DE947014T1 - Elektrochemische speicherzelle mit mindestens einer elektrode auf basis von fluorophenyl thiophenpolymer - Google Patents

Elektrochemische speicherzelle mit mindestens einer elektrode auf basis von fluorophenyl thiophenpolymer

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Publication number
DE947014T1
DE947014T1 DE0947014T DE97946276T DE947014T1 DE 947014 T1 DE947014 T1 DE 947014T1 DE 0947014 T DE0947014 T DE 0947014T DE 97946276 T DE97946276 T DE 97946276T DE 947014 T1 DE947014 T1 DE 947014T1
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DE
Germany
Prior art keywords
thiophene
poly
storage cell
electrochemical storage
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE0947014T
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English (en)
Inventor
Jennifer Giaccai
Yossef Gofer
Jeffrey Killian
Theodore Poehler
Haripada Sarker
Peter Searson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johns Hopkins University
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Johns Hopkins University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johns Hopkins University filed Critical Johns Hopkins University
Publication of DE947014T1 publication Critical patent/DE947014T1/de
Pending legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/137—Electrodes based on electro-active polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/0464—Electro organic synthesis
    • H01M4/0466—Electrochemical polymerisation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1399—Processes of manufacture of electrodes based on electro-active polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • H01M4/608—Polymers containing aromatic main chain polymers containing heterocyclic rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Medicinal Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Dispersion Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Claims (22)

DE/EPO 9470HT1 Patentansprüche
1. Elektrochemische Speicherzelle, die als mindestens eine Elektrode mindestens ein elektrisch leitfähiges Polymer umfaßt, wobei das mindestens eine elektrisch leitfähige Polymer mindestens ein Fluorphenylpolythiophen umfaßt, das ausgewählt ist aus der Gruppe bestehend aus Poly^ (2-f luorphenyl) thiophen) , Poly(3(3-fluorphenyl)thiophen) , Poly(3(2,4-difluorphenyl)thiophen),Poly(3(3,4-difluorphenyl)thiophen), Poly(3(3,5-difluorphenyl)thiophen) und Poly(3(3,4,5-trifluorphenyl)thiophen).
2. Elektrochemische Speicherzelle nach Anspruch 1, bei der die mindestens eine Elektrode eine Anode ist.
3. Elektrochemische Speicherzelle nach Anspruch 2, bei der die Anode aus Poly(3(3,4,5-trifluorphenyl)thiophen) formuliert ist.
4. Elektrochemische Speicherzelle nach Anspruch 3, bei der die mindestens eine Elektrode eine Kathode ist, die aus Poly(3(3,5-difluorphenyl)thiophen) formuliert ist.
5. Elektrochemische Speicherzelle nach Anspruch 1, bei der das mindestens eine Polymer der mindestens einen Elektrode durch Elektropolymerisation formuliert worden ist.
6. Elektrochemische Speicherzelle nach Anspruch 1, bei der das mindestens eine Polymer der mindestens einen Elektrode durch chemische Polymerisation formuliert worden ist.
7. Elektrodenspeicherzelle nach Anspruch 1, die ferner eine Polymergelelektrolytfolie umfaßt.
&egr; / E P..0 9.4 &zgr; &ogr; &mgr;..&tgr;;
DE/EP O 9.47.0U.-T.1
8. Elektrodenspeicherzelle nach Anspruch 7, bei der die Polymergelelektrolytfolie ein Tetrabutylammoniumtetrafluorboratsalz in einem Propylencarbonatlösungsmittel enthält.
9. Elektrodenspeicherzelle nach Anspruch 1, bei der das mindestens eine Polymer ein Homopolymer ist.
10. Elektrochemische Speicherzelle, die eine polymere Anode und eine polymere Kathode umfaßt, wobei die Anode und die Kathode jeweils mindestens ein Fluorphenylpolythiophen umfassen, das ausgewählt ist aus der Gruppe bestehend aus Poly(3(2-fluorphenyl)thiophen), Poly(3(3-fIuorphenyl)thiophen), Poly(3(2,4-difluorphenyl)thiophen), Poly(3(3,4-difluorphenyl)thiophen), Poly(3(3,5-difluorphenyl)thiophen) und Poly ( 3(3,4,5-trifluorphenyl)thiophen) .
11. Elektrochemische Speicherzelle nach Anspruch 10, bei der die Anode aus Poly(3(3,4,5-trifluorphenyl)thiophen formuliert worden ist.
12. Elektrochemische Speicherzelle nach Anspruch 10, bei der die Anode aus Poly(3(3,5-difluorphenyl)thiophen) formuliert-worden ist.
13. Elektrochemische Speicherzelle nach Anspruch 11, bei der die Kathode aus Poly(3(3,5-difluorphenyl)thiophen) formuliert worden ist.
14. Elektrochemiche Speicherzelle nach Anspruch 10, bei der die Anode und die Kathode jeweils durch Elektropolymerisation formuliert worden sind.
15. Elektrochemische Speicherzelle nach Anspruch 14, die ferner eine Polymergelelektrolytfolie umfaßt.
16. Elektrochemische Speicherzelle nach Anspruch 10, bei der die Polymergelelektrolytfolie Tetrabutylammoniumtetrafluorboratsalz in einem Propylencarbonatlösungsmittel enthält.
17. Elektrodenspeicherzelle nach Anspruch 10, bei der das mindestens eine Polymer ein Homopolymer ist.
18. Batterie, die die elektrochemische Speicherzelle gemäß Anspruch 1 enthält.
19. Batterie, die die elektrochemische Speicherzelle gemäß Anspruch 10 enthält.
20. Elektrode, die mindestens ein Fluorphenylpolythiophen umfaßt, das ausgewählt ist aus der Gruppe bestehend aus Poly(3(2-fluorphenyl)thiophen), Poly(3(3-fluorphenyl)-thiophen), Poly(3(2,4-difluorphenyl)thiophen), PoIy-(3(3,4-difluorphenyl)thiophen), Poly(3(3,5-difluorphenyl) thiophen) und Poly(3(3,4,5-trifluorphenyl)thiophen) .
21. Elektrode nach Anspruch 20, bei der die Elektrode eine Anode ist.
22. Elektrode nach Anspruch 20, bei der das Fluorphenylpolythiophen ein Homopolymer ist.
DE0947014T 1996-10-30 1997-10-27 Elektrochemische speicherzelle mit mindestens einer elektrode auf basis von fluorophenyl thiophenpolymer Pending DE947014T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/741,015 US5733683A (en) 1996-10-30 1996-10-30 Electrochemical storage cell containing at least one electrode formulated from a fluorophenyl thiophene polymer
PCT/US1997/018982 WO1998019355A1 (en) 1996-10-30 1997-10-27 An electrochemical storage cell containing at least one electrode formulated from a fluorophenyl thiophene polymer

Publications (1)

Publication Number Publication Date
DE947014T1 true DE947014T1 (de) 2000-02-17

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ID=24979018

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DE0947014T Pending DE947014T1 (de) 1996-10-30 1997-10-27 Elektrochemische speicherzelle mit mindestens einer elektrode auf basis von fluorophenyl thiophenpolymer

Country Status (10)

Country Link
US (1) US5733683A (de)
EP (1) EP0947014A4 (de)
JP (1) JP4259617B2 (de)
KR (1) KR20000052995A (de)
CN (1) CN100350655C (de)
AU (1) AU716318B2 (de)
CA (1) CA2270226A1 (de)
DE (1) DE947014T1 (de)
IL (1) IL129676A (de)
WO (1) WO1998019355A1 (de)

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Publication number Publication date
AU716318B2 (en) 2000-02-24
KR20000052995A (ko) 2000-08-25
JP4259617B2 (ja) 2009-04-30
EP0947014A1 (de) 1999-10-06
IL129676A (en) 2001-10-31
AU5147898A (en) 1998-05-22
CA2270226A1 (en) 1998-05-07
CN1239593A (zh) 1999-12-22
CN100350655C (zh) 2007-11-21
WO1998019355A1 (en) 1998-05-07
US5733683A (en) 1998-03-31
IL129676A0 (en) 2000-02-29
EP0947014A4 (de) 2005-12-28
JP2001504976A (ja) 2001-04-10

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