DK0856537T3 - Fastfase-polymerisation af PET - Google Patents

Fastfase-polymerisation af PET

Info

Publication number
DK0856537T3
DK0856537T3 DK98300599T DK98300599T DK0856537T3 DK 0856537 T3 DK0856537 T3 DK 0856537T3 DK 98300599 T DK98300599 T DK 98300599T DK 98300599 T DK98300599 T DK 98300599T DK 0856537 T3 DK0856537 T3 DK 0856537T3
Authority
DK
Denmark
Prior art keywords
pet
flakes
post
consumer
chunks
Prior art date
Application number
DK98300599T
Other languages
Danish (da)
English (en)
Inventor
Erden Donald Van
Gary L Vadnais
Manuel C Enriquez
Karl G Adams
James P Nelson
Original Assignee
Illinois Tool Works
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25162932&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DK0856537(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Illinois Tool Works filed Critical Illinois Tool Works
Application granted granted Critical
Publication of DK0856537T3 publication Critical patent/DK0856537T3/da

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/06Recovery or working-up of waste materials of polymers without chemical reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/287Raw material pre-treatment while feeding
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/80Solid-state polycondensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • B29B2017/0203Separating plastics from plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • B29B2017/0213Specific separating techniques
    • B29B2017/0279Optical identification, e.g. cameras or spectroscopy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/288Feeding the extrusion material to the extruder in solid form, e.g. powder or granules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06PVC, i.e. polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/003PET, i.e. poylethylene terephthalate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Laminated Bodies (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Package Frames And Binding Bands (AREA)
  • Materials For Medical Uses (AREA)
  • Push-Button Switches (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
DK98300599T 1997-02-03 1998-01-28 Fastfase-polymerisation af PET DK0856537T3 (da)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/794,538 US5886058A (en) 1997-02-03 1997-02-03 Inline solid state polymerization of pet flakes for manufacturing plastic strap

Publications (1)

Publication Number Publication Date
DK0856537T3 true DK0856537T3 (da) 2003-10-06

Family

ID=25162932

Family Applications (1)

Application Number Title Priority Date Filing Date
DK98300599T DK0856537T3 (da) 1997-02-03 1998-01-28 Fastfase-polymerisation af PET

Country Status (22)

Country Link
US (1) US5886058A (cs)
EP (1) EP0856537B1 (cs)
JP (1) JPH10259254A (cs)
KR (1) KR100257284B1 (cs)
CN (1) CN1080282C (cs)
AT (1) ATE243228T1 (cs)
AU (1) AU698052B2 (cs)
BR (1) BR9800508A (cs)
CA (1) CA2227952C (cs)
CZ (1) CZ293838B6 (cs)
DE (1) DE69815559T2 (cs)
DK (1) DK0856537T3 (cs)
ES (1) ES2201406T3 (cs)
HU (1) HU223008B1 (cs)
IL (1) IL122969A (cs)
NO (1) NO315242B1 (cs)
PL (1) PL190528B1 (cs)
PT (1) PT856537E (cs)
RU (1) RU2151154C1 (cs)
SK (1) SK284830B6 (cs)
TR (1) TR199800162A2 (cs)
TW (1) TW432086B (cs)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
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US6284808B1 (en) * 1997-02-03 2001-09-04 Illinois Tool Works Inc. Inline solid state polymerization of PET flakes for manufacturing plastic strap by removing non-crystalline materials from recycled PET
US6352426B1 (en) 1998-03-19 2002-03-05 Advanced Plastics Technologies, Ltd. Mold for injection molding multilayer preforms
TWI250934B (en) * 1997-10-17 2006-03-11 Advancsd Plastics Technologies Barrier-coated polyester articles and the fabrication method thereof
CA2284965C (en) * 1998-11-13 2003-07-08 Illinois Tool Works Inc. Inline solid state polymerization of pet flakes for manufacturing plastic strap
AUPQ294699A0 (en) * 1999-09-17 1999-10-14 Visy Plastics Pty Ltd Process for preparing food contact grade polyethylene terephthalate resin from waste pet containers
DE19953659A1 (de) * 1999-11-08 2001-05-10 Buehler Ag Verfahren und Vorrichtung zur Dekontamination von Polykondensaten
AU2001288916B2 (en) * 2000-09-05 2007-05-10 Advanced Plastics Technologies Luxembourg S.A. Multilayer containers and preforms having barrier properties utilizing recycled material
AT410942B (de) * 2001-10-29 2003-08-25 Fellinger Markus Verfahren und vorrichtung zur erhöhung der grenzviskosität von polyester
ES2706626T3 (es) 2002-04-09 2019-03-29 Signode Int Ip Holdings Llc Fleje de poliéster de alta integridad
ITMI20030048A1 (it) * 2003-01-15 2004-07-16 Vomm Chemipharma Srl Procedimento per la polimerizzazione in fase solida del
KR100981000B1 (ko) 2003-05-29 2010-09-07 에스케이케미칼주식회사 고중합도 폴리에틸렌테레프탈레이트의 고상중합방법
US20050136201A1 (en) * 2003-12-22 2005-06-23 Pepsico, Inc. Method of improving the environmental stretch crack resistance of RPET without solid stating
BRPI0402330B1 (pt) * 2004-06-14 2020-11-03 Fundação De Amparo À Pesquisa Do Estado de São Paulo processo de descontaminação de poliéster reciclado e uso do mesmo
PL1824920T3 (pl) * 2004-12-06 2010-02-26 Eastman Chem Co Koncentraty kobaltu oparte na poliestrze do kompozycji odtleniających
DE102005013701A1 (de) 2005-03-24 2006-09-28 Krones Ag Verfahren und Vorrichtung zur Dekontamination von Kunststoffflakes
EP1943074A1 (en) * 2005-08-30 2008-07-16 Advanced Plastics Technologies Luxembourg S.A. Methods and systems for controlling mold temperatures
EP2196299A1 (de) 2008-12-09 2010-06-16 Alpla Werke Alwin Lehner GmbH & CO. KG Verfahren zur Aufbereitung von rezykliertem Polyethylenterephthalat
EP2524015B2 (en) 2010-01-13 2024-04-10 Mitsubishi Polyester Film, Inc. Process for recycling waste film and product made therefrom
GB2492942A (en) * 2011-04-20 2013-01-23 Buhler Sortex Ltd Processing system and method
NL1038906C2 (en) * 2011-06-29 2013-01-03 Wavin Bv Method and system for providing an assembly of an amount of used plastic material and an information carrier carrying quality data of the amount.
RU2481951C1 (ru) * 2011-12-27 2013-05-20 Открытое акционерное общество "Институт пластмасс имени Г.С. Петрова" Способ получения полимерной ленты из вторичного полиэтилентерефталата
RU2481952C1 (ru) * 2011-12-27 2013-05-20 Открытое акционерное общество "Институт пластмасс имени Г.С. Петрова" Способ получения полимерной ленты из вторичного полиэтилентерефталата
US10695953B2 (en) 2012-05-31 2020-06-30 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous carpet filament
US10538016B2 (en) 2012-05-31 2020-01-21 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous carpet filament
US10532495B2 (en) 2012-05-31 2020-01-14 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous filament from recycled PET
US9630353B2 (en) 2012-05-31 2017-04-25 Mohawk Industries, Inc. Method of manufacturing bulked continuous filament
US9636845B2 (en) 2012-05-31 2017-05-02 Mohawk Industries, Inc. Method of manufacturing pet nurdles
US11045979B2 (en) 2012-05-31 2021-06-29 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous filament from recycled PET
US8597553B1 (en) 2012-05-31 2013-12-03 Mohawk Industries, Inc. Systems and methods for manufacturing bulked continuous filament
US9636860B2 (en) 2012-05-31 2017-05-02 Mohawk Industries, Inc. Method of manufacturing bulked continuous filament
US10487422B2 (en) 2012-05-31 2019-11-26 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous filament from colored recycled pet
US9630354B2 (en) 2012-05-31 2017-04-25 Mohawk Industries, Inc. Method of manufacturing bulked continuous filament
JP2016011337A (ja) * 2014-06-27 2016-01-21 三菱瓦斯化学株式会社 ポリエステル再生品の製造方法
DE102015118393A1 (de) * 2015-10-28 2017-05-04 STF Maschinen- & Anlagenbau GmbH Verfahren zum Sortieren von Verpackungsbehälter aus Kunststoff
WO2017080685A1 (en) * 2015-11-10 2017-05-18 Gojara Pressure control device, dispenser comprising said pressure control device and method of manufacturing
US11312837B2 (en) 2016-11-03 2022-04-26 Science Medical, LLC Systems and methods for recycling post-consumer polyester-based fabric
US10751915B2 (en) 2016-11-10 2020-08-25 Aladdin Manufacturing Corporation Polyethylene terephthalate coloring systems and methods
CH713339A1 (de) * 2017-01-03 2018-07-13 Alpla Werke Alwin Lehner Gmbh & Co Kg PET-Regranulat mit hoher intrinsischer Viskosität und Verfahren zu dessen Herstellung.
KR102457552B1 (ko) 2017-01-30 2022-10-21 알라딘 매뉴펙쳐링 코포레이션 착색된 재생 pet 로부터 벌크 연속 필라멘트를 제조하는 방법
US11279071B2 (en) 2017-03-03 2022-03-22 Aladdin Manufacturing Corporation Method of manufacturing bulked continuous carpet filament
CN111093924A (zh) 2017-09-15 2020-05-01 美国阿拉丁制造公司 聚对苯二甲酸乙二醇酯着色方法和用于制造膨化变形地毯长丝的系统
US11242622B2 (en) 2018-07-20 2022-02-08 Aladdin Manufacturing Corporation Bulked continuous carpet filament manufacturing from polytrimethylene terephthalate
CH715231A1 (de) * 2018-08-06 2020-02-14 Alpla Werke Alwin Lehner Gmbh & Co Kg Verfahren zur Aufbereitung von zur Wiederverwendung vorgesehenen Thermoplasten.
JP7175707B2 (ja) * 2018-10-23 2022-11-21 萩原工業株式会社 再生樹脂材料の不純物除去方法
CN109705547B (zh) * 2018-11-30 2022-01-21 中粮集团有限公司 耐热改性聚乳酸材料及其制备方法
KR102163351B1 (ko) 2019-11-08 2020-10-08 이경희 고강력 폴리에스터 장섬유 제조를 위한 재생 pet 칩 제조방법
JP7478356B2 (ja) * 2020-05-26 2024-05-07 大日本印刷株式会社 樹脂製品製造システムおよび樹脂製品の製造方法
KR102339830B1 (ko) 2020-10-21 2021-12-15 이경희 저점도 재활용품 pet 플레이크를 활용한 고점도 리싸이클 pet칩의 제조방법
KR102347381B1 (ko) 2020-11-05 2022-01-07 주식회사 새동방 Pet 재생칩의 제조 방법 및 이를 이용한 pet 단섬유
KR20230050530A (ko) 2021-10-07 2023-04-17 주식회사 새동방 저급 pet를 이용한 재생 pet 칩의 제조방법, 이에 따른 재생 pet 칩 및 이를 이용하여 제조된 pet 단섬유
KR102599800B1 (ko) 2021-10-12 2023-11-08 이경희 폐pet를 활용한 고품위 리싸이클 pet 칩의 제조방법

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US3767601A (en) * 1971-09-01 1973-10-23 Du Pont Solid phase polymerization of waste polyethylene terephthalate
US4077945A (en) * 1974-03-23 1978-03-07 Zimmer Aktiengesellschaft Process for making linear polyesters from ethylene glycol and terephthalic acid
US4092458A (en) * 1975-05-15 1978-05-30 E. I. Du Pont De Nemours And Company Porous laminar pellets of waste poly(ethylene terephthalate) film, and processes for drying and polymerization
US4022863A (en) * 1975-06-04 1977-05-10 Caristrap Corporation Polymer plastic strapping from polyethylene terephthalate
US4742151A (en) * 1986-06-26 1988-05-03 Toyo Boseki Kabushiki Kaisha Ultra-high-molecular-weight polyesters
DE4034459A1 (de) * 1990-10-30 1992-05-07 Hoechst Ag Verfahren zur aufbereitung thermisch beanspruchter polyester-abfaelle

Also Published As

Publication number Publication date
SK11898A3 (en) 2000-03-13
AU698052B2 (en) 1998-10-22
CZ27098A3 (cs) 1998-08-12
ES2201406T3 (es) 2004-03-16
TR199800162A2 (xx) 1998-08-21
CA2227952C (en) 2002-05-21
ATE243228T1 (de) 2003-07-15
HU223008B1 (hu) 2004-03-01
KR100257284B1 (ko) 2000-05-15
TW432086B (en) 2001-05-01
JPH10259254A (ja) 1998-09-29
IL122969A (en) 2005-06-19
EP0856537A3 (en) 2000-09-13
NO315242B1 (no) 2003-08-04
DE69815559T2 (de) 2004-05-13
HUP9800189A2 (hu) 2000-12-28
EP0856537B1 (en) 2003-06-18
CZ293838B6 (cs) 2004-08-18
RU2151154C1 (ru) 2000-06-20
AU5216598A (en) 1998-08-06
DE69815559D1 (de) 2003-07-24
PT856537E (pt) 2003-11-28
PL190528B1 (pl) 2005-12-30
CN1192451A (zh) 1998-09-09
PL324600A1 (en) 1998-08-17
EP0856537A2 (en) 1998-08-05
NO980445L (no) 1998-08-04
KR19980070986A (ko) 1998-10-26
CN1080282C (zh) 2002-03-06
CA2227952A1 (en) 1998-08-03
HUP9800189A3 (en) 2002-05-28
SK284830B6 (sk) 2005-12-01
IL122969A0 (en) 1998-08-16
HU9800189D0 (en) 1998-03-30
NO980445D0 (no) 1998-02-02
BR9800508A (pt) 1999-07-06
US5886058A (en) 1999-03-23

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