ES2113374T3 - Catalizadores quirales y reacciones de epoxidacion catalizadas por los mismos. - Google Patents
Catalizadores quirales y reacciones de epoxidacion catalizadas por los mismos.Info
- Publication number
- ES2113374T3 ES2113374T3 ES91907292T ES91907292T ES2113374T3 ES 2113374 T3 ES2113374 T3 ES 2113374T3 ES 91907292 T ES91907292 T ES 91907292T ES 91907292 T ES91907292 T ES 91907292T ES 2113374 T3 ES2113374 T3 ES 2113374T3
- Authority
- ES
- Spain
- Prior art keywords
- same
- chiral catalysts
- reactions catalyzed
- epoxidation reactions
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000006735 epoxidation reaction Methods 0.000 title 1
- VEUMANXWQDHAJV-UHFFFAOYSA-N 2-[2-[(2-hydroxyphenyl)methylideneamino]ethyliminomethyl]phenol Chemical group OC1=CC=CC=C1C=NCCN=CC1=CC=CC=C1O VEUMANXWQDHAJV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
- C07C251/24—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/48—Compounds containing oxirane rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/10—Spiro-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
- C07F19/005—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00 without metal-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/72—Epoxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
SE DESVELAN CATALIZADORES QUIRALES PARA EPOXIDACION, ENANTIOSELECTIVAMENTE, DE UNA OLEFINA PROQUIRAL, JUNTO CON METODOS DE UTILIZACION DE TALES CATALIZADORES. DE ACUERDO CON UN ASPECTO DE LA INVENCION, EL CATALIZADOR ES UN DERIVADO SALINO QUE TIENE LA ESTRUCTURA GENERAL (I)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US49699290A | 1990-03-21 | 1990-03-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2113374T3 true ES2113374T3 (es) | 1998-05-01 |
Family
ID=23975023
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91907292T Expired - Lifetime ES2113374T3 (es) | 1990-03-21 | 1991-03-21 | Catalizadores quirales y reacciones de epoxidacion catalizadas por los mismos. |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0521099B1 (es) |
JP (2) | JP3487847B2 (es) |
AT (1) | ATE161538T1 (es) |
AU (1) | AU648301B2 (es) |
CA (1) | CA2077541C (es) |
DE (1) | DE69128528T2 (es) |
DK (1) | DK0521099T3 (es) |
ES (1) | ES2113374T3 (es) |
GR (1) | GR3032114T3 (es) |
WO (1) | WO1991014694A1 (es) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK0643626T3 (da) * | 1991-08-26 | 2002-05-13 | Res Corp Technologies Inc | Fremgangsmåde til fremstilling af epoxychromaner med en chiral katalysator |
US5352814A (en) * | 1991-08-30 | 1994-10-04 | Nissan Chemical Industries, Ltd. | Asymmetric epoxidation reaction |
FI930148A (fi) * | 1992-01-18 | 1993-07-19 | Hoechst Ag | Foerfarande foer enantioselektiv epoxidation av i 6-staellning substituerade kromener |
GB9203596D0 (en) * | 1992-02-20 | 1992-04-08 | Smithkline Beecham Plc | Novel process |
CN1043425C (zh) * | 1992-08-06 | 1999-05-19 | 史密丝克莱恩比彻姆有限公司 | 亚水杨基氨基过渡金属配合物及其制法 |
AU677643B2 (en) * | 1993-04-02 | 1997-05-01 | Nissan Chemical Industries Ltd. | Heart failure remedy |
US6031115A (en) * | 1993-05-14 | 2000-02-29 | Smithkline Beecham Plc | Process for preparing epoxides |
DE69412188T2 (de) * | 1993-06-19 | 1999-03-11 | Ciba Geigy Ag | Inhibierung der Wiederabsorption von migrierenden Farbstoffen in der Waschlösung |
MX9603202A (es) * | 1994-02-04 | 1997-03-29 | Smithkline Beecham Plc | Procedimiento para epoxidacion de olefinas proquirales y un catalizador para la misma e intermediarios para hacer el catalizador. |
US5599957A (en) * | 1994-02-23 | 1997-02-04 | Nissan Chemical Industries, Ltd. | Asymmetric epoxidation reaction |
ES2221665T3 (es) * | 1994-07-21 | 2005-01-01 | Ciba Specialty Chemicals Holding Inc. | Composicion de blanqueo de tejidos. |
US5786496A (en) * | 1994-08-22 | 1998-07-28 | Northwestern University | High oxidation state metal oxo complexes of the PHAB ligand |
GB9425296D0 (en) * | 1994-12-15 | 1995-02-15 | Ciba Geigy Ag | Inhibition of dye migration |
US6262278B1 (en) | 1995-03-14 | 2001-07-17 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
US5665890A (en) * | 1995-03-14 | 1997-09-09 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
AU713573B2 (en) | 1996-07-26 | 1999-12-02 | Nissan Chemical Industries Ltd. | Chroman derivatives |
DE19719397A1 (de) * | 1997-05-07 | 1998-11-12 | Clariant Gmbh | Bleichaktive Metall-Komplexe |
US5981424A (en) * | 1997-07-31 | 1999-11-09 | Sunoco, Inc. (R&M) | Catalysts for hydroxylation and ammination of aromatics using molecular oxygen as the terminal oxidant without coreductant |
ATE279502T1 (de) * | 1997-09-09 | 2004-10-15 | Ciba Sc Holding Ag | Verfahren zur gewebepflege |
TW408203B (en) * | 1998-04-06 | 2000-10-11 | Ciba Sc Holding Ag | Process for treating textile materials and the relevant compounds |
US6521561B1 (en) * | 1998-05-01 | 2003-02-18 | President And Fellows Of Harvard College | Main-group metal based asymmetric catalysts and applications thereof |
CA2334412A1 (en) | 1998-06-03 | 1999-12-09 | Nissan Chemical Industries, Ltd. | Indan derivatives |
JP2002030079A (ja) * | 1999-08-03 | 2002-01-29 | Mitsubishi Chemicals Corp | 光学活性1,2−二置換−2,3−エポキシプロパン類の製造法 |
US6555574B1 (en) | 1999-09-24 | 2003-04-29 | Nissan Chemical Industries, Ltd. | 4-oxybenzopyran derivative |
AU7453900A (en) | 1999-10-05 | 2001-05-10 | Nissan Chemical Industries Ltd. | 4-oxybenzopyran derivative |
CN1174804C (zh) * | 2000-05-24 | 2004-11-10 | 尔艾斯特公司 | 手性萨伦催化剂及用其由外消旋环氧化物制备手性化合物的方法 |
KR100342659B1 (en) * | 2000-12-15 | 2002-07-04 | Rstech Co Ltd | Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same |
CN1279036C (zh) | 2001-06-25 | 2006-10-11 | 日产化学工业株式会社 | 抗心律失常的取代的苯并吡喃衍生物 |
US7368582B2 (en) | 2003-10-17 | 2008-05-06 | Solvay Pharmaceuticals Gmbh | Amidomethyl-substituted 2-(4-sulfonylamino)-3-hydroxy-3,4-dihydro-2H-chromen-6-yl compounds, a process and intermediates for their production, and pharmaceutical compositions containing them |
FR2875500A1 (fr) * | 2004-09-21 | 2006-03-24 | Centre Nat Rech Scient | Complexe chiraux macrocycliques utilisables comme catalyseurs |
US7714150B2 (en) | 2005-04-12 | 2010-05-11 | Solvay Pharmaceuticals Gmbh | Aminoalkyl-amidomethyl-substituted 2-(4-sulphonylamino)-3-hydroxy-3,4-dihydro-2H-chroman-6-yl derivatives |
JP2008255086A (ja) * | 2007-03-10 | 2008-10-23 | Nissan Chem Ind Ltd | 光学活性エポキシ化合物の製造方法 |
KR20240017125A (ko) | 2008-09-08 | 2024-02-06 | 사우디 아람코 테크놀로지스 컴퍼니 | 폴리카보네이트 폴리올 조성물 |
EP2264024A1 (en) | 2008-10-14 | 2010-12-22 | LEK Pharmaceuticals d.d. | Process for the preparation of enantiomerically enriched proton pump inhibitors |
TWI426090B (zh) * | 2011-05-31 | 2014-02-11 | Tsrc Corp | 製造環氧化聚合物的方法 |
JP6110379B2 (ja) | 2011-07-18 | 2017-04-05 | ノボマー, インコーポレイテッド | 金属錯体 |
WO2014031811A1 (en) | 2012-08-24 | 2014-02-27 | Novomer, Inc. | Metal complexes |
BR112015026360A2 (pt) * | 2013-04-17 | 2017-07-25 | Reliance Industries Ltd | pró-catalisador à base de metal de transição inovador e um processo para sua preparação |
WO2018151019A1 (ja) * | 2017-02-14 | 2018-08-23 | セントラル硝子株式会社 | 立体選択的な二置換ハロゲン化エポキシドの製造方法 |
US11180609B2 (en) | 2018-08-02 | 2021-11-23 | Saudi Aramco Technologies Company | Sustainable polymer compositions and methods |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2588265B3 (fr) * | 1985-10-04 | 1988-01-15 | Inst Francais Du Petrole | Procede d'adoucissement d'une charge d'hydrocarbures contenant des produits soufres |
DE3539268A1 (de) * | 1985-11-06 | 1987-05-07 | Degussa | Verfahren zur katalytischen epoxidation von olefinen mit wasserstoffperoxid |
-
1991
- 1991-03-21 JP JP50663891A patent/JP3487847B2/ja not_active Expired - Lifetime
- 1991-03-21 AT AT91907292T patent/ATE161538T1/de not_active IP Right Cessation
- 1991-03-21 CA CA002077541A patent/CA2077541C/en not_active Expired - Lifetime
- 1991-03-21 EP EP91907292A patent/EP0521099B1/en not_active Expired - Lifetime
- 1991-03-21 AU AU75553/91A patent/AU648301B2/en not_active Expired
- 1991-03-21 DE DE69128528T patent/DE69128528T2/de not_active Expired - Lifetime
- 1991-03-21 ES ES91907292T patent/ES2113374T3/es not_active Expired - Lifetime
- 1991-03-21 WO PCT/US1991/001897 patent/WO1991014694A1/en active IP Right Grant
- 1991-03-21 DK DK91907292T patent/DK0521099T3/da active
-
1998
- 1998-03-27 GR GR980400663T patent/GR3032114T3/el unknown
-
2003
- 2003-06-25 JP JP2003181619A patent/JP2004148290A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
EP0521099A1 (en) | 1993-01-07 |
CA2077541C (en) | 1998-08-18 |
JPH05507645A (ja) | 1993-11-04 |
AU7555391A (en) | 1991-10-21 |
EP0521099A4 (en) | 1993-10-20 |
DE69128528T2 (de) | 1998-07-30 |
DK0521099T3 (da) | 1998-09-07 |
ATE161538T1 (de) | 1998-01-15 |
JP3487847B2 (ja) | 2004-01-19 |
EP0521099B1 (en) | 1997-12-29 |
AU648301B2 (en) | 1994-04-21 |
DE69128528D1 (de) | 1998-02-05 |
GR3032114T3 (en) | 2000-04-27 |
CA2077541A1 (en) | 1991-09-22 |
JP2004148290A (ja) | 2004-05-27 |
WO1991014694A1 (en) | 1991-10-03 |
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