DE69914585D1 - Verfahren zur herstellung von fischer-tropsch katalysatoren - Google Patents
Verfahren zur herstellung von fischer-tropsch katalysatorenInfo
- Publication number
- DE69914585D1 DE69914585D1 DE69914585T DE69914585T DE69914585D1 DE 69914585 D1 DE69914585 D1 DE 69914585D1 DE 69914585 T DE69914585 T DE 69914585T DE 69914585 T DE69914585 T DE 69914585T DE 69914585 D1 DE69914585 D1 DE 69914585D1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst support
- production
- fischer tropsch
- acid solution
- tropsch catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 9
- 239000011260 aqueous acid Substances 0.000 abstract 3
- 239000007864 aqueous solution Substances 0.000 abstract 3
- 230000007935 neutral effect Effects 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J33/00—Protection of catalysts, e.g. by coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/0445—Preparation; Activation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ZA981440 | 1998-02-20 | ||
ZA9801440 | 1998-02-20 | ||
ZA9811882 | 1998-12-28 | ||
ZA9811882 | 1998-12-28 | ||
EP99906328.2A EP1058580B2 (de) | 1998-02-20 | 1999-02-19 | Verfahren zur herstellung von fischer-tropsch katalysatoren |
PCT/GB1999/000527 WO1999042214A1 (en) | 1998-02-20 | 1999-02-19 | Process for producing hydrocarbons from a synthesis gas, and catalysts therefor |
Publications (3)
Publication Number | Publication Date |
---|---|
DE69914585D1 true DE69914585D1 (de) | 2004-03-11 |
DE69914585T2 DE69914585T2 (de) | 2004-12-16 |
DE69914585T3 DE69914585T3 (de) | 2019-03-28 |
Family
ID=27144497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69914585.6T Expired - Lifetime DE69914585T3 (de) | 1998-02-20 | 1999-02-19 | Verfahren zur herstellung von fischer-tropsch katalysatoren |
Country Status (20)
Country | Link |
---|---|
US (1) | US6638889B1 (de) |
EP (1) | EP1058580B2 (de) |
JP (1) | JP2002503546A (de) |
KR (1) | KR20010041156A (de) |
CN (1) | CN1291116A (de) |
AT (1) | ATE258826T1 (de) |
AU (1) | AU745771B2 (de) |
BR (1) | BRPI9908011B1 (de) |
CA (1) | CA2320914A1 (de) |
DE (1) | DE69914585T3 (de) |
DZ (1) | DZ2724A1 (de) |
ES (1) | ES2212529T3 (de) |
GB (1) | GB2352194B (de) |
MX (1) | MXPA00007920A (de) |
NO (1) | NO20004147L (de) |
NZ (1) | NZ506373A (de) |
PE (1) | PE20000258A1 (de) |
PL (1) | PL342737A1 (de) |
RU (1) | RU2226127C2 (de) |
WO (1) | WO1999042214A1 (de) |
Families Citing this family (77)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DZ2724A1 (fr) | 1998-02-20 | 2003-09-01 | Sasol Tech Pty Ltd | Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs. |
AU747207B2 (en) | 1998-10-05 | 2002-05-09 | Sasol Technology (Proprietary) Limited | Impregnation process for catalysts |
BR0016078B1 (pt) | 1999-12-01 | 2014-04-01 | Sasol Tech Pty Ltd | Processo para preparar um precursor de catalisador de cobalto de fischer-tropsch. |
FR2821074B1 (fr) * | 2001-02-16 | 2004-06-04 | Inst Francais Du Petrole | Procede de synthese d'hydrocarbures en presence d'un catalyseur comprenant un metal du groupe viii supporte sur silice-alumine |
US6977273B2 (en) | 2000-03-01 | 2005-12-20 | Institut Francais Du Petrole | Process for synthesising hydrocarbons in the presence of a catalyst comprising a group VIII metal supported on silica-alumina |
AU6257801A (en) * | 2000-06-12 | 2001-12-24 | Sasol Tech Pty Ltd | Cobalt catalysts |
WO2002002229A2 (en) | 2000-07-03 | 2002-01-10 | Conoco Inc. | Fischer-tropsch processes and catalysts using aluminum borate supports |
KR20030040374A (ko) * | 2000-07-24 | 2003-05-22 | 사솔 테크날러지 (프로프라이어터리) 리미티드 | 합성기체로부터 탄화수소를 생산하는 방법 |
ES2186547B1 (es) * | 2001-06-15 | 2004-08-01 | Universidad Politecnica De Valencia | Un catalizador bimetalico para el tratamiento de aguas que contienen nitratos. |
JP2003024786A (ja) * | 2001-07-13 | 2003-01-28 | Nippon Oil Corp | フィッシャー・トロプシュ合成用触媒および炭化水素の製造法 |
US7262225B2 (en) * | 2001-07-27 | 2007-08-28 | Sasol Technology (Proprietary) Limited | Production of fischer-tropsch synthesis produced wax |
AR037036A1 (es) | 2001-10-25 | 2004-10-20 | Sasol Tech Pty Ltd | Un proceso para obtener un catalizador fischer-tropsch soportado |
WO2004035193A2 (en) | 2002-10-16 | 2004-04-29 | Conocophillips Company | Fischer-tropsch processes and catalysts made from a material comprising boehmite |
US7071239B2 (en) | 2002-10-16 | 2006-07-04 | Conocophillips Company | Fischer-Tropsch processes and catalysts using stabilized supports |
US7341976B2 (en) | 2002-10-16 | 2008-03-11 | Conocophillips Company | Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using |
EP1551785A4 (de) | 2002-10-16 | 2006-04-05 | Conocophillips Co | Stabilisierter bergangsaluminiumoxidkatalysatorträger als boehmit und daraus hergestellte katalysatoren |
US7276540B2 (en) * | 2002-11-11 | 2007-10-02 | Conocophillips Company | Supports for high surface area catalysts |
JP4870900B2 (ja) * | 2003-02-24 | 2012-02-08 | 戸田工業株式会社 | 炭化水素分解用触媒及びその製造方法、並びに該炭化水素分解用触媒を用いた水素製造方法 |
US7253136B2 (en) * | 2003-04-11 | 2007-08-07 | Exxonmobile Research And Engineering Company | Preparation of titania and cobalt aluminate catalyst supports and their use in Fischer-Tropsch synthesis |
US7163963B2 (en) | 2003-09-08 | 2007-01-16 | Conocophillips Company | Chemically and thermally stabilized alumina for Fischer-Tropsch catalysts |
WO2005046855A2 (en) | 2003-10-16 | 2005-05-26 | Conocophillips Company | Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same |
WO2005037745A1 (en) | 2003-10-16 | 2005-04-28 | Conocophillips Company | Silica-alumina catalyst support with bimodal pore distribution, catalysts, methods of making and using same |
US20050119118A1 (en) * | 2003-12-02 | 2005-06-02 | Walsh Troy L. | Water gas shift catalyst for fuel cells application |
BRPI0417133A (pt) * | 2003-12-12 | 2007-03-06 | Syntroleum Corp | composição de catalisador, método para tratar um suporte de catalisador, produto de fischer-tropsch, métodos para reduzir a ocorrência e intensidade de atrito e de desagregação de material-suporte de catalisador |
GB2410449B (en) * | 2004-01-28 | 2008-05-21 | Statoil Asa | Fischer-Tropsch catalysts |
CA2559451C (en) * | 2004-03-12 | 2010-09-14 | Saint-Gobain Ceramics & Plastics, Inc. | Spray dried alumina for catalyst carrier |
US7365040B2 (en) | 2004-04-26 | 2008-04-29 | Sasoltechnology (Proprietary) Limited | Catalysts |
WO2006032907A1 (en) | 2004-09-23 | 2006-03-30 | Statoil Asa | Promoted fischer-tropsch catalysts |
FR2879477A1 (fr) * | 2004-12-17 | 2006-06-23 | Inst Francais Du Petrole | Catalyseur a base de cobalt pour la synthese fischer-tropsch |
FR2879478B1 (fr) * | 2004-12-17 | 2007-10-26 | Inst Francais Du Petrole | Catalyseur a base de cobalt pour la synthese fisher-tropsch |
BRPI0512669B1 (pt) * | 2005-01-11 | 2015-11-24 | Basf Nederland B V | processos para a produção de um catalisador fisher-tropsch suportado |
ITMI20051410A1 (it) | 2005-07-22 | 2007-01-23 | Eni Spa | Procedimento per la preparazione di catalizzatori di fischer-tropsch ad alta stabilita' meccanica, termica e chimica |
BRPI0710913B1 (pt) * | 2006-04-27 | 2016-12-06 | Univ Wyoming | processo e catalisador para a produção de alcoóis misturados a partir de gases de síntese |
US8969236B2 (en) | 2006-04-27 | 2015-03-03 | University Of Wyoming Research Corporation | Process and catalyst for production of mixed alcohols from synthesis gas |
US8158257B2 (en) * | 2006-10-06 | 2012-04-17 | W. R. Grace & Co.-Conn. | Sulfur tolerant alumina catalyst support |
WO2008045175A1 (en) * | 2006-10-06 | 2008-04-17 | W.R. Grace & Co. - Conn. | Sulfur tolerant alumina catalyst support |
WO2008087147A1 (en) * | 2007-01-18 | 2008-07-24 | Shell Internationale Research Maatschappij B.V. | Fischer-tropsch catalyst support and catalyst |
US20080260631A1 (en) | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
CN101688123B (zh) | 2007-05-04 | 2013-02-27 | 沙索技术有限公司 | 催化剂 |
US8809215B2 (en) | 2007-05-11 | 2014-08-19 | Sasol Technology (Proprietary) Limited | Catalysts |
US20090098032A1 (en) * | 2007-10-11 | 2009-04-16 | Basf Catalysts Llc | Methods of making aluminosilicate coated alumina |
AU2009237307B2 (en) | 2008-04-15 | 2013-04-18 | Sasol Technology (Proprietary) Limited | Catalysts |
DE102008025307A1 (de) * | 2008-05-27 | 2009-12-03 | Süd-Chemie AG | Kobalt-Fischer-Tropsch-Katalysator |
US20100160464A1 (en) * | 2008-12-24 | 2010-06-24 | Chevron U.S.A. Inc. | Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst |
US8268745B2 (en) | 2009-01-08 | 2012-09-18 | China Petroleum & Chemical Corporation | Silicate-resistant desulfurization sorbent |
BRPI1011142B1 (pt) | 2009-06-03 | 2018-04-17 | Sasol Technology Proprietary | Processo para manipular um catalisador ativo, e, instalação para produzir e manipular um catalisador ativo |
GB2473071B (en) | 2009-09-01 | 2013-09-11 | Gtl F1 Ag | Fischer-tropsch catalysts |
CN102639230A (zh) | 2009-10-08 | 2012-08-15 | 格雷斯公司 | 耐硫的氧化铝催化剂载体 |
US8975304B2 (en) | 2009-10-13 | 2015-03-10 | Sasol Technology (Proprietary) Limited | Production of hydrocarbons |
GB2475492B (en) | 2009-11-18 | 2014-12-31 | Gtl F1 Ag | Fischer-Tropsch synthesis |
US7943674B1 (en) | 2009-11-20 | 2011-05-17 | Chevron U.S.A. Inc. | Zeolite supported cobalt hybrid fischer-tropsch catalyst |
GB201000993D0 (en) | 2010-01-22 | 2010-03-10 | Johnson Matthey Plc | Catalyst support |
GB2482171B (en) * | 2010-07-22 | 2018-04-11 | Gtl F1 Ag | Catalyst treatment |
WO2012020210A2 (en) | 2010-08-09 | 2012-02-16 | Gtl.F1 Ag | Fischer-tropsch catalysts |
CN102441393B (zh) * | 2010-10-12 | 2016-01-13 | 中国石油化工股份有限公司 | 一种以改性氧化铝为载体的费托合成催化剂及其应用 |
US8445550B2 (en) | 2010-11-23 | 2013-05-21 | Chevron U.S.A. Inc. | Ruthenium hybrid fischer-tropsch catalyst, and methods for preparation and use thereof |
UA108780C2 (ru) | 2011-02-09 | 2015-06-10 | Сасол Текнолоджі (Пропріетарі) Лімітед | Катализаторы |
UA109198C2 (ru) | 2011-04-28 | 2015-07-27 | Сасол Текнолоджі (Пропріетарі) Лімітед | Катализаторы |
UA113520C2 (xx) | 2011-06-07 | 2017-02-10 | Спосіб одержання щонайменше одного продукту зі щонайменше одного газоподібного реагенту в суспензійному шарі | |
WO2012168830A1 (en) | 2011-06-07 | 2012-12-13 | Sasol Technology (Proprietary) Limited | Process for producing at least one product from at least one gaseous reactant in a slurry bed |
CN102989452B (zh) * | 2011-09-09 | 2014-10-15 | 中国石油天然气股份有限公司 | 一种含复合载体的碳二前加氢催化剂及其制备方法 |
US9309166B2 (en) | 2011-12-14 | 2016-04-12 | Sasol Technology (Proprietary) Limited | Catalysts |
EP2797685A2 (de) | 2011-12-28 | 2014-11-05 | Furanix Technologies B.V | Verfahren zur durchführung einer reaktion mit einem flüssigen reaktionsgemisch |
AU2013298173B2 (en) | 2012-08-02 | 2016-11-24 | Sasol Technology (Proprietary) Limited | Catalysts |
GB201214122D0 (en) * | 2012-08-07 | 2012-09-19 | Oxford Catalysts Ltd | Treating of catalyst support |
WO2015104056A1 (en) | 2014-01-09 | 2015-07-16 | Statoil Petroleum As | Catalyst support and catalyst for fischer-tropsch synthesis |
CN103920496B (zh) * | 2014-04-22 | 2015-11-18 | 武汉凯迪工程技术研究总院有限公司 | 介孔材料包覆式钴基费托合成催化剂及其制备方法 |
US9233360B1 (en) | 2014-09-10 | 2016-01-12 | Chevron U.S.A. Inc. | Stable support for Fischer-Tropsch catalyst |
EP3344725A1 (de) * | 2015-09-04 | 2018-07-11 | Clariant Corporation | Katalysatorträgermaterialien und katalysatormaterialien für fischer-tropsch-verfahren |
CN106588526B (zh) * | 2015-10-20 | 2019-07-23 | 中国石油化工股份有限公司 | 一种以煤和炼厂干气为原料制烯烃的系统以及制烯烃的方法 |
CN105289613B (zh) * | 2015-11-04 | 2017-12-19 | 中国科学院山西煤炭化学研究所 | 氧化铝负载钴费托合成催化剂及制法和应用 |
JP6741694B2 (ja) * | 2016-01-29 | 2020-08-19 | Eneos株式会社 | フィッシャー・トロプシュ合成用触媒、フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法 |
US9975099B2 (en) | 2016-03-16 | 2018-05-22 | Kabushiki Kaisha Toshiba | Fuel synthesis catalyst and fuel synthesis system |
EA201892824A1 (ru) | 2016-08-11 | 2019-07-31 | Сасол Соутх Африка Лимитед | Кобальтосодержащая каталитическая композиция |
EP3351300A1 (de) * | 2017-01-20 | 2018-07-25 | SASOL Germany GmbH | Manganoxidhaltige aluminiumzusammensetzung, verfahren zur herstellung davon und verwendung davon |
FR3064498B1 (fr) * | 2017-03-30 | 2021-10-29 | Ifp Energies Now | Procede de preparation de catalyseurs a base de cobalt |
CN109304174B (zh) * | 2017-07-26 | 2021-08-10 | 国家能源投资集团有限责任公司 | 制备费托合成钴基催化剂的方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1200540A (en) * | 1983-10-24 | 1986-02-11 | Atomic Energy Of Canada Limited - Energie Atomique Du Canada, Limitee | Method of manufacturing a crystalline silica/platinum catalyst structure |
US4708945A (en) * | 1985-12-31 | 1987-11-24 | Exxon Research And Engineering Company | Catalysts comprising silica supported on a boehmite-like surface, their preparation and use |
US5169821A (en) * | 1991-11-14 | 1992-12-08 | Exxon Research And Engineering Company | Method for stabilizing titania supported cobalt catalyst and the catalyst for use in Fischer-Tropsch process |
EP0586196A1 (de) * | 1992-09-01 | 1994-03-09 | JOSEPH CROSFIELD & SONS LTD. | Siliziummodifizierter Hydrierungskatalysator |
US5424262A (en) * | 1994-02-25 | 1995-06-13 | Energy, Mines And Resources Canada | Fluidized cracking catalyst with in situ metal traps |
US5639798A (en) * | 1994-12-15 | 1997-06-17 | Wexford P.A. Syncrude Limited Partnership | Process and catalyst for production of hydrocarbons |
DZ2013A1 (fr) * | 1995-04-07 | 2002-10-23 | Sastech Ltd | Catalyseurs. |
AU7484796A (en) * | 1995-11-27 | 1997-06-19 | W.R. Grace & Co.-Conn. | Organically modified inorganic oxides using silane-modified inorganic oxides |
DE19641141A1 (de) | 1996-10-05 | 1998-04-16 | Rwe Dea Ag | Verfahren zur Herstellung von dispergierbaren Alumosilikaten |
DZ2724A1 (fr) | 1998-02-20 | 2003-09-01 | Sasol Tech Pty Ltd | Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs. |
-
1999
- 1999-02-16 DZ DZ990025A patent/DZ2724A1/xx active
- 1999-02-19 KR KR1020007009206A patent/KR20010041156A/ko not_active Application Discontinuation
- 1999-02-19 JP JP2000532213A patent/JP2002503546A/ja active Pending
- 1999-02-19 CN CN99803102A patent/CN1291116A/zh active Pending
- 1999-02-19 ES ES99906328T patent/ES2212529T3/es not_active Expired - Lifetime
- 1999-02-19 PL PL99342737A patent/PL342737A1/xx unknown
- 1999-02-19 PE PE1999000149A patent/PE20000258A1/es not_active Application Discontinuation
- 1999-02-19 BR BRPI9908011-7A patent/BRPI9908011B1/pt not_active IP Right Cessation
- 1999-02-19 DE DE69914585.6T patent/DE69914585T3/de not_active Expired - Lifetime
- 1999-02-19 EP EP99906328.2A patent/EP1058580B2/de not_active Expired - Lifetime
- 1999-02-19 NZ NZ506373A patent/NZ506373A/xx not_active Application Discontinuation
- 1999-02-19 AT AT99906328T patent/ATE258826T1/de not_active IP Right Cessation
- 1999-02-19 GB GB0019749A patent/GB2352194B/en not_active Expired - Fee Related
- 1999-02-19 RU RU2000124068/04A patent/RU2226127C2/ru active
- 1999-02-19 WO PCT/GB1999/000527 patent/WO1999042214A1/en not_active Application Discontinuation
- 1999-02-19 CA CA002320914A patent/CA2320914A1/en not_active Abandoned
- 1999-02-19 AU AU26302/99A patent/AU745771B2/en not_active Expired
-
2000
- 2000-08-11 US US09/636,787 patent/US6638889B1/en not_active Expired - Lifetime
- 2000-08-14 MX MXPA00007920 patent/MXPA00007920A/es unknown
- 2000-08-18 NO NO20004147A patent/NO20004147L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
PE20000258A1 (es) | 2000-04-18 |
WO1999042214A1 (en) | 1999-08-26 |
ES2212529T3 (es) | 2004-07-16 |
BR9908011A (pt) | 2000-10-31 |
MXPA00007920A (es) | 2001-06-01 |
RU2226127C2 (ru) | 2004-03-27 |
EP1058580B1 (de) | 2004-02-04 |
BRPI9908011B1 (pt) | 2015-03-31 |
EP1058580A1 (de) | 2000-12-13 |
DE69914585T2 (de) | 2004-12-16 |
NO20004147L (no) | 2000-10-19 |
CA2320914A1 (en) | 1999-08-26 |
NO20004147D0 (no) | 2000-08-18 |
PL342737A1 (en) | 2001-07-02 |
US6638889B1 (en) | 2003-10-28 |
EP1058580B2 (de) | 2019-02-06 |
GB0019749D0 (en) | 2000-09-27 |
DZ2724A1 (fr) | 2003-09-01 |
KR20010041156A (ko) | 2001-05-15 |
JP2002503546A (ja) | 2002-02-05 |
CN1291116A (zh) | 2001-04-11 |
GB2352194B (en) | 2001-06-20 |
ATE258826T1 (de) | 2004-02-15 |
NZ506373A (en) | 2003-06-30 |
GB2352194A (en) | 2001-01-24 |
AU2630299A (en) | 1999-09-06 |
DE69914585T3 (de) | 2019-03-28 |
AU745771B2 (en) | 2002-03-28 |
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