EA200702028A1 - Реакторная система и способ для производства окиси этилена - Google Patents

Реакторная система и способ для производства окиси этилена

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Publication number
EA200702028A1
EA200702028A1 EA200702028A EA200702028A EA200702028A1 EA 200702028 A1 EA200702028 A1 EA 200702028A1 EA 200702028 A EA200702028 A EA 200702028A EA 200702028 A EA200702028 A EA 200702028A EA 200702028 A1 EA200702028 A1 EA 200702028A1
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EA
Eurasian Patent Office
Prior art keywords
ethylene
reactor system
ethylene glycol
ethylene oxide
production
Prior art date
Application number
EA200702028A
Other languages
English (en)
Other versions
EA011641B1 (ru
Inventor
Алоэйсиус Николас Рене Бос
Лесли Эндрю Чутер
Джеффри Майкл Кобе
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of EA200702028A1 publication Critical patent/EA200702028A1/ru
Publication of EA011641B1 publication Critical patent/EA011641B1/ru

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067Heating or cooling the reactor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/30223Cylinder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/304Composition or microstructure of the elements
    • B01J2219/30416Ceramic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/304Composition or microstructure of the elements
    • B01J2219/30475Composition or microstructure of the elements comprising catalytically active material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)

Abstract

Заявлены реакторная система для эпоксидирования этилена, которая включает удлиненную трубу, имеющую внутренний диаметр трубы больше чем 40 мм, в которой содержится слой катализатора из частиц катализатора, содержащих серебро и промотирующий компонент, осажденный на носитель, промотирующий компонент, содержит элемент, выбранный из рения, вольфрама, молибдена и хрома; способ эпоксидирования этилена, включающий реакцию этилена с кислородом в присутствии слоя катализатора, содержащегося в реакторной системе; и способ получения этиленгликоля, эфира этиленгликоля или этаноламина, включающий получение окиси этилена в процессе эпоксидирования этилена, и превращение окиси этилена в этиленгликоль, эфир этиленгликоля, или этаноламин. Предпочтительно, внутренний диаметр трубы составляет по меньшей мере 45 мм.
EA200702028A 2005-03-22 2006-03-20 Реакторная система и способ для производства окиси этилена EA011641B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US66398405P 2005-03-22 2005-03-22
PCT/US2006/009929 WO2006102189A1 (en) 2005-03-22 2006-03-20 A reactor system and process for the manufacture of ethylene oxide

Publications (2)

Publication Number Publication Date
EA200702028A1 true EA200702028A1 (ru) 2008-02-28
EA011641B1 EA011641B1 (ru) 2009-04-28

Family

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Family Applications (1)

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EA200702028A EA011641B1 (ru) 2005-03-22 2006-03-20 Реакторная система и способ для производства окиси этилена

Country Status (12)

Country Link
US (1) US20090234144A1 (ru)
EP (1) EP1861196A1 (ru)
JP (1) JP5421587B2 (ru)
KR (1) KR20070112870A (ru)
CN (1) CN101146604A (ru)
AU (1) AU2006227295A1 (ru)
BR (1) BRPI0608862A2 (ru)
CA (1) CA2602163C (ru)
EA (1) EA011641B1 (ru)
MX (1) MX2007011550A (ru)
TW (1) TWI510475B (ru)
WO (1) WO2006102189A1 (ru)

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Also Published As

Publication number Publication date
CA2602163C (en) 2014-02-18
TWI510475B (zh) 2015-12-01
AU2006227295A1 (en) 2006-09-28
TW200640892A (en) 2006-12-01
MX2007011550A (es) 2007-10-19
US20090234144A1 (en) 2009-09-17
CN101146604A (zh) 2008-03-19
CA2602163A1 (en) 2006-09-28
WO2006102189A1 (en) 2006-09-28
KR20070112870A (ko) 2007-11-27
BRPI0608862A2 (pt) 2010-02-02
JP2008534501A (ja) 2008-08-28
JP5421587B2 (ja) 2014-02-19
EP1861196A1 (en) 2007-12-05
EA011641B1 (ru) 2009-04-28

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