EP0297001A1 - Verfahren zum Vermindern der Streuung der charakteristischen mechanischen Werte bei Wolfram-Nickel-Eisen-Legierungen - Google Patents
Verfahren zum Vermindern der Streuung der charakteristischen mechanischen Werte bei Wolfram-Nickel-Eisen-Legierungen Download PDFInfo
- Publication number
- EP0297001A1 EP0297001A1 EP88420211A EP88420211A EP0297001A1 EP 0297001 A1 EP0297001 A1 EP 0297001A1 EP 88420211 A EP88420211 A EP 88420211A EP 88420211 A EP88420211 A EP 88420211A EP 0297001 A1 EP0297001 A1 EP 0297001A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tungsten
- powders
- nickel
- values
- mechanical characteristics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 10
- 230000008569 process Effects 0.000 title claims abstract description 7
- 229910000640 Fe alloy Inorganic materials 0.000 title claims abstract description 4
- OWUGOENUEKACGV-UHFFFAOYSA-N [Fe].[Ni].[W] Chemical compound [Fe].[Ni].[W] OWUGOENUEKACGV-UHFFFAOYSA-N 0.000 title claims abstract description 4
- 230000003247 decreasing effect Effects 0.000 title 1
- 239000000843 powder Substances 0.000 claims abstract description 28
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 9
- 239000010941 cobalt Substances 0.000 claims abstract description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 7
- 239000011572 manganese Substances 0.000 claims abstract description 7
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 15
- 239000000956 alloy Substances 0.000 abstract description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 12
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052742 iron Inorganic materials 0.000 abstract description 7
- 229910052721 tungsten Inorganic materials 0.000 abstract description 7
- 239000010937 tungsten Substances 0.000 abstract description 7
- 229910052759 nickel Inorganic materials 0.000 abstract description 6
- 238000009826 distribution Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 238000005245 sintering Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 4
- 238000005496 tempering Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910003271 Ni-Fe Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/045—Alloys based on refractory metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
Definitions
- the present invention relates to a method for reducing the dispersion of the values of the mechanical characteristics of tungsten-nickel-iron alloys.
- This process is characterized in that cobalt and manganese powders are added together to the initial powder.
- the elastic limit Rp, the tensile strength Rm and the elongation A% were measured on the products after each of the following steps: sintering - degassing - wrought - tempering, identified in Figures 2 and 3 respectively by means of the letters A , B, C, D.
- the breaking strength Rm was measured in MPa, the elastic limit Rp 0.2 in MPa, the Vickers hardness in HV30, the elongation in%.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
- Conductive Materials (AREA)
- Contacts (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Analysing Materials By The Use Of Radiation (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88420211T ATE68834T1 (de) | 1987-06-23 | 1988-06-21 | Verfahren zum vermindern der streuung der charakteristischen mechanischen werte bei wolfram-nickel-eisen-legierungen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8709169A FR2617192B1 (fr) | 1987-06-23 | 1987-06-23 | Procede pour reduire la dispersion des valeurs des caracteristiques mecaniques d'alliages de tungstene-nickel-fer |
FR8709169 | 1987-06-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0297001A1 true EP0297001A1 (de) | 1988-12-28 |
EP0297001B1 EP0297001B1 (de) | 1991-10-23 |
Family
ID=9352646
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88420211A Expired - Lifetime EP0297001B1 (de) | 1987-06-23 | 1988-06-21 | Verfahren zum Vermindern der Streuung der charakteristischen mechanischen Werte bei Wolfram-Nickel-Eisen-Legierungen |
Country Status (21)
Country | Link |
---|---|
US (1) | US4931252A (de) |
EP (1) | EP0297001B1 (de) |
JP (1) | JPH08939B2 (de) |
KR (1) | KR920004706B1 (de) |
CN (1) | CN1013042B (de) |
AT (1) | ATE68834T1 (de) |
AU (1) | AU603229B2 (de) |
BR (1) | BR8803055A (de) |
CA (1) | CA1340873C (de) |
DE (1) | DE3865753D1 (de) |
ES (1) | ES2025320B3 (de) |
FR (1) | FR2617192B1 (de) |
GR (1) | GR3002979T3 (de) |
IL (1) | IL86816A (de) |
IN (1) | IN169594B (de) |
RU (1) | RU1797627C (de) |
SG (1) | SG12993G (de) |
TR (1) | TR23644A (de) |
UA (1) | UA13386A (de) |
YU (1) | YU46262B (de) |
ZA (1) | ZA884454B (de) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5019330A (en) * | 1990-08-03 | 1991-05-28 | General Electric Company | Method of forming improved tungsten ingots |
US5234487A (en) * | 1991-04-15 | 1993-08-10 | Tosoh Smd, Inc. | Method of producing tungsten-titanium sputter targets and targets produced thereby |
US5603073A (en) * | 1991-04-16 | 1997-02-11 | Southwest Research Institute | Heavy alloy based on tungsten-nickel-manganese |
US5328657A (en) * | 1992-02-26 | 1994-07-12 | Drexel University | Method of molding metal particles |
US5527376A (en) * | 1994-10-18 | 1996-06-18 | Teledyne Industries, Inc. | Composite shot |
US5713981A (en) * | 1992-05-05 | 1998-02-03 | Teledyne Industries, Inc. | Composite shot |
US6136105A (en) * | 1998-06-12 | 2000-10-24 | Lockheed Martin Corporation | Process for imparting high strength, ductility, and toughness to tungsten heavy alloy (WHA) materials |
US6527880B2 (en) | 1998-09-04 | 2003-03-04 | Darryl D. Amick | Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same |
US7267794B2 (en) * | 1998-09-04 | 2007-09-11 | Amick Darryl D | Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same |
US6270549B1 (en) | 1998-09-04 | 2001-08-07 | Darryl Dean Amick | Ductile, high-density, non-toxic shot and other articles and method for producing same |
US6248150B1 (en) | 1999-07-20 | 2001-06-19 | Darryl Dean Amick | Method for manufacturing tungsten-based materials and articles by mechanical alloying |
US6447715B1 (en) * | 2000-01-14 | 2002-09-10 | Darryl D. Amick | Methods for producing medium-density articles from high-density tungsten alloys |
US7217389B2 (en) * | 2001-01-09 | 2007-05-15 | Amick Darryl D | Tungsten-containing articles and methods for forming the same |
WO2003064961A1 (en) * | 2002-01-30 | 2003-08-07 | Amick Darryl D | Tungsten-containing articles and methods for forming the same |
US6749802B2 (en) | 2002-01-30 | 2004-06-15 | Darryl D. Amick | Pressing process for tungsten articles |
US7059233B2 (en) * | 2002-10-31 | 2006-06-13 | Amick Darryl D | Tungsten-containing articles and methods for forming the same |
US7000547B2 (en) | 2002-10-31 | 2006-02-21 | Amick Darryl D | Tungsten-containing firearm slug |
US7383776B2 (en) * | 2003-04-11 | 2008-06-10 | Amick Darryl D | System and method for processing ferrotungsten and other tungsten alloys, articles formed therefrom and methods for detecting the same |
US7422720B1 (en) | 2004-05-10 | 2008-09-09 | Spherical Precision, Inc. | High density nontoxic projectiles and other articles, and methods for making the same |
JP4916450B2 (ja) * | 2005-11-28 | 2012-04-11 | 株式会社アライドマテリアル | タングステン合金粒、それを用いた加工方法およびその製造方法 |
US8122832B1 (en) | 2006-05-11 | 2012-02-28 | Spherical Precision, Inc. | Projectiles for shotgun shells and the like, and methods of manufacturing the same |
US9046328B2 (en) | 2011-12-08 | 2015-06-02 | Environ-Metal, Inc. | Shot shells with performance-enhancing absorbers |
US10690465B2 (en) | 2016-03-18 | 2020-06-23 | Environ-Metal, Inc. | Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same |
US10260850B2 (en) | 2016-03-18 | 2019-04-16 | Environ-Metal, Inc. | Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same |
CN106834856B (zh) * | 2017-01-16 | 2018-11-16 | 西安华山金属制品有限公司 | 一种W-Ni-Fe-Y-ZrB2多相合金材料及其制备方法 |
CN115011853A (zh) * | 2022-06-17 | 2022-09-06 | 深圳艾利佳材料科技有限公司 | 延伸性高的钨合金及其制备工艺 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3888636A (en) * | 1971-02-01 | 1975-06-10 | Us Health | High density, high ductility, high strength tungsten-nickel-iron alloy & process of making therefor |
US3979209A (en) * | 1975-02-18 | 1976-09-07 | The United States Of America As Represented By The United States Energy Research And Development Administration | Ductile tungsten-nickel alloy and method for making same |
US3979234A (en) * | 1975-09-18 | 1976-09-07 | The United States Of America As Represented By The United States Energy Research And Development Administration | Process for fabricating articles of tungsten-nickel-iron alloy |
US3988118A (en) * | 1973-05-21 | 1976-10-26 | P. R. Mallory & Co., Inc. | Tungsten-nickel-iron-molybdenum alloys |
EP0183017A1 (de) * | 1984-10-20 | 1986-06-04 | DORNIER SYSTEM GmbH | Sinterverfahren für vorlegierte Wolframpulver |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4937806A (de) * | 1972-08-11 | 1974-04-08 | ||
US4762559A (en) * | 1987-07-30 | 1988-08-09 | Teledyne Industries, Incorporated | High density tungsten-nickel-iron-cobalt alloys having improved hardness and method for making same |
-
1987
- 1987-06-23 FR FR8709169A patent/FR2617192B1/fr not_active Expired
-
1988
- 1988-05-24 IN IN412/CAL/88A patent/IN169594B/en unknown
- 1988-05-27 US US07/199,913 patent/US4931252A/en not_active Expired - Lifetime
- 1988-06-21 ES ES88420211T patent/ES2025320B3/es not_active Expired - Lifetime
- 1988-06-21 TR TR88/0437A patent/TR23644A/xx unknown
- 1988-06-21 EP EP88420211A patent/EP0297001B1/de not_active Expired - Lifetime
- 1988-06-21 IL IL86816A patent/IL86816A/xx not_active IP Right Cessation
- 1988-06-21 AT AT88420211T patent/ATE68834T1/de not_active IP Right Cessation
- 1988-06-21 DE DE8888420211T patent/DE3865753D1/de not_active Expired - Lifetime
- 1988-06-21 CN CN88103710A patent/CN1013042B/zh not_active Expired
- 1988-06-21 JP JP63153360A patent/JPH08939B2/ja not_active Expired - Lifetime
- 1988-06-22 AU AU18252/88A patent/AU603229B2/en not_active Ceased
- 1988-06-22 ZA ZA884454A patent/ZA884454B/xx unknown
- 1988-06-22 KR KR1019880007535A patent/KR920004706B1/ko not_active IP Right Cessation
- 1988-06-22 YU YU120188A patent/YU46262B/sh unknown
- 1988-06-22 RU SU884356071A patent/RU1797627C/ru active
- 1988-06-22 BR BR8803055A patent/BR8803055A/pt not_active IP Right Cessation
- 1988-06-22 UA UA4356071A patent/UA13386A/uk unknown
- 1988-06-22 CA CA000570132A patent/CA1340873C/fr not_active Expired - Fee Related
-
1991
- 1991-10-24 GR GR91400633T patent/GR3002979T3/el unknown
-
1993
- 1993-02-06 SG SG129/93A patent/SG12993G/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3888636A (en) * | 1971-02-01 | 1975-06-10 | Us Health | High density, high ductility, high strength tungsten-nickel-iron alloy & process of making therefor |
US3988118A (en) * | 1973-05-21 | 1976-10-26 | P. R. Mallory & Co., Inc. | Tungsten-nickel-iron-molybdenum alloys |
US3979209A (en) * | 1975-02-18 | 1976-09-07 | The United States Of America As Represented By The United States Energy Research And Development Administration | Ductile tungsten-nickel alloy and method for making same |
US3979234A (en) * | 1975-09-18 | 1976-09-07 | The United States Of America As Represented By The United States Energy Research And Development Administration | Process for fabricating articles of tungsten-nickel-iron alloy |
EP0183017A1 (de) * | 1984-10-20 | 1986-06-04 | DORNIER SYSTEM GmbH | Sinterverfahren für vorlegierte Wolframpulver |
Also Published As
Publication number | Publication date |
---|---|
CN1013042B (zh) | 1991-07-03 |
ES2025320B3 (es) | 1992-03-16 |
FR2617192B1 (fr) | 1989-10-20 |
IL86816A (en) | 1992-06-21 |
AU1825288A (en) | 1989-01-05 |
UA13386A (uk) | 1997-02-28 |
ATE68834T1 (de) | 1991-11-15 |
BR8803055A (pt) | 1989-01-10 |
SG12993G (en) | 1993-05-21 |
AU603229B2 (en) | 1990-11-08 |
US4931252A (en) | 1990-06-05 |
FR2617192A1 (fr) | 1988-12-30 |
TR23644A (tr) | 1990-05-28 |
ZA884454B (en) | 1989-03-29 |
IN169594B (de) | 1991-11-16 |
CA1340873C (fr) | 2000-01-11 |
JPH01195247A (ja) | 1989-08-07 |
YU46262B (sh) | 1993-05-28 |
KR920004706B1 (ko) | 1992-06-13 |
RU1797627C (ru) | 1993-02-23 |
JPH08939B2 (ja) | 1996-01-10 |
DE3865753D1 (de) | 1991-11-28 |
CN1031257A (zh) | 1989-02-22 |
EP0297001B1 (de) | 1991-10-23 |
IL86816A0 (en) | 1988-11-30 |
GR3002979T3 (en) | 1993-01-25 |
KR890000193A (ko) | 1989-03-13 |
YU120188A (en) | 1990-08-31 |
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