers umfassen, wobei die wasserabsorbierenden Harzteilchen eine Struktur aufweisen, die mit einem ersten Vernetzungsmittel (a), das mindestens zwei Doppelbindungen aufweist, die mit dem Monomer copolymerisieren können, und einem zweiten Vernetzungsmittel (b), das mindestens zwei funktionelle Gruppen aufweist, die an eine Carbonsäuregruppe kovalent binden können, vernetzt ist; und wobei das hydrophile, feinkörnige Siliciumdioxidpulver (B) eine spezifische Oberfläche von 50 bis 450 m2/g und eine Wasseraffinität von mindestens 70% aufweist.
  2. Absorbierende Zusammensetzung nach Anspruch 1, wobei die wasserabsorbierenden Harzteilchen (A) durch Polymerisieren eines Monomerengemisches aus einer Acrylsäure und einem Acrylsäuresalz mit einem Vernetzungsmittel (a) und Umsetzen von Carbonsäuregruppen in dem so erhaltenen Polymer mit einem Vernetzungsmittel (b) erhältlich sind.
  3. Absorbierende Zusammensetzung nach Anspruch 1, wobei die wasserabsorbierenden Harzteilchen (A) durch Polymerisieren einer Acrylsäure mit einem Vernetzungsmittel (a), teilweises Neutralisieren von Carbonsäuregruppen in dem erhaltenen Polymer mit einem Alkalimetallsalz und dann Vernetzen von Carbonsäuregruppen in dem Polymer mit einem Vernetzungsmittel (b) erhältlich sind.
  4. Absorbierende Zusammensetzung nach Anspruch 1, wobei die wasserabsorbierenden Harzteilchen durch weiteres Vernetzen der Umgebung der Oberfläche der in den Ansprüchen 2 oder 3 erhaltenen wasserabsorbierenden Harzteilchen mit einem Vernetzungsmittel (b) erhältlich sind.
  5. Absorbierende Zusammensetzung nach einem der Ansprüche 1 bis 4, wobei die Menge des Vernetzungsmittels (a) 0,05 bis 5 Gew.-% auf der Basis des Gewichts des Monomers ist, und die Menge des Vernetzungsmittels (b) 0,01 bis 3 Gew.-% auf der Basis des Gewichts des Monomers ist.
  6. Absorbierende Zusammensetzung nach einem der Ansprüche 1 bis 5, wobei das Gewichtsverhältnis der wasserabsorbierenden Harzteilchen (A) zu dem hydrophilen, feinkörnigen Siliciumdioxidpulver (B) 100 Gewichtsteile (A) : 0,1 bis 2 Gewichtsteile (B) ist.
  7. Absorbierende Zusammensetzung nach einem der Ansprüche 1 bis 6, wobei die Menge der Teilchen mit einem Teilchendurchmesser von größer als 850 µm höchstens 5 Gew.-% und die Menge der Teilchen mit einem Teilchendurchmesser von kleiner als 150 µm höchstens 5 Gew.-% beträgt.
  8. Absorbierende Zusammensetzung nach einem der Ansprüche 1 bis 7, wobei die Zusammensetzung eine derartige Teilchengrößenverteilung aufweist, daß die Menge der Teilchen mit einem Teilchendurchmesser von größer als 710 µm höchstens 5 Gew.-% und die Menge der Teilchen mit einem Teilchendurchmesser von kleiner als 150 µm höchstens 5 Gew.-% beträgt.
  9. Absorbierende Zusammensetzung nach einem der Ansprüche 1 bis 8, wobei die Zusammensetzung eine derartige Teilchengrößenverteilung aufweist, daß die Menge der Teilchen mit einem Teilchendurchmesser von größer als 600 µm höchstens 5 Gew.-% und die Menge der Teilchen mit einem Teilchendurchmesser von kleiner als 150 µm höchstens 5 Gew.-% beträgt.
  10. Absorbierende Zusammensetzung nach einem der Ansprüche 1 bis 9, wobei das Absorptionsvermögen in Bezug auf künstlichen Urin 20 bis 50 g/g, das Elastizitätsmodul nach Scheren des künstlichen urinabsorbierenden Gels mindestens 4·10-3 N/mm2 (40 000 Dyn/cm2) und die Saugfähigkeit 10 bis 90 Sekunden ist.
  11. Verwendung der absorbierenden Zusammensetzung nach einem der Ansprüche 1 bis 10 in einer Wegwerfwindel.
  12. Wegwerfwindel, umfassend die absorbierende Zusammensetzung nach einem der Ansprüche 1 bis 10 und ein faserförmiges Material.
  13. Wegwerfwindel nach Anspruch 12, wobei das faserförmige Material mindestens ein Material, ausgewählt aus F[auschzellstoff, wärmehaftbeständiger Bikomponentenfaser und einem Gemisch davon ist.
  14. Wegwerfwindel nach einem der Ansprüche 12 und 13, wobei die Menge der absorbierenden Zusammensetzung für Wegwerfwindeln 30 bis 70 Gew.-%, basierend auf der Gesamtmenge des faserförmigen Materials und der Zusammensetzung, beträgt.
EP94108880A 1993-06-18 1994-06-09 Absorbierende Zusammensetzung und Wegwerfwindel mit dieser Zusammensetzung Revoked EP0629411B1 (de)

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US8703859B2 (en) 2006-03-27 2014-04-22 Nippon Shokubai Co., Ltd. Production method for water-absorbing resin composition
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US9328207B2 (en) 2009-10-09 2016-05-03 Basf Se Method for re-wetting surface post-cross-linked, water-absorbent polymer particles
US20170107313A1 (en) * 2014-07-11 2017-04-20 Sumitomo Seika Chemicals Co. Ltd. Method of manufacturing water-absorbent resin, water-absorbent resin, water-absorbing agent and absorbent article

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US9309375B2 (en) 2005-09-30 2016-04-12 Nippon Shokubai Co., Ltd. Water-absorbing agent having water-absorbent resin as a main component and production method of the water-absorbing agent
US8703859B2 (en) 2006-03-27 2014-04-22 Nippon Shokubai Co., Ltd. Production method for water-absorbing resin composition
US10029027B2 (en) 2006-03-27 2018-07-24 Nippon Shokubai Co., Ltd. Production method for water-absorbing resin composition
CN101627086B (zh) * 2007-03-01 2013-07-10 株式会社日本触媒 以吸水性树脂为主成分的粒状吸水剂
US9328207B2 (en) 2009-10-09 2016-05-03 Basf Se Method for re-wetting surface post-cross-linked, water-absorbent polymer particles
US20170107313A1 (en) * 2014-07-11 2017-04-20 Sumitomo Seika Chemicals Co. Ltd. Method of manufacturing water-absorbent resin, water-absorbent resin, water-absorbing agent and absorbent article
US9873755B2 (en) * 2014-07-11 2018-01-23 Sumitomo Seika Chemicals Co. Ltd. Method of manufacturing water-absorbent resin, water-absorbent resin, water-absorbing agent and absorbent article

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FI942915A (fi) 1994-12-19
FI942915A0 (fi) 1994-06-17
ES2161730T3 (es) 2001-12-16
ATE207764T1 (de) 2001-11-15
DE69428833T2 (de) 2002-07-11
DE69428833D1 (de) 2001-12-06

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