EP0432506B1 - Thermotransferfolie zur Direktbebilderung eines Druckformzylinders - Google Patents
Thermotransferfolie zur Direktbebilderung eines Druckformzylinders Download PDFInfo
- Publication number
- EP0432506B1 EP0432506B1 EP90121868A EP90121868A EP0432506B1 EP 0432506 B1 EP0432506 B1 EP 0432506B1 EP 90121868 A EP90121868 A EP 90121868A EP 90121868 A EP90121868 A EP 90121868A EP 0432506 B1 EP0432506 B1 EP 0432506B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- thermal transfer
- layer
- transfer foil
- substance
- foil according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007639 printing Methods 0.000 title claims description 24
- 239000011888 foil Substances 0.000 title claims 9
- 239000000126 substance Substances 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 13
- 239000000758 substrate Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 238000005187 foaming Methods 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 4
- 238000003384 imaging method Methods 0.000 claims description 4
- 229920001169 thermoplastic Polymers 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000003380 propellant Substances 0.000 claims 1
- 239000012815 thermoplastic material Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 4
- 239000004604 Blowing Agent Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C1/00—Forme preparation
- B41C1/10—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
- B41C1/1091—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by physical transfer from a donor sheet having an uniform coating of lithographic material using thermal means as provided by a thermal head or a laser; by mechanical pressure, e.g. from a typewriter by electrical recording ribbon therefor
Definitions
- the invention relates to a thermal transfer film for the direct imaging of a printing form cylinder by means of a pixel transfer unit working with selective heat transfer according to the preamble of patent claim 1.
- the invention has for its object to develop a generic thermal transfer film so that this distance and pressure fluctuations between thermal print head and printing form cylinder surface compensates.
- This object is achieved in that a layer of foamable material is arranged between the film substrate and the fusible substance, the response temperature for the foaming process is greater than the melting temperature of the substance.
- a thermal transfer film denoted overall by 4, is drawn between a printing form cylinder 1 and an image transfer unit 3 equipped with a plurality of individually activatable heating elements 2 by means of a transport device consisting of two coils 5, 6.
- a layer 8 of material that can be foamed under the action of heat is arranged between substrate 9 and fusible substance 7, the response temperature for the foaming process being greater than the melting temperature of substance 7.
- a separating layer 10 is additionally arranged between a layer 8 'of foamable material and a layer 7 of a fusible substance 7', which promotes the detachment of the molten substance 7 '.
- the carrier layer 9 is made of a material which is dimensionally stable in the longitudinal and transverse directions and is only slightly compressible in thickness and has good thermal conductivity.
- the layer 8 made of foamable material consists for example of a thermoplastic or a mixture containing a thermoplastic, and a blowing agent.
- the blowing agent concentration is 0.3-1.5%, preferably 0.6-1%.
- the mass is spread onto the substrate 9, e.g. Polyethylene glycol terephthalic acid ester film, applied as layer 8 of 0.002-0.01 mm, preferably 0.002-0.004 mm, in thickness.
- a layer 8 with a defined moisture content e.g. 200 g of cellulose (molecular weight 1100) are stirred into 1 l of water with the addition of 0.01% carboxymethyl cellulose (degree of substitution 0.5).
- the mixture is brought to pH 6 with NAOH and mixed in a ball mill for 3 hours.
- the mixture as layer 8 is coated onto a polyester film hydrophilized by corona discharge as substrate 9 and knife-coated. After predrying with hot air to about 60% dye content, the film coated in this way is brought to 3-4% residual moisture via press and drying rollers and subsequent hot air treatment. The residual moisture is then set to 8% in a spray system.
- the finished layer 8 has a thickness of 6 microns.
- An oleophilic layer 8 of dispersion as described above can then be applied in a prescribed manner.
- the separating layer 10 has good non-stick properties on the side facing the coating 7 in order to facilitate the detachment of molten substance parts.
- the meltable substance has oleophilic properties.
- the printing form cylinder 1 in the unimaged state, has a surface with a continuously hydrophilic property.
- Plasma or flame sprayed ceramic or metallic surfaces such as chrome, copper, etc., which, owing to its surface roughness, exert a greater adhesive force on the molten substance 7, 7 'than the layers 8 or 10.
- the pixel transmission unit 3 receives data for an illustration of the printing form cylinder 1 from a memory (not shown). According to this data, the heating elements 2 opposite each other on the back of the thermal transfer film 4 are heated by supplying energy at the level of the image-guiding parts of the printing form cylinder 1. The heat given off by the head of the heating elements 2 successively penetrates the substrate 9 or 9 ', the layer 8 or 8', the separating layer 10 which may be present and melts a narrowly defined area out of the substance 7, 7 '.
- part 7 a of the substance 7 is accepted by the cold surface of the printing form cylinder 1 and solidifies there.
- the substance parts 7 a mark the color-guiding image areas on the surface of the printing form cylinder 1 due to their oleophilic property during later printing.
- the temperature continues to rise until the response temperature of the layer 8, 8' is reached.
- the layer 8, 8 'foams interrupts the further supply of heat due to its increased strength, which is essentially due to air bubbles formed during foaming with poor thermal conductivity, and at the same time presses the molten substance 7, 7' against the surface of the printing form cylinder 1 where it sticks and freezes.
- gas or water vapor bubbles form, the effect of which is analogous to that of the foamed layer 7.
- the water vapor bubble is re-formed each time it cools down, the water condenses out, so that there is the additional advantage here shows that the rewound film has no bumps and is easier to handle.
- the sharpness of the contour of the image areas marked on the surface of the printing form cylinder 1 is not the edge sharpness of the foaming area, but the edge sharpness of the melted area in the substance 7, 7 'is decisive.
- the foamable intermediate layer 8 can also be used to advantageously compensate for larger dimensional deviations of all components involved in the range up to about one millimeter.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Optics & Photonics (AREA)
- Manufacturing & Machinery (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Manufacture Or Reproduction Of Printing Formes (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3941303 | 1989-12-14 | ||
DE3941303A DE3941303C1 (enrdf_load_stackoverflow) | 1989-12-14 | 1989-12-14 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0432506A2 EP0432506A2 (de) | 1991-06-19 |
EP0432506A3 EP0432506A3 (en) | 1991-10-16 |
EP0432506B1 true EP0432506B1 (de) | 1994-09-21 |
Family
ID=6395458
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90121868A Expired - Lifetime EP0432506B1 (de) | 1989-12-14 | 1990-11-15 | Thermotransferfolie zur Direktbebilderung eines Druckformzylinders |
Country Status (5)
Country | Link |
---|---|
US (1) | US5382964A (enrdf_load_stackoverflow) |
EP (1) | EP0432506B1 (enrdf_load_stackoverflow) |
JP (1) | JP2999243B2 (enrdf_load_stackoverflow) |
CA (1) | CA2027332C (enrdf_load_stackoverflow) |
DE (2) | DE3941303C1 (enrdf_load_stackoverflow) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5881645A (en) * | 1992-09-10 | 1999-03-16 | Lenney; John Richard | Method of thermally spraying a lithographic substrate with a particulate material |
DE4342954C2 (de) * | 1993-12-16 | 1998-01-22 | Roland Man Druckmasch | Verfahren zum Herstellen und Löschen einer löschbaren Hochdruckform, Vorrichtung zur Durchführung des Verfahrens und deren Verwendung |
EP0737133B1 (de) * | 1993-12-27 | 1998-07-29 | Hoechst Aktiengesellschaft | Thermisches auftragsverfahren für hydrophile schichten auf hydrophoben substraten und verwendung so beschichteter substrate als trägerkörper für offsetdruckplatten |
US5816161A (en) * | 1994-07-22 | 1998-10-06 | Man Roland Druckmaschinen Ag | Erasable printing plate having a smooth pore free metallic surface |
US5819661A (en) * | 1995-01-23 | 1998-10-13 | Presstek, Inc. | Method and apparatus for laser imaging of lithographic printing members by thermal non-ablative transfer |
GB2334727A (en) | 1998-02-28 | 1999-09-01 | Horsell Graphic Ind Ltd | Planographic printing member |
DE19937478B4 (de) * | 1999-08-07 | 2004-08-19 | Man Roland Druckmaschinen Ag | Thermotransferfolie zur laserinduzierten Beschichtung einer Metalloberfläche |
JP3422754B2 (ja) * | 2000-05-31 | 2003-06-30 | 三菱重工業株式会社 | 印刷用版材の作製方法、再生方法及び印刷機 |
DE10054284B4 (de) * | 2000-11-02 | 2010-04-08 | Manroland Ag | Verfahren zur Behandlung einer löschbaren lithographischen Druckform |
DE10063819B4 (de) * | 2000-12-21 | 2006-02-02 | Man Roland Druckmaschinen Ag | Maskenerstellung zur Herstellung einer Druckform |
DE102008043582A1 (de) * | 2008-11-07 | 2010-05-12 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von 6-Chlorodibenzo(d,f) (1,3,2)-dioxaphosphepin |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3248178C2 (de) * | 1982-12-27 | 1987-02-19 | Forschungsgesellschaft Druckmaschinen E.V., 6000 Frankfurt | Bildmäßige Beschichtung von Druckformen für den Flachdruck |
US4565737A (en) * | 1983-05-02 | 1986-01-21 | Canon Kabushiki Kaisha | Heat-sensitive transfer material |
JPS6141547A (ja) * | 1984-08-02 | 1986-02-27 | Toppan Printing Co Ltd | 印刷版の製造方法 |
JPS61110593A (ja) * | 1984-11-02 | 1986-05-28 | Canon Inc | 感熱転写材 |
JPS61162392A (ja) * | 1985-01-11 | 1986-07-23 | Alps Electric Co Ltd | 感熱転写媒体 |
JPS63751A (ja) * | 1986-06-20 | 1988-01-05 | Fujitsu Ltd | プリフエツチ制御方式 |
JPS6360751A (ja) * | 1986-09-01 | 1988-03-16 | Matsushita Electric Ind Co Ltd | 印刷用マスタ−及びその製造方法 |
JPS63214481A (ja) * | 1987-03-02 | 1988-09-07 | Canon Inc | 感熱転写材 |
US4897310A (en) * | 1987-12-15 | 1990-01-30 | Siemens Aktiengesellschaft | Inking ribbon for transferring color under the influence of heat |
DE3834270A1 (de) * | 1988-10-08 | 1990-04-12 | Roland Man Druckmasch | Verfahren zur herstellung von druckformen |
US5191834A (en) * | 1988-10-14 | 1993-03-09 | Man Roland Druckmaschinen Ag | Printing system with printing form having a ferro-electric layer |
US5072671A (en) * | 1988-11-09 | 1991-12-17 | Man Roland Druckmaschinen Ag | System and method to apply a printing image on a printing machine cylinder in accordance with electronically furnished image information |
-
1989
- 1989-12-14 DE DE3941303A patent/DE3941303C1/de not_active Expired - Lifetime
-
1990
- 1990-10-11 CA CA002027332A patent/CA2027332C/en not_active Expired - Lifetime
- 1990-11-15 DE DE59007252T patent/DE59007252D1/de not_active Expired - Lifetime
- 1990-11-15 EP EP90121868A patent/EP0432506B1/de not_active Expired - Lifetime
- 1990-11-29 JP JP2326129A patent/JP2999243B2/ja not_active Expired - Lifetime
-
1992
- 1992-09-11 US US07/949,271 patent/US5382964A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0432506A2 (de) | 1991-06-19 |
CA2027332C (en) | 1996-10-15 |
US5382964A (en) | 1995-01-17 |
EP0432506A3 (en) | 1991-10-16 |
JPH03189151A (ja) | 1991-08-19 |
JP2999243B2 (ja) | 2000-01-17 |
DE3941303C1 (enrdf_load_stackoverflow) | 1990-12-13 |
CA2027332A1 (en) | 1991-06-15 |
DE59007252D1 (de) | 1994-10-27 |
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