EP0331215B1 - A process for laminating textiles - Google Patents
A process for laminating textiles Download PDFInfo
- Publication number
- EP0331215B1 EP0331215B1 EP89200041A EP89200041A EP0331215B1 EP 0331215 B1 EP0331215 B1 EP 0331215B1 EP 89200041 A EP89200041 A EP 89200041A EP 89200041 A EP89200041 A EP 89200041A EP 0331215 B1 EP0331215 B1 EP 0331215B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- adhesive
- textile web
- sprayed
- textiles
- wadding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004753 textile Substances 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 19
- 238000010030 laminating Methods 0.000 title claims abstract description 5
- 239000000853 adhesive Substances 0.000 claims abstract description 33
- 230000001070 adhesive effect Effects 0.000 claims abstract description 33
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims abstract description 6
- 239000012298 atmosphere Substances 0.000 claims abstract description 4
- 239000012948 isocyanate Substances 0.000 claims abstract description 4
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 4
- 238000003475 lamination Methods 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 abstract description 6
- 238000005507 spraying Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000007921 spray Substances 0.000 abstract description 2
- 239000003292 glue Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 208000032170 Congenital Abnormalities Diseases 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000001605 fetal effect Effects 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 201000006747 infectious mononucleosis Diseases 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
- D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
- D06M17/10—Polyurethanes polyurea
Definitions
- the present invention concerns a process of the type defined in the introductory portion of claim 1 for laminating textiles, and the process of the invention is characterized by the features defined in the characterizing portion of claim 1.
- Laminated textiles for the above-mentioned purposes frequently consist of a textile web to which there is adhered a layer of natural or synthetic wadding, or of two textile webs between which a layer of wadding may be placed.
- Such laminates are produced by machine bonding the individual layers with a suitable adhesive.
- the adhesive used is often a solvent-based polyurethane, where the mixture of polyurethane and solvent contains up to 90% solvent to ensure a consistency which makes the adhesive suitable for spraying with spray guns.
- Even with the most effective suction systems it is impossible in practice to avoid occurrence of unhealthy concentrations of the solvent (most frequently ethyl acetate) in the air during the process, and these high concentrations involve various physical troubles, such as air passage irritation, dizziness, headache and at worst concentration and memory problems. To this should be added pregnant women's potential risk of embryonic or fetal deformities.
- the produced product bears the stamp of the intensive solvent treatment because the smell of the solvent sticks to the fabric for a long time and is often difficult to wash out.
- tissue of high density polyethylene or polypropylene.
- the tissue may also be produced from other polymers or polymer mixtures.
- the polymer serves as a hot melt adhesive when - interposed between the webs to be laminated - it is moved through a roller system under controlled pressure.
- the process is desirable from an environmental point of view because no vapours are released during the passage through the roller system, and the process can moreover be performed easily and rapidly, but it is vitiated by the drawback that an adequately strong tissue is necessary to ensure sufficient washing fastness of the finished laminate. If a tissue is used which is strong enought to ensure good washing fastness, the result will be a too stiff product which is inconvenient to wear.
- powdered adhesives most frequently in the form of polyamides, polyesters, low or high pressure polyethylenes, ethylene vinyl acetate copolymers or various mixed polymerisates.
- the powdered adhesive is sprinkled over the textile web, which is then moved through a heating tunnel to melt the powder.
- the web provided with adhesive is joined with the second web in a calender roller system.
- the adhesive is a moist curing mono-component polyurethane prepolymer which is sprayed on the textile web under essentially anhydrous conditions. After the textile web coated with adhesive has been joined with a web of wadding and after rolling-up of the resulting laminate, the laminate is allowed to cure in an atmosphere of normal moisture to provide a product having extremely good properties.
- the advantage of using an adhesive of this type is primarily that polyurethane melt adhesives can be used without any form of solvent. Secondly, such adhesives may be used in considerably smaller amounts than other melt adhesives.
- the process of the invention uses just 1 to 3 g of adhesive per m2 , where other melt adhesives are to be used in amounts of up to 10 to 20 g per m2 to provide sufficient washing fastness. So large amounts of adhesive make the laminate stiff and unelastic, whereas the process of the invention results in a pliable and elastic laminate which also has excellent washing features.
- Adhesives of the type used in the process of the invention have been known for some time. Thus, they have been used for one-sided gluing of plane objects of various foam materials and in other forms of gluing where only minor tensions occur. Moreover, they may be applied to wood, metal and many plastic material, just as they can replace contact glue in many cases.
- a very suitable adhesive for the purpose is TivoMelt 9600/41 from Tivoli Werke AG, Hamburg.
- This adhesive is a moist curling polyurethane prepolymer of the hot melt type. It contains maximum 1.5% free isocyanate (NCO) and no solvent, i.e. the content of dry matter is 100%.
- NCO free isocyanate
- the viscosity is around 9000 mPa.s at 130 °C, the density is about 1.1 and the softening point (ring/ball) is 45 °C.
- the flash point of the product is above 200 °C.
- the process of the invention makes no special requirements as to the type of the wadding and textile material used, except that silicone treated (water repelling) textiles are not suitable since the glue exhibits poor adhesion to such materials.
- silicone treated (water repelling) textiles When pure, i.e. non-impregnated textiles, are involved, these may be both natural and synthetic.
- the wadding which may e.g. be of cotton or polyester.
- the figure shows a machine for the use in the performance of the process of the invention.
- the textile web is unwound from a supply 1 and passed via a roller system 2 to the spraying station 3 where the adhesive is sprayed on the textile web by means of a plurality of nozzles 4 under pressure and at a temperature carefully determined by means of a thermostat, said textile web being supported by an endless carrier band 5 which rotates about a roller system 6.
- the wadding is unwound continuously from the supply roll 7, the accumulation region 8 ensuring that the web can be directed evenly to the pair of rollers 9 in which it is joined with the textile web coated with glue.
- the nozzles ensure moist-free conditions, e.g. by maintaining a carbonic acid pressure in the tank, to prevent premature curing.
- the laminated web is passed to a take-up device 10 and is allowed to cure after winding-up in normal moist atmosphere for about 24 hours.
- the result is an excellent, pliable laminate having great strength and fastness.
- the temperature at spraying must be 190 to 195 °C.
- This high temperature is obtained by means of special nozzles provided with heating elements embedded in aluminium. The temperature is raised only shortly before the nozzle tip, while it is maintained at a lower value, typically about 150 °C, during the passage through the conduits.
- the pressure in the nozzles is typically more than twice the normal pressure in such nozzles.
- the laminated textile web may be passed through the system once more with the purpose of producing a double textile web with wadding therebetween.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
- Gloves (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Inert Electrodes (AREA)
- Secondary Cells (AREA)
- Photovoltaic Devices (AREA)
- Nonwoven Fabrics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89200041T ATE74633T1 (de) | 1988-03-01 | 1989-01-09 | Verfahren zum beschichten von textilien. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK1084/88 | 1988-03-01 | ||
DK108488A DK157833C (da) | 1988-03-01 | 1988-03-01 | Fremgangsmaade til laminering af tekstiler |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0331215A2 EP0331215A2 (en) | 1989-09-06 |
EP0331215A3 EP0331215A3 (en) | 1991-01-09 |
EP0331215B1 true EP0331215B1 (en) | 1992-04-08 |
Family
ID=8100821
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89200041A Expired - Lifetime EP0331215B1 (en) | 1988-03-01 | 1989-01-09 | A process for laminating textiles |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0331215B1 (no) |
JP (1) | JPH0791769B2 (no) |
AT (1) | ATE74633T1 (no) |
DE (1) | DE68901148D1 (no) |
DK (1) | DK157833C (no) |
ES (1) | ES2032098T3 (no) |
FI (1) | FI88455C (no) |
GR (1) | GR3004626T3 (no) |
NO (1) | NO167706C (no) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK232289D0 (da) * | 1989-05-12 | 1989-05-12 | Dansk Transfertryk | Fremgangsmaade til diskontinuerlig laminering af tekniske tekstiler og lignende materialer |
FR2649866B1 (fr) * | 1989-06-29 | 1993-09-17 | Picardie Lainiere | Textile destine a l'entoilage et son procede de fabrication |
EP0448825A3 (en) * | 1990-03-23 | 1992-04-29 | Bayer Ag | Melt adhesive process |
DE9017007U1 (de) * | 1990-12-17 | 1991-03-07 | Viktor Achter GmbH & Co KG, 41751 Viersen | Textile Warenbahn |
US5436051A (en) * | 1993-07-26 | 1995-07-25 | Velcro Industries, B.V. | Hook and loop fasteners and method of making same |
GB9505403D0 (en) * | 1995-03-17 | 1995-05-03 | Courtaulds Textiles Holdings | Process for manufacturing laminated fabrics |
US5656351A (en) * | 1996-01-16 | 1997-08-12 | Velcro Industries B.V. | Hook and loop fastener including an epoxy binder |
US5723534A (en) * | 1996-10-11 | 1998-03-03 | Polyfoam Products, Inc. | Two part polyurethane-based adhesive system |
EP0888743A1 (de) | 1997-07-02 | 1999-01-07 | Firma Carl Freudenberg | Strukturiertes Textilmaterial aus mindestens zwei Basisvliesen und Verfahren zur seiner Herstellung |
NL1021065C2 (nl) * | 2002-07-12 | 2004-01-20 | Goede Beheer B V L | Werkwijze voor het lamineren van textiel. |
NL1023144C2 (nl) | 2003-04-10 | 2004-10-13 | Goyarts B V | Wasbare onderlegger en werkwijze voor het vervaardigen van een dergelijke onderlegger. |
EP1593724A1 (de) * | 2004-05-05 | 2005-11-09 | Imatep S.A. | Verwendung lösemittelbasierter Reaktivklebstoffe mit hohem Feststoffanteil zum Beschichten oder Laminieren flexibler Substrate, insbesondere textiler Substrate, bevorzugt mittels eines beheizten Sprühauftrags |
JP4158838B2 (ja) | 2006-12-01 | 2008-10-01 | Dic株式会社 | 湿気硬化性ポリウレタンホットメルト接着剤およびこれを用いた積層シート |
EP2248598B2 (de) * | 2009-05-07 | 2016-06-08 | Robatech AG | Vorrichtung mit mehreren Trockenluftdüsen sowie Verfahren zum Abgeben eines Klebstoffs |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1495460A (fr) * | 1966-05-24 | 1967-09-22 | Albert Maillard Ets | Revêtement composite notamment pour vêtements, articles de literie ou autres |
DE1930340B2 (de) * | 1969-06-14 | 1976-11-18 | Bayer Ag, 5090 Leverkusen | Heissversiegelung von textilen flaechengebilden |
US3847722A (en) * | 1972-01-27 | 1974-11-12 | Minnesota Mining & Mfg | Impregnated materials for leak prevention |
JPS6043356B2 (ja) * | 1976-10-12 | 1985-09-27 | 財団法人微生物化学研究会 | 耐性菌に有効なカナマイシンc誘導体およびそれらの製造法 |
CH636235B (de) * | 1977-09-06 | 1900-01-01 | Sandoz Ag | Verfahren zur herstellung von polyurethanen und deren verwendung in binderdispersionen zum verkleben von fasern in vliesstoffen. |
US4293814A (en) * | 1979-08-08 | 1981-10-06 | Ford Motor Company | Crankshaft position sensor circuitry for providing stable cyclical output signals without regard to peak to peak variations in sensor signals |
JPS61266678A (ja) * | 1985-05-15 | 1986-11-26 | Toray Ind Inc | 柔軟性立毛シ−トおよびその製造方法 |
-
1988
- 1988-03-01 DK DK108488A patent/DK157833C/da not_active IP Right Cessation
-
1989
- 1989-01-09 ES ES198989200041T patent/ES2032098T3/es not_active Expired - Lifetime
- 1989-01-09 DE DE8989200041T patent/DE68901148D1/de not_active Expired - Fee Related
- 1989-01-09 AT AT89200041T patent/ATE74633T1/de not_active IP Right Cessation
- 1989-01-09 EP EP89200041A patent/EP0331215B1/en not_active Expired - Lifetime
- 1989-01-12 FI FI890157A patent/FI88455C/fi not_active IP Right Cessation
- 1989-01-13 NO NO890164A patent/NO167706C/no unknown
- 1989-11-24 JP JP1306333A patent/JPH0791769B2/ja not_active Expired - Fee Related
-
1992
- 1992-05-18 GR GR920400953T patent/GR3004626T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
NO890164D0 (no) | 1989-01-13 |
NO890164L (no) | 1989-09-04 |
FI890157A (fi) | 1989-09-02 |
FI890157A0 (fi) | 1989-01-12 |
EP0331215A3 (en) | 1991-01-09 |
JPH03167356A (ja) | 1991-07-19 |
FI88455C (fi) | 1993-05-25 |
DE68901148D1 (de) | 1992-05-14 |
EP0331215A2 (en) | 1989-09-06 |
ES2032098T3 (es) | 1993-01-01 |
DK108488D0 (da) | 1988-03-01 |
DK157833C (da) | 1991-04-29 |
GR3004626T3 (no) | 1993-04-28 |
ATE74633T1 (de) | 1992-04-15 |
NO167706B (no) | 1991-08-26 |
DK157833B (da) | 1990-02-26 |
DK108488A (da) | 1989-09-02 |
NO167706C (no) | 1991-12-04 |
JPH0791769B2 (ja) | 1995-10-04 |
FI88455B (fi) | 1993-02-15 |
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