EP0075770B1 - Textilbehandlungsmittel und ihre Verwendung zum Ausrüsten von Textilmaterialien - Google Patents
Textilbehandlungsmittel und ihre Verwendung zum Ausrüsten von Textilmaterialien Download PDFInfo
- Publication number
- EP0075770B1 EP0075770B1 EP82108390A EP82108390A EP0075770B1 EP 0075770 B1 EP0075770 B1 EP 0075770B1 EP 82108390 A EP82108390 A EP 82108390A EP 82108390 A EP82108390 A EP 82108390A EP 0075770 B1 EP0075770 B1 EP 0075770B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- atoms
- textile
- radical
- weight
- finishing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004753 textile Substances 0.000 title claims description 23
- 239000000463 material Substances 0.000 title claims description 14
- 239000000203 mixture Substances 0.000 title description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 28
- -1 alkenyl radical Chemical class 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 13
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 5
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 125000004185 ester group Chemical group 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 235000003441 saturated fatty acids Nutrition 0.000 claims description 4
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 4
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 4
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 3
- 229920005645 diorganopolysiloxane polymer Polymers 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 238000009981 jet dyeing Methods 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 150000003254 radicals Chemical class 0.000 claims description 3
- SLRMQYXOBQWXCR-UHFFFAOYSA-N 2154-56-5 Chemical compound [CH2]C1=CC=CC=C1 SLRMQYXOBQWXCR-UHFFFAOYSA-N 0.000 claims description 2
- 125000005265 dialkylamine group Chemical group 0.000 claims description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000013011 aqueous formulation Substances 0.000 claims 3
- 150000003973 alkyl amines Chemical class 0.000 claims 1
- 238000007598 dipping method Methods 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 239000004758 synthetic textile Substances 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 238000009958 sewing Methods 0.000 description 9
- CZHYKKAKFWLGJO-UHFFFAOYSA-N dimethyl phosphite Chemical compound COP([O-])OC CZHYKKAKFWLGJO-UHFFFAOYSA-N 0.000 description 8
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000005956 quaternization reaction Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 4
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 235000021357 Behenic acid Nutrition 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 229940116226 behenic acid Drugs 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 3
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 3
- QOHMWDJIBGVPIF-UHFFFAOYSA-N n',n'-diethylpropane-1,3-diamine Chemical compound CCN(CC)CCCN QOHMWDJIBGVPIF-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- SRBSSROHORQGBO-UHFFFAOYSA-N 11-methyldodecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C SRBSSROHORQGBO-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- PYSGFFTXMUWEOT-UHFFFAOYSA-N 3-(dimethylamino)propan-1-ol Chemical compound CN(C)CCCO PYSGFFTXMUWEOT-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- DLQDGVZAEYZNTG-UHFFFAOYSA-N dimethyl hydrogen phosphite Chemical compound COP(O)OC DLQDGVZAEYZNTG-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229910001651 emery Inorganic materials 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000009499 grossing Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229940050176 methyl chloride Drugs 0.000 description 2
- KMBPCQSCMCEPMU-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-methylpropane-1,3-diamine Chemical compound NCCCN(C)CCCN KMBPCQSCMCEPMU-UHFFFAOYSA-N 0.000 description 2
- ODZZIKZQNODXFS-UHFFFAOYSA-N n,n'-dimethyl-n'-[2-(methylamino)ethyl]ethane-1,2-diamine Chemical compound CNCCN(C)CCNC ODZZIKZQNODXFS-UHFFFAOYSA-N 0.000 description 2
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical compound C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 125000001302 tertiary amino group Chemical group 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- MYXJVXKNGPJOBH-PFONDFGASA-N (z)-2-(2-ethylhexyl)octadec-9-enoic acid Chemical compound CCCCCCCC\C=C/CCCCCCC(C(O)=O)CC(CC)CCCC MYXJVXKNGPJOBH-PFONDFGASA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- GSAHAZJWNMHSNI-UHFFFAOYSA-N 2,2-bis(dodecanoyloxymethyl)butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC GSAHAZJWNMHSNI-UHFFFAOYSA-N 0.000 description 1
- SNZWDWNPSNBXCW-UHFFFAOYSA-N 2-(2-ethylhexyl)octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)CC(CC)CCCC SNZWDWNPSNBXCW-UHFFFAOYSA-N 0.000 description 1
- MXZROAOUCUVNHX-UHFFFAOYSA-N 2-Aminopropanol Chemical compound CCC(N)O MXZROAOUCUVNHX-UHFFFAOYSA-N 0.000 description 1
- WTVHSVDFIHETFS-UHFFFAOYSA-N 2-[2-[2-[2-(2-dodecanoyloxyethoxy)ethoxy]ethoxy]ethoxy]ethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOCCOCCOCCOCCOC(=O)CCCCCCCCCCC WTVHSVDFIHETFS-UHFFFAOYSA-N 0.000 description 1
- FOKDITTZHHDEHD-PFONDFGASA-N 2-ethylhexyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(CC)CCCC FOKDITTZHHDEHD-PFONDFGASA-N 0.000 description 1
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000159846 Centrosema pascuorum Species 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- IBKKMFMBXQARGV-UHFFFAOYSA-N [3-nonanoyloxy-2,2-bis(nonanoyloxymethyl)propyl] nonanoate Chemical compound CCCCCCCCC(=O)OCC(COC(=O)CCCCCCCC)(COC(=O)CCCCCCCC)COC(=O)CCCCCCCC IBKKMFMBXQARGV-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ULBTUVJTXULMLP-UHFFFAOYSA-N butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCC ULBTUVJTXULMLP-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- SILSDTWXNBZOGF-KUZBFYBWSA-N chembl111058 Chemical compound CCSC(C)CC1CC(O)=C(\C(CC)=N\OC\C=C\Cl)C(=O)C1 SILSDTWXNBZOGF-KUZBFYBWSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 238000009732 tufting Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Definitions
- acylated alkanolamines, A. which are described, for example, by K. Lindner “Tenside-Textile Aid-Washing Raw Materials •, 2nd Edition, Volume 1, pp. 904 and 993, and by Schwartz-Perry“ Surface Active Agents 1949, Vol. 1, p 173, contain amide and / or ester groups, depending on the alkanolamines used.
- carboxylic acids of natural or synthetic origin are used, for. B. lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid or their mixtures, such as those used for B. from coconut oil, palm kernel oil or tallow, or branched chain acids from oxosynthesis, for. B. isostearic acid, or its acid chlorides use.
- Stearic acid and behenic acid are preferably used in the form of their technical qualities.
- Suitable amines containing hydroxyl groups include monoethanolamine, diethanolamine, triethanolamine, N-methyl-diethanolamine, N- (2-aminoethyl) -ethanolamine, 1-amino-propanol and bis- (2-hydroxy-propyl) -amine.
- N- (2-Aminoethyl) ethanolamine, monoethanolamine and diethanolamine are preferably used.
- Preferred compounds B are reaction products of technical stearic acid or behenic acid with 3-amino-1-dimethylamino-propane or 3-amino-1-diethylamino-propane, which are quaternized with dimethyl sulfate or dimethyl phosphite.
- the quaternization is carried out by conventional methods without a solvent or in a solution medium, whereby in addition to water or ethyl alcohol, the acylated alkanolamines A. can also be used in molten form, provided that they do not contain a tertiary nitrogen atom.
- Suitable quaternizing agents are: methyl chloride, dimethyl sulfate, dimethyl phosphite or ethylene oxide, in which case the reaction is carried out in sulfuric or phosphoric acid solution.
- the substances of the two groups of substances A and B can also be prepared in a one-pot process by reacting mixtures of the amines mentioned for both groups with fatty acids and then quaternizing the proportion of tertiary amino groups.
- carboxylic acid esters C preference is given to using mono- to tetravalent alcohols with 3-20 C atoms, the alkyl chains of which can be interrupted by oxygen.
- Ethylene oxide adducts of fatty acids, fatty alcohols, fatty amines or alkylphenols can optionally be used to improve the solubility.
- the optimal degree of oxyethylation differs from case to case and can be from 3-50 moles of ethylene oxide per mole of starting substance.
- aqueous emulsions of dimethylpolysiloxanes having average molecular weights of 1,000 to 100,000, prepared by emulsion polymerization, can be used.
- compositions according to the invention can also contain other constituents as are customary in textile auxiliaries. These include protective colloids, perfumes, fungicides or bactericides as well as anti-foaming agents.
- the mixtures according to the invention are converted into water-containing preparations.
- the mixtures are heated above the melting point and, with stirring after the appropriate amount of warm water has been added, are stirred homogeneously.
- liquid stable solutions or emulsions are obtained which preferably contain 10-30% by weight of the textile treatment agents according to the invention.
- the mixtures can be applied to the textile material by known methods in the exhaust process (reel runner, nozzle-dyeing unit), by padding or by spraying. It is a particular advantage that the textile treatment agents according to the invention can be applied with nozzle-dyeing units.
- Textile processing processes such as sewing or tufting, place high demands on the textile material with regard to surface smoothness.
- High needle speeds lead to thermal and mechanical stresses on the sewing material, which can lead to thread breaks and stitch breakage damage if the surface is not smooth.
- This disadvantage can be avoided by providing the textile material with a smoothing finish.
- De-A-3003851 describes dispersions of oxidized waxes
- DE-A-2535768 uses dispersions of polysiloxanes and hydrocarbons or fluorine-containing polymers to achieve high surface smoothness. It is also known to use fatty acid esters as lubricants together with paraffin hydrocarbons.
- the agents according to the invention are excellent plasticizers and smoothing agents for textile materials of all kinds.
- Table 1 shows the molar amounts of the components used for the preparation of the acylated alkanolamines A and the acid numbers as they were obtained after the reaction under reduced pressure and elevated temperature. (See table 1 page 4 f ; )
- Table 2 shows the molar ratio in which the individual components for the production of the basic fatty acid amides or fatty acid esters were used, which serve as starting products for the production of the quaternary ammonium salts.
- the last line shows the acid numbers obtained when the components reacted at elevated temperature and pressure.
- Table 3 gives an overview of the production of the quaternary ammonium salts used.
- Part of the material was dried at 80 ° C, steamed twice for 10 seconds at 120 ° C and at 23 ° C u. 65% rel. Conditioned moisture.
- Another part of the finished material was steamed twice at 120 ° C for 10 seconds after drying at 80 ° C, then fixed at 170 ° C for a further 20 seconds and then at 23 ° C and 65% rel. Conditioned moisture.
- the fabric sections were then stretched in a stretching frame under an elongation of 88% and the number of stitch-blasting damage over a seam length of 80 cm was determined in the backlight.
- Table 6 shows the determined test data in comparison to an untreated product. (See table 6 page 6 f.)
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3138181 | 1981-09-25 | ||
| DE19813138181 DE3138181A1 (de) | 1981-09-25 | 1981-09-25 | Textilbehandlungsmittel und ihre verwendung zum ausruesten von textilmaterialien |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0075770A2 EP0075770A2 (de) | 1983-04-06 |
| EP0075770A3 EP0075770A3 (en) | 1985-01-16 |
| EP0075770B1 true EP0075770B1 (de) | 1986-11-12 |
Family
ID=6142590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP82108390A Expired EP0075770B1 (de) | 1981-09-25 | 1982-09-11 | Textilbehandlungsmittel und ihre Verwendung zum Ausrüsten von Textilmaterialien |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4446034A (enrdf_load_stackoverflow) |
| EP (1) | EP0075770B1 (enrdf_load_stackoverflow) |
| JP (1) | JPS5860070A (enrdf_load_stackoverflow) |
| DE (2) | DE3138181A1 (enrdf_load_stackoverflow) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60139868A (ja) * | 1983-12-24 | 1985-07-24 | ライオン株式会社 | 柔軟剤組成物 |
| GB8400899D0 (en) * | 1984-01-13 | 1984-02-15 | Procter & Gamble | Granular detergent compositions |
| GB2188653A (en) * | 1986-04-02 | 1987-10-07 | Procter & Gamble | Biodegradable fabric softeners |
| GB8817961D0 (en) * | 1988-07-28 | 1988-09-01 | Dow Corning Ltd | Compositions & process for treatment of textiles |
| GB8916307D0 (en) * | 1989-07-17 | 1989-08-31 | Unilever Plc | Fabric softening composition |
| DE4026029A1 (de) * | 1989-09-07 | 1992-02-20 | Sandoz Ag | Waessrige aminopolysiloxanmikroemulsionen, deren herstellung und verwendung |
| US5059442A (en) * | 1989-09-19 | 1991-10-22 | Nabisco Brands, Inc. | Primary amide esters as low calorie fat mimetics |
| US5234720A (en) * | 1990-01-18 | 1993-08-10 | Eastman Kodak Company | Process of preparing lubricant-impregnated fibers |
| JPH0759793B2 (ja) * | 1990-08-22 | 1995-06-28 | 花王株式会社 | 柔軟仕上剤 |
| JPH0759792B2 (ja) * | 1990-08-22 | 1995-06-28 | 花王株式会社 | 柔軟仕上剤 |
| US5830240A (en) * | 1996-10-23 | 1998-11-03 | Solutia Inc. | Fibers and textile materials having enhanced dyeability and finish compositions used thereon |
| US5944852A (en) * | 1996-10-23 | 1999-08-31 | Solutia Inc. | Dyeing process |
| DE19651447C1 (de) * | 1996-12-11 | 1997-10-02 | Henkel Kgaa | Mittel für die Avivage von Textil- und Keratinfasern und Verwendung von Hydroxycarbonsäureestern zur Herstellung von Avivagemitteln |
| DE19708133C1 (de) * | 1997-02-28 | 1997-12-11 | Henkel Kgaa | Mittel für die Avivage von Textil- und Keratinfasern sowie die Verwendung von Hydroxycarbonsäureestern zur Herstellung von Avivagemitteln |
| US5780401A (en) * | 1997-03-14 | 1998-07-14 | The Lubrizol Corporation | Non-flating slip-enhancing additives for coatings |
| DE19714044C1 (de) * | 1997-04-05 | 1998-04-16 | Henkel Kgaa | Hydrophile Avivagemittel sowie Verwendung von Mischungen, enthaltend Esterquats und Siliconverbindungen zur Herstellung derselben |
| DE19859294A1 (de) * | 1998-12-22 | 2000-06-29 | Bayer Ag | Textilbehandlungsmittel, Verfahren zu deren Herstellung sowie deren Verwendung |
| JP2002541339A (ja) * | 1999-03-29 | 2002-12-03 | バイエル アクチェンゲゼルシャフト | 織物用処理剤、それの製造方法およびそれの使用 |
| KR100351235B1 (ko) * | 1999-12-15 | 2002-09-09 | 주식회사 아이씨켐 | 합성섬유 처리용 유제 조성물 |
| JP6178720B2 (ja) * | 2013-12-25 | 2017-08-09 | 花王株式会社 | 液体柔軟剤組成物 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE154712C (enrdf_load_stackoverflow) * | ||||
| US1983349A (en) * | 1930-09-29 | 1934-12-04 | Dreyfus Camille | Textile material and method of making the same |
| FR1281984A (fr) * | 1959-11-25 | 1962-01-19 | Bayer Ag | Perfectionnements aux moyens pour empêcher le chargement électrostatique des hauts polymères synthétiques |
| US3223545A (en) * | 1962-10-08 | 1965-12-14 | Phillips Petroleum Co | Dialkanol amide antistatic composition for polyolefins |
| US3451927A (en) * | 1964-07-08 | 1969-06-24 | Lever Brothers Ltd | Fabric conditioner |
| US3652419A (en) * | 1968-03-06 | 1972-03-28 | Witco Chemical Corp | Antistatic fiber lubricant |
| US3868270A (en) * | 1972-12-04 | 1975-02-25 | Du Pont | Fibers with finish containing organic phosphates and sulphates |
| JPS6014146B2 (ja) * | 1977-01-29 | 1985-04-11 | ライオン株式会社 | 繊維柔軟化組成物 |
| DE2966013D1 (en) * | 1979-01-11 | 1983-09-01 | Procter & Gamble | Concentrated fabric softening composition |
| DE3066798D1 (en) * | 1979-04-21 | 1984-04-12 | Procter & Gamble | Fabric softening composition |
| GR67665B (enrdf_load_stackoverflow) * | 1979-05-21 | 1981-09-02 | Unilever Nv |
-
1981
- 1981-09-25 DE DE19813138181 patent/DE3138181A1/de not_active Withdrawn
-
1982
- 1982-09-08 US US06/415,866 patent/US4446034A/en not_active Expired - Lifetime
- 1982-09-11 EP EP82108390A patent/EP0075770B1/de not_active Expired
- 1982-09-11 DE DE8282108390T patent/DE3274270D1/de not_active Expired
- 1982-09-21 JP JP57163276A patent/JPS5860070A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| EP0075770A3 (en) | 1985-01-16 |
| JPS6323314B2 (enrdf_load_stackoverflow) | 1988-05-16 |
| US4446034A (en) | 1984-05-01 |
| DE3138181A1 (de) | 1983-04-14 |
| DE3274270D1 (en) | 1987-01-02 |
| JPS5860070A (ja) | 1983-04-09 |
| EP0075770A2 (de) | 1983-04-06 |
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