DK1857507T3 - Oxidationsstabile jernoxidpigmenter, fremgangsmåde til fremstilling heraf samt anvendelse heraf - Google Patents
Oxidationsstabile jernoxidpigmenter, fremgangsmåde til fremstilling heraf samt anvendelse heraf Download PDFInfo
- Publication number
- DK1857507T3 DK1857507T3 DK07009134.3T DK07009134T DK1857507T3 DK 1857507 T3 DK1857507 T3 DK 1857507T3 DK 07009134 T DK07009134 T DK 07009134T DK 1857507 T3 DK1857507 T3 DK 1857507T3
- Authority
- DK
- Denmark
- Prior art keywords
- iron oxide
- oxide pigments
- general formula
- pigment
- weight
- Prior art date
Links
- 239000001034 iron oxide pigment Substances 0.000 title claims description 80
- 238000000034 method Methods 0.000 title claims description 39
- 230000008569 process Effects 0.000 title claims description 30
- 239000000049 pigment Substances 0.000 claims description 65
- 230000003647 oxidation Effects 0.000 claims description 54
- 238000007254 oxidation reaction Methods 0.000 claims description 54
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 39
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 33
- 150000001875 compounds Chemical class 0.000 claims description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- 238000013112 stability test Methods 0.000 claims description 24
- 239000000725 suspension Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 20
- 238000000576 coating method Methods 0.000 claims description 19
- 230000005291 magnetic effect Effects 0.000 claims description 19
- 239000011248 coating agent Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000004568 cement Substances 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 239000004566 building material Substances 0.000 claims description 11
- 125000002723 alicyclic group Chemical group 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 239000011083 cement mortar Substances 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 150000008065 acid anhydrides Chemical class 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 101150009274 nhr-1 gene Proteins 0.000 claims description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 2
- 239000011509 cement plaster Substances 0.000 claims description 2
- 239000004567 concrete Substances 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 239000004922 lacquer Substances 0.000 claims 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 34
- 239000000523 sample Substances 0.000 description 26
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 21
- 150000002894 organic compounds Chemical class 0.000 description 21
- -1 heterocyclic organic compounds Chemical class 0.000 description 19
- 238000012360 testing method Methods 0.000 description 18
- 235000010338 boric acid Nutrition 0.000 description 17
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 16
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 16
- 229960002645 boric acid Drugs 0.000 description 14
- 239000000126 substance Substances 0.000 description 13
- 238000001035 drying Methods 0.000 description 11
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 10
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 10
- 239000007787 solid Substances 0.000 description 9
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- 239000008187 granular material Substances 0.000 description 8
- 235000013980 iron oxide Nutrition 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000004327 boric acid Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000005711 Benzoic acid Substances 0.000 description 4
- 239000006004 Quartz sand Substances 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 231100000331 toxic Toxicity 0.000 description 4
- 230000002588 toxic effect Effects 0.000 description 4
- 229910000859 α-Fe Inorganic materials 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 229910017356 Fe2C Inorganic materials 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 125000005619 boric acid group Chemical class 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002391 heterocyclic compounds Chemical class 0.000 description 3
- 150000002431 hydrogen Chemical group 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- 229910002588 FeOOH Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- BGRDGMRNKXEXQD-UHFFFAOYSA-N Maleic hydrazide Chemical compound OC1=CC=C(O)N=N1 BGRDGMRNKXEXQD-UHFFFAOYSA-N 0.000 description 2
- 239000005983 Maleic hydrazide Substances 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 150000001334 alicyclic compounds Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 230000006399 behavior Effects 0.000 description 2
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- 229940067573 brown iron oxide Drugs 0.000 description 2
- 229910001567 cementite Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 230000035558 fertility Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 230000019612 pigmentation Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 125000003107 substituted aryl group Chemical group 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- OFUIFLZWMQEMFY-UHFFFAOYSA-N 1,2-dihydropyridazine-3,4-dione Chemical compound O=C1C=CNNC1=O OFUIFLZWMQEMFY-UHFFFAOYSA-N 0.000 description 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- KGLPWQKSKUVKMJ-UHFFFAOYSA-N 2,3-dihydrophthalazine-1,4-dione Chemical compound C1=CC=C2C(=O)NNC(=O)C2=C1 KGLPWQKSKUVKMJ-UHFFFAOYSA-N 0.000 description 1
- WFCSWCVEJLETKA-UHFFFAOYSA-N 2-piperazin-1-ylethanol Chemical compound OCCN1CCNCC1 WFCSWCVEJLETKA-UHFFFAOYSA-N 0.000 description 1
- UIKUBYKUYUSRSM-UHFFFAOYSA-N 3-morpholinopropylamine Chemical compound NCCCN1CCOCC1 UIKUBYKUYUSRSM-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 1
- FKCMADOPPWWGNZ-YUMQZZPRSA-N [(2r)-1-[(2s)-2-amino-3-methylbutanoyl]pyrrolidin-2-yl]boronic acid Chemical compound CC(C)[C@H](N)C(=O)N1CCC[C@H]1B(O)O FKCMADOPPWWGNZ-YUMQZZPRSA-N 0.000 description 1
- YYPYFBVEXBVLBS-UHFFFAOYSA-N [B].[S] Chemical class [B].[S] YYPYFBVEXBVLBS-UHFFFAOYSA-N 0.000 description 1
- 150000001260 acyclic compounds Chemical class 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 239000011455 calcium-silicate brick Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- CJYBKFFVXWWBMY-UHFFFAOYSA-N dodecyl 2-hydroxybenzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1O CJYBKFFVXWWBMY-UHFFFAOYSA-N 0.000 description 1
- 231100000351 embryotoxic Toxicity 0.000 description 1
- 230000001779 embryotoxic effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000005293 ferrimagnetic effect Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000015654 memory Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229960003921 octisalate Drugs 0.000 description 1
- WCJLCOAEJIHPCW-UHFFFAOYSA-N octyl 2-hydroxybenzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1O WCJLCOAEJIHPCW-UHFFFAOYSA-N 0.000 description 1
- MOWNZPNSYMGTMD-UHFFFAOYSA-N oxidoboron Chemical class O=[B] MOWNZPNSYMGTMD-UHFFFAOYSA-N 0.000 description 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000004892 pyridazines Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 239000011150 reinforced concrete Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 description 1
- WRECIMRULFAWHA-UHFFFAOYSA-N trimethyl borate Chemical compound COB(OC)OC WRECIMRULFAWHA-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910006540 α-FeOOH Inorganic materials 0.000 description 1
- 229910006299 γ-FeOOH Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/22—Compounds of iron
- C09C1/24—Oxides of iron
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/30—Oxides other than silica
- C04B14/308—Iron oxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/54—Pigments; Dyes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Civil Engineering (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compounds Of Iron (AREA)
- Paints Or Removers (AREA)
- Developing Agents For Electrophotography (AREA)
Claims (17)
1. Oxidationsstabile jernoxidpigmenter med et Fe (11)-indhold på i det mindste 5 vægt-%, regnet som FeO, som har en belægning, kendetegnet ved, at belægningen består af en eller flere forbindelser med den almene formel (I) R-(COOX)n idet R er en mættet eller umættet, lineær eller forgrenet alifatisk gruppe med 1 til 15 C-atomer, som i givet fald er substitueret en eller flere gange med halogen og/eller NH2 og/eller OH og/eller NHR1 og/eller NR22 og/eller OR1, eller er en alicyklisk gruppe med 4 til 26 C-atomer, som i givet fald er substitueret en eller flere gange med halogen og/eller NH2 og/eller OH og/eller NHR1 og/eller NR22 og/eller OR1 og/eller R1, idet R1 er en mættet eller umættet, lineær eller forgrenet i givet fald substitueret alifatisk gruppe med hver især 1 til 10 C-atomer eller en i givet fald substitueret alicyklisk eller aromatisk gruppe med hver især 6 til 10 C-atomer; X står for hydrogen, alkalimetal, NR24 hvor R2 er H eller en lineær eller forgrenet alifatisk, alicyklisk eller aromatisk gruppe, jordalkalimetal, ½ Al eller 1¾ Fe, og n står for et helt tal fra 1 til 10, og jernoxidpigmenterne har en oxidationsstabilitet ifølge oxidationsstabilitets-testen på å 10°C i forhold til det ikke belagte jernoxidpigment.
2. Jernoxidpigmenter ifølge krav 1, kendetegnet ved, at jernoxidpigmenterne har en oxidationsstabilitet på ^ 20°C i forhold til det ikke belagte jernoxidpigment.
3. Jernoxidpigmenter ifølge et eller flere af kravene 1 til 2, kendetegnet ved, at belægningen består af en forbindelse med den almene formel (I), idet R står for en mættet lineær eller forgrenet alifatisk gruppe med 1 til 15 C-atomer, navnlig med 1 til 8 C-atomer.
4. Jernoxidpigmenter ifølge et eller flere af kravene 1 til 3, kendetegnet ved, at belægningen består af en forbindelse med den almene formel (I), idet X står for hydrogen, eller et alkalimetal, navnlig natrium eller kalium.
5. Jernoxidpigmenter ifølge et eller flere af kravene 1 til 4, kendetegnet ved, at belægningen består af en forbindelse med den almene formel (I), idet n står for et helt tal < 5, navnlig < 3.
6. Jernoxidpigmenter ifølge et eller flere af kravene 1 til 5, kendetegnet ved, at forbindelserne med den almene formel (I) er syreanhydrider.
7. Jernoxidpigmenter ifølge et eller flere af kravene 1 til 5, kendetegnet ved, at forbindelserne med den almene formel (I) endvidere også indeholder vand.
8. Jernoxidpigmenter ifølge et eller flere af kravene 1 til 5, kendetegnet ved, at forbindelser med den almene formel (I) er acetater.
9. Jernoxidpigmenter ifølge et eller flere af kravene 1 til 6, kendetegnet ved, at forbindelserne med den almene formel (I) foreligger i en mængde på 0.1 til 10 vægt-%, navnlig på 0.2 til 3 vægt-%, i det belagte pigment.
10. Jernoxidpigmenter ifølge et eller flere af kravene 1 til 7, kendetegnet ved, at jernoxidpigmenterne har et restfugtindhold på < 5 vægt-%, navnlig på < 3.5 vægt-%.
11. Fremgangsmåde til fremstilling af jernoxidpigmenter ifølge et eller flere af kravene 1 til 10, kendetegnet ved, at jernoxidpigmenter med et Fe(II)-indhold på i det mindste 5 vægt-%, regnet som FeO med i det mindste en forbindelse med den almene formel (I) blandes, og blandingen i givet fald tørres og/eller males.
12. Fremgangsmåde til fremstilling af jernoxidpigmenter ifølge krav 11, kendetegnet ved, at jernoxidpigmenter med et Fe(II)-indhold på i det mindste 5 vægt-%, regnet som FeO blandes i en suspension eller pasta med i det mindste en forbindelse med den almene formel (I), og blandingen tørres og i givet fald males.
13. Fremgangsmåde til fremstilling af jernoxidpigmenter ifølge krav 12, kendetegnet ved, at pigmentsuspensionen er en suspension eller pasta fra pigmentfremstillingsprocessen.
14. Fremgangsmåde til fremstilling af jernoxidpigmenter ifølge krav 12, kendetegnet ved, at pigmentsuspensionen er en ny dispersion af agglomererede partikler.
15. Fremgangsmåde ifølge et af kravene 11 til 14, kendetegnet ved, at jernoxidpigmenterne afsluttende udsættes for en temperaturbehandling ved 200°C til 800°C i en ikke- eller svagt oxideret atmosfære.
16. Anvendelse af jernoxidpigmenterne ifølge et eller flere af kravene 1 til 10 eller af de ifølge fremgangsmåden ifølge kravene 11 til 15 fremstillede jernoxidpigmenter til indfarvning af kalk- og/eller cementbundne byggematerialer, til indfarvning af kunststoffer, lakker, dispersionsmalinger og til fremstilling af magnetiske indspilningsmedier og tonere.
17. Anvendelse ifølge krav 16, kendetegnet ved, at de kalk-og/eller cementbundne byggematerialer er beton, cementmørtel, puds og/eller kalksandsten.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE200610023245 DE102006023245A1 (de) | 2006-05-18 | 2006-05-18 | Oxidationsstabile Eisenoxidpigmente, Verfahren zu ihrer Herstellung sowie deren Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK1857507T3 true DK1857507T3 (da) | 2018-02-26 |
Family
ID=38226488
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK07009134.3T DK1857507T3 (da) | 2006-05-18 | 2007-05-07 | Oxidationsstabile jernoxidpigmenter, fremgangsmåde til fremstilling heraf samt anvendelse heraf |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7410536B2 (da) |
| EP (1) | EP1857507B1 (da) |
| JP (2) | JP5674254B2 (da) |
| CN (1) | CN101077944B (da) |
| AU (1) | AU2007201994A1 (da) |
| BR (1) | BRPI0702297A (da) |
| CA (1) | CA2588534A1 (da) |
| DE (1) | DE102006023245A1 (da) |
| DK (1) | DK1857507T3 (da) |
| ES (1) | ES2658313T3 (da) |
| MX (1) | MX2007005909A (da) |
| PL (1) | PL1857507T3 (da) |
| TR (1) | TR201802192T4 (da) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2641998A1 (en) * | 2004-01-16 | 2013-09-25 | Battelle Memorial Institute | Apparatus for producing ferrate (VI) |
| WO2007075153A2 (en) * | 2004-11-12 | 2007-07-05 | Battelle Memorial Institute | Decontaminant |
| ES2296522B1 (es) * | 2006-05-26 | 2009-04-01 | Europea De Minerales Y Derivados, S.L. | Masa pesada para la fabricacion de productos con alta capacidad de radio-proteccion. |
| US8663607B2 (en) | 2007-03-09 | 2014-03-04 | Battelle Memorial Institute | Ferrate(VI)-containing compositions and methods of using ferrate(VI) |
| US8944048B2 (en) * | 2008-03-26 | 2015-02-03 | Battelle Memorial Institute | Apparatus and methods of providing diatomic oxygen (O2) using ferrate(VI)-containing compositions |
| US8722147B2 (en) * | 2008-10-17 | 2014-05-13 | Battelle Memorial Institute | Corrosion resistant primer coating |
| EP3347329B1 (en) * | 2015-09-07 | 2021-06-16 | De Cavis AG | Catalytically active foam formation powder |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2502657A1 (de) * | 1975-01-23 | 1976-07-29 | Bayer Ag | Leicht magnetisch ausrichtbare magnetische eisenoxide |
| US4264462A (en) * | 1977-10-04 | 1981-04-28 | Bayer Aktiengesellschaft | Stabilization of magnetite pigments with heterocyclic nitrogen compounds |
| DE3211327A1 (de) * | 1982-03-27 | 1983-09-29 | Bayer Ag, 5090 Leverkusen | Thermostabile eisenoxidpigmente |
| JPS60130655A (ja) * | 1983-12-19 | 1985-07-12 | Kanebo Ltd | パラアミノ安息香酸多価金属塩−被覆顔料及びその製造法 |
| JPS60137003A (ja) * | 1983-12-26 | 1985-07-20 | Toda Kogyo Corp | 磁気記録用磁性酸化鉄粒子粉末の処理法 |
| JPS61289012A (ja) * | 1985-06-15 | 1986-12-19 | Nonogawa Shoji:Kk | 化粧料 |
| JPH0624986B2 (ja) * | 1986-07-04 | 1994-04-06 | 戸田工業株式会社 | 球形を呈したマグネタイト粒子粉末及びその製造法 |
| DE3726048A1 (de) * | 1987-08-06 | 1989-02-16 | Bayer Ag | Thermostabile eisenoxidpigmente, verfahren zu iher herstellung sowie deren verwendung |
| JP2743028B2 (ja) * | 1990-02-21 | 1998-04-22 | 戸田工業株式会社 | 酸化鉄超常磁性体微粒子粉末及びその製造法 |
| JPH043902A (ja) * | 1990-04-21 | 1992-01-08 | Toda Kogyo Corp | 磁気記録用針状磁性酸化鉄粒子粉末及びその製造法 |
| DE4139052A1 (de) * | 1991-11-28 | 1993-06-03 | Bayer Ag | Thermostabile eisenoxidpigmente, verfahren zu ihrer herstellung sowie deren verwendung |
| JP3132525B2 (ja) * | 1992-04-17 | 2001-02-05 | ソニー株式会社 | 金属磁性粉及び磁気記録媒体 |
| DE4322886C2 (de) * | 1993-07-09 | 1995-04-20 | Bayer Ag | Thermostabile Eisenoxidpigmente, Verfahren zu ihrer Herstellung sowie deren Verwendung |
| JP3651017B2 (ja) * | 1994-03-22 | 2005-05-25 | 三菱マテリアル株式会社 | 球状マグネタイト粒子およびその製造方法 |
| WO1996018457A1 (en) * | 1994-12-14 | 1996-06-20 | Shell Internationale Research Maatschappij B.V. | Restructured iron oxide |
| US6083476A (en) * | 1996-05-08 | 2000-07-04 | Mitsui Mining & Smelting Company, Ltd. | Black ultrafine magnetite particles and process for preparing the same |
| US5954991A (en) * | 1997-04-04 | 1999-09-21 | Hong; Chin-Yih Rex | Ordered structures in homogeneous magnetic fluid thin films and method of preparation |
| JP2000123353A (ja) * | 1998-10-13 | 2000-04-28 | Sony Corp | 磁気記録媒体およびその製造方法 |
| DE19958168A1 (de) * | 1999-12-02 | 2001-06-07 | Bayer Ag | Verfahren zur Herstellung von Eisenoxidpigmenten |
| JP4474557B2 (ja) * | 1999-12-15 | 2010-06-09 | Ｄｏｗａエレクトロニクス株式会社 | 塗布型磁気記録媒体の下層用粉末の製造法 |
| WO2003027771A1 (en) * | 2001-09-28 | 2003-04-03 | Höganäs Ab | Electrophotographic carrier core magnetite powder |
-
2006
- 2006-05-18 DE DE200610023245 patent/DE102006023245A1/de not_active Withdrawn
-
2007
- 2007-05-01 US US11/799,182 patent/US7410536B2/en active Active
- 2007-05-04 AU AU2007201994A patent/AU2007201994A1/en not_active Abandoned
- 2007-05-07 DK DK07009134.3T patent/DK1857507T3/da active
- 2007-05-07 ES ES07009134.3T patent/ES2658313T3/es active Active
- 2007-05-07 PL PL07009134T patent/PL1857507T3/pl unknown
- 2007-05-07 EP EP07009134.3A patent/EP1857507B1/de active Active
- 2007-05-07 TR TR2018/02192T patent/TR201802192T4/tr unknown
- 2007-05-11 CA CA 2588534 patent/CA2588534A1/en not_active Abandoned
- 2007-05-17 MX MX2007005909A patent/MX2007005909A/es active IP Right Grant
- 2007-05-17 JP JP2007132020A patent/JP5674254B2/ja active Active
- 2007-05-18 CN CN2007101079307A patent/CN101077944B/zh active Active
- 2007-05-18 BR BRPI0702297-2A patent/BRPI0702297A/pt not_active Application Discontinuation
-
2014
- 2014-09-29 JP JP2014198443A patent/JP2015052116A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE102006023245A1 (de) | 2007-11-22 |
| US20070266899A1 (en) | 2007-11-22 |
| EP1857507A2 (de) | 2007-11-21 |
| TR201802192T4 (tr) | 2018-03-21 |
| EP1857507A3 (de) | 2008-08-27 |
| MX2007005909A (es) | 2009-02-16 |
| ES2658313T3 (es) | 2018-03-09 |
| JP5674254B2 (ja) | 2015-02-25 |
| CN101077944B (zh) | 2013-05-08 |
| JP2008001889A (ja) | 2008-01-10 |
| EP1857507B1 (de) | 2017-11-22 |
| CN101077944A (zh) | 2007-11-28 |
| AU2007201994A1 (en) | 2007-12-06 |
| US7410536B2 (en) | 2008-08-12 |
| PL1857507T3 (pl) | 2018-04-30 |
| JP2015052116A (ja) | 2015-03-19 |
| BRPI0702297A (pt) | 2008-01-15 |
| CA2588534A1 (en) | 2007-11-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DK1857506T3 (da) | Oxidationsstabile jernoxidpigmenter, fremgangsmåde til fremstilling heraf samt anvendelse heraf | |
| DK1857507T3 (da) | Oxidationsstabile jernoxidpigmenter, fremgangsmåde til fremstilling heraf samt anvendelse heraf | |
| KR910006994B1 (ko) | 열 안정성 산화철 안료 및 이의 제조방법 | |
| JP5388404B2 (ja) | プラスチックおよび建材を着色するための色の濃さが濃い還元−および酸化−安定な黒色酸化鉄顔料 | |
| CA2338913A1 (en) | Process for the production of iron oxide and its use | |
| JP2000264639A (ja) | ストロンチウム鉄酸化物粒子粉末及びその製造方法 | |
| US5667579A (en) | Thermally stable iron oxide pigments, a process for their preparation and their use | |
| AU2013216576A1 (en) | Oxidation-stable iron oxide pigments, process for preparing them and their use | |
| AU2013216577A1 (en) | Oxidation-stable iron oxide pigments, process for preparing them and their use | |
| JP3034142B2 (ja) | 熱安定性酸化鉄顔料、その製造法及びその利用 | |
| KR102476176B1 (ko) | Al을 함유하는 산화철 안료 |