EP0601967B1 - Flüssigwaschmittel - Google Patents
Flüssigwaschmittel Download PDFInfo
- Publication number
- EP0601967B1 EP0601967B1 EP93810772A EP93810772A EP0601967B1 EP 0601967 B1 EP0601967 B1 EP 0601967B1 EP 93810772 A EP93810772 A EP 93810772A EP 93810772 A EP93810772 A EP 93810772A EP 0601967 B1 EP0601967 B1 EP 0601967B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent composition
- hydrogen
- liquid detergent
- composition according
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title claims description 48
- 239000000203 mixture Substances 0.000 title claims description 36
- 239000007788 liquid Substances 0.000 title claims description 31
- 229910052739 hydrogen Inorganic materials 0.000 claims description 40
- 239000001257 hydrogen Substances 0.000 claims description 40
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims description 29
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 29
- 150000002431 hydrogen Chemical class 0.000 claims description 26
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 24
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 24
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 19
- 229910052736 halogen Inorganic materials 0.000 claims description 19
- 150000002367 halogens Chemical class 0.000 claims description 19
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 16
- 150000001768 cations Chemical class 0.000 claims description 15
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 12
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 12
- -1 sulfonic acid radical Chemical class 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 239000004753 textile Substances 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Chemical group 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000006081 fluorescent whitening agent Substances 0.000 claims 16
- 125000001309 chloro group Chemical group Cl* 0.000 claims 6
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 3
- 238000004061 bleaching Methods 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 10
- UCFFGYASXIPWPD-UHFFFAOYSA-N methyl hypochlorite Chemical compound COCl UCFFGYASXIPWPD-UHFFFAOYSA-N 0.000 description 8
- 230000003287 optical effect Effects 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 150000004965 peroxy acids Chemical class 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002888 zwitterionic surfactant Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000005600 alkyl phosphonate group Chemical group 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical group OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 238000007046 ethoxylation reaction Methods 0.000 description 2
- 239000001087 glyceryl triacetate Substances 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229960002622 triacetin Drugs 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- ZMLPKJYZRQZLDA-UHFFFAOYSA-N 1-(2-phenylethenyl)-4-[4-(2-phenylethenyl)phenyl]benzene Chemical group C=1C=CC=CC=1C=CC(C=C1)=CC=C1C(C=C1)=CC=C1C=CC1=CC=CC=C1 ZMLPKJYZRQZLDA-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- YFCYUVCULJDGGQ-UHFFFAOYSA-N Cc1c(-c(cc2)ccc2-c2ccc(C(C34)(C3N=O)Oc3c4cccc3)cc2)[o]c2ccccc12 Chemical compound Cc1c(-c(cc2)ccc2-c2ccc(C(C34)(C3N=O)Oc3c4cccc3)cc2)[o]c2ccccc12 YFCYUVCULJDGGQ-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241000700196 Galea musteloides Species 0.000 description 1
- 101001096355 Homo sapiens Replication factor C subunit 3 Proteins 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 102100037855 Replication factor C subunit 3 Human genes 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000008131 glucosides Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940097407 palm kernel acid Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- PLQISZLZPSPBDP-UHFFFAOYSA-M sodium;pentadecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCS([O-])(=O)=O PLQISZLZPSPBDP-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/614—Optical bleaching or brightening in aqueous solvents
- D06L4/621—Optical bleaching or brightening in aqueous solvents with anionic brighteners
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/65—Optical bleaching or brightening with mixtures of optical brighteners
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/657—Optical bleaching or brightening combined with other treatments, e.g. finishing, bleaching, softening, dyeing or pigment printing
Definitions
- the present invention relates to new, highly concentrated, aqueous and liquid detergents containing targeted disulfonated dibenzfuranylbiphenyls as optical brighteners, their preparation and their use.
- optical brighteners in liquid detergents is known. They soak on the items to be washed during treatment and, due to their special light absorption / emission properties, lead to an elimination of the yellowish tones or an improvement in the degree of whiteness.
- EP-A-167 205 proposes to use monosulfonated stilbene triazolyl, triazine or distyrylbiphenyl brighteners in anionic liquid detergents.
- EP-A-394 998 e.g. Liquid detergent with a content of 25 to 65 wt.% Water known.
- EP-A-364 027 e.g. aqueous, peracid-containing liquid detergents described, which contain optical brighteners that are stable to the peracid.
- halogens are fluorine, chlorine and bromine, but especially chlorine.
- C 1 -C 4 alkyl radicals come straight or branched alkyl groups such as methyl, ethyl, n-propyl, iso-propyl, butyl and t-butyl-n into consideration as C 1 -C 4 -alkoxy come straight or branched alkoxy groups such as methoxy , Ethoxy, n-propoxy, iso-propoxy, n-butoxy and t-butoxy.
- alkyl (or alkoxy) radicals can in turn be substituted with, for example, aryl (phenyl or naphthyl), C 1 -C 4 alkyl (methyl, ethyl, n-propyl, isopropyl, n-butyl) or t-butyl), C 1 -C 4 alkoxy (methoxy, ethoxy, n-propoxy, iso-propoxy, n-butoxy or t-butoxy), OH or CN groups.
- aryl phenyl or naphthyl
- C 1 -C 4 alkyl methyl, ethyl, n-propyl, isopropyl, n-butyl
- C 1 -C 4 alkoxy methoxy, ethoxy, n-propoxy, iso-propoxy, n-butoxy or t-butoxy
- OH or CN groups OH or CN groups.
- M in the meaning of a non-chromophoric cation preferably represents alkali metal such as lithium, sodium, potassium and optionally substituted ammonium such as ammonium, mono-, di- or triethanolammonium, mono-, di- or tripropanolammonium or tri- or tetramethylammonium.
- alkali metal such as lithium, sodium, potassium and optionally substituted ammonium such as ammonium, mono-, di- or triethanolammonium, mono-, di- or tripropanolammonium or tri- or tetramethylammonium.
- Sodium, potassium and ammonium are particularly preferred.
- Liquid detergents are known and commercially available detergents, as are described, for example, in EP-A-167 205 or US-4 507 219 or EP-A-293 040.
- Anionic, nonionic, cationic or zwitterionic surfactants can be used as surfactants.
- Useful surfactants are e.g. in U.S. 4,285,841, U.S. 3,929,678, U.S. 4,284,532 and GB 2,041,986.
- the surfactants designated as preferred in EP-A-167 205 are used.
- Nonionic surfactants are, for example, polyhydroxy fatty acid amides, as described in WO 92/06172, and alkylphenols. Furthermore, there are also alkyl polyglucosides of C 9 -C 15 -alkylene with 1-10 glucoside units such as, for example, nonylglucoside and allyl (C 12 -C 15 ) -poly (1-10) -glucoside, sorbine esters such as, for example, polyoxyethylene sorbitan monopalmitate, fatty acid ethanolamides such as, for example, coconut fatty acid diethanolamide and fatty acid ethanolamine such as tetradecylamine oxide in question.
- alkyl polyglucosides of C 9 -C 15 -alkylene with 1-10 glucoside units such as, for example, nonylglucoside and allyl (C 12 -C 15 ) -poly (1-10) -glucoside
- sorbine esters such as, for example, poly
- Detergent builders or polymers include e.g. the preferably polycarboxylated compounds mentioned in U.S. 4,321,165 and U.S. 4,284,532 such as citric acid or maleic acid / acrylic acid copolymers, as well as e.g. the lignin sulfonates, formaldehyde addition products, polyethylene glycols, polyvinylpyrolidones, polyvinylimidazoles, and Al / Mg silicates.
- the lignin sulfonates e.g. the preferably polycarboxylated compounds mentioned in U.S. 4,321,165 and U.S. 4,284,532 such as citric acid or maleic acid / acrylic acid copolymers, as well as e.g. the lignin sulfonates, formaldehyde addition products, polyethylene glycols, polyvinylpyrolidones, polyvinylimidazoles, and Al / Mg silicates.
- Zwitterionic surfactants are e.g. Aminocarboxylic acids and alkylamine oxides.
- Cationic surfactants are e.g. quaternary ammonium or amine compounds.
- the formulation can contain 1 to 10% of common detergent additives such as, for example, enzymes, enzyme stabilizers, antioxidants, preservatives and disinfectants, emulsifiers, thickeners, foam regulators, stabilizers, antiredeposition agents, fragrances and colorants, complexing agents or sequestering agents and solvents.
- common detergent additives such as, for example, enzymes, enzyme stabilizers, antioxidants, preservatives and disinfectants, emulsifiers, thickeners, foam regulators, stabilizers, antiredeposition agents, fragrances and colorants, complexing agents or sequestering agents and solvents.
- salts e.g. Formates, acetates and sodium chloride can be used.
- Targeted liquid detergents containing sulfonated dibenzofuranylbiphenyls can also be used e.g. also described in EP-A-293 040, contain up to 20% by weight of one or more bleaching agents such as phthalocyanines, peracids such as perborates or diperoxydicarboxylic acids, or peracid precursors and peracid activators or peracid catalysts.
- bleaching agents such as phthalocyanines, peracids such as perborates or diperoxydicarboxylic acids, or peracid precursors and peracid activators or peracid catalysts.
- the formulation is produced by mixing the components with stirring.
- the formulation thus obtained is stable for months and does not sediment.
- optical brighteners used is e.g. in EP-A-394 998.
- the detergents obtained in Examples 1 and 2 are used in a concentration of 7.5 g / l for washing bleached cotton at 60 ° C. After rinsing and drying, high degrees of whiteness are achieved with negligible stain formation.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH3528/92 | 1992-11-17 | ||
| CH3528/92A CH684485A5 (de) | 1992-11-17 | 1992-11-17 | Flüssigwaschmittel. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0601967A1 EP0601967A1 (de) | 1994-06-15 |
| EP0601967B1 true EP0601967B1 (de) | 1996-10-09 |
Family
ID=4257953
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP93810772A Expired - Lifetime EP0601967B1 (de) | 1992-11-17 | 1993-11-09 | Flüssigwaschmittel |
| EP94901548A Expired - Lifetime EP0672099B1 (en) | 1992-11-17 | 1993-11-16 | Stable liquid detergent compositions inhibiting dye transfer |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94901548A Expired - Lifetime EP0672099B1 (en) | 1992-11-17 | 1993-11-16 | Stable liquid detergent compositions inhibiting dye transfer |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5468884A (ko) |
| EP (2) | EP0601967B1 (ko) |
| JP (2) | JPH08503509A (ko) |
| KR (1) | KR940011622A (ko) |
| AU (2) | AU5609794A (ko) |
| BR (1) | BR9304741A (ko) |
| CA (1) | CA2103097A1 (ko) |
| CH (1) | CH684485A5 (ko) |
| DE (2) | DE59304117D1 (ko) |
| ES (1) | ES2092800T3 (ko) |
| MX (1) | MX9307033A (ko) |
| TW (1) | TW237475B (ko) |
| WO (1) | WO1994011480A1 (ko) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH684485A5 (de) * | 1992-11-17 | 1994-09-30 | Ciba Geigy Ag | Flüssigwaschmittel. |
| US5776878A (en) * | 1994-01-13 | 1998-07-07 | The Procter & Gamble Company | Liquid detergent compositions containing brighteners and polymers for preventing fabric spotting |
| CN1145093A (zh) * | 1994-03-30 | 1997-03-12 | 普罗格特-甘布尔公司 | 具有改进的增白和染料转移抑制效果的洗衣用洗涤剂条 |
| GB9409465D0 (en) * | 1994-05-12 | 1994-06-29 | Ciba Geigy Ag | Protective use |
| DE69533417T2 (de) * | 1994-05-12 | 2005-08-18 | Ciba Specialty Chemicals Holding Inc. | Textilbehandlungen |
| US5922083A (en) * | 1995-04-03 | 1999-07-13 | Procter & Gamble Company | Detergent composition comprising a mutant amylase enzyme and oxygen bleaching agent |
| EP0736594A1 (en) * | 1995-04-03 | 1996-10-09 | The Procter & Gamble Company | Soaker compositions |
| EP0756001A1 (en) * | 1995-07-24 | 1997-01-29 | The Procter & Gamble Company | Detergent compositions comprising specific amylase and a specific surfactant system |
| DE19751860C1 (de) * | 1997-11-22 | 1999-08-19 | Henkel Ecolab Gmbh & Co Ohg | Waschverfahren und Zubereitung zu seiner Durchführung |
| JP5396707B2 (ja) * | 2007-11-07 | 2014-01-22 | ライオンハイジーン株式会社 | 洗浄剤組成物 |
| EP2711413B2 (de) † | 2012-09-25 | 2022-04-13 | Miele & Cie. KG | Waschmittel und Verfahren zur Dosierung eines Waschmittels |
| EP3277784A1 (en) | 2015-04-02 | 2018-02-07 | Unilever Plc. | Composition |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3000830A (en) * | 1952-12-05 | 1961-09-19 | Fong Willie | Use of polyvinylpyrrolidone as a soil-suspending agent |
| DE1114606B (de) * | 1956-04-10 | 1961-10-05 | Willi Maurer K G | Waschmittel fuer Weiss- und Buntwaesche |
| US4002423A (en) * | 1971-08-13 | 1977-01-11 | Hoechst Aktiengesellschaft | Benzofuran derivatives process for their preparation and their use as optical brighteners |
| DE2437090A1 (de) * | 1974-08-01 | 1976-02-19 | Hoechst Ag | Reinigungsmittel |
| GB2040987B (en) * | 1977-06-29 | 1982-08-25 | Procter & Gamble | Solid detergent composition for improved greasy soil removal |
| DE3063434D1 (en) * | 1979-05-16 | 1983-07-07 | Procter & Gamble Europ | Highly concentrated fatty acid containing liquid detergent compositions |
| US4284532A (en) * | 1979-10-11 | 1981-08-18 | The Procter & Gamble Company | Stable liquid detergent compositions |
| GB8316760D0 (en) * | 1983-06-20 | 1983-07-20 | Unilever Plc | Detergent bleach compositions |
| US4507219A (en) * | 1983-08-12 | 1985-03-26 | The Proctor & Gamble Company | Stable liquid detergent compositions |
| EP0167205B1 (en) * | 1984-07-03 | 1992-03-11 | The Procter & Gamble Company | Stable liquid detergents containing anionic surfactant and monosulfonated brightener |
| US4970029A (en) * | 1984-07-03 | 1990-11-13 | The Procter & Gamble Company | Stable liquid detergent containing anionic surfactant and monosulfonated brightener |
| GB8712430D0 (en) * | 1987-05-27 | 1987-07-01 | Procter & Gamble | Liquid detergent |
| US5139695A (en) * | 1988-01-14 | 1992-08-18 | Ciba-Geigy Corporation | Stable bleaching compositions containing fluorescent whitening agents |
| CH678585B5 (ko) * | 1988-01-14 | 1992-04-15 | Ciba Geigy Ag | |
| EP0350449A3 (de) * | 1988-07-08 | 1990-10-24 | Ciba-Geigy Ag | Optische Aufheller enthaltende Flüssigwaschmittel |
| GB8824108D0 (en) * | 1988-10-14 | 1988-11-23 | Unilever Plc | Bleaching & detergent compositions |
| EP0394988B1 (de) * | 1989-04-25 | 1994-10-12 | Maschinenfabrik Müller-Weingarten AG | Vorrichtung zur Schmierung eines Gie kolbens an einer Druckgie maschine |
| US5279772A (en) * | 1989-04-28 | 1994-01-18 | Ciba-Geigy Corporation | Liquid detergents containing specifically disulfonated dibenzofuranyl-biphenyls as flourescent whitening agents |
| EP0394998B1 (de) * | 1989-04-28 | 1996-03-27 | Ciba-Geigy Ag | Flüssigwaschmittel |
| US5106523A (en) * | 1989-06-16 | 1992-04-21 | The Clorox Company | Thickened acidic liquid composition with amine fwa useful as a bleaching agent vehicle |
| US5174927A (en) * | 1990-09-28 | 1992-12-29 | The Procter & Gamble Company | Process for preparing brightener-containing liquid detergent compositions with polyhydroxy fatty acid amines |
| MX9207050A (es) * | 1991-12-19 | 1993-06-01 | Ciba Geigy Ag | Dispersion de blanqueador estable durante el almacenamiento |
| US5234617A (en) * | 1992-04-20 | 1993-08-10 | Kathleen B. Hunter | Aqueous liquid bleach compositions with fluorescent whitening agent and polyvinyl pyrrolidone or polyvinyl alcohol |
| CH684485A5 (de) * | 1992-11-17 | 1994-09-30 | Ciba Geigy Ag | Flüssigwaschmittel. |
| GB9224052D0 (en) * | 1992-11-17 | 1993-01-06 | Unilever Plc | Non aqueous liquid detergent compositions |
-
1992
- 1992-11-17 CH CH3528/92A patent/CH684485A5/de not_active IP Right Cessation
-
1993
- 1993-10-15 TW TW082108540A patent/TW237475B/zh active
- 1993-11-09 ES ES93810772T patent/ES2092800T3/es not_active Expired - Lifetime
- 1993-11-09 DE DE59304117T patent/DE59304117D1/de not_active Expired - Fee Related
- 1993-11-09 EP EP93810772A patent/EP0601967B1/de not_active Expired - Lifetime
- 1993-11-11 MX MX9307033A patent/MX9307033A/es not_active IP Right Cessation
- 1993-11-12 US US08/152,331 patent/US5468884A/en not_active Expired - Fee Related
- 1993-11-15 KR KR1019930024178A patent/KR940011622A/ko not_active Application Discontinuation
- 1993-11-15 CA CA002103097A patent/CA2103097A1/en not_active Abandoned
- 1993-11-16 WO PCT/US1993/011141 patent/WO1994011480A1/en active IP Right Grant
- 1993-11-16 DE DE69309488T patent/DE69309488T2/de not_active Expired - Fee Related
- 1993-11-16 AU AU56097/94A patent/AU5609794A/en not_active Abandoned
- 1993-11-16 EP EP94901548A patent/EP0672099B1/en not_active Expired - Lifetime
- 1993-11-16 BR BR9304741A patent/BR9304741A/pt not_active Application Discontinuation
- 1993-11-16 AU AU50741/93A patent/AU664123B2/en not_active Ceased
- 1993-11-16 JP JP6512469A patent/JPH08503509A/ja active Pending
- 1993-11-17 JP JP5287141A patent/JPH06200292A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US5468884A (en) | 1995-11-21 |
| EP0601967A1 (de) | 1994-06-15 |
| AU664123B2 (en) | 1995-11-02 |
| MX9307033A (es) | 1994-06-30 |
| DE69309488T2 (de) | 1997-11-06 |
| TW237475B (ko) | 1995-01-01 |
| ES2092800T3 (es) | 1996-12-01 |
| KR940011622A (ko) | 1994-06-21 |
| AU5609794A (en) | 1994-06-08 |
| JPH08503509A (ja) | 1996-04-16 |
| WO1994011480A1 (en) | 1994-05-26 |
| DE59304117D1 (de) | 1996-11-14 |
| BR9304741A (pt) | 1994-07-05 |
| EP0672099B1 (en) | 1997-04-02 |
| DE69309488D1 (de) | 1997-05-07 |
| EP0672099A1 (en) | 1995-09-20 |
| CA2103097A1 (en) | 1994-05-18 |
| JPH06200292A (ja) | 1994-07-19 |
| EP0672099A4 (en) | 1995-08-03 |
| CH684485A5 (de) | 1994-09-30 |
| AU5074193A (en) | 1994-06-02 |
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