EA019075B1 - Способ получения модифицированных полипропиленовых композиций - Google Patents
Способ получения модифицированных полипропиленовых композиций Download PDFInfo
- Publication number
- EA019075B1 EA019075B1 EA201170234A EA201170234A EA019075B1 EA 019075 B1 EA019075 B1 EA 019075B1 EA 201170234 A EA201170234 A EA 201170234A EA 201170234 A EA201170234 A EA 201170234A EA 019075 B1 EA019075 B1 EA 019075B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- ethylene
- propylene copolymer
- propylene
- composition
- mass
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 93
- -1 polypropylene Polymers 0.000 title claims abstract description 77
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 58
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 57
- 238000004519 manufacturing process Methods 0.000 title description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 63
- 229920001577 copolymer Polymers 0.000 claims abstract description 52
- 238000000034 method Methods 0.000 claims abstract description 50
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000005977 Ethylene Substances 0.000 claims abstract description 38
- 239000011159 matrix material Substances 0.000 claims abstract description 35
- 239000002253 acid Substances 0.000 claims abstract description 25
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 25
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 23
- 229920001971 elastomer Polymers 0.000 claims abstract description 22
- 150000002978 peroxides Chemical class 0.000 claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- 239000004711 α-olefin Substances 0.000 claims abstract description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 16
- 229920001384 propylene homopolymer Polymers 0.000 claims abstract description 16
- 239000000155 melt Substances 0.000 claims abstract description 14
- 239000000806 elastomer Substances 0.000 claims abstract description 10
- 241000282376 Panthera tigris Species 0.000 claims description 19
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 16
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 12
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 239000008116 calcium stearate Substances 0.000 claims description 11
- 235000013539 calcium stearate Nutrition 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical group CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 claims description 5
- 238000009825 accumulation Methods 0.000 claims description 3
- 229920005629 polypropylene homopolymer Polymers 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 10
- 238000003860 storage Methods 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 230000002000 scavenging effect Effects 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 65
- 238000002156 mixing Methods 0.000 description 17
- 239000000047 product Substances 0.000 description 15
- 239000000654 additive Substances 0.000 description 14
- 238000002474 experimental method Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 12
- 239000003381 stabilizer Substances 0.000 description 12
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 11
- 239000000370 acceptor Substances 0.000 description 9
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- 238000001746 injection moulding Methods 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 6
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 6
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 6
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 4
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 4
- 230000006399 behavior Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 229920001684 low density polyethylene Polymers 0.000 description 4
- 239000004702 low-density polyethylene Substances 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 4
- 238000000518 rheometry Methods 0.000 description 4
- 229920002725 thermoplastic elastomer Polymers 0.000 description 4
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 3
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000004627 transmission electron microscopy Methods 0.000 description 3
- FPAZNLSVMWRGQB-UHFFFAOYSA-N 1,2-bis(tert-butylperoxy)-3,4-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=C(OOC(C)(C)C)C(OOC(C)(C)C)=C1C(C)C FPAZNLSVMWRGQB-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 125000004386 diacrylate group Chemical group 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- BOOBDAVNHSOIDB-UHFFFAOYSA-N (2,3-dichlorobenzoyl) 2,3-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC(C(=O)OOC(=O)C=2C(=C(Cl)C=CC=2)Cl)=C1Cl BOOBDAVNHSOIDB-UHFFFAOYSA-N 0.000 description 1
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- GWQOYRSARAWVTC-UHFFFAOYSA-N 1,4-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=C(C(C)(C)OOC(C)(C)C)C=C1 GWQOYRSARAWVTC-UHFFFAOYSA-N 0.000 description 1
- VVFNNEKHSFZNKA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-ene Chemical compound CC(C)(C)OOC(C)(C)C=CC(C)(C)OOC(C)(C)C VVFNNEKHSFZNKA-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- PSYGHMBJXWRQFD-UHFFFAOYSA-N 2-(2-sulfanylacetyl)oxyethyl 2-sulfanylacetate Chemical compound SCC(=O)OCCOC(=O)CS PSYGHMBJXWRQFD-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920011250 Polypropylene Block Copolymer Polymers 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 229960005069 calcium Drugs 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- 229940078456 calcium stearate Drugs 0.000 description 1
- OEUVSBXAMBLPES-UHFFFAOYSA-L calcium stearoyl-2-lactylate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O.CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O OEUVSBXAMBLPES-UHFFFAOYSA-L 0.000 description 1
- 239000003916 calcium stearoyl-2-lactylate Substances 0.000 description 1
- 235000010957 calcium stearoyl-2-lactylate Nutrition 0.000 description 1
- QSSGIYRIEKPVTG-UHFFFAOYSA-L calcium;nonanoate Chemical compound [Ca+2].CCCCCCCCC([O-])=O.CCCCCCCCC([O-])=O QSSGIYRIEKPVTG-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- MPRVXUYAJZZBHG-UHFFFAOYSA-K dicarbonoperoxoyloxyalumanyl hydroxy carbonate Chemical compound [Al+3].OOC([O-])=O.OOC([O-])=O.OOC([O-])=O MPRVXUYAJZZBHG-UHFFFAOYSA-K 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- OUHCLAKJJGMPSW-UHFFFAOYSA-L magnesium;hydrogen carbonate;hydroxide Chemical compound O.[Mg+2].[O-]C([O-])=O OUHCLAKJJGMPSW-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000004978 peroxycarbonates Chemical class 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229940057977 zinc stearate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08013231 | 2008-07-23 | ||
| PCT/EP2009/005069 WO2010009825A1 (en) | 2008-07-23 | 2009-07-10 | Process for preparing modified polypropylene compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201170234A1 EA201170234A1 (ru) | 2011-10-31 |
| EA019075B1 true EA019075B1 (ru) | 2013-12-30 |
Family
ID=39952204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201170234A EA019075B1 (ru) | 2008-07-23 | 2009-07-10 | Способ получения модифицированных полипропиленовых композиций |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20110118400A1 (enExample) |
| EP (1) | EP2315804B1 (enExample) |
| JP (1) | JP5513503B2 (enExample) |
| KR (1) | KR101593256B1 (enExample) |
| CN (1) | CN102105527A (enExample) |
| EA (1) | EA019075B1 (enExample) |
| MX (1) | MX2011000864A (enExample) |
| WO (1) | WO2010009825A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2747968C1 (ru) * | 2017-02-03 | 2021-05-18 | Бореалис Аг | Применение полимерной композиции для производства изделий с улучшенной окрашиваемостью и улучшенным внешним видом поверхности |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012049690A1 (en) * | 2010-10-14 | 2012-04-19 | Reliance Industries Ltd. | A process for preparing high melt strength propylene polymers |
| ES2488621T3 (es) * | 2011-08-11 | 2014-08-28 | Borealis Ag | Composición mejorada en cuanto a la visibilidad del rayado y con baja pegajosidad superficial |
| EP2767559B1 (en) | 2011-10-11 | 2018-11-21 | Braskem S.A. | Polypropylene for the production of thermoformed articles, large, deep, complex and/or thick articles, process for thermoforming modified polypropylene into large, deep, complex and/or thick articles, and use of the polypropylene |
| US9416265B2 (en) * | 2012-11-30 | 2016-08-16 | Exxonmobil Chemical Patents Inc. | Methods of forming compositions and articles |
| EP2746326B2 (en) | 2012-12-19 | 2024-06-12 | Borealis AG | Automotive compound with reduced tigerskin |
| WO2015107532A1 (en) * | 2014-01-17 | 2015-07-23 | Reliance Industries Limited | Thermoformable polyolefin compositions |
| CN106459488B (zh) * | 2014-03-14 | 2019-09-13 | 美利肯公司 | 改性的多相聚烯烃组合物 |
| CN104292635A (zh) * | 2014-09-30 | 2015-01-21 | 苏州博利迈新材料科技有限公司 | 一种超高冲击强度的汽车保险杠复合材料及其制备方法 |
| WO2016085535A1 (en) | 2014-11-26 | 2016-06-02 | Milliken & Company | Modified heterophasic polyolefin composition |
| JP6362783B2 (ja) * | 2014-12-19 | 2018-07-25 | アブ・ダビ・ポリマーズ・カンパニー・リミテッド・（ブルージュ）・リミテッド・ライアビリティ・カンパニーＡｂｕ Ｄｈａｂｉ Ｐｏｌｙｍｅｒｓ Ｃｏ． Ｌｔｄ （Ｂｏｒｏｕｇｅ） Ｌ．Ｌ．Ｃ． | バッテリケースの優れた応力白化性能 |
| US20170349735A1 (en) * | 2014-12-19 | 2017-12-07 | Sabic Global Technologies B.V. | Process for the preparation of a heterophasic propylene copolymer |
| WO2015138305A1 (en) | 2015-02-10 | 2015-09-17 | Milliken & Company | Thermoplastic polymer compositions |
| WO2016140690A1 (en) | 2015-03-05 | 2016-09-09 | Milliken & Company | Modified heterophasic polyolefin composition |
| CN116925465A (zh) * | 2015-09-13 | 2023-10-24 | 美利肯公司 | 用于制备异相聚合物组合物的方法 |
| JP6884571B2 (ja) * | 2016-12-26 | 2021-06-09 | 日東電工株式会社 | 伸縮性フィルム、伸縮性積層体、およびそれを含む物品 |
| EP3645626B1 (en) * | 2017-06-26 | 2021-03-24 | Borealis AG | Polypropylene composition with excellent surface appearance |
| EP3732020B1 (en) * | 2017-12-26 | 2023-05-17 | Braskem America, Inc. | Method of additive manufacturing using high performance polyolefins |
| SG11202103665RA (en) * | 2018-10-12 | 2021-05-28 | Nouryon Chemicals Int Bv | Solid organic peroxide composition |
| CN113597446B (zh) * | 2019-03-21 | 2023-08-29 | Sabic环球技术有限责任公司 | 添加剂组合物 |
| US11286317B2 (en) * | 2019-04-12 | 2022-03-29 | Indian Oil Corporation Limited | Morphology modified heterophase propylene copolymers and their products thereof |
| EP4036130B1 (en) | 2021-01-29 | 2023-03-22 | Borealis AG | Modification of polyethylene copolymer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6310140B1 (en) * | 1998-01-19 | 2001-10-30 | Borealis Gmbh | Thermoplastic elastomers of good dyeability and high strength and elasticity as well as impact-resistant polymer blends produced therefrom |
| US20080150261A1 (en) * | 2004-12-30 | 2008-06-26 | Multibase Sa | Polyolefin Composition Intended For Producing a Cover For Housing a Motor Vehicle Safety Airbag |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1190681B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPH0235770B2 (ja) * | 1982-11-18 | 1990-08-13 | Mitsui Petrochemical Ind | Horipuropirensoseibutsunoseizohoho |
| US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| JP2959805B2 (ja) * | 1990-05-21 | 1999-10-06 | 三井化学株式会社 | 熱可塑性エラストマーの製造方法 |
| JP2898353B2 (ja) * | 1990-05-21 | 1999-05-31 | 三井化学株式会社 | 熱可塑性エラストマー組成物 |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| JP2896615B2 (ja) * | 1991-05-24 | 1999-05-31 | チッソ株式会社 | 架橋ポリオレフィン組成物の製造方法 |
| US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| US5707569A (en) * | 1994-02-15 | 1998-01-13 | E. I. Du Pont De Nemours And Company | Processing aid system for polyolefins |
| JPH0873546A (ja) * | 1994-06-23 | 1996-03-19 | Basf Ag | 不飽和エステルで部分的に架橋された合成樹脂材料 |
| US5468808A (en) * | 1994-09-12 | 1995-11-21 | Exxon Chemical Patents Inc. | Reduction of flow marks in rubber modified polypropylene |
| JPH08183889A (ja) * | 1994-12-28 | 1996-07-16 | Nippon Petrochem Co Ltd | ポリプロピレン樹脂組成物およびその組成物からなる容器 |
| DE69620440T3 (de) * | 1995-11-24 | 2010-05-20 | Chisso Corp. | Propylenzusammensetzung, verfahren zu deren herstellung, polypropylenzusammensetzung und geformte gegenstände |
| DE19646118A1 (de) * | 1996-11-08 | 1998-05-14 | Basf Ag | Mit ungesättigten Estern teilvernetzte Kunststoffmassen |
| US6204348B1 (en) * | 1997-05-20 | 2001-03-20 | Borealis Gmbh | Modified polypropylenes of improved processability |
| FI974175L (fi) * | 1997-11-07 | 1999-05-08 | Borealis As | Menetelmä polypropeenin valmistamiseksi |
| JP2000154270A (ja) * | 1998-11-19 | 2000-06-06 | Chisso Corp | 発泡ポリプロピレン系組成物及び発泡成形体 |
| DE10084514B4 (de) * | 2000-02-28 | 2007-05-24 | Asahi Kasei Kabushiki Kaisha | Olefinische Kautschukzusammensetzung |
| US6372847B1 (en) * | 2000-05-10 | 2002-04-16 | Exxon Mobil Chemical Patents, Inc. | Polyolefin compositions having improved low temperature toughness |
| JP3937696B2 (ja) * | 2000-06-30 | 2007-06-27 | 住友化学株式会社 | ポリプロピレン系樹脂組成物 |
| JP4116765B2 (ja) * | 2000-10-31 | 2008-07-09 | 株式会社プライムポリマー | 自動車用成形天井材およびその製造方法 |
| US6777476B2 (en) * | 2002-03-09 | 2004-08-17 | Hyundai Motor Company | Polypropylene resin composition |
| CA2430861A1 (en) * | 2002-06-03 | 2003-12-03 | The University Of British Columiba | Extrusion aid combination |
| ATE431840T1 (de) * | 2002-08-20 | 2009-06-15 | Borealis Tech Oy | Polypropylenzusammensetzung |
| US6906137B2 (en) * | 2003-03-26 | 2005-06-14 | Dupont Dow Elastomers Llc | Process aid masterbatch for melt processable polymers |
| JP4666893B2 (ja) * | 2003-07-08 | 2011-04-06 | 東燃化学株式会社 | 変性ポリプロピレンの乳化組成物 |
| US7016802B2 (en) * | 2003-09-05 | 2006-03-21 | Tyco Electronics Corporation | Photocontrol devices having flexible mounted photosensors and methods of calibrating the same |
| JP4736587B2 (ja) * | 2004-10-05 | 2011-07-27 | 住友化学株式会社 | 複合体製造用熱可塑性エラストマー組成物及び複合体 |
| US20070004864A1 (en) * | 2005-06-24 | 2007-01-04 | University Of Florida Research Foundation | Method to enhance impact strength properties of melt processed polypropylene resins |
| KR20080080569A (ko) * | 2005-12-05 | 2008-09-04 | 제이에스알 가부시끼가이샤 | 열가소성 엘라스토머 조성물, 발포체 및 그의 제조 방법 |
| WO2011076555A1 (en) * | 2009-12-21 | 2011-06-30 | Basell Poliolefine Italia S.R.L. | Impact-resistant polyolefin compositions |
-
2009
- 2009-07-10 EP EP09777147A patent/EP2315804B1/en active Active
- 2009-07-10 US US13/054,607 patent/US20110118400A1/en not_active Abandoned
- 2009-07-10 MX MX2011000864A patent/MX2011000864A/es active IP Right Grant
- 2009-07-10 JP JP2011519065A patent/JP5513503B2/ja active Active
- 2009-07-10 KR KR1020117004095A patent/KR101593256B1/ko active Active
- 2009-07-10 WO PCT/EP2009/005069 patent/WO2010009825A1/en not_active Ceased
- 2009-07-10 EA EA201170234A patent/EA019075B1/ru not_active IP Right Cessation
- 2009-07-10 CN CN2009801287909A patent/CN102105527A/zh active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6310140B1 (en) * | 1998-01-19 | 2001-10-30 | Borealis Gmbh | Thermoplastic elastomers of good dyeability and high strength and elasticity as well as impact-resistant polymer blends produced therefrom |
| US20080150261A1 (en) * | 2004-12-30 | 2008-06-26 | Multibase Sa | Polyolefin Composition Intended For Producing a Cover For Housing a Motor Vehicle Safety Airbag |
Non-Patent Citations (1)
| Title |
|---|
| DATABASE WPI Week 198428, Thomson Scientific, London, GB; AN 1984-172989, XP002504869 -& JP 59 093709 A (MITSUI PETROCHEM IND CO LTD.), 30 May 1984 (1984-05-30), cited in the application abstract * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2747968C1 (ru) * | 2017-02-03 | 2021-05-18 | Бореалис Аг | Применение полимерной композиции для производства изделий с улучшенной окрашиваемостью и улучшенным внешним видом поверхности |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102105527A (zh) | 2011-06-22 |
| JP2011528733A (ja) | 2011-11-24 |
| EP2315804A1 (en) | 2011-05-04 |
| EA201170234A1 (ru) | 2011-10-31 |
| WO2010009825A1 (en) | 2010-01-28 |
| KR101593256B1 (ko) | 2016-02-12 |
| JP5513503B2 (ja) | 2014-06-04 |
| KR20110030704A (ko) | 2011-03-23 |
| EP2315804B1 (en) | 2012-08-29 |
| US20110118400A1 (en) | 2011-05-19 |
| MX2011000864A (es) | 2011-03-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EA019075B1 (ru) | Способ получения модифицированных полипропиленовых композиций | |
| JP2011528733A5 (enExample) | ||
| CN1328314C (zh) | 用过氧化物和自由基活性助剂进行流变学改性的热塑性弹性体组合物 | |
| KR101559638B1 (ko) | 고용융장력 프로필렌 폴리머의 제조 과정 | |
| US10000631B2 (en) | Polypropylene-based resin sheet and formed object | |
| ES2382704T3 (es) | Elastómeros de olefina termoplásticos, reticulables, y elastómeros de olefina termoestables, reticulados, obtenidos a partir de éstos | |
| MXPA04002355A (es) | Elastomeros termoplasticos y procedimiento para la elaboracion de los mismos. | |
| CN110408123A (zh) | 用于制备包含非均相丙烯共聚物和滑石的组合物的方法 | |
| CA2463428A1 (en) | Thermoplastic elastomers compositions | |
| WO2016181641A1 (ja) | 樹脂組成物、及びこれを用いた合成木材 | |
| MXPA05003390A (es) | Composiciones elastomericas termoplasticas modificadas reologicamente para perfiles extruidos. | |
| JP2009510250A (ja) | 過酸化物で硬化された熱可塑性加硫ゴムとその製造方法 | |
| US20070004861A1 (en) | High melt strength polypropylene resins and method for making same | |
| JP7128318B2 (ja) | プロピレン系樹脂組成物及びその射出成形体 | |
| AU2005279250A1 (en) | Thermoplastic polyolefin composition | |
| TW202142573A (zh) | 高熔融強度聚丙烯及其製備方法 | |
| WO2007137661A1 (en) | A polyolefin composition with improved stress whitening resistance | |
| CN102653616B (zh) | 丙烯树脂组合物 | |
| JP6694390B2 (ja) | 非カーペット型床材用の光沢が低減された熱可塑性ポリオレフィン | |
| JP2012229303A (ja) | プロピレン系樹脂組成物及びその射出成形体 | |
| US11117995B2 (en) | Process for preparing high melt strength polypropylene | |
| JP5350600B2 (ja) | ポリプロピレン系樹脂組成物およびそれからなる成形体 | |
| CN1703451A (zh) | 用于压出型材的流变改性热塑性弹性体组合物 | |
| KR100538713B1 (ko) | 투명성 및 진공성형성이 우수한 폴리올레핀 수지 조성물 | |
| KR100538712B1 (ko) | 투명성 및 진공성형성이 우수한 폴리프로필렌 수지 조성물 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM |