MX2011000864A - Proceso para preparar composiciones de polipropileno modificado. - Google Patents
Proceso para preparar composiciones de polipropileno modificado.Info
- Publication number
- MX2011000864A MX2011000864A MX2011000864A MX2011000864A MX2011000864A MX 2011000864 A MX2011000864 A MX 2011000864A MX 2011000864 A MX2011000864 A MX 2011000864A MX 2011000864 A MX2011000864 A MX 2011000864A MX 2011000864 A MX2011000864 A MX 2011000864A
- Authority
- MX
- Mexico
- Prior art keywords
- mass
- ethylene
- propylene
- modified polypropylene
- alpha
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 102
- -1 polypropylene Polymers 0.000 title claims abstract description 82
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 64
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 61
- 238000004519 manufacturing process Methods 0.000 title description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 64
- 238000000034 method Methods 0.000 claims abstract description 55
- 229920001577 copolymer Polymers 0.000 claims abstract description 54
- 230000008569 process Effects 0.000 claims abstract description 44
- 239000005977 Ethylene Substances 0.000 claims abstract description 42
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000011159 matrix material Substances 0.000 claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- 239000002253 acid Substances 0.000 claims abstract description 26
- 229920001971 elastomer Polymers 0.000 claims abstract description 26
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 26
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 25
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- 150000002978 peroxides Chemical class 0.000 claims abstract description 21
- 239000004711 α-olefin Substances 0.000 claims abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 17
- 229920001384 propylene homopolymer Polymers 0.000 claims abstract description 17
- 239000000806 elastomer Substances 0.000 claims abstract description 13
- 239000000155 melt Substances 0.000 claims abstract description 10
- 238000003860 storage Methods 0.000 claims abstract description 7
- 239000002516 radical scavenger Substances 0.000 claims description 22
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 20
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 229920000573 polyethylene Polymers 0.000 claims description 13
- 239000004698 Polyethylene Substances 0.000 claims description 12
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 12
- 239000008116 calcium stearate Substances 0.000 claims description 12
- 235000013539 calcium stearate Nutrition 0.000 claims description 12
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical group CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 230000002000 scavenging effect Effects 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 64
- 238000002156 mixing Methods 0.000 description 17
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 12
- 239000000654 additive Substances 0.000 description 12
- 239000003381 stabilizer Substances 0.000 description 12
- 238000002474 experimental method Methods 0.000 description 9
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 6
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 6
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 6
- 206010040925 Skin striae Diseases 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 238000000518 rheometry Methods 0.000 description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 229920001684 low density polyethylene Polymers 0.000 description 4
- 239000004702 low-density polyethylene Substances 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 3
- 238000004435 EPR spectroscopy Methods 0.000 description 3
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 238000004627 transmission electron microscopy Methods 0.000 description 2
- BOOBDAVNHSOIDB-UHFFFAOYSA-N (2,3-dichlorobenzoyl) 2,3-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC(C(=O)OOC(=O)C=2C(=C(Cl)C=CC=2)Cl)=C1Cl BOOBDAVNHSOIDB-UHFFFAOYSA-N 0.000 description 1
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- GWQOYRSARAWVTC-UHFFFAOYSA-N 1,4-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=C(C(C)(C)OOC(C)(C)C)C=C1 GWQOYRSARAWVTC-UHFFFAOYSA-N 0.000 description 1
- KQMPMWGWJLNKPC-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCC(OC(=O)C(C)=C)OC(=O)C(C)=C KQMPMWGWJLNKPC-UHFFFAOYSA-N 0.000 description 1
- VVFNNEKHSFZNKA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-ene Chemical compound CC(C)(C)OOC(C)(C)C=CC(C)(C)OOC(C)(C)C VVFNNEKHSFZNKA-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- CQWIMCKDNIEDCG-UHFFFAOYSA-N CCC=CCC.C(C1=CC=CC=C1)(=O)OO Chemical compound CCC=CCC.C(C1=CC=CC=C1)(=O)OO CQWIMCKDNIEDCG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 206010033307 Overweight Diseases 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920011250 Polypropylene Block Copolymer Polymers 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 229960005069 calcium Drugs 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- 229940078456 calcium stearate Drugs 0.000 description 1
- OEUVSBXAMBLPES-UHFFFAOYSA-L calcium stearoyl-2-lactylate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O.CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O OEUVSBXAMBLPES-UHFFFAOYSA-L 0.000 description 1
- 239000003916 calcium stearoyl-2-lactylate Substances 0.000 description 1
- 235000010957 calcium stearoyl-2-lactylate Nutrition 0.000 description 1
- QSSGIYRIEKPVTG-UHFFFAOYSA-L calcium;nonanoate Chemical compound [Ca+2].CCCCCCCCC([O-])=O.CCCCCCCCC([O-])=O QSSGIYRIEKPVTG-UHFFFAOYSA-L 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000008395 clarifying agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- MPRVXUYAJZZBHG-UHFFFAOYSA-K dicarbonoperoxoyloxyalumanyl hydroxy carbonate Chemical compound [Al+3].OOC([O-])=O.OOC([O-])=O.OOC([O-])=O MPRVXUYAJZZBHG-UHFFFAOYSA-K 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229920005676 ethylene-propylene block copolymer Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- OUHCLAKJJGMPSW-UHFFFAOYSA-L magnesium;hydrogen carbonate;hydroxide Chemical compound O.[Mg+2].[O-]C([O-])=O OUHCLAKJJGMPSW-UHFFFAOYSA-L 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 150000004978 peroxycarbonates Chemical class 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- 229940049953 phenylacetate Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229950010765 pivalate Drugs 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 101150025733 pub2 gene Proteins 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229940057977 zinc stearate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08013231 | 2008-07-23 | ||
| PCT/EP2009/005069 WO2010009825A1 (en) | 2008-07-23 | 2009-07-10 | Process for preparing modified polypropylene compositions |
Publications (1)
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| EP2627686A4 (en) * | 2010-10-14 | 2014-04-09 | Reliance Ind Ltd | PROCESS FOR THE PREPARATION OF PROPYLENE POLYMERS WITH HIGH MELT RESISTANCE |
| EP2557117B1 (en) * | 2011-08-11 | 2014-06-11 | Borealis AG | Composition with improved scratch visibility and low surface tack |
| BR112014008748B1 (pt) | 2011-10-11 | 2020-06-16 | Braskem S.A. | Copolímero heterofásico modificado de polipropileno, artigos grandes, profundos, complexos e/ou espessos, processo para termoformagem de copolímero heterofásico modificado de polipropileno, e, uso do mesmo |
| US9416265B2 (en) * | 2012-11-30 | 2016-08-16 | Exxonmobil Chemical Patents Inc. | Methods of forming compositions and articles |
| EP2746326B2 (en) | 2012-12-19 | 2024-06-12 | Borealis AG | Automotive compound with reduced tigerskin |
| IN2014MU00160A (enExample) * | 2014-01-17 | 2015-08-28 | Reliance Ind Ltd | |
| KR20160132958A (ko) * | 2014-03-14 | 2016-11-21 | 밀리켄 앤드 캄파니 | 개질된 헤테로상 폴리올레핀 조성물 |
| CN104292635A (zh) * | 2014-09-30 | 2015-01-21 | 苏州博利迈新材料科技有限公司 | 一种超高冲击强度的汽车保险杠复合材料及其制备方法 |
| DE112015005311T5 (de) | 2014-11-26 | 2017-08-24 | Milliken & Company | Modifizierte heterophasische Polyolefin-Zusammensetzung |
| WO2016097107A1 (en) * | 2014-12-19 | 2016-06-23 | Sabic Global Technologies B.V. | Process for the preparation of a heterophasic propylene copolymer |
| EP3234008B1 (en) * | 2014-12-19 | 2019-02-20 | Abu Dhabi Polymers Co. Ltd (Borouge) LLC. | Superior stress whitening performance for battery cases |
| KR102124239B1 (ko) | 2015-02-10 | 2020-06-17 | 밀리켄 앤드 캄파니 | 열가소성 중합체 조성물 |
| EP3265514B1 (en) | 2015-03-05 | 2023-08-02 | Milliken & Company | Modified heterophasic polyolefin composition |
| RU2687248C1 (ru) | 2015-09-13 | 2019-05-08 | Милликен Энд Компани | Способ получения гетерофазных полимерных композиций |
| JP6884571B2 (ja) | 2016-12-26 | 2021-06-09 | 日東電工株式会社 | 伸縮性フィルム、伸縮性積層体、およびそれを含む物品 |
| ES2958562T3 (es) * | 2017-02-03 | 2024-02-09 | Borealis Ag | Uso de una composición polimérica para la producción de artículos con capacidad de pintado y apariencia superficial mejoradas |
| UA123193C2 (uk) * | 2017-06-26 | 2021-02-24 | Бореаліс Аґ | Поліпропіленова композиція з відмінним зовнішнім виглядом |
| EP3732020B1 (en) * | 2017-12-26 | 2023-05-17 | Braskem America, Inc. | Method of additive manufacturing using high performance polyolefins |
| SG11202103665RA (en) * | 2018-10-12 | 2021-05-28 | Nouryon Chemicals Int Bv | Solid organic peroxide composition |
| WO2020188002A1 (en) * | 2019-03-21 | 2020-09-24 | Sabic Global Technologies B.V. | Additive composition |
| US11286317B2 (en) | 2019-04-12 | 2022-03-29 | Indian Oil Corporation Limited | Morphology modified heterophase propylene copolymers and their products thereof |
| EP4036130B1 (en) | 2021-01-29 | 2023-03-22 | Borealis AG | Modification of polyethylene copolymer |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1190681B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPH0235770B2 (ja) | 1982-11-18 | 1990-08-13 | Mitsui Petrochemical Ind | Horipuropirensoseibutsunoseizohoho |
| US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| JP2959805B2 (ja) * | 1990-05-21 | 1999-10-06 | 三井化学株式会社 | 熱可塑性エラストマーの製造方法 |
| JP2898353B2 (ja) * | 1990-05-21 | 1999-05-31 | 三井化学株式会社 | 熱可塑性エラストマー組成物 |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| JP2896615B2 (ja) * | 1991-05-24 | 1999-05-31 | チッソ株式会社 | 架橋ポリオレフィン組成物の製造方法 |
| US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| US5707569A (en) * | 1994-02-15 | 1998-01-13 | E. I. Du Pont De Nemours And Company | Processing aid system for polyolefins |
| JPH0873546A (ja) * | 1994-06-23 | 1996-03-19 | Basf Ag | 不飽和エステルで部分的に架橋された合成樹脂材料 |
| US5468808A (en) * | 1994-09-12 | 1995-11-21 | Exxon Chemical Patents Inc. | Reduction of flow marks in rubber modified polypropylene |
| JPH08183889A (ja) * | 1994-12-28 | 1996-07-16 | Nippon Petrochem Co Ltd | ポリプロピレン樹脂組成物およびその組成物からなる容器 |
| DE69620440T3 (de) * | 1995-11-24 | 2010-05-20 | Chisso Corp. | Propylenzusammensetzung, verfahren zu deren herstellung, polypropylenzusammensetzung und geformte gegenstände |
| DE19646118A1 (de) * | 1996-11-08 | 1998-05-14 | Basf Ag | Mit ungesättigten Estern teilvernetzte Kunststoffmassen |
| US6204348B1 (en) * | 1997-05-20 | 2001-03-20 | Borealis Gmbh | Modified polypropylenes of improved processability |
| FI974175L (fi) * | 1997-11-07 | 1999-05-08 | Borealis As | Menetelmä polypropeenin valmistamiseksi |
| DE19801687A1 (de) * | 1998-01-19 | 1999-07-22 | Danubia Petrochem Polymere | Thermoplastische Elastomere guter Einfärbbarkeit und hoher Festigkeit und Elastizität sowie daraus hergestellte hochschlagzähe Polymerblends |
| JP2000154270A (ja) * | 1998-11-19 | 2000-06-06 | Chisso Corp | 発泡ポリプロピレン系組成物及び発泡成形体 |
| DE10084514B4 (de) * | 2000-02-28 | 2007-05-24 | Asahi Kasei Kabushiki Kaisha | Olefinische Kautschukzusammensetzung |
| US6372847B1 (en) * | 2000-05-10 | 2002-04-16 | Exxon Mobil Chemical Patents, Inc. | Polyolefin compositions having improved low temperature toughness |
| JP3937696B2 (ja) * | 2000-06-30 | 2007-06-27 | 住友化学株式会社 | ポリプロピレン系樹脂組成物 |
| JP4116765B2 (ja) * | 2000-10-31 | 2008-07-09 | 株式会社プライムポリマー | 自動車用成形天井材およびその製造方法 |
| US6777476B2 (en) * | 2002-03-09 | 2004-08-17 | Hyundai Motor Company | Polypropylene resin composition |
| US20040014861A1 (en) * | 2002-06-03 | 2004-01-22 | Savvas Hatzikiriakos | Extrusion aid combinations |
| DE60232409D1 (de) * | 2002-08-20 | 2009-07-02 | Borealis Tech Oy | Polypropylenzusammensetzung |
| US6906137B2 (en) * | 2003-03-26 | 2005-06-14 | Dupont Dow Elastomers Llc | Process aid masterbatch for melt processable polymers |
| JP4666893B2 (ja) * | 2003-07-08 | 2011-04-06 | 東燃化学株式会社 | 変性ポリプロピレンの乳化組成物 |
| US7016802B2 (en) * | 2003-09-05 | 2006-03-21 | Tyco Electronics Corporation | Photocontrol devices having flexible mounted photosensors and methods of calibrating the same |
| JP4736587B2 (ja) * | 2004-10-05 | 2011-07-27 | 住友化学株式会社 | 複合体製造用熱可塑性エラストマー組成物及び複合体 |
| EP1676884A1 (fr) | 2004-12-30 | 2006-07-05 | Multibase S.A.S. | Composition polyolefinique destinee a realiser un capot pour logement d'un coussin d'air de securite d'un vehicule automobile |
| US20070004864A1 (en) * | 2005-06-24 | 2007-01-04 | University Of Florida Research Foundation | Method to enhance impact strength properties of melt processed polypropylene resins |
| US20090270525A1 (en) * | 2005-12-05 | 2009-10-29 | Jsr Corporation | Thermoplastic elastomer composition, foam product, and process for production of the composition or foam product |
| JP5843782B2 (ja) * | 2009-12-21 | 2016-01-13 | サンアロマー株式会社 | 耐衝撃性ポリオレフィン組成物 |
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- 2009-07-10 WO PCT/EP2009/005069 patent/WO2010009825A1/en not_active Ceased
- 2009-07-10 EP EP09777147A patent/EP2315804B1/en active Active
- 2009-07-10 CN CN2009801287909A patent/CN102105527A/zh active Pending
- 2009-07-10 US US13/054,607 patent/US20110118400A1/en not_active Abandoned
- 2009-07-10 MX MX2011000864A patent/MX2011000864A/es active IP Right Grant
- 2009-07-10 KR KR1020117004095A patent/KR101593256B1/ko active Active
- 2009-07-10 EA EA201170234A patent/EA019075B1/ru not_active IP Right Cessation
- 2009-07-10 JP JP2011519065A patent/JP5513503B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EA201170234A1 (ru) | 2011-10-31 |
| EP2315804B1 (en) | 2012-08-29 |
| US20110118400A1 (en) | 2011-05-19 |
| KR20110030704A (ko) | 2011-03-23 |
| WO2010009825A1 (en) | 2010-01-28 |
| CN102105527A (zh) | 2011-06-22 |
| JP2011528733A (ja) | 2011-11-24 |
| JP5513503B2 (ja) | 2014-06-04 |
| KR101593256B1 (ko) | 2016-02-12 |
| EA019075B1 (ru) | 2013-12-30 |
| EP2315804A1 (en) | 2011-05-04 |
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