EA015997B9 - СПОСОБ ПОЛУЧЕНИЯ МЕТАЛЛАЛЮМОФОСФАТНОГО (МеАФО) МОЛЕКУЛЯРНОГО СИТА - Google Patents

СПОСОБ ПОЛУЧЕНИЯ МЕТАЛЛАЛЮМОФОСФАТНОГО (МеАФО) МОЛЕКУЛЯРНОГО СИТА

Info

Publication number
EA015997B9
EA015997B9 EA200901233A EA200901233A EA015997B9 EA 015997 B9 EA015997 B9 EA 015997B9 EA 200901233 A EA200901233 A EA 200901233A EA 200901233 A EA200901233 A EA 200901233A EA 015997 B9 EA015997 B9 EA 015997B9
Authority
EA
Eurasian Patent Office
Prior art keywords
desirable
meapo
alo
tia
metalloaluminophosphate
Prior art date
Application number
EA200901233A
Other languages
English (en)
Other versions
EA200901233A1 (ru
EA015997B1 (ru
Inventor
Вальтер Вермейрен
Николай Нестеренко
Каролина Петитто
Франческо Ди Ренцо
Франсуа Фажюла
Original Assignee
Тотал Петрокемикалс Рисерч Фелюй
Сентр Насьональ Де Ля Решерш Сьянтифик (Снрс)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Тотал Петрокемикалс Рисерч Фелюй, Сентр Насьональ Де Ля Решерш Сьянтифик (Снрс) filed Critical Тотал Петрокемикалс Рисерч Фелюй
Publication of EA200901233A1 publication Critical patent/EA200901233A1/ru
Publication of EA015997B1 publication Critical patent/EA015997B1/ru
Publication of EA015997B9 publication Critical patent/EA015997B9/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/322—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a sulfur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Настоящее изобретение относится к способу получения металлалюмофосфатного (МеАФО) молекулярного сита, включающему: а) образование реакционной смеси, содержащей влияющий на текстуру агент (ВТА), органический темплатный агент (ТЕМП), по меньшей мере один реакционноспособный неорганический источник МеО, нерастворимый в ВТА, реакционноспособные источники AlОи PO; б) кристаллизацию вышеуказанной реакционной смеси до образования кристаллов металлалюмофосфата; в) извлечение твердого продукта реакции; г) промывку указанного продукта водой для удаления ВТА и д) обжиг указанного продукта для удаления органического темплата. В обычном воплощении указанная реакционная смесь имеет следующий состав, выраженный в показателях молярных отношений оксидов: ТЕМП/AlО=0,3-5, более предпочтительно 0,5-2; MeO/AlО=0,005-2,0, более предпочтительно 0,022-0,8; РО/AlО=0,5-2, более предпочтительно 0,8-1,2; ВТА/AlО=3-30, более предпочтительно 6-20. В обычном воплощении металлалюмофосфатные (МеАФО) молекулярные сита, полученные вышеописанным способом, имеют слоистую морфологию кристаллов, имеющих эмпирический химический состав на безводной основе после синтеза и обжига, выраженный формулой HMeAlPO, где y+z+k=1, x≤y, значение у составляет от 0,0008 до 0,4 и более предпочтительно от 0,005 до 0,18; значение z составляет от 0,25 до 0,67 и более предпочтительно от 0,38 до 0,5525; значение k составляет от 0,2 до 0,67 и более предпочтительно от 0,36 до 0,54; причем указанное молекулярное сито имеет преимущественно пластинчатую морфологию кристаллов. В преимущественном воплощении МеАФО, полученные по способу согласно изобретению, по существу, имеют структуру СНА или AEI либо их смеси. Предпочтительно они, по существу, имеют структуру САФО 18 или САФО 34 либо их смеси. Настоящее изобретение также
EA200901233A 2007-03-13 2008-03-10 СПОСОБ ПОЛУЧЕНИЯ МЕТАЛЛАЛЮМОФОСФАТНОГО (МеАФО) МОЛЕКУЛЯРНОГО СИТА EA015997B9 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07300861A EP1970351A1 (en) 2007-03-13 2007-03-13 Method of preparing metalloaluminophosphate (Meapo) molecular sieve
US93945607P 2007-05-22 2007-05-22
PCT/EP2008/052813 WO2008110528A1 (en) 2007-03-13 2008-03-10 Method for preparing metalloaluminophosphate (meapo) molecular sieve

Publications (3)

Publication Number Publication Date
EA200901233A1 EA200901233A1 (ru) 2010-04-30
EA015997B1 EA015997B1 (ru) 2012-01-30
EA015997B9 true EA015997B9 (ru) 2012-03-30

Family

ID=38312291

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200901233A EA015997B9 (ru) 2007-03-13 2008-03-10 СПОСОБ ПОЛУЧЕНИЯ МЕТАЛЛАЛЮМОФОСФАТНОГО (МеАФО) МОЛЕКУЛЯРНОГО СИТА

Country Status (5)

Country Link
US (1) US20100216629A1 (ru)
EP (2) EP1970351A1 (ru)
CN (1) CN101679054B (ru)
EA (1) EA015997B9 (ru)
WO (1) WO2008110528A1 (ru)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2338865A1 (en) 2009-12-22 2011-06-29 Total Petrochemicals Research Feluy Process for removing oxygenated contaminants from an hydrocarbon stream
EP2338864A1 (en) 2009-12-22 2011-06-29 Total Petrochemicals Research Feluy Process for removing oxygenated contaminants from an hydrocarbon stream
EP2348004A1 (en) 2010-01-25 2011-07-27 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process
CN102476806A (zh) * 2010-11-30 2012-05-30 中国科学院大连化学物理研究所 一种在低共熔混合物中合成超大微孔磷酸铝分子筛的方法
CN102001682B (zh) * 2010-12-10 2012-09-05 黑龙江大学 一种微波加热合成杂原子取代MeAPO-31分子筛的方法
DE102010055730A1 (de) * 2010-12-22 2012-06-28 Süd-Chemie AG Verfahren zur Herstellung von Titano-(Silico)-Alumo-Phosphat
US9352270B2 (en) 2011-04-11 2016-05-31 ADA-ES, Inc. Fluidized bed and method and system for gas component capture
AU2013317997B2 (en) 2012-09-20 2016-04-07 ADA-ES, Inc. Method and system to reclaim functional sites on a sorbent contaminated by heat stable salts
WO2015084817A1 (en) 2013-12-02 2015-06-11 Johnson Matthey Public Limited Company Mixed template synthesis of high silica cu-cha
CN105828943B (zh) * 2013-12-20 2019-03-08 科莱恩产品（德国）有限公司 用于使含氧化合物转化成烯烃的含磷催化剂
CN106809860B (zh) * 2015-11-27 2019-03-19 中国科学院大连化学物理研究所 一种ats型金属磷酸铝分子筛的离子热合成方法
GB2551871A (en) * 2016-04-22 2018-01-03 Johnson Matthey Plc STA-18, A new member of the SFW family of molecular sieve zeotypes, methods of preparation and use
GB2551622A (en) * 2016-04-22 2017-12-27 Johnson Matthey Plc STA-19, A new member of the GME family of molecular sieve zeotypes, methods of preparation and use
KR20190003615A (ko) * 2016-04-28 2019-01-09 존슨 맛쎄이 퍼블릭 리미티드 컴파니 신규 분자체 프레임워크 유형인 sta-20, 제조 방법 및 용도
WO2017204993A1 (en) * 2016-05-25 2017-11-30 Uop Llc High charge density metallophosphate molecular sieves
CN108602054B (zh) * 2016-05-25 2021-09-24 环球油品公司 高电荷密度金属磷酸盐分子筛
CN108147427A (zh) * 2016-12-05 2018-06-12 中国科学院大连化学物理研究所 一种cha型杂原子金属磷酸铝分子筛及预成型合成方法
CN108147422A (zh) * 2016-12-05 2018-06-12 中国科学院大连化学物理研究所 一种cha型磷酸镁铝分子筛及预成型合成方法
KR20210135222A (ko) * 2019-03-14 2021-11-12 존슨 맛쎄이 퍼블릭 리미티드 컴파니 Cha-함유 분자체 jmz-1s 및 제조 방법
CN111097511B (zh) * 2019-12-25 2023-02-28 山东江岳科技开发股份有限公司 一种sapo-34分子筛催化剂生产装置

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4677243A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
WO2002070407A1 (en) * 2001-03-01 2002-09-12 Exxonmobil Chemical Patents Inc. A Corporation Of State Of Delaware Silicoaluminophosphate molecular sieve
US20040082825A1 (en) * 2002-10-29 2004-04-29 Brown Stephen H. Use of molecular sieves for the conversion of oxygenates to olefins
US20050090390A1 (en) * 2003-10-27 2005-04-28 Council Of Scientific And Industrial Research Process for the preparation of porous crystalline silicoaluminophosphate molecular sieves
US20060147364A1 (en) * 2004-12-30 2006-07-06 Council Of Scientific And Industrial Research Process for synthesising porous crystalline aluminophosphate molecular sieves

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5160500A (en) * 1985-10-21 1992-11-03 Mobil Oil Corporation Zeolite synthesis using an alcohol or like molecules
US5300277A (en) * 1990-01-25 1994-04-05 Mobil Oil Corporation Synthesis of mesoporous crystalline material
US6953767B2 (en) * 2001-03-01 2005-10-11 Exxonmobil Chemical Patents Inc. Silicoaluminophosphate molecular sieve

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4677243A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
WO2002070407A1 (en) * 2001-03-01 2002-09-12 Exxonmobil Chemical Patents Inc. A Corporation Of State Of Delaware Silicoaluminophosphate molecular sieve
US20040082825A1 (en) * 2002-10-29 2004-04-29 Brown Stephen H. Use of molecular sieves for the conversion of oxygenates to olefins
US20050090390A1 (en) * 2003-10-27 2005-04-28 Council Of Scientific And Industrial Research Process for the preparation of porous crystalline silicoaluminophosphate molecular sieves
US20060147364A1 (en) * 2004-12-30 2006-07-06 Council Of Scientific And Industrial Research Process for synthesising porous crystalline aluminophosphate molecular sieves

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
VENKATATHRI N.: "Synthesis and NMR characterization of SAPO-35 from non-aqueous systems using hexamethyleneimine template", MATERIALS RESEARCH BULLETIN, ELSEVIER, KIDLINGTON, GB, vol. 40, no. 7, 12 July 2005 (2005-07-12), pages 1157-1165, XP004914396, ISSN: 0025-5408, Experimental section: Synthesis *
WU X. ET AL.: "Effect of feed composition on methanol conversion to light olefins over SAPO-34", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE. AMSTERDAM, NL, vol. 218, no. 1-2, 25 September 2001 (2001-09-25), pages 241-250, XP004300335, ISSN: 0926-860X, page 244, 245 *

Also Published As

Publication number Publication date
EA200901233A1 (ru) 2010-04-30
CN101679054B (zh) 2012-07-18
EP2121524A1 (en) 2009-11-25
WO2008110528A1 (en) 2008-09-18
US20100216629A1 (en) 2010-08-26
EP1970351A1 (en) 2008-09-17
CN101679054A (zh) 2010-03-24
EA015997B1 (ru) 2012-01-30

Similar Documents

Publication Publication Date Title
EA015997B9 (ru) СПОСОБ ПОЛУЧЕНИЯ МЕТАЛЛАЛЮМОФОСФАТНОГО (МеАФО) МОЛЕКУЛЯРНОГО СИТА
EA200901232A1 (ru) Металлоалюмофосфатные молекулярные сита с многослойной кристаллической морфологией и их получение
TW200744950A (en) Method of preparing a molecular sieve composition
US7148172B2 (en) High silica chabazite, its synthesis and its use in the conversion of oxygenates to olefins
MY157590A (en) Solvothermal synthesis process of SAPO molecular sieves and catalysts prepared thereby
MY151944A (en) Process for preparing silicoaluminophosphate (sapo) molecular sieves, catalysts containing said sieves and catalytic dehydration processes using said catalysts
CN106794998B (zh) 从mse骨架型分子筛中除去夹杂碱金属阳离子
WO2007039851A3 (en) Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated organic group
CN105692647A (zh) 一种ssz-13分子筛的制备方法
WO2009016153A3 (en) Phosphorus modified molecular sieves, their use in conversion of organics to olefins
CA2613052A1 (en) Enhancement of molecular sieve performance
US20060292053A1 (en) Process for manufacture of silicoaluminophosphate molecular sieves
NO174341B (no) Fremg. for fremst. av krystallinske mikroporoese SiAl-fosfater med kontr. Si-innh, krystallinske mikroporoese SiAl-fosfater med forbedret stabilitet mot deaktivering og en anv. av disseved fremstilling av olefiner fra metanol
US6685905B2 (en) Silicoaluminophosphate molecular sieves
CN107915237B (zh) 一种孪晶sapo-34分子筛及其合成方法和一种甲醇制烯烃的方法
Zheng et al. The tailored synthesis of nanosized SAPO-34 via time-controlled silicon release enabled by an organosilane precursor
Lin et al. Tetraalkylammonium salt/alcohol mixtures as deep eutectic solvents for syntheses of high-silica zeolites
JP2018526315A (ja) ゼオライトｓｓｚ−９８を調製するための方法
TW200831454A (en) Process for producing propylene
TW200930456A (en) Catalyst composition and process for preparing linear alpha-olefins
CN104098109A (zh) 一种球形zsm-5沸石分子筛及其制备和应用
CN114572997B (zh) 丝光沸石分子筛以及制备方法、应用
WO2005082848A3 (en) Method for preparing pyrrolidine oximes
Venkatathri et al. Synthesis and characterization of TAPO-31 molecular sieves using tripropylamine template
Gopal et al. Organotemplate-free hydrothermal synthesis of NaNKX-2 aluminophosphite basic catalyst

Legal Events

Date Code Title Description
TH4A Publication of the corrected specification to eurasian patent
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU