EP0411282B1 - Verwendung von ausscheidungshärtenden ferritisch-perlitischen (AFP -) Stählen als Werkstoff für Gaswechselventile von Verbrennungsmotoren - Google Patents
Verwendung von ausscheidungshärtenden ferritisch-perlitischen (AFP -) Stählen als Werkstoff für Gaswechselventile von Verbrennungsmotoren Download PDFInfo
- Publication number
- EP0411282B1 EP0411282B1 EP90110888A EP90110888A EP0411282B1 EP 0411282 B1 EP0411282 B1 EP 0411282B1 EP 90110888 A EP90110888 A EP 90110888A EP 90110888 A EP90110888 A EP 90110888A EP 0411282 B1 EP0411282 B1 EP 0411282B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- valves
- steels
- combustion engines
- steel
- valve
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title claims description 39
- 239000010959 steel Substances 0.000 title claims description 39
- 239000000463 material Substances 0.000 title claims description 15
- 238000002485 combustion reaction Methods 0.000 title claims description 5
- 238000004881 precipitation hardening Methods 0.000 title claims description 3
- 239000007789 gas Substances 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 238000003723 Smelting Methods 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 239000005864 Sulphur Substances 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 239000004411 aluminium Substances 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- 239000012535 impurity Substances 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 229910052748 manganese Inorganic materials 0.000 claims 2
- 239000011572 manganese Substances 0.000 claims 2
- 229910052758 niobium Inorganic materials 0.000 claims 2
- 239000010955 niobium Substances 0.000 claims 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910019974 CrSi Inorganic materials 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000005261 decarburization Methods 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910000734 martensite Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
- F01L3/00—Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
- F01L3/02—Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
Definitions
- the invention relates to the use of precipitation hardening ferritic-pearlitic steels, so-called AFP steels, as a material for gas exchange valves of internal combustion engines.
- Gas exchange valves are intake and exhaust valves in internal combustion engines that regulate the gas exchange in the engine and seal the working area of the cylinder to the outside.
- FIG. 1 (1) V. editor, T. Kreul, S. Engineer: "Precious structural steels in automobiles", Thyssen Technical Reports 2 (1986), pp. 233-240
- valve manufacturers take into account the different material properties of the valve materials when designing the differently loaded valves.
- lightly loaded inlet valves as single-metal valves (“mono valves") are often made from steel 1.4718 (x 45 CrSi 93).
- tempered, ground rods are partially conductively heated and at the same time compressed in a pear shape. Then the valve plate is forged in the die, then tempered or tempered and finally the final machining takes place.
- the valve manufacturer is often forced to combine valve materials with one another in a sensible manner. As shown in Fig. 1 using the example of a bimetal valve, e.g.
- valve disc made of steel 1.4871 (X 53 CrMnNi N 21 9) with a steel 1.4718 (X 45 CrSi 93) the high heat resistance and hot gas corrosion resistance of the hardenable austenitic steel can be combined with the high wear resistance and the good sliding properties of the hardenable martensitic steel.
- valve materials made of steel 1.4718 (X 45 CrSi 9 3) or modifications are made for intake valves and low-stress exhaust valves and for stems of intake and exhaust bimetallic valves.
- These steels are processed by the steel manufacturer and valve manufacturer in accordance with the main production sequences as shown in FIGS. 2 and 3.
- the invention is based on the object, instead of the previously used martensitic carbide steels, which have to be heat-treated several times according to the production sequence both for the steel producer and for the valve manufacturer, to use steels which achieve the required valve properties without heat treatment as far as possible and require less machining effort.
- AFP steels both after rolling to wire and after upsetting and drop forging with controlled cooling of hot-forming temperature in air (“state BY”), have mechanical-technological values which are comparable to those of steel 1.4718.
- Table 1 shows the chemical composition
- Table 2 and Fig. 4 the strength properties at room temperature and elevated temperatures.
- Table 3 and Fig. 5 indicate the creep rupture strength of the comparison materials 1.4718 (X 45 CrSi 9 3) and an AFP steel.
- AFP steels in the BY condition are a sensible alternative to the well-known steel 1.4718.
- the intake valves made from the AFP steel to be used according to the invention at a valve manufacturer were cooled in still air after upsetting and drop forging and tested in engine test benches without tempering and other heat treatment. The results found are also positive and sufficient compared to the previously used steel 1.4718.
- Steels to be used according to the invention have the advantage over the materials previously used for gas exchange valves that they can be simplified according to the production sequences shown in FIGS. 6 and 7 and can thus be produced more cost-effectively.
- the first thing that is noticeable when using AFP steels is the absence of heat treatments at the steelmaker and valve manufacturer.
- the lower crack and decarburization sensitivity of AFP steels compared to steel 1.4718 and the lack of decarburization due to the absence of heat treatment processes mean that the semi-finished product that is required today for further rolling in steel 1.4718 due to partial stain grinding on AFP steels be replaced.
- the machining allowance for centerless grinding of bar steel can be reduced or even saved entirely by using drawn bars instead of ground bars in AFP steels as the raw material for the production of gas exchange valves.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Catalysts (AREA)
- Output Control And Ontrol Of Special Type Engine (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT90110888T ATE93549T1 (de) | 1989-06-09 | 1990-06-08 | Verwendung von ausscheidungshaertenden ferritisch- perlitischen (afp -) staehlen als werkstoff fuer gaswechselventile von verbrennungsmotoren. |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3918869 | 1989-06-09 | ||
DE3918869 | 1989-06-09 | ||
DE4014072A DE4014072A1 (de) | 1989-06-09 | 1990-05-02 | Verwendung von ausscheidungshaertenden ferritisch-perlitischen (afp-)staehlen als werkstoff fuer gaswechselventile von verbrennungsmotoren |
DE4014072 | 1990-05-02 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0411282A2 EP0411282A2 (de) | 1991-02-06 |
EP0411282A3 EP0411282A3 (en) | 1991-07-31 |
EP0411282B1 true EP0411282B1 (de) | 1993-08-25 |
Family
ID=25881758
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90110888A Expired - Lifetime EP0411282B1 (de) | 1989-06-09 | 1990-06-08 | Verwendung von ausscheidungshärtenden ferritisch-perlitischen (AFP -) Stählen als Werkstoff für Gaswechselventile von Verbrennungsmotoren |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0411282B1 (ko) |
JP (1) | JP2820776B2 (ko) |
KR (1) | KR0151154B1 (ko) |
CA (1) | CA2018636C (ko) |
DE (2) | DE4014072A1 (ko) |
ES (1) | ES2045652T3 (ko) |
FI (1) | FI96327C (ko) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4109628C2 (de) * | 1990-07-12 | 1997-04-17 | Mahle Gmbh | Verwendung eines ausscheidungshärtenden ferritisch perlitischen Stahls |
DE4137240A1 (de) * | 1991-11-13 | 1993-05-19 | Thyssen Edelstahlwerke Ag | Verwendung von afp-staehlen fuer die herstellung von werkzeugen |
DE4341811A1 (de) * | 1993-12-08 | 1995-06-14 | Man B & W Diesel Ag | Gaswechselventil für eine Brennkraftmaschine |
DE4343565C1 (de) * | 1993-12-21 | 1995-06-08 | Ver Schmiedewerke Gmbh | Verfahren zur Herstellung von Schienenrädern und Schienenradteilen |
DE4406896C1 (de) * | 1994-03-03 | 1995-06-29 | Daimler Benz Ag | Verfahren zum Härten von Einmetall-Ventilen, insbesondere von Einlaßventilen für Brennkraftmaschinen |
DE19618477C2 (de) * | 1996-05-08 | 2000-08-03 | Trw Deutschland Gmbh | Herstellungsverfahren für ein nitriertes Bimetallventil |
DE10029299C2 (de) * | 2000-06-14 | 2003-03-27 | Daimler Chrysler Ag | Mehrteilig zusammengesetztes Ventil für Hubkolbenmaschinen |
DE10031927A1 (de) * | 2000-06-30 | 2002-01-24 | Daimler Chrysler Ag | Mehrteilig zusammengesetztes Leichtbauventil für Hubkolbenmaschinen |
DE10037132A1 (de) * | 2000-07-31 | 2002-02-14 | Volkswagen Ag | Tellerventil und Verfahren zum Herstellen eines Tellerventils |
DE102007021101A1 (de) * | 2007-05-03 | 2008-11-06 | Mahle International Gmbh | Legierter Stahl und dessen Verwendung |
DE102007026018B4 (de) | 2007-06-04 | 2023-01-19 | Scania Cv Ab | Bimetallventil mit einem kegelstumpfförmig ausgebildeten Bereich des Ventilschafts |
DE102008061237A1 (de) * | 2008-12-09 | 2010-06-10 | Man Diesel Se | Gaswechselventil und Verfahren zu seiner Herstellung |
DE102013210897A1 (de) * | 2013-06-11 | 2014-12-11 | Mahle International Gmbh | Verfahren zur Herstellung eines gebauten Hohlventils einer Brennkraftmaschine |
CN107514316A (zh) * | 2015-05-18 | 2017-12-26 | 夏志清 | 一种柴油发动机气缸盖 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1007175A (en) * | 1961-07-05 | 1965-10-13 | Trafik Ab | Alloys |
GB1101193A (en) * | 1966-01-21 | 1968-01-31 | United Steel Companies Ltd | Steel |
US3846184A (en) * | 1968-08-06 | 1974-11-05 | Bethlehem Steel Corp | Wear resistant steel |
US3562028A (en) * | 1968-08-28 | 1971-02-09 | Inland Steel Co | Tough,high strength steel article |
JPS5845354A (ja) * | 1981-09-10 | 1983-03-16 | Daido Steel Co Ltd | はだ焼鋼 |
JPS62274051A (ja) * | 1986-05-21 | 1987-11-28 | Kobe Steel Ltd | 耐疲労性、耐へたり性に優れた弁ばね用鋼線 |
DE3719569C2 (de) * | 1986-07-05 | 1988-06-23 | Thyssen Edelstahlwerke Ag | Mikrolegierte Stähle. |
JPS6468424A (en) * | 1987-09-07 | 1989-03-14 | Kobe Steel Ltd | Production of high-toughness non-tempered hot forging having excellent fatigue resistance and machinability |
-
1990
- 1990-05-02 DE DE4014072A patent/DE4014072A1/de active Granted
- 1990-06-08 CA CA002018636A patent/CA2018636C/en not_active Expired - Lifetime
- 1990-06-08 DE DE90110888T patent/DE59002456D1/de not_active Expired - Lifetime
- 1990-06-08 EP EP90110888A patent/EP0411282B1/de not_active Expired - Lifetime
- 1990-06-08 ES ES90110888T patent/ES2045652T3/es not_active Expired - Lifetime
- 1990-06-09 KR KR1019900008591A patent/KR0151154B1/ko not_active IP Right Cessation
- 1990-06-11 JP JP2152484A patent/JP2820776B2/ja not_active Expired - Lifetime
- 1990-06-11 FI FI902899A patent/FI96327C/fi active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
FI902899A0 (fi) | 1990-06-11 |
FI96327B (fi) | 1996-02-29 |
DE4014072C2 (ko) | 1991-12-05 |
KR0151154B1 (ko) | 1998-11-16 |
EP0411282A2 (de) | 1991-02-06 |
JP2820776B2 (ja) | 1998-11-05 |
CA2018636C (en) | 2000-10-24 |
DE4014072A1 (de) | 1990-12-20 |
CA2018636A1 (en) | 1990-12-09 |
ES2045652T3 (es) | 1994-01-16 |
FI96327C (fi) | 1996-06-10 |
DE59002456D1 (de) | 1993-09-30 |
JPH03219045A (ja) | 1991-09-26 |
KR910001081A (ko) | 1991-01-30 |
EP0411282A3 (en) | 1991-07-31 |
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