DK0521099T3 - Chirale katalysatorer og epoxidationsreaktioner katalyseret derved - Google Patents

Chirale katalysatorer og epoxidationsreaktioner katalyseret derved

Info

Publication number
DK0521099T3
DK0521099T3 DK91907292T DK91907292T DK0521099T3 DK 0521099 T3 DK0521099 T3 DK 0521099T3 DK 91907292 T DK91907292 T DK 91907292T DK 91907292 T DK91907292 T DK 91907292T DK 0521099 T3 DK0521099 T3 DK 0521099T3
Authority
DK
Denmark
Prior art keywords
chiral catalysts
reactions catalyzed
epoxidation reactions
catalysts
chiral
Prior art date
Application number
DK91907292T
Other languages
Danish (da)
English (en)
Inventor
Eric N Jacobsen
Wei Zhang
Original Assignee
Res Corp Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Res Corp Technologies Inc filed Critical Res Corp Technologies Inc
Application granted granted Critical
Publication of DK0521099T3 publication Critical patent/DK0521099T3/da

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/24—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/48—Compounds containing oxirane rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/10—Spiro-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C07F13/005—Compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • C07F19/005—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00 without metal-C linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DK91907292T 1990-03-21 1991-03-21 Chirale katalysatorer og epoxidationsreaktioner katalyseret derved DK0521099T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US49699290A 1990-03-21 1990-03-21
PCT/US1991/001897 WO1991014694A1 (en) 1990-03-21 1991-03-21 Chiral catalysts and epoxidation reactions catalyzed thereby

Publications (1)

Publication Number Publication Date
DK0521099T3 true DK0521099T3 (da) 1998-09-07

Family

ID=23975023

Family Applications (1)

Application Number Title Priority Date Filing Date
DK91907292T DK0521099T3 (da) 1990-03-21 1991-03-21 Chirale katalysatorer og epoxidationsreaktioner katalyseret derved

Country Status (10)

Country Link
EP (1) EP0521099B1 (ja)
JP (2) JP3487847B2 (ja)
AT (1) ATE161538T1 (ja)
AU (1) AU648301B2 (ja)
CA (1) CA2077541C (ja)
DE (1) DE69128528T2 (ja)
DK (1) DK0521099T3 (ja)
ES (1) ES2113374T3 (ja)
GR (1) GR3032114T3 (ja)
WO (1) WO1991014694A1 (ja)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993003838A1 (en) * 1991-08-26 1993-03-04 Research Corporation Technologies, Inc. Chiral catalysts, catalytic oxidation and disproportionation reactions, and methods of producing epoxychromans and taxol
US5352814A (en) * 1991-08-30 1994-10-04 Nissan Chemical Industries, Ltd. Asymmetric epoxidation reaction
FI930148A (fi) * 1992-01-18 1993-07-19 Hoechst Ag Foerfarande foer enantioselektiv epoxidation av i 6-staellning substituerade kromener
GB9203596D0 (en) * 1992-02-20 1992-04-08 Smithkline Beecham Plc Novel process
JP3322877B2 (ja) * 1992-08-06 2002-09-09 スミスクライン・ビーチャム・パブリック・リミテッド・カンパニー キラル触媒およびその触媒によるエポキシ化反応
AU677643B2 (en) * 1993-04-02 1997-05-01 Nissan Chemical Industries Ltd. Heart failure remedy
US6031115A (en) * 1993-05-14 2000-02-29 Smithkline Beecham Plc Process for preparing epoxides
ES2121174T3 (es) * 1993-06-19 1998-11-16 Ciba Geigy Ag Inhibicion de la reabsorcion de colorantes migrantes en el licor de lavado.
KR100359972B1 (ko) * 1994-02-04 2003-01-24 스미스클라인비이참피이엘시이 프로키랄올레핀의에폭시드화방법,이를위한촉매및이촉매의제조용중간체
US5599957A (en) * 1994-02-23 1997-02-04 Nissan Chemical Industries, Ltd. Asymmetric epoxidation reaction
EP0693550B1 (en) * 1994-07-21 2004-06-16 Ciba SC Holding AG Fabric bleaching composition
US5786496A (en) * 1994-08-22 1998-07-28 Northwestern University High oxidation state metal oxo complexes of the PHAB ligand
GB9425296D0 (en) * 1994-12-15 1995-02-15 Ciba Geigy Ag Inhibition of dye migration
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US6262278B1 (en) 1995-03-14 2001-07-17 President And Fellows Of Harvard College Stereoselective ring opening reactions
ATE242230T1 (de) 1996-07-26 2003-06-15 Nissan Chemical Ind Ltd Chroman derivate
DE19719397A1 (de) * 1997-05-07 1998-11-12 Clariant Gmbh Bleichaktive Metall-Komplexe
US5981424A (en) * 1997-07-31 1999-11-09 Sunoco, Inc. (R&M) Catalysts for hydroxylation and ammination of aromatics using molecular oxygen as the terminal oxidant without coreductant
ES2229466T3 (es) 1997-09-09 2005-04-16 Ciba Specialty Chemicals Holding Inc. Metodo para el cuidado del tejido.
TW408203B (en) * 1998-04-06 2000-10-11 Ciba Sc Holding Ag Process for treating textile materials and the relevant compounds
US6521561B1 (en) * 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
US6486178B1 (en) 1998-06-03 2002-11-26 Nissan Chemical Industries, Ltd. Indane derivatives
JP2002030079A (ja) * 1999-08-03 2002-01-29 Mitsubishi Chemicals Corp 光学活性１，２−二置換−２，３−エポキシプロパン類の製造法
EP1214307B1 (en) 1999-09-24 2004-04-07 Nissan Chemical Industries, Ltd. 4-oxybenzopyran derivative
US6677371B1 (en) 1999-10-05 2004-01-13 Nissan Chemical Industries, Ltd. 4-oxybenzopyran derivative
JP3962587B2 (ja) * 2000-05-24 2007-08-22 アールエステック カンパニー リミテッド 新規キラルサレン触媒及びこれを使用してラセミエポキシドからキラル化合物を製造する方法
KR100342659B1 (en) 2000-12-15 2002-07-04 Rstech Co Ltd Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same
KR100869897B1 (ko) 2001-06-25 2008-11-24 닛산 가가쿠 고교 가부시키 가이샤 부정맥 치료용 치환 벤조피란 유도체
US7368582B2 (en) 2003-10-17 2008-05-06 Solvay Pharmaceuticals Gmbh Amidomethyl-substituted 2-(4-sulfonylamino)-3-hydroxy-3,4-dihydro-2H-chromen-6-yl compounds, a process and intermediates for their production, and pharmaceutical compositions containing them
FR2875500A1 (fr) * 2004-09-21 2006-03-24 Centre Nat Rech Scient Complexe chiraux macrocycliques utilisables comme catalyseurs
US7714150B2 (en) 2005-04-12 2010-05-11 Solvay Pharmaceuticals Gmbh Aminoalkyl-amidomethyl-substituted 2-(4-sulphonylamino)-3-hydroxy-3,4-dihydro-2H-chroman-6-yl derivatives
JP2008255086A (ja) * 2007-03-10 2008-10-23 Nissan Chem Ind Ltd 光学活性エポキシ化合物の製造方法
NO2337809T3 (ja) 2008-09-08 2017-12-30
EP2264024A1 (en) 2008-10-14 2010-12-22 LEK Pharmaceuticals d.d. Process for the preparation of enantiomerically enriched proton pump inhibitors
TWI426090B (zh) * 2011-05-31 2014-02-11 Tsrc Corp 製造環氧化聚合物的方法
US9593203B2 (en) 2011-07-18 2017-03-14 Novomer, Inc. Metal complexes
KR102096761B1 (ko) 2012-08-24 2020-04-03 사우디 아람코 테크놀로지스 컴퍼니 금속 착물
EP2986622B2 (en) * 2013-04-17 2021-03-10 Reliance Industries Limited A novel transition metal based pro-catalyst and a process for its preparation
WO2018151019A1 (ja) * 2017-02-14 2018-08-23 セントラル硝子株式会社 立体選択的な二置換ハロゲン化エポキシドの製造方法
WO2020028606A1 (en) 2018-08-02 2020-02-06 Saudi Aramco Technologies Company Sustainable polymer compositions and methods

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2588265B3 (fr) * 1985-10-04 1988-01-15 Inst Francais Du Petrole Procede d'adoucissement d'une charge d'hydrocarbures contenant des produits soufres
DE3539268A1 (de) * 1985-11-06 1987-05-07 Degussa Verfahren zur katalytischen epoxidation von olefinen mit wasserstoffperoxid

Also Published As

Publication number Publication date
EP0521099A1 (en) 1993-01-07
ATE161538T1 (de) 1998-01-15
AU648301B2 (en) 1994-04-21
DE69128528D1 (de) 1998-02-05
WO1991014694A1 (en) 1991-10-03
CA2077541A1 (en) 1991-09-22
ES2113374T3 (es) 1998-05-01
AU7555391A (en) 1991-10-21
EP0521099B1 (en) 1997-12-29
GR3032114T3 (en) 2000-04-27
JP3487847B2 (ja) 2004-01-19
DE69128528T2 (de) 1998-07-30
CA2077541C (en) 1998-08-18
EP0521099A4 (en) 1993-10-20
JPH05507645A (ja) 1993-11-04
JP2004148290A (ja) 2004-05-27

Similar Documents

Publication Publication Date Title
DK0521099T3 (da) Chirale katalysatorer og epoxidationsreaktioner katalyseret derved
ES2171159T3 (es) Procedimiento para la preparacion de epoxicromanos con un catalizador quiral.
BR8907211A (pt) Processo para epoxidacao seletiva de olefinas
DE3779350D1 (de) Katalytischer reaktionsapparat.
DE3574937D1 (de) Reaktor zum durchfuehren von heterogenen, katalysierten chemischen reaktionen.
DE68901604D1 (de) Kohlenwasserstoffumwandlungskatalysator und verfahren, das diesen katalysator anwendet.
MX9810300A (en) Oxidation catalyst and process for the production of epoxides from olefines, hydrogen and oxygen using said oxidation catalyst
NO883826D0 (no) Fremgangsmaate ved heterogen katalyse.
DE3878460T2 (de) Umlaufwirbelbettreaktor.
AU1022799A (en) Epoxidation process using supported silver catalysts treated with carbon dioxide
ES2165229T3 (es) Procedimiento de epoxidacion que utiliza un catalizador soportado de oro.
ATE117998T1 (de) Epoxydierungsverfahren.
NO864447L (no) Katalysator-forloeper, f.eks. for ammoniakksyntese-katalysatorer.
DE68901294D1 (de) Katalysator zur wasserstoffbehandlung von kohlenwasserstoffen.
DE68917597D1 (de) Katalytisches hydrofluorierungsverfahren.
NO980526L (no) Dinafazepiniumsalter anvendelige som enantioselektive epoksyderingskatalysatorer
ATE148695T1 (de) Epoxidation mittels thalium-aktivierten silberkatalysatoren
ATE104341T1 (de) Herstellung von immunonaehe-katalysatoren.
DE3766788D1 (de) Molybdaen-alkalimetall-aethylenglykolkomplexe, verwendbar als epoxydationskatalysatoren und ihr herstellungsverfahren.
IT8719830A0 (it) Procedimento per la realizzazione di reazioni enzimatiche entro un solvente organico.
DE3785068T2 (de) Katalysatorszusammensetzungen und damit katalysierten zusammensetzungen.
GB9812235D0 (en) Oxidation process
NO871297L (no) Katalysatorkomponenter til alfa-olefin-polymerisasjonskatalysatorer og fremgangsmaate for fremstilling av disse.
NO903168L (no) Katalysator, fremgangsmaate til fremstilling av en katalysatorbaerer og bruk av katalysatoren til dimerisering av alkener.
DE3873752T2 (de) Verfahren zur herstellung von molybdaen-alkylenglycol-komplexen, brauchbar als epoxydationskatalysatoren.