EE04339B1 - Meetod kinniste pooridega vahtsilikaatse materjali saamiseks eelistatult jäätmetest ning selle meetodiga valmistatud materjal - Google Patents
Meetod kinniste pooridega vahtsilikaatse materjali saamiseks eelistatult jäätmetest ning selle meetodiga valmistatud materjalInfo
- Publication number
- EE04339B1 EE04339B1 EEP200000416A EEP200000416A EE04339B1 EE 04339 B1 EE04339 B1 EE 04339B1 EE P200000416 A EEP200000416 A EE P200000416A EE P200000416 A EEP200000416 A EE P200000416A EE 04339 B1 EE04339 B1 EE 04339B1
- Authority
- EE
- Estonia
- Prior art keywords
- weight
- parts
- mixture
- waste
- obtaining
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000000463 material Substances 0.000 title abstract 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title abstract 2
- 239000006260 foam Substances 0.000 title 1
- 239000002699 waste material Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 4
- 239000003513 alkali Substances 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- PVOXCLVRHYZZEP-UHFFFAOYSA-M [OH-].[O-2].[Ti+3] Chemical compound [OH-].[O-2].[Ti+3] PVOXCLVRHYZZEP-UHFFFAOYSA-M 0.000 abstract 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 abstract 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052901 montmorillonite Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/023—Fired or melted materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/027—Lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249967—Inorganic matrix in void-containing component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249967—Inorganic matrix in void-containing component
- Y10T428/249969—Of silicon-containing material [e.g., glass, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249976—Voids specified as closed
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249987—With nonvoid component of specified composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249987—With nonvoid component of specified composition
- Y10T428/249991—Synthetic resin or natural rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU9802622A HU224808B1 (en) | 1998-11-12 | 1998-11-12 | Method for producing of silicate foam product from waste material |
| PCT/HU1999/000017 WO2000029345A1 (en) | 1998-11-12 | 1999-03-05 | Process for the preparation, preferably from waste materials, of silicate foam with closed pores, and the product produced by the process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EE200000416A EE200000416A (et) | 2001-12-17 |
| EE04339B1 true EE04339B1 (et) | 2004-08-16 |
Family
ID=90014220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EEP200000416A EE04339B1 (et) | 1998-11-12 | 1999-03-05 | Meetod kinniste pooridega vahtsilikaatse materjali saamiseks eelistatult jäätmetest ning selle meetodiga valmistatud materjal |
Country Status (29)
| Country | Link |
|---|---|
| US (1) | US6541108B1 (id) |
| EP (1) | EP1047643B1 (id) |
| JP (1) | JP3814483B2 (id) |
| KR (1) | KR100359628B1 (id) |
| CN (1) | CN1122649C (id) |
| AT (1) | ATE221512T1 (id) |
| AU (1) | AU748235B2 (id) |
| BR (1) | BR9906912A (id) |
| CA (1) | CA2318240C (id) |
| CZ (1) | CZ300820B6 (id) |
| DE (1) | DE69902349T2 (id) |
| DK (1) | DK1047643T3 (id) |
| EA (1) | EA002232B1 (id) |
| EE (1) | EE04339B1 (id) |
| ES (1) | ES2181404T3 (id) |
| HK (1) | HK1035709A1 (id) |
| HR (1) | HRP20000447B1 (id) |
| HU (1) | HU224808B1 (id) |
| ID (1) | ID27475A (id) |
| IL (1) | IL137138A (id) |
| NO (1) | NO331566B1 (id) |
| NZ (1) | NZ505672A (id) |
| PL (1) | PL190886B1 (id) |
| PT (1) | PT1047643E (id) |
| RS (1) | RS49507B (id) |
| SK (1) | SK284474B6 (id) |
| TR (1) | TR200002123T1 (id) |
| UA (1) | UA59431C2 (id) |
| WO (1) | WO2000029345A1 (id) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002047073A (ja) * | 2000-08-02 | 2002-02-12 | Inax Corp | 多孔質焼結体及びその製造方法 |
| GB2381268B (en) * | 2001-12-22 | 2004-04-14 | Univ Exeter | Ceramic material and method of manufacture |
| US20070059199A1 (en) * | 2003-05-19 | 2007-03-15 | Labuschagne Francois J | Process for material treatment |
| JP4646504B2 (ja) * | 2003-07-25 | 2011-03-09 | 日本建設技術株式会社 | 発泡ガラス製造方法 |
| FR2867186B1 (fr) * | 2004-03-04 | 2006-10-06 | Valorisation Ceramique Du Pays | Procede de fabrication d'elements de construction incorporant des boues d'epuration |
| EP1955986A1 (en) * | 2007-01-18 | 2008-08-13 | Sika Technology AG | Light weight aggregate |
| GB201122431D0 (en) * | 2011-12-24 | 2012-02-08 | Evans Michael | Aggregates |
| RU2487842C1 (ru) * | 2011-12-29 | 2013-07-20 | Юлия Алексеевна Щепочкина | Шихта для изготовления пеностекла |
| GB2565261B (en) * | 2017-01-05 | 2021-05-19 | Gent Tim | A glass Briquette forming system |
| CZ2017179A3 (cs) * | 2017-03-29 | 2018-12-05 | AMT s.r.o. Příbram | Zpěnitelná směs pro výrobu pěnového skla a způsob její přípravy |
| DE102017127624A1 (de) | 2017-11-22 | 2019-05-23 | Schott Ag | Beschichtetes Glas- oder Glaskeramik-Substrat, Beschichtung umfassend geschlossene Poren sowie Verfahren zur Beschichtung eines Substrats |
| CN108529916B (zh) * | 2018-04-27 | 2020-12-01 | 济南大学 | 一种自荧光硫铝酸盐水泥熟料及其制备方法 |
| CN108863170A (zh) * | 2018-07-20 | 2018-11-23 | 张军 | 一种含有活性炭的建筑材料及其制备方法 |
| CN109734292A (zh) * | 2019-02-25 | 2019-05-10 | 谭桂容 | 一种耐冲击泡沫玻璃的制备方法 |
| CN113336528B (zh) * | 2021-07-06 | 2022-12-09 | 蚌埠学院 | 一种以石英砂尾矿为原料的泡沫陶瓷材料及其制备方法 |
| CN113955961B (zh) * | 2021-10-18 | 2023-03-17 | 东南大学 | 一种固体废弃物表面原位生长c-s-h凝胶的制备方法 |
| CN115353374B (zh) * | 2022-08-24 | 2023-04-25 | 济南大学 | 一种超薄涂层的泡沫陶瓷的制备方法及其制备的钯催化剂 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1796014A1 (de) * | 1968-08-16 | 1972-03-02 | Gruenzweig & Hartmann | Verfahren zur Herstellung von Formteilen aus thermisch geschaeumten Silikaten |
| CH503669A (de) * | 1968-08-29 | 1971-02-28 | Wasagchemie Ag | Verfahren zur Herstellung sehr leichter verschäumter Alkalisilikatpartikel |
| US3874861A (en) * | 1968-09-05 | 1975-04-01 | Kurz Fredrik W A | Method of producing foamed glass |
| US3625723A (en) * | 1969-08-05 | 1971-12-07 | Horizons Research Inc | Foamed ceramic comprising fly ash and phosphoric acid |
| SU1335544A1 (ru) * | 1986-01-30 | 1987-09-07 | А.Б. Истру | Пеностекло |
| JP2586759B2 (ja) * | 1991-07-01 | 1997-03-05 | 株式会社イナックス | 発泡建材及びその製造方法 |
| JPH0768864B2 (ja) * | 1992-06-05 | 1995-07-26 | 株式会社イセキ開発工機 | シールド装置 |
| DE19530792A1 (de) * | 1995-08-22 | 1997-02-27 | Gerhard Fabritz | Baustoff für den Hochbau |
| RU2114797C1 (ru) * | 1996-02-28 | 1998-07-10 | Вячеслав Фролович Павлов | Способ получения пористых стекломатериалов из металлургических шлаков |
| KR19980075814A (ko) * | 1997-03-28 | 1998-11-16 | 김주환 | 탄화규소를 이용한 발포세라믹재 |
| KR100262623B1 (ko) * | 1998-03-18 | 2001-01-15 | 이한용 | 단열재용 발포유리 유리조성 및 그 제조방법 |
-
1998
- 1998-11-12 HU HU9802622A patent/HU224808B1/hu not_active IP Right Cessation
-
1999
- 1999-03-05 US US09/600,063 patent/US6541108B1/en not_active Expired - Fee Related
- 1999-03-05 ES ES99910570T patent/ES2181404T3/es not_active Expired - Lifetime
- 1999-03-05 EA EA200000763A patent/EA002232B1/ru not_active IP Right Cessation
- 1999-03-05 AU AU29495/99A patent/AU748235B2/en not_active Ceased
- 1999-03-05 SK SK1056-2000A patent/SK284474B6/sk not_active IP Right Cessation
- 1999-03-05 TR TR200002123T patent/TR200002123T1/xx unknown
- 1999-03-05 CZ CZ20002514A patent/CZ300820B6/cs not_active IP Right Cessation
- 1999-03-05 CN CN99802112A patent/CN1122649C/zh not_active Expired - Fee Related
- 1999-03-05 ID ID20001542A patent/ID27475A/id unknown
- 1999-03-05 WO PCT/HU1999/000017 patent/WO2000029345A1/en active Application Filing
- 1999-03-05 CA CA 2318240 patent/CA2318240C/en not_active Expired - Fee Related
- 1999-03-05 DK DK99910570T patent/DK1047643T3/da active
- 1999-03-05 JP JP2000582340A patent/JP3814483B2/ja not_active Expired - Fee Related
- 1999-03-05 IL IL13713899A patent/IL137138A/en not_active IP Right Cessation
- 1999-03-05 DE DE1999602349 patent/DE69902349T2/de not_active Expired - Lifetime
- 1999-03-05 NZ NZ50567299A patent/NZ505672A/xx not_active IP Right Cessation
- 1999-03-05 KR KR1020007007651A patent/KR100359628B1/ko not_active IP Right Cessation
- 1999-03-05 RS YU44700 patent/RS49507B/sr unknown
- 1999-03-05 EP EP99910570A patent/EP1047643B1/en not_active Expired - Lifetime
- 1999-03-05 PL PL341839A patent/PL190886B1/pl not_active IP Right Cessation
- 1999-03-05 AT AT99910570T patent/ATE221512T1/de active
- 1999-03-05 PT PT99910570T patent/PT1047643E/pt unknown
- 1999-03-05 BR BR9906912A patent/BR9906912A/pt not_active IP Right Cessation
- 1999-03-05 EE EEP200000416A patent/EE04339B1/xx not_active IP Right Cessation
- 1999-05-03 UA UA2000084804A patent/UA59431C2/uk unknown
-
2000
- 2000-07-03 HR HR20000447 patent/HRP20000447B1/xx not_active IP Right Cessation
- 2000-07-11 NO NO20003567A patent/NO331566B1/no not_active IP Right Cessation
-
2001
- 2001-09-12 HK HK01106432A patent/HK1035709A1/xx not_active IP Right Cessation
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| KB4A | Valid patent at the end of a year |
Effective date: 20041231 |
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| KB4A | Valid patent at the end of a year |
Effective date: 20051231 |
|
| KB4A | Valid patent at the end of a year |
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