CN101679053B - 具有层状晶体形态的金属磷酸铝分子筛及其制备 - Google Patents
具有层状晶体形态的金属磷酸铝分子筛及其制备 Download PDFInfo
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- CN101679053B CN101679053B CN2008800152276A CN200880015227A CN101679053B CN 101679053 B CN101679053 B CN 101679053B CN 2008800152276 A CN2008800152276 A CN 2008800152276A CN 200880015227 A CN200880015227 A CN 200880015227A CN 101679053 B CN101679053 B CN 101679053B
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- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- HFXKQSZZZPGLKQ-UHFFFAOYSA-N cyclopentamine Chemical compound CNC(C)CC1CCCC1 HFXKQSZZZPGLKQ-UHFFFAOYSA-N 0.000 description 1
- 229960003263 cyclopentamine Drugs 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 1
- UZBQIPPOMKBLAS-UHFFFAOYSA-N diethylazanide Chemical compound CC[N-]CC UZBQIPPOMKBLAS-UHFFFAOYSA-N 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 1
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
- GTCDARUMAMVCRO-UHFFFAOYSA-M tetraethylazanium;acetate Chemical compound CC([O-])=O.CC[N+](CC)(CC)CC GTCDARUMAMVCRO-UHFFFAOYSA-M 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000010555 transalkylation reaction Methods 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates (SAPO compounds)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
-
- B01J35/50—
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates (SAPO compounds), e.g. CoSAPO
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/54—Phosphates, e.g. APO or SAPO compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
- C07C1/322—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a sulfur atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J2029/062—Mixtures of different aluminosilicates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Abstract
Description
实施例 | 3 |
摩尔组成 | 1TEAOH/0.1 SiO2/0.9 P2O5/0.9 Al2O3/12 TIA |
TEAOH(在水中,浓度40%),g | 28.03 |
异丙醇Al 98%,g | 27.82 |
TIA,g | 27.81 MeOH |
Aerosil 200,g | 0.50 |
H3PO4(在水中,浓度85%),g | 15.80 |
条件 | 160℃、3天 |
XRD | SAPO-18 |
SEM | 层状 |
实施例 | 4 |
摩尔组成 | 1 TEAOH/0.3 SiO2/1 P2O5/1 Al2O3/12 TIA |
TEAOH(在水中,浓度35%),g | 28.00 |
异丙醇Al 98%,g | 27.80 |
TIA,g | 50.15EG |
Aerosil 200,g | 1.34 |
H3PO4(在水中,浓度85%),g | 15.30 |
条件 | 3天、160℃ |
XRD | SAPO-18 |
SEM | 层状 |
实施例 | 7 |
摩尔组成 | 1 TEAOH/0.6 SiO2/1 P2O5/1 Al2O3/12 TIA |
TEAOH(在水中,浓度35%),g | 28.10 |
异丙醇Al 98%,g | 27.80 |
TIA,g | 50.08EG |
Aerosil 200,g | 2.50 |
H3PO4(在水中,浓度85%),g | 15.30 |
条件 | 3天、160℃ |
XRD | SAPO-18 |
SEM | 层状 |
实施例 | 8 |
摩尔组成 | 1 TEAOH/0.6 SiO2/0.9 P2O5/0.9 Al2O3/12 TIA |
TEAOH(在水中,浓度40%),g | 28.03 |
异丙醇Al 98%,g | 27.82 |
TIA,g | 39.99Eth |
Aerosil 200,g | 3.06 |
H3PO4(在水中,浓度85%),g | 15.80 |
条件 | 3天、160℃ |
XRD | SAPO-34 |
SEM | 层状,图2 |
实施例 | 9 |
摩尔组成 | 1 TEAOH/0.3 SiO2/1 P2O5/1 Al2O3/12 TIA |
TEAOH(在水中,浓度35%),g | 28.10 |
异丙醇Al98%,g | 27.80 |
TIA,g | 50.08EG |
Aerosil 200,g | 1.34 |
H3PO4(在水中,浓度85%),g | 15.50 |
条件 | 3天、190℃ |
XRD | SAPO-18 |
SEM | 层状 |
实施例 | 12 |
凝胶的摩尔组成 | 0.7 TEAOH/0.1 SiO2/1 Al2O3/15EG/1 P2O5 |
TEAOH(在水中,浓度35%),g | 9.81 |
异丙醇Al 98%,g | 13.89 |
TIA,g | 31.35EG |
Aerosil 200,g | 0.20 |
H3PO4(在水中,浓度85%),g | 7.69 |
条件 | 160℃、4天 |
XRD | SAPO-18 |
SEM | 层状 |
实施例 | 13 |
摩尔组成 | 2 TEAOH/0.1 SiO2/1 Al2O3/1 P2O5/6EG |
TEAOH(在水中,浓度35%),g | 28.00 |
异丙醇Al 98%,g | 13.90 |
TIA,g | 12.54EG |
Aerosil 200,g | 0.20 |
H3PO4(在水中,浓度85%),g | 7.69 |
条件 | 160℃、4天 |
XRD | SAPO-18 |
SEM | 层状,图3 |
实施例 | 14 |
摩尔组成 | 1 TEAOH/0.05 SiO2/1 Al2O3/1 P2O5/12EG |
TEAOH(在水中,浓度35%),g | 14.00 |
异丙醇Al 98%,g | 13.90 |
TIA,g | 25.08EG |
Aerosil 200,g | 0.10 |
H3PO4(在水中,浓度85%),g | 7.7 |
条件 | 160℃、4天 |
XRD | SAPO-18 |
SEM | 层状 |
实施例 | 对比例I |
配方 | US 6 540 970 B1 |
摩尔组成 | 2 TEAOH/0.1 SiO2/1 Al2O3/1 P2O5/50 H2O/8Eth |
H2O,g | 19.90 |
TEAOH(在水中,浓度35%),g | 60.00 |
Al源(catapal B),g其为水合氧化铝 | 10.04 |
乙醇,g | 26.28 |
Si源TEOS,g | 1.52 |
H3PO4(在水中,浓度85%),g | 16.44 |
条件 | 195℃、1天 |
XRD | SAPO-34/18 |
SEM | 立方晶体,图4 |
实施例 | 对比例II |
摩尔组成 | 0.4 SiO2∶1 Al2O3∶0.9 P2O5∶50 H2O∶1.9 DPEA |
H2O,g | 66.92 |
H3PO4(在水中,浓度85%),g | 16.73 |
Al源(catapal B),g其为水合氧化铝 | 11.35 |
Aerosil 200,g | 1.96 |
DPEA,g | 20.00 |
条件 | 160℃、7天 |
XRD | SAPO-18 |
SEM | 立方,图5 |
实施例 | 对比例IIIa | 对比例IIIb |
配方参考文献 | US 6 334 994 | Microporous Mesoporous1999,29,159 |
摩尔组成 | 0.075 SiO2/Al2O3/0.98P2O5/2 TEAOH | 0.3 SiO2/Al2O3/0.98 P2O5/2 TEAOH |
H2O,g | 18.06 | 36.08 |
异丙醇Al 98%,g | 13.80 | 27.23 |
H3PO4(在水中,浓度85%),g | 7.52 | 15.17 |
HCl,g | 0.12 | 0.20 |
LudoxAS 40(40%氧化硅),g | 0.54 | 4.00 |
TEAOH(在水中,浓度35%),g | 28.20 | 56.08 |
XRD | SAPO-18 | SAPO-34 |
SEM | 层状立方,图6 | 立方,图7 |
实施例 | 对比例IV,与US 6 953 767 B2的实施例1相同 |
摩尔组成 | 0.15 SiO2/1 Al2O3/1 P2O5/1 TEAOH/35H2O |
条件 | 175℃、8小时 |
转速,rpm | 60 |
H2O,g | 32.13 |
氧化铝(Condea Pural SB),g | 19.85 |
H3PO4(在水中,浓度85%),g | 33.55 |
Ludox AS 40(40%氧化硅),g | 3.32 |
TEAOH(在水中,浓度35%),g | 61.40 |
总重量,g | 150.25 |
XRD | AEI/CHA~0.2 |
SEM | 层状立方,图8 |
SAPO-18 | SAPO-18 | SAPO-18 | SAPO-18 | SAPO-34/18 | SAPO-18 | |
形态 | 层状 | 层状 | 层状 | 层状 | 立方 | 立方 |
实施例的催化剂 | 实施例1 | 实施例5 | 实施例10 | 实施例14 | 对比例I | 对比例II |
流出物中的甲烷 | 2.8 | 1.7 | 2.9 | 2.8 | 4.7 | 4.9 |
链烷烃(包括大于C1的)烯烃二烯烃芳烃 | 8.790.70.40.1 | 3.695.90.20.3 | 5.494.20.40.1 | 8.291.00.20.5 | 10.185.43.80.7 | 9.385.94.20.6 |
C2纯度C3纯度C3/C2C2+C3 | 99991.270.4 | 99991.272.7 | 99991.274.3 | 98991.373.2 | 95971.073.2 | 97971.070.8 |
乙烯 | 32.1 | 33.5 | 34.1 | 31.7 | 36.0 | 35.1 |
丙烯 | 38.3 | 39.2 | 40.2 | 41.5 | 37.3 | 35.7 |
SAPO-18 | SAPO-34 | |
形态 | 层状 | 层状立方 |
实施例12 | 对比例IIIa | |
81/742 | 81/752 | |
流出物中的甲烷 | 2.0 | 2.5 |
C2纯度 | 100 | 100 |
C3纯度 | 100 | 98 |
C3/C2 | 1.2 | 1.0 |
C2+C3 | 78.0 | 80.0 |
乙烯 | 36.0 | 41.0 |
丙烯 | 42.0 | 39.0 |
Claims (59)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
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EP07300860.9 | 2007-03-13 | ||
EP07300860A EP1970350A1 (en) | 2007-03-13 | 2007-03-13 | Metalloaluminophosphate molecular sieves with lamellar crystal morphology and their preparation |
US93944007P | 2007-05-22 | 2007-05-22 | |
US60/939,440 | 2007-05-22 | ||
PCT/EP2008/052807 WO2008110526A1 (en) | 2007-03-13 | 2008-03-10 | Metalloaluminophosphate molecular sieves with lamellar crystal morphology and their preparation |
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CN101679053A CN101679053A (zh) | 2010-03-24 |
CN101679053B true CN101679053B (zh) | 2011-12-28 |
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CN2008800152276A Expired - Fee Related CN101679053B (zh) | 2007-03-13 | 2008-03-10 | 具有层状晶体形态的金属磷酸铝分子筛及其制备 |
Country Status (5)
Country | Link |
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US (1) | US8518370B2 (zh) |
EP (2) | EP1970350A1 (zh) |
CN (1) | CN101679053B (zh) |
EA (1) | EA016215B1 (zh) |
WO (1) | WO2008110526A1 (zh) |
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EP2161242A1 (en) * | 2008-08-29 | 2010-03-10 | Total Petrochemicals Research Feluy | Method for Preparing Crystalline Metalloaluminophosphate (MeAPO) Molecular Sieve from Amorphous Materials |
EP2161243A1 (en) * | 2008-08-29 | 2010-03-10 | Total Petrochemicals Research Feluy | Method for preparing metalloaluminophosphate (MeAPO) molecular sieves |
EP2338865A1 (en) | 2009-12-22 | 2011-06-29 | Total Petrochemicals Research Feluy | Process for removing oxygenated contaminants from an hydrocarbon stream |
EP2338864A1 (en) | 2009-12-22 | 2011-06-29 | Total Petrochemicals Research Feluy | Process for removing oxygenated contaminants from an hydrocarbon stream |
EP2348004A1 (en) | 2010-01-25 | 2011-07-27 | Total Petrochemicals Research Feluy | Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process |
CN101857244B (zh) * | 2010-06-22 | 2012-02-29 | 上海兖矿能源科技研发有限公司 | 一种磷酸硅铝分子筛及其制备方法和应用 |
WO2012142084A1 (en) | 2011-04-11 | 2012-10-18 | ADA-ES, Inc. | Fluidized bed method and system for gas component capture |
TWI432262B (zh) | 2012-08-10 | 2014-04-01 | China Petrochemical Dev Corp Taipei Taiwan | Method for making epoxides |
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CN103964457B (zh) * | 2013-01-29 | 2016-12-28 | 中国科学院过程工程研究所 | 一种sapo分子筛及其制备方法和用途 |
CN104511271B (zh) * | 2013-09-24 | 2017-12-15 | 中国石油化工股份有限公司 | 一种分子筛、其制造方法及其应用 |
BR102016026121B1 (pt) * | 2015-11-09 | 2021-09-14 | China Petroleum & Chemical Corporation | Peneira molecular scm-10, processo para sua produção, composição e uso |
BR102016026135B1 (pt) * | 2015-11-09 | 2021-09-21 | Shanghai Research Institute Of Petrochemical Technology, Sinopec | Peneira molecular que apresenta a estrutura sfe, processo para sua produção, composição e uso |
BR102016026128B1 (pt) | 2015-11-09 | 2022-10-04 | Shanghai Research Institute Of Petrochemical Technology, Sinopec | Peneiras moleculares scm-11, processo para a produção das mesmas, seus usos e composição de peneira molecular |
CN106809860B (zh) * | 2015-11-27 | 2019-03-19 | 中国科学院大连化学物理研究所 | 一种ats型金属磷酸铝分子筛的离子热合成方法 |
WO2017187418A1 (en) * | 2016-04-28 | 2017-11-02 | Johnson Matthey Public Limited Company | Sta-20, a novel molecular sieve framework type, methods of preparation and use |
CN108495711B (zh) * | 2016-05-25 | 2021-08-03 | 环球油品公司 | 高电荷密度金属铝磷硅酸盐分子筛MeAPSO-82 |
EP3642157B1 (en) * | 2017-06-19 | 2021-03-10 | Sachem, Inc. | Morpholinium-based quaternary ammonium cation and aei type zeolite made therewith |
US20200261857A1 (en) * | 2017-08-10 | 2020-08-20 | Total Research & Technology Feluy | MeAPO-18 Membranes with Lamellar Crystal Morphology and Their Preparation |
CN109395771B (zh) * | 2018-09-26 | 2021-07-16 | 昆明理工大学 | 一种酯化-皂化反应催化剂及其制备方法和应用 |
CN111115655B (zh) * | 2018-10-30 | 2022-07-12 | 中国石油化工股份有限公司 | 共晶纳米分子筛、制备方法及其应用 |
CN113753916B (zh) * | 2020-06-01 | 2023-05-02 | 中国石油化工股份有限公司 | Sapo复合分子筛及其制备方法和其用途 |
CN114180594B (zh) * | 2020-09-14 | 2023-05-02 | 中国石油化工股份有限公司 | 一种ith分子筛的制备方法 |
CN113000021B (zh) * | 2021-02-18 | 2023-07-21 | 北京明星绿能化工科技有限公司 | 用于精制分离相变蜡的梯级孔分子筛的制备及应用方法 |
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- 2008-03-10 WO PCT/EP2008/052807 patent/WO2008110526A1/en active Application Filing
- 2008-03-10 EA EA200901232A patent/EA016215B1/ru not_active IP Right Cessation
- 2008-03-10 CN CN2008800152276A patent/CN101679053B/zh not_active Expired - Fee Related
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EA016215B1 (ru) | 2012-03-30 |
US20100179296A1 (en) | 2010-07-15 |
CN101679053A (zh) | 2010-03-24 |
WO2008110526A1 (en) | 2008-09-18 |
US8518370B2 (en) | 2013-08-27 |
EP1970350A1 (en) | 2008-09-17 |
EA200901232A1 (ru) | 2010-04-30 |
EP2121523A1 (en) | 2009-11-25 |
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