DE69834182T2 - Flüssigkristalline polyesterzusammensetzungen enthaltend russ - Google Patents
Flüssigkristalline polyesterzusammensetzungen enthaltend russ Download PDFInfo
- Publication number
- DE69834182T2 DE69834182T2 DE69834182T DE69834182T DE69834182T2 DE 69834182 T2 DE69834182 T2 DE 69834182T2 DE 69834182 T DE69834182 T DE 69834182T DE 69834182 T DE69834182 T DE 69834182T DE 69834182 T2 DE69834182 T2 DE 69834182T2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- residues
- mole percent
- liquid crystalline
- glass fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 97
- 229920000728 polyester Polymers 0.000 title claims description 90
- 239000007788 liquid Substances 0.000 title claims description 60
- 238000012360 testing method Methods 0.000 claims description 70
- 239000003365 glass fiber Substances 0.000 claims description 69
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 55
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 49
- 238000000465 moulding Methods 0.000 claims description 47
- 239000006229 carbon black Substances 0.000 claims description 46
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 31
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims description 30
- 125000005274 4-hydroxybenzoic acid group Chemical group 0.000 claims description 19
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 17
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 claims description 16
- 125000003118 aryl group Chemical group 0.000 claims description 14
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 239000004973 liquid crystal related substance Substances 0.000 claims description 11
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 5
- XBNGYFFABRKICK-UHFFFAOYSA-N 2,3,4,5,6-pentafluorophenol Chemical compound OC1=C(F)C(F)=C(F)C(F)=C1F XBNGYFFABRKICK-UHFFFAOYSA-N 0.000 claims description 4
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachloro-phenol Natural products OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 claims description 4
- 235000019241 carbon black Nutrition 0.000 description 41
- 229920000106 Liquid crystal polymer Polymers 0.000 description 33
- 230000000052 comparative effect Effects 0.000 description 27
- 238000000034 method Methods 0.000 description 17
- 239000004071 soot Substances 0.000 description 14
- 238000001746 injection moulding Methods 0.000 description 10
- AKOGNYJNGMLDOA-UHFFFAOYSA-N (4-acetyloxyphenyl) acetate Chemical compound CC(=O)OC1=CC=C(OC(C)=O)C=C1 AKOGNYJNGMLDOA-UHFFFAOYSA-N 0.000 description 9
- GDBUZIKSJGRBJP-UHFFFAOYSA-N 4-acetoxy benzoic acid Chemical compound CC(=O)OC1=CC=C(C(O)=O)C=C1 GDBUZIKSJGRBJP-UHFFFAOYSA-N 0.000 description 9
- 239000003063 flame retardant Substances 0.000 description 9
- -1 polyethylene Polymers 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000008188 pellet Substances 0.000 description 5
- 239000011342 resin composition Substances 0.000 description 5
- 239000007790 solid phase Substances 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000010933 acylation Effects 0.000 description 3
- 238000005917 acylation reaction Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 229920006038 crystalline resin Polymers 0.000 description 3
- 150000002009 diols Chemical group 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012778 molding material Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical compound C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- MNPYETDBTVUTDQ-UHFFFAOYSA-N 4-propanoyloxybenzoic acid Chemical compound CCC(=O)OC1=CC=C(C(O)=O)C=C1 MNPYETDBTVUTDQ-UHFFFAOYSA-N 0.000 description 1
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- OKKJLVBELUTLKV-MZCSYVLQSA-N Deuterated methanol Chemical compound [2H]OC([2H])([2H])[2H] OKKJLVBELUTLKV-MZCSYVLQSA-N 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- HPGJOUYGWKFYQW-UHFFFAOYSA-N diphenyl benzene-1,4-dicarboxylate Chemical compound C=1C=C(C(=O)OC=2C=CC=CC=2)C=CC=1C(=O)OC1=CC=CC=C1 HPGJOUYGWKFYQW-UHFFFAOYSA-N 0.000 description 1
- DOFDKNLHJKJCMO-UHFFFAOYSA-N diphenyl naphthalene-2,6-dicarboxylate Chemical compound C=1C=C2C=C(C(=O)OC=3C=CC=CC=3)C=CC2=CC=1C(=O)OC1=CC=CC=C1 DOFDKNLHJKJCMO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002934 diuretic Substances 0.000 description 1
- 230000001882 diuretic effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
- C08G63/605—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds the hydroxy and carboxylic groups being bound to aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/0373—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement containing additives, e.g. fillers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Connector Housings Or Holding Contact Members (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52639 | 1979-06-27 | ||
| US4883097P | 1997-06-06 | 1997-06-06 | |
| US48830P | 1997-06-06 | ||
| US09/052,639 US6121369A (en) | 1997-06-06 | 1998-03-31 | Liquid crystalline polyester compositions containing carbon black |
| PCT/US1998/011584 WO1998055547A1 (en) | 1997-06-06 | 1998-06-05 | Liquid crystalline polyester compositions containing carbon black |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69834182D1 DE69834182D1 (de) | 2006-05-24 |
| DE69834182T2 true DE69834182T2 (de) | 2007-03-08 |
Family
ID=26726573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69834182T Expired - Fee Related DE69834182T2 (de) | 1997-06-06 | 1998-06-05 | Flüssigkristalline polyesterzusammensetzungen enthaltend russ |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6121369A (enExample) |
| EP (1) | EP0986613B1 (enExample) |
| JP (1) | JP2002514261A (enExample) |
| CN (1) | CN1165580C (enExample) |
| BR (1) | BR9809943A (enExample) |
| DE (1) | DE69834182T2 (enExample) |
| WO (1) | WO1998055547A1 (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6348163B1 (en) | 1998-09-18 | 2002-02-19 | Eastman Chemical Company | Liquid crystalline polyesters compositions containing aromatic phosphonites and a process for the preparation thereof |
| EP1312631A3 (en) * | 1998-09-18 | 2003-06-25 | Eastman Chemical Company | Liquid crystalline polyesters having a surprisingly good combination of a low melting point, a high heat distortion temperature, a low melt viscosity, and a high tensile elongation |
| US5969083A (en) * | 1998-09-18 | 1999-10-19 | Eastman Chemical Company | Liquid crystalline polyesters having a surprisingly good combination of a low melting point, a high heat distortion temperature, a low melt viscosity, and a high tensile elongation |
| JP4118425B2 (ja) * | 1998-12-18 | 2008-07-16 | ポリプラスチックス株式会社 | コネクター用液晶性ポリマー組成物およびコネクター |
| TW491879B (en) * | 1999-05-13 | 2002-06-21 | Sumitomo Chemical Co | Liquid crystal polyester resin composition and molded article |
| TWI230178B (en) * | 1999-05-13 | 2005-04-01 | Sumitomo Chemical Co | Liquid crystal polyester resin composition and molded article thereof |
| CA2393259A1 (en) * | 2000-01-13 | 2001-07-19 | E.I. Du Pont De Nemours And Company | Liquid crystalline polymer compositions containing small particle size fillers |
| US6890988B2 (en) * | 2002-02-27 | 2005-05-10 | Sumitomo Chemical Company, Limited | Aromatic polyester |
| JP2004051867A (ja) * | 2002-07-23 | 2004-02-19 | Sumitomo Chem Co Ltd | 芳香族液晶ポリエステルフィルムおよびその金属積層体 |
| JP2004157272A (ja) * | 2002-11-06 | 2004-06-03 | Sharp Corp | マスターバッチ及び電子写真用トナー |
| TWI359159B (en) * | 2003-11-05 | 2012-03-01 | Sumitomo Chemical Co | Aromatic liquid-crystalline polyester |
| WO2005099984A1 (ja) * | 2004-04-15 | 2005-10-27 | Polyplastics Co., Ltd. | 繊維状充填剤の長さが制御された樹脂組成物ペレットの製造方法 |
| JP4758079B2 (ja) * | 2004-07-14 | 2011-08-24 | 上野製薬株式会社 | 液晶ポリエステル樹脂およびその製造方法 |
| JP2006045298A (ja) * | 2004-08-03 | 2006-02-16 | Ntn Corp | 液晶ポリエステル樹脂組成物 |
| DE602006004859D1 (de) * | 2005-04-19 | 2009-03-05 | Du Pont | Flüssigkristallines polymer enthaltende zusammensetzung |
| US20080153959A1 (en) * | 2006-12-20 | 2008-06-26 | General Electric Company | Thermally Conducting and Electrically Insulating Moldable Compositions and Methods of Manufacture Thereof |
| CN101981123B (zh) * | 2008-03-28 | 2012-11-21 | 吉坤日矿日石能源株式会社 | 照相机模块用液晶聚酯树脂组合物 |
| JP5325442B2 (ja) * | 2008-03-28 | 2013-10-23 | Ｊｘ日鉱日石エネルギー株式会社 | カメラモジュール用液晶ポリエステル樹脂組成物 |
| TW201030087A (en) * | 2008-10-30 | 2010-08-16 | Solvay Advanced Polymers Llc | Power LED device with a reflector made of aromatic polyester and/or wholly aromatic polyester |
| CN101768448B (zh) * | 2008-12-30 | 2013-06-12 | 上海普利特化工新材料有限公司 | 一种含炭黑的液晶高分子复合物及其制备方法 |
| US9056950B2 (en) | 2010-07-23 | 2015-06-16 | Ticona Gmbh | Composite polymeric articles formed from extruded sheets containing a liquid crystal polymer |
| WO2012131829A1 (ja) * | 2011-03-25 | 2012-10-04 | 東レ株式会社 | 熱可塑性樹脂組成物およびそれを用いた成形品 |
| US9284435B2 (en) | 2012-10-16 | 2016-03-15 | Ticona Llc | Antistatic liquid crystalline polymer composition |
| WO2014074227A1 (en) | 2012-11-09 | 2014-05-15 | Ticona Llc | Liquid crystalline polymer composition for films |
| EP2935515B1 (en) | 2012-12-19 | 2020-04-15 | Ticona LLC | Liquid crystalline composition having a dark black color |
| CN103194080A (zh) * | 2013-04-27 | 2013-07-10 | 苏州正豪塑胶电子有限公司 | 一种耐腐蚀插接件 |
| WO2015094486A1 (en) | 2013-12-19 | 2015-06-25 | Ticona Llc | Liquid crystalline composition having a pearly luster |
| CN103819927B (zh) * | 2014-03-12 | 2016-04-20 | 华东理工大学 | 一种浅色抗静电液晶高分子复合材料及其制备方法 |
| CN108276741A (zh) * | 2017-12-26 | 2018-07-13 | 上海普利特化工新材料有限公司 | 一种耐高温高流动高刚性绝缘液晶聚酯复合材料的制备方法 |
| US11637365B2 (en) | 2019-08-21 | 2023-04-25 | Ticona Llc | Polymer composition for use in an antenna system |
| US11258184B2 (en) | 2019-08-21 | 2022-02-22 | Ticona Llc | Antenna system including a polymer composition having a low dissipation factor |
| US11912817B2 (en) | 2019-09-10 | 2024-02-27 | Ticona Llc | Polymer composition for laser direct structuring |
| US12209164B2 (en) | 2019-09-10 | 2025-01-28 | Ticona Llc | Polymer composition and film for use in 5G applications |
| US11555113B2 (en) | 2019-09-10 | 2023-01-17 | Ticona Llc | Liquid crystalline polymer composition |
| US12294185B2 (en) | 2019-09-10 | 2025-05-06 | Ticona Llc | Electrical connector formed from a polymer composition having a low dielectric constant and dissipation factor |
| US12142820B2 (en) | 2019-09-10 | 2024-11-12 | Ticona Llc | 5G system containing a polymer composition |
| US11646760B2 (en) | 2019-09-23 | 2023-05-09 | Ticona Llc | RF filter for use at 5G frequencies |
| US11917753B2 (en) | 2019-09-23 | 2024-02-27 | Ticona Llc | Circuit board for use at 5G frequencies |
| US11721888B2 (en) | 2019-11-11 | 2023-08-08 | Ticona Llc | Antenna cover including a polymer composition having a low dielectric constant and dissipation factor |
| US12104010B2 (en) | 2021-02-04 | 2024-10-01 | Ticona Llc | Polymer composition for an electric circuit protection device |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4169933A (en) * | 1977-08-08 | 1979-10-02 | Eastman Kodak Company | Liquid crystal copolyesters containing terephthalic acid and 2,6-naphthalenedicarboxylic acid |
| US5124397A (en) * | 1990-04-19 | 1992-06-23 | Nippon Petrochemicals Company, Limited | Resin composition for sliding movement and sealing member comprising same |
| US5110896A (en) * | 1990-12-10 | 1992-05-05 | E. I. Du Pont De Nemours And Company | Thermotropic liquid crystalline polyester compositions |
| JPH05311049A (ja) * | 1992-04-30 | 1993-11-22 | Unitika Ltd | 液晶ポリエステル樹脂組成物 |
| JP3057913B2 (ja) * | 1992-06-11 | 2000-07-04 | 日本電気株式会社 | 所在地表示機能付き電話装置 |
| JP3362489B2 (ja) * | 1993-12-28 | 2003-01-07 | 東レ株式会社 | 液晶性樹脂組成物および成形品 |
| JP2889121B2 (ja) * | 1994-06-30 | 1999-05-10 | 帝人株式会社 | 防炎性黒原着ポリエステル繊維 |
| DE69512256T2 (de) * | 1994-08-31 | 2000-05-11 | E.I. Du Pont De Nemours And Co., Wilmington | Flüssigkristalline harzzusammensetzung |
| JPH08220407A (ja) * | 1995-02-17 | 1996-08-30 | Toray Ind Inc | 光ピックアップレンズホルダー |
-
1998
- 1998-03-31 US US09/052,639 patent/US6121369A/en not_active Expired - Lifetime
- 1998-06-05 WO PCT/US1998/011584 patent/WO1998055547A1/en not_active Ceased
- 1998-06-05 CN CNB988079623A patent/CN1165580C/zh not_active Expired - Lifetime
- 1998-06-05 DE DE69834182T patent/DE69834182T2/de not_active Expired - Fee Related
- 1998-06-05 BR BR9809943-4A patent/BR9809943A/pt not_active Application Discontinuation
- 1998-06-05 JP JP50288799A patent/JP2002514261A/ja not_active Ceased
- 1998-06-05 EP EP98926315A patent/EP0986613B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6121369A (en) | 2000-09-19 |
| BR9809943A (pt) | 2000-08-01 |
| EP0986613B1 (en) | 2006-04-12 |
| CN1265696A (zh) | 2000-09-06 |
| CN1165580C (zh) | 2004-09-08 |
| JP2002514261A (ja) | 2002-05-14 |
| EP0986613A1 (en) | 2000-03-22 |
| DE69834182D1 (de) | 2006-05-24 |
| WO1998055547A1 (en) | 1998-12-10 |
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| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |