EP0542070A1 - Fil hybride de fibres en polyamide et de fibres de renforcement - Google Patents

Fil hybride de fibres en polyamide et de fibres de renforcement Download PDF

Info

Publication number
EP0542070A1
EP0542070A1 EP92118673A EP92118673A EP0542070A1 EP 0542070 A1 EP0542070 A1 EP 0542070A1 EP 92118673 A EP92118673 A EP 92118673A EP 92118673 A EP92118673 A EP 92118673A EP 0542070 A1 EP0542070 A1 EP 0542070A1
Authority
EP
European Patent Office
Prior art keywords
polyamide
hybrid yarn
fibers
yarn
hybrid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP92118673A
Other languages
German (de)
English (en)
Other versions
EP0542070B1 (fr
Inventor
Joerg Dr. Vogelsang
Giorgio Dr. Greening
Regina Laws
Peter Dr. Ittemann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cytec Technology Corp
Original Assignee
BASF SE
Cytec Technology Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Cytec Technology Corp filed Critical BASF SE
Publication of EP0542070A1 publication Critical patent/EP0542070A1/fr
Application granted granted Critical
Publication of EP0542070B1 publication Critical patent/EP0542070B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/40—Yarns in which fibres are united by adhesives; Impregnated yarns or threads
    • D02G3/402—Yarns in which fibres are united by adhesives; Impregnated yarns or threads the adhesive being one component of the yarn, i.e. thermoplastic yarn
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2936—Wound or wrapped core or coating [i.e., spiral or helical]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065—Including strand which is of specific structural definition
    • Y10T442/313—Strand material formed of individual filaments having different chemical compositions
    • Y10T442/3138—Including inorganic filament
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/40—Knit fabric [i.e., knit strand or strip material]
    • Y10T442/425—Including strand which is of specific structural definition
    • Y10T442/438—Strand material formed of individual filaments having different chemical compositions

Definitions

  • the invention relates to hybrid yarn made of polyamide fibers and reinforcing fibers.
  • Hybrid yarns in which thermoplastic fibers and reinforcing fibers are intimately mixed, have been used increasingly in recent years for the production of high-performance composite materials.
  • the hybrid yarns and the fabrics made from them are very flexible and can therefore be deformed as required. If they are consolidated by pressing at temperatures above the softening point of the thermoplastic, it melts and forms a matrix in which the reinforcing fibers are embedded in the preferred direction.
  • EP-B 156 599 describes a process for the production of hybrid yarn from carbon fibers and thermoplastic fibers, in which the two types of fiber are spread apart, mixed with one another by being brought together via rollers or rods, and the mixed yarn is then optionally wrapped with another thermoplastic yarn. Such wrapping results in a good thread closure, so that the yarn can be easily woven without the addition of a size.
  • Hybrid yarn based on the thermoplastics mentioned in the examples of EP-B 156 599 is not suitable for the production of inexpensive and easily processable high-performance composite materials. In principle, however, this is possible with polyamides, which, in addition to many others, are also mentioned in the description of EP-B 156 599. Attempting to produce hybrid yarns from the usual high and medium viscosity polyamide fibers shows that the time required for consolidation into the composite material is relatively long and that some mechanical properties of the composite materials, in particular the transverse tensile strength, are too low.
  • the invention was therefore based on the object of providing a hybrid yarn which does not have these disadvantages.
  • This object is achieved in that an extremely low-viscosity polyamide is used in the production of hybrid yarn from polyamide fibers and reinforcing fibers.
  • the invention accordingly relates to a hybrid yarn composed of polyamide fibers A and reinforcing fibers B, in which the individual filaments of the two types of fiber are mixed, and which is wrapped in a polyamide yarn A ', the polyamide A having a melt viscosity of less than 220 Pa ⁇ s (measured according to DIN 54 811 at a shear rate of 100 s ⁇ 1 and at a temperature which is 30 ° C above the melting point or the glass transition temperature of the polyamide).
  • GB-A 2 105 247 describes fiber composite materials which are produced by wrapping a fiber core made of reinforcing fibers with a thermoplastic thread.
  • the core consists of a carbon fiber yarn and two ends of a nylon multifilament yarn, and a nylon multifilament yarn is also used as the wrapping yarn.
  • the three multifilament yarns are arranged side by side in the fiber core; the individual filaments have not been mixed, the fiber composite material therefore has a low level of mechanical properties.
  • Preferred reinforcing fibers B are carbon fibers and glass fibers.
  • fibers made of ceramic materials, silicon carbide and boron nitride are also suitable, as well as those made of polymers with a softening point which is more than 70 ° C. above the softening point of polyamide A, for example from polyether ketone or fully aromatic polyamides.
  • polyamide fibers A preferably polyamide-6 and polyamide-6.6.
  • polyamide-6,6 T, polyamide-6,10, polyamide-10, and a polyamide made of adipic acid and 1,3-xylylenediamine and copolyamides based on the corresponding monomers are also suitable.
  • the polyamides A have a melt viscosity of less than 220, preferably less than 180 Pa ⁇ s, measured in accordance with DIN 54 811 at a shear rate of 100 s ⁇ 1 and at a temperature which is 30 ° C. above the melting point (in the case of partially crystalline) Polyamides) or above the glass transition temperature (in the case of amorphous polyamides) of the polymer.
  • the hybrid yarns are preferably produced in accordance with EP-B 156 599 by spreading the two types of fiber separately from one another by blowing with air and then mixing them by bringing them together over rolls or rods.
  • the spreading can in principle also be carried out by a liquid jet, by electrostatic charging or by separating the individual filaments by means of combs.
  • intimate mixing of the individual filaments is obtained, so that thermoplastic and reinforcing fibers are evenly and statistically distributed in the mixed yarn.
  • Such intimate mixing is not necessary for all applications; one can also dispense with spreading the starting fibers and mix them using simple methods, e.g. by pulling them together over rollers or rods or swirling them together in an air stream.
  • a polyamide yarn A ' is used for this, preferably the same polyamide as that used for the polyamide fiber A.
  • a different type of polyamide can also be used; basically also a polyamide, whose melt viscosity is over 220 Pa ⁇ s.
  • the wrapping yarn should preferably have a titer of 40 to 100 dtex.
  • the proportions should preferably be chosen so that the finished hybrid yarn contains 26 to 80% by weight of polyamide fibers A, 20 to 75% by weight of reinforcing fibers B and 0.2 to 3% by weight of wrapping yarn A '.
  • the hybrid yarn according to the invention can be processed into woven, knitted or braided fabrics without the additional application of a size.
  • a plurality of yarns can be laid down in parallel to scrims or ribbons, a plurality of such scrims being stacked parallel or at predetermined angles to one another can be. You can also wind the yarns over tubes to tubes.
  • These semi-finished products can then be consolidated into composites by pressing at temperatures above the softening point of the polyamide and, if necessary, deformed. It is advisable to apply a size to the semi-finished product beforehand, which can reduce the consolidation time.
  • This is preferably an aqueous dispersion of a thermoplastic which is compatible with polyamide A.
  • the composite materials based on the hybrid yarn according to the invention can be used to produce heavy-duty articles, e.g. Tennis racket frames, baseball and hockey sticks, frames for badminton and squash rackets, and bicycle frames.
  • heavy-duty articles e.g. Tennis racket frames, baseball and hockey sticks, frames for badminton and squash rackets, and bicycle frames.
  • Ultramid®B a polyamide 6 from BASF AG with different melt viscosity, was spun into a multifilament yarn made of 184 filaments with a total of 217 tex using a single-stage spin-stretching process. Two of these yarns were intimately mixed together with a Celion® G30-500 carbon fiber yarn from Celion Carbon Fibers, consisting of 12,000 individual carbon filaments, as described in EP 156 599, by spreading the individual multifilament yarns with air and then together over and were brought together under two bars. Then they are wound with a 6 tex strong auxiliary yarn (consisting of 12 single filaments) made of Ultramid®B (melt viscosity 260 Pa ⁇ s). The winding rate of the auxiliary yarn was 150 turns / m of the resulting hybrid yarn. The product had an even distribution of thermoplastic and carbon fibers, it contained 64.1% carbon fibers 34.8% polyamide fibers A 1.1% thread A '.
  • a consolidated test specimen was then produced from the hybridized and wound thread thus produced.
  • the hybridized yarn was wound on a metal reel with a free area of 220 mm x 270 mm inside. A total of six layers (three on each side) were wound and then the reel was placed between two steel tools designed for this purpose, which were to transmit pressure and heat to the wound hybrid yarn.
  • the hybrid yarn was consolidated in a hot press.
  • the tool was placed in the press preheated to the temperature T and kept at a pressure of 5.5 bar for 15 minutes so that the hybridized yarn was heated to T. The pressure was then increased to 14 bar within one minute and this pressure was held for Z minutes. The tool was then cooled in the same press for 10 minutes by inserting cooling cassettes between the hybrid yarn tool and the press jaws. A 2 mm thick, consolidated plate with a smooth, non-porous surface was found when the tool was opened.
  • the material was subjected to a 90 ° tensile test according to SAC-MA 4-88.
  • the 2 mm thick plate was cut into 25 mm x 210 mm specimens with a diamond saw, taking care to ensure that the reinforcement fibers were aligned exactly parallel to the 25 mm long side of the specimens was respected.
  • the tensile strength is shown in the table.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Reinforced Plastic Materials (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Artificial Filaments (AREA)
  • Woven Fabrics (AREA)
EP92118673A 1991-11-14 1992-10-31 Fil hybride de fibres en polyamide et de fibres de renforcement Expired - Lifetime EP0542070B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4137406 1991-11-14
DE19914137406 DE4137406A1 (de) 1991-11-14 1991-11-14 Hybridgarn aus polyamidfasern und verstaerkungsfasern
US07/970,455 US5464684A (en) 1991-11-14 1992-11-02 Hybrid yarn comprising a core of intermixed polyamide filaments and reinforcing rilaments wherein the core is wrapped by a polyamide fiber

Publications (2)

Publication Number Publication Date
EP0542070A1 true EP0542070A1 (fr) 1993-05-19
EP0542070B1 EP0542070B1 (fr) 1996-07-10

Family

ID=25909115

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92118673A Expired - Lifetime EP0542070B1 (fr) 1991-11-14 1992-10-31 Fil hybride de fibres en polyamide et de fibres de renforcement

Country Status (4)

Country Link
US (1) US5464684A (fr)
EP (1) EP0542070B1 (fr)
JP (1) JPH05247761A (fr)
DE (1) DE4137406A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0768405A1 (fr) * 1995-10-11 1997-04-16 Hoechst Trevira GmbH & Co. KG Tissu avec étanchéité réglable au gaz et/ou aux liquides comprenant des fils hybrides, procédé pour son traitement altérieur, structure textile avec étanchéité au gaz et/ou aux liquides prédéterminée et son utilisation
DE102007028373A1 (de) * 2007-06-11 2008-12-24 Technische Universität Dresden Faserverbundwerkstoff und Verfahren zur Herstellung von Faserverbundwerkstoffen
WO2011134995A1 (fr) * 2010-04-30 2011-11-03 Deutsche Institute Für Textil- Und Faserforschung Denkendorf Fil hybride pour la fabrication de pièces moulées
WO2023012226A3 (fr) * 2021-08-05 2023-06-08 Universität Stuttgart Composites fibres-matrice transparents structuraux et procédés de fabrication de ceux-ci

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4412376C3 (de) * 1994-04-13 1999-09-09 Buck Halbzeug
US5756206A (en) * 1995-03-15 1998-05-26 Custom Composite Materials, Inc. Flexible low bulk pre-impregnated tow
ATE207554T1 (de) 1995-08-11 2001-11-15 Alfred Buck Halbzeug für verbundwerkstoff
DE19613965A1 (de) * 1996-04-09 1997-10-16 Hoechst Trevira Gmbh & Co Kg Schrumpfarme Hybridgarne, Verfahren zu deren Herstellung und deren Verwendung
US20010007706A1 (en) * 1996-09-16 2001-07-12 Matthew B. Hoyt Colored fibers having resistance to ozone fading
US6531218B2 (en) 1996-09-16 2003-03-11 Basf Corporation Dyed sheath/core fibers and methods of making same
DE69907907T2 (de) 1998-06-08 2004-03-11 Complastik Corp., Lowell Verbundgegenstände insbesondere prepregs, vorformlinge, laminate und sandwich formteile, und verfahren zu deren herstellung
US6117548A (en) * 1998-12-18 2000-09-12 Glen Raven Mills, Inc. Self-coating composite stabilizing yarn
US6557590B2 (en) 1998-12-29 2003-05-06 Glen Raven, Inc. Decorative outdoor fabrics
AU2002241584A1 (en) 2000-12-06 2002-06-18 Complastik Corporation Hybrid composite articles and methods for their production
JP2003055850A (ja) * 2001-08-10 2003-02-26 Fukushima Prefecture 複合糸および繊維強化プラスチック
EP1594341B1 (fr) * 2004-05-06 2008-01-23 Harman/Becker Automotive Systems GmbH Membrane de haut-parleur
US7185481B2 (en) * 2005-02-15 2007-03-06 Banom, Inc. Cut resistant yarns for glove and sleeves, gloves and sleeves made with such yarns and methods of making such cut resistant yarns
PL1743964T3 (pl) * 2005-07-15 2009-04-30 Teijin Aramid Bv Kord
KR101196689B1 (ko) * 2007-06-20 2012-11-08 로디아 오퍼레이션스 복합 폴리아미드 물품
GB2477531B (en) * 2010-02-05 2015-02-18 Univ Leeds Carbon fibre yarn and method for the production thereof
JP2014173196A (ja) * 2013-03-06 2014-09-22 Gifu Univ 混繊糸、織物および編み物、複合材料、並びに、複合材料の製造方法
CN105764961A (zh) * 2013-08-01 2016-07-13 英威达技术有限公司 连续纤维热塑性复合材料
US20150137409A1 (en) * 2013-11-21 2015-05-21 Hsien-Hsiao Hsieh Method For Forming Textile Article
EP3332055A2 (fr) 2015-08-03 2018-06-13 Kordsa Teknik Tekstil Anonim Sirketi Procédé de fabrication de préimprégné thermoplastique
WO2017116349A1 (fr) 2015-12-31 2017-07-06 Kordsa Teknik Tekstil Anonim Sirketi Procédé de production de pré-imprégné thermoplastique
DE102020105167A1 (de) 2020-02-27 2021-09-02 Thüringisches Institut für Textil- und Kunststoff-Forschung e. V. Rudolstadt Verfahren zur Herstellung eines Hybridgarnes
JP7354037B2 (ja) 2020-03-23 2023-10-02 株式会社日立ハイテクサイエンス 集束イオンビーム加工装置
BE1030711B1 (nl) * 2022-07-12 2024-02-12 Sioen Ind Composietprofiel en gemengd garen voor het vervaardigen van composietprofielen

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2105247A (en) * 1981-06-23 1983-03-23 Courtaulds Plc Process for making a fibre-reinforced moulding
EP0156599A1 (fr) * 1984-03-15 1985-10-02 BASF Aktiengesellschaft Mélange de fibres de carbone et de fibres thermoplastiques
EP0156600A1 (fr) * 1984-03-15 1985-10-02 Celanese Corporation Mélanges de différentes fibres

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3625809A (en) * 1970-02-24 1971-12-07 Owens Corning Fiberglass Corp Filament blend products
US4259394A (en) * 1979-09-26 1981-03-31 Huyck Corporation Papermaking fabrics with enhanced dimensional stability
DE4036926A1 (de) * 1990-11-20 1992-05-21 Basf Ag Verfahren zur herstellung von hybridgarn
US5227236A (en) * 1991-07-29 1993-07-13 Basf Aktiengesellschaft Process for preparing thermoplastic matrix fiber-reinforced prepregs and composite structure products formed thereby

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2105247A (en) * 1981-06-23 1983-03-23 Courtaulds Plc Process for making a fibre-reinforced moulding
EP0156599A1 (fr) * 1984-03-15 1985-10-02 BASF Aktiengesellschaft Mélange de fibres de carbone et de fibres thermoplastiques
EP0156600A1 (fr) * 1984-03-15 1985-10-02 Celanese Corporation Mélanges de différentes fibres

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0768405A1 (fr) * 1995-10-11 1997-04-16 Hoechst Trevira GmbH & Co. KG Tissu avec étanchéité réglable au gaz et/ou aux liquides comprenant des fils hybrides, procédé pour son traitement altérieur, structure textile avec étanchéité au gaz et/ou aux liquides prédéterminée et son utilisation
US5863644A (en) * 1995-10-11 1999-01-26 Hoechst Trevira Gmbh & Co Kg Woven and laid hybrid yarn structures of adjustable gas and/or liquid tightness, further processing thereof, textile sheet materials of predetermined gas and/or permeability, and use thereof
DE102007028373A1 (de) * 2007-06-11 2008-12-24 Technische Universität Dresden Faserverbundwerkstoff und Verfahren zur Herstellung von Faserverbundwerkstoffen
DE102007028373B4 (de) * 2007-06-11 2012-12-20 Technische Universität Dresden Faserverbundwerkstoff und Verfahren zur Herstellung von Faserverbundwerkstoffen
WO2011134995A1 (fr) * 2010-04-30 2011-11-03 Deutsche Institute Für Textil- Und Faserforschung Denkendorf Fil hybride pour la fabrication de pièces moulées
WO2023012226A3 (fr) * 2021-08-05 2023-06-08 Universität Stuttgart Composites fibres-matrice transparents structuraux et procédés de fabrication de ceux-ci

Also Published As

Publication number Publication date
EP0542070B1 (fr) 1996-07-10
US5464684A (en) 1995-11-07
DE4137406A1 (de) 1993-05-19
JPH05247761A (ja) 1993-09-24

Similar Documents

Publication Publication Date Title
EP0542070B1 (fr) Fil hybride de fibres en polyamide et de fibres de renforcement
DE3315360C2 (de) Schmelzklebende Fasern aus Polyethylen und deren Verwendung in Verbundfasern
DE60011310T2 (de) Ballistisches Material enthaltend hochfeste Polyethylenfasern
DE1660354A1 (de) Polypropylenverbundfaeden und Verfahren zu ihrer Herstellung
DE3935264A1 (de) Formmasse fuer thermoplastische verbundstoffe
EP0133893A2 (fr) Procédé pour la fabrication de corps moulés renforcés de fibres
DE3544523C2 (fr)
EP1705269B1 (fr) Matériau fibreux thermoplastique filé à partir d'une matière première contenant un polyhydroxyéther, son procédé de préparation et ses utilisations
DE4243465A1 (en) Hybrid yarn with polyamide and reinforcing fibres - has 5-20 micron polyamide filaments to give greater strength fabrics and consolidated composites
DE3408769A1 (de) Verfahren zur herstellung von faserverstaerkten formkoerpern und profilen
EP0173221B1 (fr) Fil polyester à haute résistance et procédé pour sa fabrication
EP0801159A2 (fr) Fils hybrides à faible retrait, méthode pour sa fabrication et son utilisation
DE69928741T2 (de) Armierungsgewebe für Bauwerke
EP0345463B1 (fr) Procédé pour préparer d'une façon continue des bandes thermoplastiques renforcées par des fibres, le produit obtenu et son application
DE2161967C3 (de) Verfahren zur Herstellung eines Drahtes aus hochmolekularen, linearen Polyestern
DE3539185A1 (de) Verfahren zur herstellung von polypropylen-faeden
EP2171138B1 (fr) Procédé de filage
DE69904361T3 (de) Hochorientierte polyolefinfaser
DE19533094B4 (de) Verfahren zur Herstellung eines Polymerverbundmaterials und polymeres Verbundmaterial
DE1479995C3 (de) Glasfaserhaltige gewebte Textilschicht zur Herstellung von Laminaten mit verbesserter innerer Haftung
EP0627301B1 (fr) Matériau composite renforcé par des fibres de verre et son procédé de fabrication
EP0630995A2 (fr) Fil de polyéthylène-naphtalate et procédé pour sa production
WO2020079121A1 (fr) Polyéthers aromatiques étirés
DE10237803B4 (de) Verbundwerkstoff aus Polypropylenverstärkung und Polypropylenmatrix sowie verschiedene Verfahren zu dessen Herstellung
DE2159358A1 (de) Faserverstärkte Harzverbundstoffe und Verfahren zu deren Herstellung

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): CH DE FR GB IT LI NL

17P Request for examination filed

Effective date: 19931118

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: CYTEC TECHNOLOGY CORP.

17Q First examination report despatched

Effective date: 19940729

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): CH DE FR GB IT LI NL

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: A. BRAUN, BRAUN, HERITIER, ESCHMANN AG PATENTANWAE

REF Corresponds to:

Ref document number: 59206735

Country of ref document: DE

Date of ref document: 19960814

ET Fr: translation filed
ITF It: translation for a ep patent filed

Owner name: MODIANO & ASSOCIATI S.R.L.

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19961010

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19991220

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20001031

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20001031

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20040915

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20040921

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20041004

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20041029

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 20051031

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20051031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060501

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060503

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20051031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060630

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20060501

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20060630