EP0332702A1 - Procede pour obtenir une image en relief sur un support - Google Patents
Procede pour obtenir une image en relief sur un support Download PDFInfo
- Publication number
- EP0332702A1 EP0332702A1 EP88901156A EP88901156A EP0332702A1 EP 0332702 A1 EP0332702 A1 EP 0332702A1 EP 88901156 A EP88901156 A EP 88901156A EP 88901156 A EP88901156 A EP 88901156A EP 0332702 A1 EP0332702 A1 EP 0332702A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- relief
- liquid dispersion
- image
- base
- destabilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims abstract description 106
- 239000006185 dispersion Substances 0.000 claims abstract description 85
- 239000000203 mixture Substances 0.000 claims abstract description 75
- 239000007788 liquid Substances 0.000 claims abstract description 62
- 239000012528 membrane Substances 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 28
- 239000002562 thickening agent Substances 0.000 claims description 10
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 7
- 230000008447 perception Effects 0.000 claims description 6
- 239000003792 electrolyte Substances 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 239000004815 dispersion polymer Substances 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- 238000007639 printing Methods 0.000 abstract description 42
- 230000008021 deposition Effects 0.000 abstract 1
- 230000000368 destabilizing effect Effects 0.000 abstract 1
- 239000002585 base Substances 0.000 description 43
- 238000004519 manufacturing process Methods 0.000 description 23
- 239000000123 paper Substances 0.000 description 23
- 230000035515 penetration Effects 0.000 description 12
- 238000007650 screen-printing Methods 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 11
- 239000000843 powder Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 8
- 239000004744 fabric Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- -1 casein alkali salts Chemical class 0.000 description 6
- 238000007646 gravure printing Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000008399 tap water Substances 0.000 description 6
- 235000020679 tap water Nutrition 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000007664 blowing Methods 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000003655 tactile properties Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 150000004804 polysaccharides Chemical class 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229920006051 Capron® Polymers 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 210000003484 anatomy Anatomy 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000036512 infertility Effects 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 150000004812 organic fluorine compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/02—Dusting, e.g. with an anti-offset powder for obtaining raised printing such as by thermogravure ; Varnishing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/16—Braille printing
Definitions
- the invention relates to methods for producing individual types of printed matter and, in particular, to a method for forming relief images on a basis.
- Disadvantages of the known methods for the production of relief include a large amount of energy which is required to deform the base material and an absolute impossibility of use in cases where a base material cannot tolerate deformation due to its low strength or if a deformation of the functionality of a product, e.g. Membranes, can interfere.
- the flat relief image is applied by application in the process for forming relief images on a base, which comprises the execution of a flat relief image on a base and a subsequent treatment of the base and image by means of a composition which contains a relief-forming material at least once executes at least one composition which contains a destabilizer of a liquid dispersion, and the base and image are treated by means of a liquid dispersion whose disperse phase serves as a relief-forming material.
- an aqueous polymer dispersion as the liquid dispersion. Natural, synthetic and artificial polymers and mixtures thereof are used as polymers in this process.
- a disperse phase can be both polymers belonging to elastomers and hardened polymers as well as their mixtures. Thanks to this fact, it is possible to give a relief-forming material the broadest spectrum of chemical, physical and mechanical properties confer, whereby the functional and usage properties of the products are determined with relief images.
- the elastomers used as relief-forming substances ensure such properties of the relief image as elasticity and flexibility.
- the polymers, which are in a hardened state ensure such properties of the relief image as hardness, smoothness and wear resistance. It is expedient to use a mixture of the said polymers, which reduces the brittleness and prevents the relief image from bursting in the course of its shrinkage on a rigid basis.
- composition with a destabilizer is given rheological properties that correspond to the operating modes of the printing technology, e.g. correspond to a screen printing
- a thickener is also an adhesive which improves the connection of the shaped relief to the print carrier.
- a thickener can also act as a depot that extends destabilizer excretion into the dispersion.
- the finished product has relief elements with a height of 0.5, 0.8 or 1.2 mm.
- a polybutadiene styrene dispersion with a disperse phase content of 25% by mass is used as the liquid dispersion.
- the holding time of the base with the image in the dispersion is 1 minute.
- the base with the shaped relief is then rinsed with tap water over a period of 5 minutes until the dispersion is removed from the penetration points and allowed to dry at 125 ° C. for 30 minutes.
- the product obtained has relief points with a height of 0.9 mm.
- the product is produced similarly to Example 2, but a dispersion of a polypropylene benzene solution in dimethylformamide with a disperse phase content of 20% by mass is used as the liquid dispersion.
- the finished product has relief points with a height of 0.3 mm.
- the composition with a destabilizer and the liquid dispersion described in Example 2 are used in the production of decorative products.
- the relief image is carried out using a composition with a destabilizer using a flow master and allowed to air dry at room temperature for 2 hours, after which the relief image is again carried out on the corresponding image parts using the same composition using the destabilizer and dried the air at room temperature over the course of 2 hours, after which the relief image on the corresponding parts of the image is carried out for the third time using the same composition using the destabilizer and is dried in the air over the course of 2 hours. Then hold the base with the image in the liquid dispersion for 70 seconds.
- the base with the shaped relief is then rinsed with tap water over a period of 5 minutes until the dispersion is removed from the penetration points and allowed to dry at 125 ° C. for 30 minutes.
- An ornamental product (a map) is obtained with relief images which have different height values of 0.6 mm, 1.0 mm and 1.3 mm. The product is colored and varnished.
- the third part of the picture on the basis is carried out by the following composition (in mass%):
- the proposed invention makes it possible to produce Braille printed matter for the blind.
- the relief images obtained by the method according to the invention are of high quality with regard to tactical perception.
- the relief fillets and the variety of possible surface properties, which include roughness and smoothness, hardness and softness, choice of height, color, sterility, adhesive strength on the basis and other properties are ensured by a broad spectrum of polymers that exist in the form of a liquid dispersion .
- composition can be given a different kind of rheological characteristics with a destabilizer of the liquid dispersion, which can give a flat relief image using any known means, not only using polygraphic methods, but also with the help of a spring, a flow master, one Permit drawing spring or an atomizer.
Landscapes
- Printing Methods (AREA)
- Materials For Photolithography (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Le procédé décrit consiste à imprimer un dessin plat de l'image sur le support au moins une fois et au moyen d'au moins une composition renfermant un déstabilisant de dispersion liquide, et à traiter ensuite le support revêtu du dessin plat au moyen d'une dispersion liquide. L'image en relief se forme par dépôt de la phase dispersée provenant de la dispersion.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/SU1987/000088 WO1989001830A1 (fr) | 1987-08-24 | 1987-08-24 | Procede pour obtenir une image en relief sur un support |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0332702A1 true EP0332702A1 (fr) | 1989-09-20 |
| EP0332702A4 EP0332702A4 (fr) | 1990-06-05 |
Family
ID=21617127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19880901156 Ceased EP0332702A4 (fr) | 1987-08-24 | 1987-08-24 | Procede pour obtenir une image en relief sur un support. |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0332702A4 (fr) |
| JP (1) | JPH02501202A (fr) |
| BR (1) | BR8707860A (fr) |
| FI (1) | FI891911L (fr) |
| WO (1) | WO1989001830A1 (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100144651A1 (en) | 2005-07-07 | 2010-06-10 | Aditech Pharma Ab | Novel glucopyranose esters and glucofuranose esters of alkyl- fumarates and their pharmaceutical use |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1546280A (en) * | 1923-11-20 | 1925-07-14 | Belin Edouard | Process and apparatus for treating inked documents |
| GB524121A (en) * | 1938-02-09 | 1940-07-30 | Interchem Corp | Improvements in or relating to the setting of wet films of filmforming compositions,such as printing inks |
| DE1102775B (de) * | 1959-04-10 | 1961-03-23 | Fritz Busche Druckereigesellsc | Verfahren zur Herstellung von polyesterbeschichteten Druckerzeugnissen |
| CA1024014A (fr) * | 1973-08-03 | 1978-01-10 | Roger F. Bartholomew | Enduits protecteurs pour les articles de beta-spodumene |
| SU1000301A1 (ru) * | 1982-01-05 | 1983-02-28 | Киевский Филиал По Специальным Видам Печати Всесоюзного Научно-Исследовательского Института Комплексных Проблем Полиграфии | Композици дл печатного тампона |
| SU1286440A1 (ru) * | 1984-10-23 | 1987-01-30 | Московский Лесотехнический Институт | Способ изготовлени декоративной панели с рельефной поверхностью |
-
1987
- 1987-08-24 JP JP62506302A patent/JPH02501202A/ja active Pending
- 1987-08-24 EP EP19880901156 patent/EP0332702A4/fr not_active Ceased
- 1987-08-24 FI FI891911A patent/FI891911L/fi not_active Application Discontinuation
- 1987-08-24 WO PCT/SU1987/000088 patent/WO1989001830A1/fr not_active Ceased
- 1987-08-24 BR BR8707860A patent/BR8707860A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FI891911A7 (fi) | 1989-04-21 |
| WO1989001830A1 (fr) | 1989-03-09 |
| FI891911A0 (fi) | 1989-04-21 |
| JPH02501202A (ja) | 1990-04-26 |
| FI891911L (fi) | 1989-04-21 |
| BR8707860A (pt) | 1989-10-31 |
| EP0332702A4 (fr) | 1990-06-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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