DK0794004T3 - Katalysatorer til dehydrogenering af ethylbenzen til styren - Google Patents

Katalysatorer til dehydrogenering af ethylbenzen til styren

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Publication number
DK0794004T3
DK0794004T3 DK97103427T DK97103427T DK0794004T3 DK 0794004 T3 DK0794004 T3 DK 0794004T3 DK 97103427 T DK97103427 T DK 97103427T DK 97103427 T DK97103427 T DK 97103427T DK 0794004 T3 DK0794004 T3 DK 0794004T3
Authority
DK
Denmark
Prior art keywords
ethylbenzene
dehydrogenation
catalysts
styrene
oxides
Prior art date
Application number
DK97103427T
Other languages
Danish (da)
English (en)
Inventor
Luigi Cavalli
Carlo Rubini
Esterino Conca
Original Assignee
Sued Chemie Mt Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sued Chemie Mt Srl filed Critical Sued Chemie Mt Srl
Application granted granted Critical
Publication of DK0794004T3 publication Critical patent/DK0794004T3/da

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321Catalytic processes
    • C07C5/322Catalytic processes with metal oxides or metal sulfides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • C07C5/3332Catalytic processes with metal oxides or metal sulfides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04Alkali metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/26Chromium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/30Tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/745Iron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/78Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with alkali- or alkaline earth metals or beryllium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/83Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with rare earths or actinides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85Chromium, molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85Chromium, molybdenum or tungsten
    • C07C2523/86Chromium
    • CCHEMISTRY; METALLURGY
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    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85Chromium, molybdenum or tungsten
    • C07C2523/88Molybdenum
    • C07C2523/881Molybdenum and iron
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    • C07ORGANIC CHEMISTRY
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    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85Chromium, molybdenum or tungsten
    • C07C2523/888Tungsten

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DK97103427T 1996-03-08 1997-03-03 Katalysatorer til dehydrogenering af ethylbenzen til styren DK0794004T3 (da)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT96MI000447A IT1283207B1 (it) 1996-03-08 1996-03-08 Catalizzatori per la deidrogenazione di etilbenzene a stirene

Publications (1)

Publication Number Publication Date
DK0794004T3 true DK0794004T3 (da) 2003-10-06

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
DK97103427T DK0794004T3 (da) 1996-03-08 1997-03-03 Katalysatorer til dehydrogenering af ethylbenzen til styren

Country Status (25)

Country Link
US (1) US6166280A (zh)
EP (1) EP0794004B1 (zh)
JP (1) JPH10359A (zh)
KR (1) KR970064714A (zh)
CN (1) CN1085951C (zh)
AT (1) ATE242660T1 (zh)
AU (1) AU716285B2 (zh)
BR (1) BR9701231A (zh)
CA (1) CA2199218A1 (zh)
CZ (1) CZ65097A3 (zh)
DE (1) DE69722689T2 (zh)
DK (1) DK0794004T3 (zh)
ES (1) ES2200091T3 (zh)
HR (1) HRP970129B1 (zh)
HU (1) HU218961B (zh)
ID (1) ID16428A (zh)
IT (1) IT1283207B1 (zh)
MX (1) MX9701681A (zh)
NO (1) NO313909B1 (zh)
PL (1) PL318846A1 (zh)
PT (1) PT794004E (zh)
RU (1) RU2167711C2 (zh)
SK (1) SK282102B6 (zh)
TW (1) TW444003B (zh)
UA (1) UA42783C2 (zh)

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DE19814080A1 (de) * 1998-03-30 1999-10-07 Basf Ag Katalysator zur Dehydrierung von Kohlenwasserstoffen, insbesondere zur Dehydrierung von Ethylbenzol zu Styrol, sowie Verfahren zu seiner Herstellung
IT1306194B1 (it) * 1999-01-08 2001-05-30 Sued Chemie Mt Srl Catalizzatori per reazioni esotermiche su letto fisso.
CN1243702C (zh) 1999-08-31 2006-03-01 三井化学株式会社 三异丙基苯和二异丙基苯的脱氢方法
IT1313647B1 (it) * 1999-09-30 2002-09-09 Snam Progetti Procedimento per la deidrogenazione di etilbenzene a stirene.
KR100358074B1 (ko) * 1999-11-02 2002-10-25 한국화학연구원 방향족 탄화수소의 탈수소화 반응용 혼합촉매
EP1953209A1 (en) * 2000-06-29 2008-08-06 Neuftec Limited A fuel additive
TWI267401B (en) * 2002-01-30 2006-12-01 Shell Int Research A catalyst, its preparation and its use in a dehydrogenation process
ITMI20020702A1 (it) * 2002-04-05 2003-10-06 Univ Degli Studi Milano Catalizzatore per deidrogenazione dell'etilbenzene a stirene
US7282619B2 (en) 2003-10-14 2007-10-16 Shell Oil Company Method of operating a dehydrogenation reactor system
US7297402B2 (en) 2004-04-15 2007-11-20 Shell Oil Company Shaped particle having an asymmetrical cross sectional geometry
CN1299822C (zh) * 2004-07-13 2007-02-14 华东理工大学 用于乙苯氧化脱氢制苯乙烯的纳米碳纤维催化剂及其成型方法
TW200719968A (en) * 2005-10-31 2007-06-01 Sued Chemie Ag Catalyst molding for partial oxidation reactions
CN101279266B (zh) * 2007-04-04 2010-07-21 中国石油化工股份有限公司 节能的乙苯脱氢制苯乙烯催化剂
TWI583405B (zh) * 2008-02-28 2017-05-21 艾伯維有限公司 錠劑及其製備
US8524969B2 (en) * 2008-07-22 2013-09-03 Fina Technology, Inc. Dehydrogenation reactions of hydrocarbons to alkenes
EP2329878A4 (en) * 2008-09-22 2013-08-21 Univ Waseda DEHYDRATION CATALYST FOR ALKYLAROMATIC COMPOUNDS WITH HIGH REDOX CATALYSIS, METHOD FOR THE PREPARATION OF THE CATALYST AND DEHYDRATION METHOD THEREWITH
DE102008056797A1 (de) 2008-11-11 2010-05-12 Kmk Lizence Ltd. Vorrichtung sowie Verfahren zum Herstellen von Tuben
WO2013106039A1 (en) * 2011-04-27 2013-07-18 Fina Technology, Inc. Dehydrogenation reactions of n-butene to butadiene
CN103120942B (zh) * 2011-11-18 2015-08-12 中国石油化工股份有限公司 用于烷基芳烃脱氢制备烷烯基芳烃的节能催化剂
CN117138838A (zh) 2015-07-22 2023-12-01 巴斯夫公司 用于乙酸乙烯酯单体产生制备的高几何表面积催化剂
CN106423239B (zh) * 2015-08-12 2019-01-25 中国石油化工股份有限公司 高稳定苯乙烯催化剂
CN106423187B (zh) * 2015-08-12 2019-02-19 中国石油化工股份有限公司 苯乙烯催化剂
CN106423238B (zh) * 2015-08-12 2019-01-25 中国石油化工股份有限公司 苯乙烯催化剂及其制备方法
CN108722403B (zh) * 2017-04-20 2019-09-27 中国石油化工股份有限公司 一种丙烷脱氢催化剂及其制备方法和丙烷脱氢制丙烯的方法
CN111054370A (zh) * 2018-10-16 2020-04-24 中国石油化工股份有限公司 制备苯乙烯的高强度催化剂
RU2726125C1 (ru) * 2020-01-10 2020-07-09 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Катализатор для дегидрирования алкилароматических углеводородов
CN114478165A (zh) * 2020-10-27 2022-05-13 中国石油化工股份有限公司 生产苯乙烯的方法
RU2753669C1 (ru) * 2020-11-17 2021-08-19 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Катализатор для гетерогенных реакций с пониженным гидравлическим сопротивлением слоя
CN113941322B (zh) * 2021-11-22 2022-08-09 西南化工研究设计院有限公司 一种氧化铝包覆式酯交换催化剂的制备方法

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US5023225A (en) * 1989-07-21 1991-06-11 United Catalysts Inc. Dehydrogenation catalyst and process for its preparation
DE3930533C1 (zh) * 1989-09-13 1991-05-08 Degussa Ag, 6000 Frankfurt, De
IT1256156B (it) * 1992-10-06 1995-11-29 Montecatini Tecnologie Srl Catalizzatore in granuli particolarmente per la deidrogenazione ossidativa di metanolo a formaldeide

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NO313909B1 (no) 2002-12-23
US6166280A (en) 2000-12-26
HRP970129A2 (en) 1998-04-30
CZ65097A3 (en) 1997-09-17
SK282102B6 (sk) 2001-11-06
DE69722689D1 (de) 2003-07-17
MX9701681A (es) 1998-04-30
EP0794004B1 (en) 2003-06-11
RU2167711C2 (ru) 2001-05-27
ITMI960447A1 (it) 1997-09-08
PT794004E (pt) 2003-10-31
ITMI960447A0 (zh) 1996-03-08
NO971062L (no) 1997-09-09
CN1161882A (zh) 1997-10-15
AU1510397A (en) 1997-09-11
CN1085951C (zh) 2002-06-05
ID16428A (id) 1997-09-25
BR9701231A (pt) 1998-08-25
UA42783C2 (uk) 2001-11-15
HRP970129B1 (en) 2002-04-30
AU716285B2 (en) 2000-02-24
ATE242660T1 (de) 2003-06-15
EP0794004A1 (en) 1997-09-10
HU9700554D0 (en) 1997-04-28
ES2200091T3 (es) 2004-03-01
KR970064714A (ko) 1997-10-13
IT1283207B1 (it) 1998-04-16
DE69722689T2 (de) 2004-05-13
HUP9700554A2 (hu) 1998-03-02
HU218961B (hu) 2001-01-29
HUP9700554A3 (en) 1998-03-30
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