EA032939B1 - Способ получения метилацетата - Google Patents

Способ получения метилацетата

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Publication number
EA032939B1
EA032939B1 EA201890301A EA201890301A EA032939B1 EA 032939 B1 EA032939 B1 EA 032939B1 EA 201890301 A EA201890301 A EA 201890301A EA 201890301 A EA201890301 A EA 201890301A EA 032939 B1 EA032939 B1 EA 032939B1
Authority
EA
Eurasian Patent Office
Prior art keywords
methyl acetate
present
catalyst
molecular sieve
zeolite molecular
Prior art date
Application number
EA201890301A
Other languages
English (en)
Other versions
EA201890301A1 (ru
Inventor
Хончао Лю
Вэньлян Чжу
Юн Лю
Юмин Ни
Чжунминь Лю
Линьин Ван
Пэн Тянь
Original Assignee
Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс filed Critical Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс
Publication of EA201890301A1 publication Critical patent/EA201890301A1/ru
Publication of EA032939B1 publication Critical patent/EA032939B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7019—EMT-type, e.g. EMC-2, ECR-30, CSZ-1, ZSM-3 or ZSM-20
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7069—EMT-type, e.g. EMC-2, ECR-30, CSZ-1, ZSM-3 or ZSM-20
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7438—EMT-type, e.g. EMC-2, ECR-30, CSZ-1, ZSM-3 or ZSM-20
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7638—EMT-type, e.g. EMC-2, ECR-30, CSZ-1, ZSM-3 or ZSM-20
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds

Abstract

Изобретение обеспечивает способ получения метилацетата, способ предусматривает стадию, на которой диметиловый эфир и сырьевой газ, содержащий монооксид углерода, проходят через реактор, загруженный катализатором, для проведения реакции карбонилирования; причем катализатор содержит кислотное цеолитное молекулярное сито типа ЕМТ. Настоящее изобретение обеспечило новый способ получения метилацетата. В способе настоящего изобретения карбонилирование проводят в присутствии катализатора, содержащего кислотное цеолитное молекулярное сито типа ЕМТ, и активность реакции высока, а стабильность была значительно повышена, удовлетворяя требованию промышленного производства.
EA201890301A 2015-07-20 2015-12-08 Способ получения метилацетата EA032939B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201510427090.7A CN106365995B (zh) 2015-07-20 2015-07-20 一种乙酸甲酯的生产方法
PCT/CN2015/096653 WO2017012246A1 (zh) 2015-07-20 2015-12-08 一种乙酸甲酯的生产方法

Publications (2)

Publication Number Publication Date
EA201890301A1 EA201890301A1 (ru) 2018-07-31
EA032939B1 true EA032939B1 (ru) 2019-08-30

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Family Applications (1)

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EA201890301A EA032939B1 (ru) 2015-07-20 2015-12-08 Способ получения метилацетата

Country Status (11)

Country Link
US (1) US10287233B2 (ru)
EP (1) EP3326996B1 (ru)
JP (1) JP6523549B2 (ru)
CN (1) CN106365995B (ru)
AU (1) AU2015403144B2 (ru)
BR (1) BR112018001186B1 (ru)
CA (1) CA2993875A1 (ru)
EA (1) EA032939B1 (ru)
SA (1) SA518390760B1 (ru)
WO (1) WO2017012246A1 (ru)
ZA (1) ZA201800637B (ru)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106365994B (zh) * 2015-07-20 2019-01-01 中国科学院大连化学物理研究所 一种低级脂肪羧酸烷基酯的生产方法
CN106964396B (zh) * 2017-04-14 2019-06-28 中触媒新材料股份有限公司 用于二甲醚羰基化反应的rth型拓扑结构分子筛催化剂及其制备方法和应用
WO2019061358A1 (zh) 2017-09-29 2019-04-04 中国科学院大连化学物理研究所 一种合成气直接生产乙酸甲酯和/或乙酸的方法
CN109574839B (zh) * 2017-09-29 2021-08-31 中国科学院大连化学物理研究所 一种合成气直接生产乙酸甲酯和/或乙酸的方法
CN111514925B (zh) * 2019-02-02 2021-06-15 中国科学院大连化学物理研究所 一种二甲醚生产乙酸甲酯联产丙酮催化剂、其制备方法及其应用
CN111517955A (zh) * 2019-02-02 2020-08-11 中国科学院大连化学物理研究所 一种二甲醚羰基化生产乙酸甲酯的方法
CN111517956A (zh) * 2019-02-02 2020-08-11 中国科学院大连化学物理研究所 一种二甲醚生产乙酸甲酯联产丙烯酸甲酯的方法
EP3919470A4 (en) * 2019-02-02 2022-03-23 Dalian Institute of Chemical Physics, Chinese Academy of Sciences PROCESS FOR THE PRODUCTION OF METHYL ACETATE BY CARBONYLATION OF DIMETHYL ETHER
CN111514940A (zh) * 2019-02-02 2020-08-11 中国科学院大连化学物理研究所 一种一步法制备丙酮的催化剂、其制备方法及其应用
CN110694679B (zh) * 2019-10-30 2023-04-18 上海绿强新材料有限公司 一种emt/fau核壳分子筛催化剂及其制备方法和应用
CN112791743B (zh) * 2019-11-13 2022-04-15 中国科学院大连化学物理研究所 一种二甲醚羰基化生产乙酸甲酯的催化剂、其制备方法及其应用
CN111087002B (zh) * 2019-12-04 2021-10-22 延长中科（大连）能源科技股份有限公司 一种丝光沸石分子筛的制备方法及应用
CN113019391B (zh) * 2019-12-09 2023-07-25 中科榆林能源技术运营有限责任公司 一种乙酸环己酯加氢制备环己醇和乙醇的催化剂、其制备方法和应用
CN111921539B (zh) * 2020-08-11 2022-11-11 广东工业大学 一种Ni-Ru/GO双金属催化剂及其制备方法
CN113019441B (zh) * 2021-03-17 2021-11-02 中国矿业大学 一种原位掺杂金属铁的mor分子筛的制备方法及应用
CN115138391A (zh) * 2021-03-29 2022-10-04 高化学株式会社 低温羰基化分子筛催化剂及其用途
CN113996337B (zh) * 2021-12-06 2023-08-22 陕西延长石油（集团）有限责任公司 一种催化高碳氢比合成气制乙酸的催化剂及其制备方法与应用
CN115591574A (zh) * 2022-10-08 2023-01-13 扬州晨化新材料股份有限公司（Cn） 一种多孔氧化铝负载金属铜催化剂及其制备方法
CN116212943A (zh) * 2022-12-05 2023-06-06 江苏宏邦化工科技有限公司 一种新型碱性催化剂的制备方法及其在制备甲基庚烯酮中的应用

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070238897A1 (en) * 2005-05-05 2007-10-11 The Regents Of The University Of California Process for carbonylation of alkyl ethers
CN101600678A (zh) * 2006-12-15 2009-12-09 加州大学评议会 脂肪醇和/或其反应性衍生物羰基化的方法
CN101613274A (zh) * 2008-06-25 2009-12-30 中国科学院大连化学物理研究所 一种二甲醚羰基化制备乙酸甲酯的方法
CN101903325A (zh) * 2007-12-20 2010-12-01 英国石油化学品有限公司 生产乙酸和/或乙酸甲酯的羰基化方法
CN103896769A (zh) * 2012-12-25 2014-07-02 中国科学院大连化学物理研究所 一种二甲醚羰基化制备乙酸甲酯的方法
CN104725224A (zh) * 2013-12-23 2015-06-24 中国科学院大连化学物理研究所 制备聚甲氧基二甲醚羰化物及甲氧基乙酸甲酯的方法
CN104725229A (zh) * 2013-12-23 2015-06-24 中国科学院大连化学物理研究所 制备聚甲氧基二甲醚羰化物及甲氧基乙酸甲酯的方法
CN104725230A (zh) * 2013-12-23 2015-06-24 中国科学院大连化学物理研究所 制备聚甲氧基二甲醚羰化物及甲氧基乙酸甲酯的方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0793634B1 (en) * 1994-11-23 1999-08-18 Exxon Chemical Patents Inc. Hydrocarbon conversion process using a zeolite bound zeolite catalyst
JP3965527B2 (ja) * 1995-06-21 2007-08-29 日産化学工業株式会社 ピラゾールのｎ−アルキル化方法
DE19713071A1 (de) 1997-03-27 1998-10-01 Basf Ag Verfahren zur Herstellung von 1,1-Diphenylethanen
US6127432A (en) 1998-01-29 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates and catalysts therefor
US20060252959A1 (en) * 2005-05-05 2006-11-09 The Regents Of The University Of California Process for carbonylation of alkyl ethers
CN100431959C (zh) * 2005-10-19 2008-11-12 中国石油化工股份有限公司 一种emt沸石的合成方法
EP1985606A1 (en) 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP1985607A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP2251314A1 (en) 2009-05-14 2010-11-17 BP Chemicals Limited Carbonylation process
JP2012131721A (ja) * 2010-12-20 2012-07-12 Tosoh Corp ４，４’−メチレンジアニリンの製造方法
JP2012250971A (ja) * 2011-05-12 2012-12-20 Tosoh Corp 芳香族ポリアミンの製造方法
CN102950018B (zh) * 2011-08-26 2014-12-24 中国科学院大连化学物理研究所 用于二甲醚羰基化合成乙酸甲酯的催化剂及其制备方法
CN103170360B (zh) * 2011-12-23 2015-03-25 中国科学院大连化学物理研究所 一种二甲醚羰基化催化剂及其制备方法及应用
CN103191782B (zh) * 2012-01-09 2015-08-26 爱普香料集团股份有限公司 负载型固体酸催化剂及其应用于制备酯类香料的方法
CN103012062B (zh) * 2012-12-20 2015-04-22 上海戊正工程技术有限公司 一种合成气间接生产乙醇的工艺及其应用
CN103896767B (zh) * 2012-12-25 2016-01-06 中国科学院大连化学物理研究所 一种制备乙酸甲酯的方法
CN103896770B (zh) * 2012-12-25 2015-10-28 中国科学院大连化学物理研究所 一种生产乙酸甲酯的方法
CN103896766B (zh) * 2012-12-25 2015-12-09 中国科学院大连化学物理研究所 一种生产乙酸甲酯的方法
CN103896768B (zh) * 2012-12-25 2016-03-09 中国科学院大连化学物理研究所 一种制备乙酸甲酯的方法
KR20150125720A (ko) 2013-03-08 2015-11-09 비피 케미칼즈 리미티드 카르보닐화 방법
CN103657715B (zh) * 2013-12-04 2015-08-19 中国科学院山西煤炭化学研究所 甲醇或二甲醚羰基化合成醋酸甲酯的催化剂及制法和应用
CN106365994B (zh) * 2015-07-20 2019-01-01 中国科学院大连化学物理研究所 一种低级脂肪羧酸烷基酯的生产方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070238897A1 (en) * 2005-05-05 2007-10-11 The Regents Of The University Of California Process for carbonylation of alkyl ethers
CN101600678A (zh) * 2006-12-15 2009-12-09 加州大学评议会 脂肪醇和/或其反应性衍生物羰基化的方法
CN101903325A (zh) * 2007-12-20 2010-12-01 英国石油化学品有限公司 生产乙酸和/或乙酸甲酯的羰基化方法
CN101613274A (zh) * 2008-06-25 2009-12-30 中国科学院大连化学物理研究所 一种二甲醚羰基化制备乙酸甲酯的方法
CN103896769A (zh) * 2012-12-25 2014-07-02 中国科学院大连化学物理研究所 一种二甲醚羰基化制备乙酸甲酯的方法
CN104725224A (zh) * 2013-12-23 2015-06-24 中国科学院大连化学物理研究所 制备聚甲氧基二甲醚羰化物及甲氧基乙酸甲酯的方法
CN104725229A (zh) * 2013-12-23 2015-06-24 中国科学院大连化学物理研究所 制备聚甲氧基二甲醚羰化物及甲氧基乙酸甲酯的方法
CN104725230A (zh) * 2013-12-23 2015-06-24 中国科学院大连化学物理研究所 制备聚甲氧基二甲醚羰化物及甲氧基乙酸甲酯的方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CELIK, F.E. et al. "An Investigation into the Mechanism and Kinetics of Dimethoxymethane Carbonylation over FAU and MFI Zeolites", JOURNAL OF CATALYSIS, vol 274, 02 August 2010 (02. 08. 2010), ISSN: 0021-9517, pages 150-162 *
GAO, Daowei et al. "Research Advance On EMT Zeolite Synthesis and Application", CHEMICAL PRODUCTION AND TECHNOLOGY, vol 19, no 6, 31 December 2012 (31. 12. 2012), ISSN: 1006-6829, pages 46-50 *
W.U., Wenbing et al. "Process of Synthesis and Application of Methyl Acetate", JIANGSU CHEMICAL INDUSTRY, vol 32, no 5, 31 October 2004 (31. 10. 2004), ISSN: 1002-1116, pages 11-14 *

Also Published As

Publication number Publication date
SA518390760B1 (ar) 2021-07-14
ZA201800637B (en) 2019-07-31
WO2017012246A1 (zh) 2017-01-26
EP3326996A1 (en) 2018-05-30
JP2018520191A (ja) 2018-07-26
AU2015403144B2 (en) 2020-04-16
AU2015403144A1 (en) 2018-02-08
BR112018001186A2 (ru) 2017-01-26
BR112018001186B1 (pt) 2022-02-15
CA2993875A1 (en) 2017-01-26
US10287233B2 (en) 2019-05-14
CN106365995B (zh) 2018-06-05
EP3326996A4 (en) 2018-07-25
JP6523549B2 (ja) 2019-06-05
CN106365995A (zh) 2017-02-01
EP3326996B1 (en) 2020-04-22
EA201890301A1 (ru) 2018-07-31
US20180370896A1 (en) 2018-12-27

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