ES468716A1 - Un procedimiento para la deshidrogenacion de hidrocarburos - Google Patents

Un procedimiento para la deshidrogenacion de hidrocarburos

Info

Publication number
ES468716A1
ES468716A1 ES468716A ES468716A ES468716A1 ES 468716 A1 ES468716 A1 ES 468716A1 ES 468716 A ES468716 A ES 468716A ES 468716 A ES468716 A ES 468716A ES 468716 A1 ES468716 A1 ES 468716A1
Authority
ES
Spain
Prior art keywords
dehydrogenation catalyst
dehydrogenation
hydrocarbons
cerium
molybdenum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES468716A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of ES468716A1 publication Critical patent/ES468716A1/es
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/322—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un procedimiento para la deshidrogenación de hidrocarburos, que comprende deshidrogenar un hidrocarburo a una temperatura comprenda entre 500ºC y 700ºC en presencia de vapor de agua y en presencia de un catalizador que comprende: (a) de 10 a 95 por ciento en peso de un óxido de hierro, medido como óxido férrico; (b) de 3 a 30 por ciento en peso de óxido de potasio y/o carbonato de potasio medido como óxido de potasio y/o carbonato de potasio medido como óxido de potasio; © de 0,01 a 9 por ciento en peso de un óxido de vanadio, medido como pentóxido de vanadio; (d) de 0.01 a 20 por ciento en peso de óxido de molideno y/u óxido de wolframio, medidos como el trióxido; (e) de 0,01 a 50 por ciento en peso de un óxido de cerio, medido como óxido ceroso; (f) de 0 a 50 por ciento en peso de un óxido de cobalto, medido como óxido cobaltoso; y (g) de 0 a 30 por ciento en peso de un óxido de cromo, medido como óxido crómico.
ES468716A 1977-04-14 1978-04-12 Un procedimiento para la deshidrogenacion de hidrocarburos Expired ES468716A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US78764677A 1977-04-14 1977-04-14

Publications (1)

Publication Number Publication Date
ES468716A1 true ES468716A1 (es) 1979-10-01

Family

ID=25142147

Family Applications (1)

Application Number Title Priority Date Filing Date
ES468716A Expired ES468716A1 (es) 1977-04-14 1978-04-12 Un procedimiento para la deshidrogenacion de hidrocarburos

Country Status (19)

Country Link
US (1) US4144197A (es)
JP (1) JPS53129190A (es)
AR (1) AR223460A1 (es)
BE (1) BE865830A (es)
BR (1) BR7802256A (es)
CA (1) CA1115260A (es)
DE (1) DE2815874C3 (es)
ES (1) ES468716A1 (es)
FR (1) FR2387199A1 (es)
GB (1) GB1557143A (es)
IN (1) IN148558B (es)
IT (1) IT1095580B (es)
MX (1) MX147003A (es)
NL (1) NL186370C (es)
PT (1) PT67893B (es)
SU (1) SU1077556A3 (es)
TR (1) TR19704A (es)
YU (1) YU40034B (es)
ZA (1) ZA781576B (es)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3132014A1 (de) * 1981-08-13 1983-03-03 Basf Ag, 6700 Ludwigshafen Dehydrierungskatalysator, verfahren zur herstellung desselben und verwendung zur dehydrierung von ethylbenzol zu styrol
US4467046A (en) * 1982-01-07 1984-08-21 Smith James L Dehydrogenation catalyst
JPS58177148A (ja) * 1982-04-13 1983-10-17 Mitsubishi Petrochem Co Ltd スチレン製造用触媒
US4511672A (en) * 1982-07-29 1985-04-16 Monsanto Company Catalyst and reverse disproportionation process
US4419526A (en) * 1982-07-29 1983-12-06 Monsanto Company Catalyst and reverse disproportionation process
US4448894A (en) * 1982-07-29 1984-05-15 Monsanto Company Catalyst and reverse disproportionation process
US4439628A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4490477A (en) * 1982-07-29 1984-12-25 Monsanto Company Catalyst and reverse disproportionation process
US4487849A (en) * 1982-07-29 1984-12-11 Monsanto Company Catalyst for the reverse disproportionation process
US4439627A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4474897A (en) * 1982-07-29 1984-10-02 Monsanto Company Catalyst useable in a reverse disproportionation process
US4514519A (en) * 1982-07-29 1985-04-30 Monsanto Company Catalyst and reverse disproportionation process
US4439626A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4440968A (en) * 1982-07-29 1984-04-03 Monsanto Company Catalyst and reverse disproportionation process
US4419527A (en) * 1982-07-29 1983-12-06 Monsanto Company Catalyst and reverse disproportionation process
US4440967A (en) * 1982-07-29 1984-04-03 Monsanto Company Catalyst and reverse disproportionation process
EP0101913A3 (de) * 1982-08-03 1986-07-30 BASF Aktiengesellschaft Dehydrierungskatalysator
US4404123A (en) * 1982-12-15 1983-09-13 Mobil Oil Corporation Catalysts for para-ethyltoluene dehydrogenation
US4758543A (en) * 1987-07-01 1988-07-19 The Dow Chemical Company Dehydrogenation catalyst
US4804799A (en) * 1987-08-28 1989-02-14 The Dow Chemical Company Dehydrogenation catalyst
US4973791A (en) * 1989-07-20 1990-11-27 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing an alkali-promoted molybdate catalyst
US5258347A (en) * 1989-07-20 1993-11-02 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing a molybdate catalyst composition
DE4324905A1 (de) * 1993-07-24 1995-01-26 Basf Ag Dehydrierungskatalysator und dessen Verwendung
KR100373572B1 (ko) * 1994-12-14 2003-04-21 쉘 인터내셔널 리써치 마챠피즈 비 브이 탈수소화촉매및방법
JP4376966B2 (ja) * 1994-12-14 2009-12-02 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 再構造化された酸化鉄
CA2207560A1 (en) * 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Large particle dehydrogenation catalyst and process
DE19535416A1 (de) * 1995-09-23 1997-03-27 Basf Ag Verfahren zur Herstellung von Katalysatoren für selektive Dehydrierungen
CN1076632C (zh) * 1998-03-30 2001-12-26 中国石油化工总公司 烷基芳烃脱氢催化剂
DE19814081A1 (de) * 1998-03-30 1999-10-07 Basf Ag Katalysator zur Dehydrierung von 1,1-Diphenylethan und substituierten 1,1-Diarylethanen
CN1076633C (zh) * 1998-03-30 2001-12-26 中国石油化工总公司 低温烷基芳烃脱氢催化剂
US6242379B1 (en) 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts
US6756339B1 (en) 1998-04-01 2004-06-29 Sud-Chemie Inc. Dehydrogenation catalysts
KR20030072541A (ko) * 2002-03-04 2003-09-15 한국화학연구원 이산화탄소 산화제를 사용한 알킬방향족 탄화수소의탈수소화 방법
US7244868B2 (en) * 2002-06-25 2007-07-17 Shell Oil Company Process for the dehydrogenation of an unsaturated hydrocarbon
WO2004060839A1 (en) * 2002-12-19 2004-07-22 Dow Global Technologies Inc. Dehydrogenation of alkyl aromatic compound over a rare earth catalyst
US20040242945A1 (en) * 2003-05-29 2004-12-02 Pelati Joseph E. Dehydrogenation of alkyl aromatic compound over a gallium-zinc catalyst
US20100081855A1 (en) * 2008-09-30 2010-04-01 Fina Technology, Inc. Semi-Supported Dehydrogenation Catalyst
CN106807453A (zh) * 2017-01-23 2017-06-09 山东三维石化工程股份有限公司 丁烯氧化脱氢制备丁二烯催化剂的方法
CN112023911B (zh) * 2020-09-14 2021-09-14 昆明理工大学 一种气相苯乙烯诱导型CeO2催化剂的制备方法

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* Cited by examiner, † Cited by third party
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US3179707A (en) * 1962-03-21 1965-04-20 Monsanto Co Dehydrogenation of ethylbenzene
US3904552A (en) * 1973-03-08 1975-09-09 Girdler Chemical Dehyrogenation catalyst
CA1074773A (en) * 1975-07-03 1980-04-01 Gregor H. Riesser Dehydrogenation catalyst and process

Also Published As

Publication number Publication date
SU1077556A3 (ru) 1984-02-29
CA1115260A (en) 1981-12-29
IN148558B (es) 1981-04-04
DE2815874B2 (de) 1980-05-29
NL186370C (nl) 1990-11-16
JPS5728291B2 (es) 1982-06-16
IT7822246A0 (it) 1978-04-12
FR2387199B1 (es) 1980-08-08
AU3501478A (en) 1979-10-18
TR19704A (tr) 1979-10-11
YU87278A (en) 1982-10-31
DE2815874C3 (de) 1981-09-24
YU40034B (en) 1985-06-30
US4144197A (en) 1979-03-13
DE2815874A1 (de) 1978-10-19
BE865830A (nl) 1978-10-10
FR2387199A1 (fr) 1978-11-10
IT1095580B (it) 1985-08-10
ZA781576B (en) 1979-03-28
NL7803708A (nl) 1978-10-17
BR7802256A (pt) 1979-01-23
GB1557143A (en) 1979-12-05
PT67893B (en) 1979-11-14
AR223460A1 (es) 1981-08-31
PT67893A (en) 1978-05-01
MX147003A (es) 1982-09-22
JPS53129190A (en) 1978-11-10
NL186370B (nl) 1990-06-18

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Effective date: 20000601