DEE0008407MA

DEE0008407MA -

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Publication number: DEE0008407MA
Authority: DE; Germany
Prior art keywords: diffusing; emulsion layers; silver; developer; dye
Prior art date
Legal status : Active

Application number

Other languages

German (de)

English (en)

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239000000839 emulsion Substances 0.000 claims description 74
239000000975 dye Substances 0.000 claims description 67
239000000463 material Substances 0.000 claims description 56
229910052709 silver Inorganic materials 0.000 claims description 37
239000004332 silver Substances 0.000 claims description 37
BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 30
229920000159 gelatin Polymers 0.000 claims description 18
235000019322 gelatine Nutrition 0.000 claims description 18
229910052736 halogen Inorganic materials 0.000 claims description 17
238000000034 method Methods 0.000 claims description 17
108010010803 Gelatin Proteins 0.000 claims description 16
239000008273 gelatin Substances 0.000 claims description 16
235000011852 gelatine desserts Nutrition 0.000 claims description 16
150000002367 halogens Chemical class 0.000 claims description 16
150000003839 salts Chemical class 0.000 claims description 14
239000011780 sodium chloride Substances 0.000 claims description 14
-1 aromatic halogen Chemical class 0.000 claims description 10
238000004040 coloring Methods 0.000 claims description 9
238000007254 oxidation reaction Methods 0.000 claims description 9
230000002378 acidificating Effects 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 8
230000003647 oxidation Effects 0.000 claims description 8
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 8
238000009792 diffusion process Methods 0.000 claims description 7
239000000126 substance Substances 0.000 claims description 7
125000003118 aryl group Chemical group 0.000 claims description 6
125000003396 thiol group Chemical group [H]S* 0.000 claims description 6
125000003277 amino group Chemical group 0.000 claims description 5
229910001385 heavy metal Inorganic materials 0.000 claims description 4
125000001841 imino group Chemical class [H]N=* 0.000 claims description 4
230000003595 spectral Effects 0.000 claims description 3
HWGJWYNMDPTGTD-UHFFFAOYSA-N 1H-azonine Chemical group C=1C=CC=CNC=CC=1 HWGJWYNMDPTGTD-UHFFFAOYSA-N 0.000 claims description 2
RZVHIXYEVGDQDX-UHFFFAOYSA-N Anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 claims description 2
OARRHUQTFTUEOS-UHFFFAOYSA-N Safranin Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N)C=C2[N+]=1C1=CC=CC=C1 OARRHUQTFTUEOS-UHFFFAOYSA-N 0.000 claims description 2
238000010521 absorption reaction Methods 0.000 claims 3
238000001429 visible spectrum Methods 0.000 claims 2
125000004429 atoms Chemical group 0.000 claims 1
239000006185 dispersion Substances 0.000 description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
239000000203 mixture Substances 0.000 description 10
230000033458 reproduction Effects 0.000 description 10
230000000875 corresponding Effects 0.000 description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
239000003795 chemical substances by application Substances 0.000 description 7
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
239000000047 product Substances 0.000 description 6
LUMLZKVIXLWTCI-NSCUHMNNSA-N (E)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 5
CBCKQZAAMUWICA-UHFFFAOYSA-N P-Phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 5
GGCZERPQGJTIQP-UHFFFAOYSA-M Sodium 2-anthraquinonesulfonate Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)[O-])=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-M 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
239000001397 quillaja saponaria molina bark Substances 0.000 description 5
150000007949 saponins Chemical class 0.000 description 5
IOLCXVTUBQKXJR-UHFFFAOYSA-M Potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
WQGWDDDVZFFDIG-UHFFFAOYSA-N Pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 4
HKZLPVFGJNLROG-UHFFFAOYSA-M Silver chloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 4
GEHJYWRUCIMESM-UHFFFAOYSA-L Sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
239000003513 alkali Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000003756 stirring Methods 0.000 description 4
229960000583 Acetic Acid Drugs 0.000 description 3
QVQLCTNNEUAWMS-UHFFFAOYSA-N Barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 3
CBEQRNSPHCCXSH-UHFFFAOYSA-N Iodine monobromide Chemical compound IBr CBEQRNSPHCCXSH-UHFFFAOYSA-N 0.000 description 3
229910001864 baryta Inorganic materials 0.000 description 3
WVDDGKGOMKODPV-UHFFFAOYSA-N benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
235000019441 ethanol Nutrition 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
239000007800 oxidant agent Substances 0.000 description 3
JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
230000035945 sensitivity Effects 0.000 description 3
238000000926 separation method Methods 0.000 description 3
239000000080 wetting agent Substances 0.000 description 3
YCIMNLLNPGFGHC-UHFFFAOYSA-N Catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
239000001828 Gelatine Substances 0.000 description 2
229940079877 Pyrogallol Drugs 0.000 description 2
239000002250 absorbent Substances 0.000 description 2
230000002745 absorbent Effects 0.000 description 2
239000002253 acid Substances 0.000 description 2
230000005540 biological transmission Effects 0.000 description 2
239000000969 carrier Substances 0.000 description 2
230000000295 complement Effects 0.000 description 2
239000004744 fabric Substances 0.000 description 2
239000000834 fixative Substances 0.000 description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
150000002391 heterocyclic compounds Chemical class 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000004848 polyfunctional curative Substances 0.000 description 2
239000001488 sodium phosphate Substances 0.000 description 2
235000010265 sodium sulphite Nutrition 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 2
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
229910000406 trisodium phosphate Inorganic materials 0.000 description 2
235000019801 trisodium phosphate Nutrition 0.000 description 2
ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
OZFUEQNYOBIXTB-VJOYVCHSSA-N 2-[(2E,5E)-5-[[4-[4-(2,2-diphenylethenyl)phenyl]-2,3,3a,8b-tetrahydro-1H-cyclopenta[b]indol-7-yl]methylidene]-2-(3-ethyl-4-oxo-2-sulfanylidene-1,3-thiazolidin-5-ylidene)-4-oxo-1,3-thiazolidin-3-yl]acetic acid Chemical compound O=C1N(CC)C(=S)S\C1=C(\S\1)N(CC(O)=O)C(=O)C/1=C\C1=CC=C(N(C2C3CCC2)C=2C=CC(C=C(C=4C=CC=CC=4)C=4C=CC=CC=4)=CC=2)C3=C1 OZFUEQNYOBIXTB-VJOYVCHSSA-N 0.000 description 1
XYXNTHIYBIDHGM-UHFFFAOYSA-N Ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
WDIHJSXYQDMJHN-UHFFFAOYSA-L Barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
HLIMPDUXBZNSPB-UHFFFAOYSA-N C(C)(=S)NC1=C2C=CC=C(C2=CC=C1)O Chemical compound C(C)(=S)NC1=C2C=CC=C(C2=CC=C1)O HLIMPDUXBZNSPB-UHFFFAOYSA-N 0.000 description 1
XYDJGBOFUHOSKN-UHFFFAOYSA-N C(C1=CC=CC=C1)(=O)C1=CC=C2C(=NNC2=C1)NC(=O)C Chemical compound C(C1=CC=CC=C1)(=O)C1=CC=C2C(=NNC2=C1)NC(=O)C XYDJGBOFUHOSKN-UHFFFAOYSA-N 0.000 description 1
ANRHNWWPFJCPAZ-UHFFFAOYSA-M CHEMBL593252 Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
229920002521 Macromolecule Polymers 0.000 description 1
AJDUTMFFZHIJEM-UHFFFAOYSA-N N-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
229940076133 SODIUM CARBONATE MONOHYDRATE Drugs 0.000 description 1
206010070834 Sensitisation Diseases 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L Sodium thiosulphate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Vitamin C Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
125000003282 alkyl amino group Chemical group 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
150000003931 anilides Chemical class 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
235000010323 ascorbic acid Nutrition 0.000 description 1
229960005070 ascorbic acid Drugs 0.000 description 1
239000011668 ascorbic acid Substances 0.000 description 1
229910001626 barium chloride Inorganic materials 0.000 description 1
159000000009 barium salts Chemical class 0.000 description 1
235000019445 benzyl alcohol Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
238000005266 casting Methods 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003086 colorant Substances 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
150000001989 diazonium salts Chemical class 0.000 description 1
MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000005538 encapsulation Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
PUSKHXMZPOMNTQ-UHFFFAOYSA-N ethyl 2,1,3-benzoselenadiazole-5-carboxylate Chemical compound CCOC(=O)C1=CC=C2N=[Se]=NC2=C1 PUSKHXMZPOMNTQ-UHFFFAOYSA-N 0.000 description 1
125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
230000000763 evoked Effects 0.000 description 1
238000005755 formation reaction Methods 0.000 description 1
239000012362 glacial acetic acid Substances 0.000 description 1
PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
239000001046 green dye Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
125000000687 hydroquinonyl group Chemical class C1(O)=C(C=C(O)C=C1)* 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
150000002605 large molecules Chemical class 0.000 description 1
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
230000001590 oxidative Effects 0.000 description 1
239000002245 particle Substances 0.000 description 1
SOUHUMACVWVDME-UHFFFAOYSA-N phenosafranine Chemical compound [Cl-].C12=CC(N)=CC=C2N=C2C=CC(N)=CC2=[N+]1C1=CC=CC=C1 SOUHUMACVWVDME-UHFFFAOYSA-N 0.000 description 1
238000005554 pickling Methods 0.000 description 1
229920002717 polyvinylpyridine Polymers 0.000 description 1
WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Inorganic materials [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
MIMJFNVDBPUTPB-UHFFFAOYSA-N potassium hexacyanoferrate(3-) Chemical compound [K+].[K+].[K+].N#C[Fe-3](C#N)(C#N)(C#N)(C#N)C#N MIMJFNVDBPUTPB-UHFFFAOYSA-N 0.000 description 1
238000004382 potting Methods 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000001047 purple dye Substances 0.000 description 1
230000008313 sensitization Effects 0.000 description 1
230000001235 sensitizing Effects 0.000 description 1
239000011734 sodium Substances 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
229940001607 sodium bisulfite Drugs 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
241000894007 species Species 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
239000001043 yellow dye Substances 0.000 description 1