EA200901232A1 - Металлоалюмофосфатные молекулярные сита с многослойной кристаллической морфологией и их получение - Google Patents

Металлоалюмофосфатные молекулярные сита с многослойной кристаллической морфологией и их получение

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Publication number
EA200901232A1
EA200901232A1 EA200901232A EA200901232A EA200901232A1 EA 200901232 A1 EA200901232 A1 EA 200901232A1 EA 200901232 A EA200901232 A EA 200901232A EA 200901232 A EA200901232 A EA 200901232A EA 200901232 A1 EA200901232 A1 EA 200901232A1
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EA
Eurasian Patent Office
Prior art keywords
meapo
metalloaluminophosphate
halide
oxygen
crystal morphology
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EA200901232A
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English (en)
Other versions
EA016215B1 (ru
Inventor
Вальтер Вермейрен
Николай Нестеренко
Каролина Петитто
Франческо Ди Ренцо
Франсуа Фажюла
Original Assignee
Тотал Петрокемикалс Рисерч Фелюй
Сентр Насьональ Де Ля Решерш Сьянтифик (Снрс)
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Publication of EA200901232A1 publication Critical patent/EA200901232A1/ru
Publication of EA016215B1 publication Critical patent/EA016215B1/ru

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54—Phosphates, e.g. APO or SAPO compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/322—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a sulfur atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J2029/062—Mixtures of different aluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)

Abstract

Настоящее изобретение относится к металлоалюмофосфатному (МеАРО) молекулярному ситу со слоистой морфологией кристаллов, эмпирический химический состав которого в безводном состоянии после синтеза и прокаливания выражен формулой HMeAlPO, в которой y+z+k=1 и х≤у, и при этом указанное молекулярное сито имеет преимущественно пластинчатую морфологию кристаллов, ширина (W) и толщина (Т) которых соответствуют соотношению W/T≥10, которое предпочтительно находится в диапазоне от 10 до 100. В предпочтительном примере осуществления Т составляет 0,15 мкм или менее, более желательно Т составляет 0,1 мкм или менее, еще более желательно Т составляет 0,08 мкм или менее и благоприятный диапазон составляет от 0,01 до 0,07 мкм и предпочтительно от 0,04 до 0,07 мкм. Вышеуказанное металлоалюмофосфатное молекулярное сито может быть приготовлено в соответствии со способом, включающим: а) образование реакционной смеси, содержащей влияющее на текстуру вещество (ВВТ), и органический темплатный агент (TEMP), по меньшей мере один реакционноспособный неорганический источник MeO, по существу, не растворимый в ВВТ, реакционноспособные источники AlOи PO; b) кристаллизацию полученной вышеуказанной реакционной смеси, протекающую до образования кристаллов металлоалюмофосфата; с) извлечение твердого продукта реакции; а) промывку продукта водой для удаления ВВТ и е) кальцинацию продукта для удаления органического темплатного агента. В преимущественном примере осуществления изобретения МеАРО, по существу, имеют структуру СНА или структуру AEI или их смесь. Предпочтительно структура МеАРО представляет собой структуру SAPO 18 или структуру SAPO 34 или их смесь. Настоящее изобретение относится также к катализаторам, состоящим из вышеуказанных металлоалюмофосфатных молекулярных сит или включающим вышеуказанные молекулярные сита МеАРО. Настоящее изобретение также относится к способу приготовления олефиновых продуктов из кислородсодержащего, галогенидсодержащего или серосодержащего сырья, в соответствии с которым указанное кислородсодержащее, галогенидсодержащее или серосодержащее сырье вводят в контакт с вышеуказанным катализатором в условиях, пригодных для превращения кислородсодержащего, галогенидсодержащего или серосодержащего сырья в олефиновые продукты.
EA200901232A 2007-03-13 2008-03-10 Металлоалюмофосфатные молекулярные сита с многослойной кристаллической морфологией и их получение EA016215B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07300860A EP1970350A1 (en) 2007-03-13 2007-03-13 Metalloaluminophosphate molecular sieves with lamellar crystal morphology and their preparation
US93944007P 2007-05-22 2007-05-22
PCT/EP2008/052807 WO2008110526A1 (en) 2007-03-13 2008-03-10 Metalloaluminophosphate molecular sieves with lamellar crystal morphology and their preparation

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Publication Number Publication Date
EA200901232A1 true EA200901232A1 (ru) 2010-04-30
EA016215B1 EA016215B1 (ru) 2012-03-30

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Country Link
US (1) US8518370B2 (ru)
EP (2) EP1970350A1 (ru)
CN (1) CN101679053B (ru)
EA (1) EA016215B1 (ru)
WO (1) WO2008110526A1 (ru)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2161243A1 (en) * 2008-08-29 2010-03-10 Total Petrochemicals Research Feluy Method for preparing metalloaluminophosphate (MeAPO) molecular sieves
EP2161242A1 (en) * 2008-08-29 2010-03-10 Total Petrochemicals Research Feluy Method for Preparing Crystalline Metalloaluminophosphate (MeAPO) Molecular Sieve from Amorphous Materials
EP2338865A1 (en) 2009-12-22 2011-06-29 Total Petrochemicals Research Feluy Process for removing oxygenated contaminants from an hydrocarbon stream
EP2338864A1 (en) 2009-12-22 2011-06-29 Total Petrochemicals Research Feluy Process for removing oxygenated contaminants from an hydrocarbon stream
EP2348004A1 (en) 2010-01-25 2011-07-27 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process
CN101857244B (zh) * 2010-06-22 2012-02-29 上海兖矿能源科技研发有限公司 一种磷酸硅铝分子筛及其制备方法和应用
CA2832887A1 (en) 2011-04-11 2012-10-18 ADA-ES, Inc. Fluidized bed method and system for gas component capture
US9278314B2 (en) 2012-04-11 2016-03-08 ADA-ES, Inc. Method and system to reclaim functional sites on a sorbent contaminated by heat stable salts
TWI432262B (zh) 2012-08-10 2014-04-01 China Petrochemical Dev Corp Taipei Taiwan Method for making epoxides
CN103964457B (zh) * 2013-01-29 2016-12-28 中国科学院过程工程研究所 一种sapo分子筛及其制备方法和用途
CN104511271B (zh) * 2013-09-24 2017-12-15 中国石油化工股份有限公司 一种分子筛、其制造方法及其应用
BR102016026121B1 (pt) * 2015-11-09 2021-09-14 China Petroleum & Chemical Corporation Peneira molecular scm-10, processo para sua produção, composição e uso
BR102016026135B1 (pt) * 2015-11-09 2021-09-21 Shanghai Research Institute Of Petrochemical Technology, Sinopec Peneira molecular que apresenta a estrutura sfe, processo para sua produção, composição e uso
BR102016026128B1 (pt) * 2015-11-09 2022-10-04 Shanghai Research Institute Of Petrochemical Technology, Sinopec Peneiras moleculares scm-11, processo para a produção das mesmas, seus usos e composição de peneira molecular
CN106809860B (zh) * 2015-11-27 2019-03-19 中国科学院大连化学物理研究所 一种ats型金属磷酸铝分子筛的离子热合成方法
JP2019518694A (ja) * 2016-04-28 2019-07-04 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ Ｓｔａ−２０、新規なモレキュラーシーブ骨格タイプ、調製及び使用方法
WO2017205023A1 (en) * 2016-05-25 2017-11-30 Uop Llc HIGH CHARGE DENSITY METALLOALUMINOPHOSPHOSILICATE MOLECULAR SIEVES MeAPSO-82
TWI754761B (zh) * 2017-06-19 2022-02-11 美商沙琛公司 基於嗎福啉之四級銨陽離子及以此製造之aei型沸石
US20200261857A1 (en) * 2017-08-10 2020-08-20 Total Research & Technology Feluy MeAPO-18 Membranes with Lamellar Crystal Morphology and Their Preparation
CN109395771B (zh) * 2018-09-26 2021-07-16 昆明理工大学 一种酯化-皂化反应催化剂及其制备方法和应用
CN111115655B (zh) * 2018-10-30 2022-07-12 中国石油化工股份有限公司 共晶纳米分子筛、制备方法及其应用
CN113753916B (zh) * 2020-06-01 2023-05-02 中国石油化工股份有限公司 Sapo复合分子筛及其制备方法和其用途
CN114180594B (zh) * 2020-09-14 2023-05-02 中国石油化工股份有限公司 一种ith分子筛的制备方法
CN113000021B (zh) * 2021-02-18 2023-07-21 北京明星绿能化工科技有限公司 用于精制分离相变蜡的梯级孔分子筛的制备及应用方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4677243A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
US6812372B2 (en) * 2001-03-01 2004-11-02 Exxonmobil Chemical Patents Inc. Silicoaluminophosphate molecular sieve
US6953767B2 (en) * 2001-03-01 2005-10-11 Exxonmobil Chemical Patents Inc. Silicoaluminophosphate molecular sieve
US7009086B2 (en) * 2002-10-29 2006-03-07 Exxonmobil Chemical Patents Inc. Use of molecular sieves for the conversion of oxygenates to olefins
US7037874B2 (en) * 2003-10-27 2006-05-02 Council Of Scientific And Industrial Research Process for the preparation of porous crystalline silicoaluminophosphate molecular sieves
CN1274596C (zh) * 2004-05-28 2006-09-13 中国石油化工股份有限公司 含金属离子硅磷铝分子筛的制备方法
US20060147364A1 (en) * 2004-12-30 2006-07-06 Council Of Scientific And Industrial Research Process for synthesising porous crystalline aluminophosphate molecular sieves
CN1314587C (zh) * 2005-04-14 2007-05-09 南京工业大学 一种sapo－34分子筛的制备方法

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US20100179296A1 (en) 2010-07-15
CN101679053A (zh) 2010-03-24
EP2121523A1 (en) 2009-11-25
US8518370B2 (en) 2013-08-27
WO2008110526A1 (en) 2008-09-18
CN101679053B (zh) 2011-12-28
EP1970350A1 (en) 2008-09-17
EA016215B1 (ru) 2012-03-30

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