FR2387199A1 - Catalyseur de deshydrogenation et procede pour le preparer - Google Patents

Catalyseur de deshydrogenation et procede pour le preparer

Info

Publication number
FR2387199A1
FR2387199A1 FR7810759A FR7810759A FR2387199A1 FR 2387199 A1 FR2387199 A1 FR 2387199A1 FR 7810759 A FR7810759 A FR 7810759A FR 7810759 A FR7810759 A FR 7810759A FR 2387199 A1 FR2387199 A1 FR 2387199A1
Authority
FR
France
Prior art keywords
oxide
measuring
weight
potassium
preparing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7810759A
Other languages
English (en)
Other versions
FR2387199B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2387199A1 publication Critical patent/FR2387199A1/fr
Application granted granted Critical
Publication of FR2387199B1 publication Critical patent/FR2387199B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/322—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un catalyseur. Ce catalyseur comprend : a. De 20 à 95 % en poids d'un oxyde de fer, en mesurant en oxyde ferrique; b. De 3 a 30 % en poids d'oxyde de potassium et/ou de carbonate de potassium, en mesurant en oxyde de potassium; c. De 0,01 à 9 % en poids d'un oxyde de vanadium, en mesurant en pentoxyde de vanadium; d De 0,01 à 20 % en poids d'oxyde de molybdène et/ou d'oxyde de tungstène, en mesurant en trioxyde; e. De 0,01 à 50 % en poids d'un oxyde de cérium, en mesurant en oxyde céreux; f De 0 à 50 % en poids d'un oxyde de cobalt, en mesurant en oxyde cobalteux; et g. e 0 à 30 % en poids d'un oxyde de chrome, en mesurant en oxyde chromique. Application à la déshydrogénation d'hydrocarbures.
FR7810759A 1977-04-14 1978-04-12 Catalyseur de deshydrogenation et procede pour le preparer Granted FR2387199A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US78764677A 1977-04-14 1977-04-14

Publications (2)

Publication Number Publication Date
FR2387199A1 true FR2387199A1 (fr) 1978-11-10
FR2387199B1 FR2387199B1 (fr) 1980-08-08

Family

ID=25142147

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7810759A Granted FR2387199A1 (fr) 1977-04-14 1978-04-12 Catalyseur de deshydrogenation et procede pour le preparer

Country Status (19)

Country Link
US (1) US4144197A (fr)
JP (1) JPS53129190A (fr)
AR (1) AR223460A1 (fr)
BE (1) BE865830A (fr)
BR (1) BR7802256A (fr)
CA (1) CA1115260A (fr)
DE (1) DE2815874C3 (fr)
ES (1) ES468716A1 (fr)
FR (1) FR2387199A1 (fr)
GB (1) GB1557143A (fr)
IN (1) IN148558B (fr)
IT (1) IT1095580B (fr)
MX (1) MX147003A (fr)
NL (1) NL186370C (fr)
PT (1) PT67893B (fr)
SU (1) SU1077556A3 (fr)
TR (1) TR19704A (fr)
YU (1) YU40034B (fr)
ZA (1) ZA781576B (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0072439A2 (fr) * 1981-08-13 1983-02-23 BASF Aktiengesellschaft Catalyseur de déshydrogénation, procédé de préparation et d'utilisation dans la déshydrogénation d'éthylbenzène en styrolène
WO1996018594A1 (fr) * 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Catalyseur de deshydrogenation a grosses particules et procede associe
WO1996018458A1 (fr) * 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Catalyseur de deshydrogenation et procede associe

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4467046A (en) * 1982-01-07 1984-08-21 Smith James L Dehydrogenation catalyst
JPS58177148A (ja) * 1982-04-13 1983-10-17 Mitsubishi Petrochem Co Ltd スチレン製造用触媒
US4440967A (en) * 1982-07-29 1984-04-03 Monsanto Company Catalyst and reverse disproportionation process
US4419527A (en) * 1982-07-29 1983-12-06 Monsanto Company Catalyst and reverse disproportionation process
US4511672A (en) * 1982-07-29 1985-04-16 Monsanto Company Catalyst and reverse disproportionation process
US4474897A (en) * 1982-07-29 1984-10-02 Monsanto Company Catalyst useable in a reverse disproportionation process
US4487849A (en) * 1982-07-29 1984-12-11 Monsanto Company Catalyst for the reverse disproportionation process
US4439626A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4439627A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4490477A (en) * 1982-07-29 1984-12-25 Monsanto Company Catalyst and reverse disproportionation process
US4439628A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4440968A (en) * 1982-07-29 1984-04-03 Monsanto Company Catalyst and reverse disproportionation process
US4419526A (en) * 1982-07-29 1983-12-06 Monsanto Company Catalyst and reverse disproportionation process
US4514519A (en) * 1982-07-29 1985-04-30 Monsanto Company Catalyst and reverse disproportionation process
US4448894A (en) * 1982-07-29 1984-05-15 Monsanto Company Catalyst and reverse disproportionation process
EP0101913A3 (fr) * 1982-08-03 1986-07-30 BASF Aktiengesellschaft Catalyseur de deshydrogénation
US4404123A (en) * 1982-12-15 1983-09-13 Mobil Oil Corporation Catalysts for para-ethyltoluene dehydrogenation
US4758543A (en) * 1987-07-01 1988-07-19 The Dow Chemical Company Dehydrogenation catalyst
US4804799A (en) * 1987-08-28 1989-02-14 The Dow Chemical Company Dehydrogenation catalyst
US5258347A (en) * 1989-07-20 1993-11-02 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing a molybdate catalyst composition
US4973791A (en) * 1989-07-20 1990-11-27 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing an alkali-promoted molybdate catalyst
DE4324905A1 (de) * 1993-07-24 1995-01-26 Basf Ag Dehydrierungskatalysator und dessen Verwendung
WO1996018457A1 (fr) * 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Oxyde de fer restructure
DE19535416A1 (de) * 1995-09-23 1997-03-27 Basf Ag Verfahren zur Herstellung von Katalysatoren für selektive Dehydrierungen
DE19814081A1 (de) * 1998-03-30 1999-10-07 Basf Ag Katalysator zur Dehydrierung von 1,1-Diphenylethan und substituierten 1,1-Diarylethanen
CN1076632C (zh) * 1998-03-30 2001-12-26 中国石油化工总公司 烷基芳烃脱氢催化剂
CN1076633C (zh) * 1998-03-30 2001-12-26 中国石油化工总公司 低温烷基芳烃脱氢催化剂
US6242379B1 (en) 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts
US6756339B1 (en) 1998-04-01 2004-06-29 Sud-Chemie Inc. Dehydrogenation catalysts
KR20030072541A (ko) * 2002-03-04 2003-09-15 한국화학연구원 이산화탄소 산화제를 사용한 알킬방향족 탄화수소의탈수소화 방법
US7244868B2 (en) * 2002-06-25 2007-07-17 Shell Oil Company Process for the dehydrogenation of an unsaturated hydrocarbon
AU2003298831A1 (en) * 2002-12-19 2004-07-29 Dow Global Technologies Inc. Dehydrogenation of alkyl aromatic compound over a rare earth catalyst
WO2004110966A1 (fr) * 2003-05-29 2004-12-23 Dow Global Technologies, Inc. Deshydrogenation d'un compose aromatique alkyle au moyen d'un catalyseur contenant du gallium et du zinc
US20100081855A1 (en) * 2008-09-30 2010-04-01 Fina Technology, Inc. Semi-Supported Dehydrogenation Catalyst
CN106807453A (zh) * 2017-01-23 2017-06-09 山东三维石化工程股份有限公司 丁烯氧化脱氢制备丁二烯催化剂的方法
CN112023911B (zh) * 2020-09-14 2021-09-14 昆明理工大学 一种气相苯乙烯诱导型CeO2催化剂的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2629635A1 (de) * 1975-07-03 1977-01-27 Shell Int Research Dehydrierungskatalysator und seine verwendung bei der dehydrierung von kohlenwasserstoffen

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3179707A (en) * 1962-03-21 1965-04-20 Monsanto Co Dehydrogenation of ethylbenzene
US3904552A (en) * 1973-03-08 1975-09-09 Girdler Chemical Dehyrogenation catalyst

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2629635A1 (de) * 1975-07-03 1977-01-27 Shell Int Research Dehydrierungskatalysator und seine verwendung bei der dehydrierung von kohlenwasserstoffen

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0072439A2 (fr) * 1981-08-13 1983-02-23 BASF Aktiengesellschaft Catalyseur de déshydrogénation, procédé de préparation et d'utilisation dans la déshydrogénation d'éthylbenzène en styrolène
EP0072439A3 (en) * 1981-08-13 1984-05-09 Basf Aktiengesellschaft Dehydrogenation catalyst, process for its preparation and its use in the dehydrogenation of ethyl benzene to styrene
WO1996018594A1 (fr) * 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Catalyseur de deshydrogenation a grosses particules et procede associe
WO1996018458A1 (fr) * 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Catalyseur de deshydrogenation et procede associe
US5962757A (en) * 1994-12-14 1999-10-05 Shell Oil Company Dehydrogenation catalyst and process

Also Published As

Publication number Publication date
TR19704A (tr) 1979-10-11
YU87278A (en) 1982-10-31
IN148558B (fr) 1981-04-04
IT7822246A0 (it) 1978-04-12
SU1077556A3 (ru) 1984-02-29
AU3501478A (en) 1979-10-18
ES468716A1 (es) 1979-10-01
MX147003A (es) 1982-09-22
AR223460A1 (es) 1981-08-31
BR7802256A (pt) 1979-01-23
JPS5728291B2 (fr) 1982-06-16
NL186370C (nl) 1990-11-16
DE2815874B2 (de) 1980-05-29
ZA781576B (en) 1979-03-28
YU40034B (en) 1985-06-30
IT1095580B (it) 1985-08-10
DE2815874C3 (de) 1981-09-24
FR2387199B1 (fr) 1980-08-08
NL186370B (nl) 1990-06-18
DE2815874A1 (de) 1978-10-19
PT67893A (en) 1978-05-01
US4144197A (en) 1979-03-13
NL7803708A (nl) 1978-10-17
GB1557143A (en) 1979-12-05
JPS53129190A (en) 1978-11-10
PT67893B (en) 1979-11-14
BE865830A (nl) 1978-10-10
CA1115260A (fr) 1981-12-29

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