EP0027787A1 - Installation pour recueillir la chaleur de brames produites en coulée continue - Google Patents
Installation pour recueillir la chaleur de brames produites en coulée continue Download PDFInfo
- Publication number
- EP0027787A1 EP0027787A1 EP80890104A EP80890104A EP0027787A1 EP 0027787 A1 EP0027787 A1 EP 0027787A1 EP 80890104 A EP80890104 A EP 80890104A EP 80890104 A EP80890104 A EP 80890104A EP 0027787 A1 EP0027787 A1 EP 0027787A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cooling chamber
- slabs
- water
- heat
- cooling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009749 continuous casting Methods 0.000 title claims description 3
- 238000009434 installation Methods 0.000 title 1
- 238000011084 recovery Methods 0.000 title 1
- 238000001816 cooling Methods 0.000 claims abstract description 67
- 239000002826 coolant Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- 239000008236 heating water Substances 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims 1
- 239000003570 air Substances 0.000 description 25
- 230000005855 radiation Effects 0.000 description 3
- 239000012080 ambient air Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000012432 intermediate storage Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
- B22D11/124—Accessories for subsequent treating or working cast stock in situ for cooling
- B22D11/1246—Nozzles; Spray heads
Definitions
- the invention relates to a method for extracting the sensible heat from slabs cast in a continuous casting process, the slabs, after being cut to length, being passed through a cooling chamber within which heat is released from the slabs to a cooling medium, and to systems for carrying out the method.
- the slabs emerging from the cooling chamber have a temperature of more than 400 ° C. If you want to reduce the outlet temperature of the slabs to below 400 ° C, it would be necessary to increase the residence time of the slabs within the cooling chamber many times over. Since the slabs are produced continuously, either several cooling chambers connected in parallel would have to be arranged next to one another or a cooling chamber of extreme length would have to be provided.
- a low slab outlet temperature of below 400 ° C, in particular from 150 to 200 C, is not only important because of the greater heat yield, but also important in order to make the intermediate storage as small as possible - the slabs can be stacked closer together at low temperatures - and around to achieve shorter interim storage times.
- the invention aims to avoid these disadvantages and difficulties and has as its object to provide a method and a plant for carrying out the method by which a greater heat yield of the heat of the slabs can be achieved than before, but with the residence time of the slabs in the cooling chamber remains within tolerable limits, so that it can be found with a relatively small and accordingly economical cooling chamber.
- cooling medium in the cooling chamber is brought into direct contact with the slab surfaces and the heated cooling medium is used outside the cooling chamber as a heating medium, in particular for a circulating medium guided in a thermodynamic cycle.
- Air is preferably passed through the cooling chamber as the cooling medium, so that despite the low slab exit temperature too short cooling chamber on the slabs is avoided.
- water is sprayed onto the surface of the slabs as the cooling medium in the cooling chamber, the steam formed is extracted from the cooling chamber and the heat of the steam is used to heat water, as a result of which the cooling chamber is kept particularly short and the slab outlet temperature is kept particularly low can.
- This variant is advantageous for certain steel grades that can withstand abrupt cooling.
- the steam condensed after the heat is released into the water is expediently circulated.
- a system for carrying out the method according to the invention with a cooling chamber provided with inlet and outlet locks and a transport device for the slabs within the cooling chamber is characterized in that an air inlet line connected to a blower opens in the area of the outlet lock of the cooling chamber and at the other end of the cooling chamber in An air outlet line is connected to the area of the entrance lock.
- a heat exchanger for heating water is expediently provided in the air outlet line, which heat exchanger is connected in line with a turbine and a condenser via a closed steam cycle system, the turbine being able to serve as a drive for a generator.
- a further heat exchanger for preheating the feed water is connected in the air outlet line following the heat exchanger.
- the height of the cooling chamber is a multiple of the height of the slabs and the transport device receives slab stacks formed from a plurality of slabs stacked at a distance from one another.
- a system for carrying out the method according to the invention with a cooling chamber and a transport device for the slabs within the cooling chamber is characterized in that at least one water supply line with spray nozzles is provided in the cooling chamber and that a steam suction line is provided on the ceiling of the cooling chamber, in which a heat exchanger for heating water is provided.
- a return line for the steam condensed in the heat exchanger connects to the heat exchanger and opens into the water supply line, so that the cooling water sprayed onto the slabs can be circulated.
- a water drain is expediently provided in the bottom of the cooling chamber and opens into the water supply line.
- FIG. 1 shows a schematic diagram in which air is provided as the cooling medium.
- Fig. 2 shows the plan of the cooling chamber shown schematically in Fig. 1.
- 3 shows a schematic diagram analogous to FIG. 1, water being provided as the cooling medium.
- the conveyed with a conveyor, for example a R 1 ollgang to the cooling chamber 2 slabs 3 are divided from the cast strand 4 in pieces of predetermined length. 5
- the slabs 3 are fed transversely (in the direction of arrow 6) to the longitudinal direction of the cooling chamber 2.
- the slabs 3 are stacked in front of the cooling chamber 2, the slabs being kept at a distance by spacers 7 inserted between them.
- the stacking can be done by a crane or similar lifting equipment.
- the cooling chamber 2 has an inlet 8 and an outlet lock 9 in order to seal the interior 10 of the cooling chamber against outside air during the introduction and removal of the slab stacks 11.
- These locks 8, 9 are equipped with either lifting gates or swing gates.
- the slab stacks 11 are moved within the cooling chamber by means of a conveyor device, not shown.
- the stacks can be transported using various systems, e.g. by means of walking beams or by means of trolleys with external rollers or by means of a roller table.
- the cooling chamber 2 is inclined downwards in the direction in which the slabs 3 pass, so that the slab stacks 11 can be transported more easily.
- an air inlet line 12 opens into the cooling chamber, through which air is blown into the interior 10 of the cooling chamber 2 by means of a blower 13.
- an air outlet line 14 is provided, in which heat exchangers 15, 16 are provided. These heat exchangers are used to generate steam for the water carried in the closed steam cycle system 17.
- the steam emerging from the heat exchangers 15, 16 is fed to a turbine 18 which drives a generator 19.
- the expanded steam is led from the turbine into a condenser 20.
- the water emerging from the condenser is fed to a feed water tank 22 with degasser via a further heat exchanger 21, which is connected downstream of the first-mentioned heat exchangers 15, 16 in the air outlet line 14.
- the water is fed from the feed water tank to the heat exchangers by means of a pump 23.
- a Part of the steam is fed to the feed water tank via line 24 for preheating the feed water.
- This steam cycle corresponds to that of a conventional small calorific power plant.
- the slabs enter the cooling chamber 2 at a temperature of approximately 900 ° C. and have a temperature of only 250 ° C. when they leave the cooling chamber.
- the amount of heat introduced into the cooling chamber 2 with the slabs is 30,000 kJ, whereas the heat escaping with the slabs is 9,000 kJ.
- External power of around 630 kW is required for the blower.
- 5,300 kJ are the heat loss at the locks and the air that flows into the open air after leaving the downstream heat exchanger.
- the condenser 20 causes a heat loss of approximately 10,900 kJ.
- the generator output is approximately 4,800 kW.
- the air used as the heating medium can only be cooled down to a certain temperature, which depends on the design of the heat exchanger.
- the heat exchanger 21 connected downstream in the air outlet line 14 is provided.
- the water inlet temperature in this downstream heat exchanger 21 is substantially lower (approx. 40 ° C.), so that the air can be cooled even further.
- the air, which is still higher than the ambient air and exits from this downstream heat exchanger 21, can either be released into the atmosphere (FIG. 1, open circuit) or fed back to the suction side of the blower 13, as a result of which a closed circuit is created.
- the amount of heat removed by air from the cooling chamber could also be used differently, for example this air could be used for hot water use for drying purposes or as preheated combustion air for a boiler system.
- the slabs 3 are also conveyed through a cooling chamber 25 transversely to their longitudinal direction in the direction of arrow 6.
- the slabs 3 lie next to one another in one layer. They are sprayed with water which emerges from water supply lines 27 equipped with spray nozzles 26. These spray nozzles are arranged both on the tops of the slabs 3 and in the vicinity of the undersides of the slabs.
- the steam generated in the cooling chamber is sucked off on the ceiling 28 through a steam suction line 29 by means of a fan 30. Ambient air entering at the two ends 31, 32 of the cooling chamber 25 is also sucked in through this steam suction line.
- the cooling chamber is under a slight negative pressure by the fan 30, it is not necessary to provide locks at the ends 31, 32.
- the steam-air mixture is fed via the suction line 29 to a heat exchanger 33 in which the steam condenses.
- the extracted air also exits through a line 34.
- the condensed steam is supplied to the water supply lines 27 via a return line 35, a pump 36 and a filter 37.
- the water escaping through line 34 with the air must be replaced.
- a water outlet 39 is provided in the bottom 38 of the cooling chamber, through which the sprayed water, which has not been converted into steam, is likewise fed to the return line 35.
- the heat exchanger 33 is used to heat water which is circulated by means of a pump 40 via a hot water tank 41.
- Hot water with a temperature of 55 to 85 ° C. can be taken from the hot water tank, for example for underfloor heating.
- the inlet temperature of the water returned to the hot water tank 41 from the underfloor heating is about 30 ° C.
- An external power of 100 kW is required for the blower 30.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Heat Treatments In General, Especially Conveying And Cooling (AREA)
- Continuous Casting (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT6790/79 | 1979-10-18 | ||
AT0679079A AT363209B (de) | 1979-10-18 | 1979-10-18 | Verfahren zur gewinnung der fuehlbaren waerme von im stranggiessverfahren gegossenen brammen sowie anlage zur durchfuehrung dieses verfahrens |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0027787A1 true EP0027787A1 (fr) | 1981-04-29 |
EP0027787B1 EP0027787B1 (fr) | 1984-01-11 |
Family
ID=3589783
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP80890104A Expired EP0027787B1 (fr) | 1979-10-18 | 1980-09-12 | Installation pour recueillir la chaleur de brames produites en coulée continue |
Country Status (8)
Country | Link |
---|---|
US (1) | US4351633A (fr) |
EP (1) | EP0027787B1 (fr) |
JP (1) | JPS56154214A (fr) |
AT (1) | AT363209B (fr) |
BR (1) | BR8006693A (fr) |
CA (1) | CA1157223A (fr) |
DE (1) | DE3066096D1 (fr) |
ES (2) | ES496055A0 (fr) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3203016A1 (de) * | 1982-01-29 | 1983-08-11 | Oschatz Gmbh | Anlage zur gewinnung der fuehlbaren waerme von heissen werkstuecken |
DE4328301A1 (de) * | 1993-08-23 | 1995-03-02 | Fhw Brenntechnik Gmbh | Verfahren zur Gewinnung von Energie aus einem keramischen Brennofen für den Brand von Keramik, insbesondere Tunnelofen für Ziegel sowie Anlage zur Durchführung dieses Verfahrens |
EP0960670A1 (fr) * | 1998-05-28 | 1999-12-01 | Kawasaki Steel Corporation | Procédé pour refroidir des brames au moyen d'eau et une cuve contenant l'eau de refroidissement |
WO2010099929A1 (fr) * | 2009-03-02 | 2010-09-10 | Sms Siemag Ag | Procédé et installation de fabrication et/ou d'usinage d'une brame ou d'une bande de matériau métallique |
WO2011138171A3 (fr) * | 2010-05-07 | 2011-12-29 | Sms Siemag Ag | Procédé et dispositif pour récupérer de l'énergie en aval d'une installation de coulée continue |
WO2011051220A3 (fr) * | 2009-10-28 | 2012-01-12 | Sms Siemag Ag | Procédé de récupération d'énergie dans des installations métallurgiques et installation métallurgique à base d'éléments thermiques |
CN102341198A (zh) * | 2009-11-21 | 2012-02-01 | Sms西马格股份公司 | 用于铸造和轧制金属的设备和方法 |
WO2013113714A1 (fr) * | 2012-01-31 | 2013-08-08 | Centre de Recherches Métallurgiques asbl - Centrum voor Research in de Metallurgie vzw | Installation et procédé de récupération d'énergie à l'aide de co2 supercritique |
EP2495068A3 (fr) * | 2011-03-01 | 2014-06-25 | Deggendorfer Werkstätten e.V. | Dispositif et procédé de refroidissement d'un tronçon de matière chauffé |
WO2016178641A1 (fr) * | 2015-05-06 | 2016-11-10 | Topal Ömer Ali | Échangeur de chaleur perdue pour pièces métalliques chaudes finies |
EP2432601B2 (fr) † | 2009-05-18 | 2017-10-25 | Primetals Technologies Germany GmbH | Procédé et dispositif destinés à la récupération d'énergie à partir d'un collet de bande laminée à chaud |
CN108788058A (zh) * | 2018-06-21 | 2018-11-13 | 泽州县金秋铸造有限责任公司 | 一种余热收集装置 |
CN111272000A (zh) * | 2020-01-21 | 2020-06-12 | 董荣华 | 板坯汽化冷却装置以及板坯显热回收发电系统 |
CN112170799A (zh) * | 2020-09-30 | 2021-01-05 | 首钢集团有限公司 | 一种板坯连铸机扇形段冷却装置及控制方法 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT365498B (de) * | 1980-04-15 | 1982-01-25 | Voest Alpine Ag | Verfahren zur gewinnung fuehlbarer waerme von einem im stranggiessverfahren gegossenen gussstrang und einrichtung zur durchfuehrung des verfahrens |
JPS5741867A (en) * | 1980-08-25 | 1982-03-09 | Sumitomo Heavy Ind Ltd | Continuous casting machine |
JPS58215255A (ja) * | 1982-06-09 | 1983-12-14 | Sumitomo Heavy Ind Ltd | 連続鋳造機の顕熱回収装置 |
DE3340498C2 (de) * | 1983-11-09 | 1986-03-13 | Hans Lingl Anlagenbau Und Verfahrenstechnik Gmbh & Co Kg, 7910 Neu-Ulm | Einrichtung zum Rückführen von Leerpaletten in einem Schnelltrockner für keramische Formlinge |
DE19619836B4 (de) * | 1996-05-17 | 2005-05-12 | Alstom | Einrichtung zur Speisewasser-Vorsteuerung eines Kühllufttemperaturreglers für einen Kühlluftkühler |
US5809943A (en) * | 1997-05-14 | 1998-09-22 | Asea Brown Boveri Ag | Device for precontrolling the feedwater of a cooling-air temperature controller for a cooling-air cooler |
DE102009031557A1 (de) | 2009-03-02 | 2010-09-09 | Sms Siemag Ag | Energierückgewinnung in Warmbandstraßen durch Umwandlung der Kühlwärme der Stranggießanlage sowie der Restwärme von Brammen und Coils in elektrische Energie oder sonstige Nutzung der aufgefangenen Prozesswärme |
DE102010047693A1 (de) | 2010-10-06 | 2012-04-12 | Sms Siemag Ag | Vorrichtung zur Energierückgewinnung in hüttentechnischen Anlagen |
DE102012210182A1 (de) * | 2012-06-18 | 2013-12-19 | Siemens Aktiengesellschaft | Verfahren zur Wärmerückgewinnung in einer Metallverarbeitungsanlage, sowie Metallverarbeitungsanlage |
JP6118635B2 (ja) * | 2013-05-17 | 2017-04-19 | 富士電子工業株式会社 | 高周波焼入装置 |
JP6032235B2 (ja) * | 2014-03-31 | 2016-11-24 | Jfeスチール株式会社 | 熱電発電設備を備えた連続鋳造設備およびそれを用いた熱電発電方法 |
WO2020012221A1 (fr) | 2018-07-11 | 2020-01-16 | Arcelormittal | Procédé de transfert de chaleur et dispositif associé |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2311603A1 (fr) * | 1975-05-22 | 1976-12-17 | Kawasaki Heavy Ind Ltd | Appareil pour refroidir des blooms, des brames d'acier et analogues |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1778747A (en) * | 1925-02-21 | 1930-10-21 | Oscar L Barnebey | Tunnel kiln |
US3285706A (en) * | 1960-09-26 | 1966-11-15 | Alliance Color And Chemical Co | Continuous fusion apparatus |
JPS4833849A (fr) * | 1971-09-02 | 1973-05-14 | ||
SU553939A3 (ru) * | 1971-12-06 | 1977-04-05 | Кавасаки Юкогио Кабусики Кайся (Фирма) | Устройство дл охлаждени изделий |
JPS5317965B2 (fr) * | 1972-11-30 | 1978-06-12 | ||
SU432057A1 (ru) * | 1972-12-22 | 1974-06-15 | Конвейерная установка для транспортирования горячих грузов | |
DE2809567A1 (de) * | 1978-03-06 | 1979-09-20 | Babcock Ag | Verfahren und vorrichtung zum thermischen regenrieren von beladenem aktivkoks- oder aktivkohlegranulat |
US4211187A (en) * | 1978-04-10 | 1980-07-08 | Farris William C | Energy conservation system for hot water heaters and storage tanks |
-
1979
- 1979-10-18 AT AT0679079A patent/AT363209B/de not_active IP Right Cessation
-
1980
- 1980-09-12 DE DE8080890104T patent/DE3066096D1/de not_active Expired
- 1980-09-12 EP EP80890104A patent/EP0027787B1/fr not_active Expired
- 1980-10-03 US US06/193,548 patent/US4351633A/en not_active Expired - Lifetime
- 1980-10-06 CA CA000361623A patent/CA1157223A/fr not_active Expired
- 1980-10-14 JP JP14356880A patent/JPS56154214A/ja active Granted
- 1980-10-17 BR BR8006693A patent/BR8006693A/pt unknown
- 1980-10-17 ES ES496055A patent/ES496055A0/es active Granted
-
1981
- 1981-10-22 ES ES506477A patent/ES506477A0/es active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2311603A1 (fr) * | 1975-05-22 | 1976-12-17 | Kawasaki Heavy Ind Ltd | Appareil pour refroidir des blooms, des brames d'acier et analogues |
Non-Patent Citations (1)
Title |
---|
PATENTS ABSTRACTS OF JAPAN, Band 3, Nr. 59, 19 Mai 1979, Seite 119 C46 & JP-A-54 035 102 * |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3203016A1 (de) * | 1982-01-29 | 1983-08-11 | Oschatz Gmbh | Anlage zur gewinnung der fuehlbaren waerme von heissen werkstuecken |
DE4328301A1 (de) * | 1993-08-23 | 1995-03-02 | Fhw Brenntechnik Gmbh | Verfahren zur Gewinnung von Energie aus einem keramischen Brennofen für den Brand von Keramik, insbesondere Tunnelofen für Ziegel sowie Anlage zur Durchführung dieses Verfahrens |
EP0960670A1 (fr) * | 1998-05-28 | 1999-12-01 | Kawasaki Steel Corporation | Procédé pour refroidir des brames au moyen d'eau et une cuve contenant l'eau de refroidissement |
US6250370B1 (en) | 1998-05-28 | 2001-06-26 | Kawasaki Steel Corporation | Method for water-cooling hot metal slabs |
TWI404582B (zh) * | 2009-03-02 | 2013-08-11 | Sms Siemag Ag | 金屬材料構成的金屬板或金屬帶的製造及/或加工的方法與設備 |
WO2010099929A1 (fr) * | 2009-03-02 | 2010-09-10 | Sms Siemag Ag | Procédé et installation de fabrication et/ou d'usinage d'une brame ou d'une bande de matériau métallique |
EP2432601B2 (fr) † | 2009-05-18 | 2017-10-25 | Primetals Technologies Germany GmbH | Procédé et dispositif destinés à la récupération d'énergie à partir d'un collet de bande laminée à chaud |
EP2494272B1 (fr) | 2009-10-28 | 2015-07-01 | SMS Siemag AG | Procédé de récupération d'énergie dans des installations métallurgiques et installation métallurgique à base d'éléments thermiques |
WO2011051220A3 (fr) * | 2009-10-28 | 2012-01-12 | Sms Siemag Ag | Procédé de récupération d'énergie dans des installations métallurgiques et installation métallurgique à base d'éléments thermiques |
CN102341198A (zh) * | 2009-11-21 | 2012-02-01 | Sms西马格股份公司 | 用于铸造和轧制金属的设备和方法 |
WO2011138171A3 (fr) * | 2010-05-07 | 2011-12-29 | Sms Siemag Ag | Procédé et dispositif pour récupérer de l'énergie en aval d'une installation de coulée continue |
EP2495068A3 (fr) * | 2011-03-01 | 2014-06-25 | Deggendorfer Werkstätten e.V. | Dispositif et procédé de refroidissement d'un tronçon de matière chauffé |
WO2013113714A1 (fr) * | 2012-01-31 | 2013-08-08 | Centre de Recherches Métallurgiques asbl - Centrum voor Research in de Metallurgie vzw | Installation et procédé de récupération d'énergie à l'aide de co2 supercritique |
BE1020489A3 (fr) * | 2012-01-31 | 2013-11-05 | Centre Rech Metallurgique | Installation et procede de recuperation d'energie a l'aide de co2 supercritique. |
WO2016178641A1 (fr) * | 2015-05-06 | 2016-11-10 | Topal Ömer Ali | Échangeur de chaleur perdue pour pièces métalliques chaudes finies |
CN108788058A (zh) * | 2018-06-21 | 2018-11-13 | 泽州县金秋铸造有限责任公司 | 一种余热收集装置 |
CN111272000A (zh) * | 2020-01-21 | 2020-06-12 | 董荣华 | 板坯汽化冷却装置以及板坯显热回收发电系统 |
CN112170799A (zh) * | 2020-09-30 | 2021-01-05 | 首钢集团有限公司 | 一种板坯连铸机扇形段冷却装置及控制方法 |
Also Published As
Publication number | Publication date |
---|---|
AT363209B (de) | 1981-07-27 |
ES8202940A1 (es) | 1982-03-01 |
ATA679079A (de) | 1980-12-15 |
ES8206822A1 (es) | 1982-08-16 |
ES496055A0 (es) | 1982-03-01 |
CA1157223A (fr) | 1983-11-22 |
US4351633A (en) | 1982-09-28 |
ES506477A0 (es) | 1982-08-16 |
EP0027787B1 (fr) | 1984-01-11 |
DE3066096D1 (en) | 1984-02-16 |
JPS6318648B2 (fr) | 1988-04-19 |
JPS56154214A (en) | 1981-11-28 |
BR8006693A (pt) | 1981-04-22 |
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