DE69801837D1 - Nanokomposite mit aktivierten grenzflächen hergestellt durch mechanische zermahlung von magnesiumhydriden und deren verwendung zur wasserstoffspeicherung - Google Patents

Nanokomposite mit aktivierten grenzflächen hergestellt durch mechanische zermahlung von magnesiumhydriden und deren verwendung zur wasserstoffspeicherung

Info

Publication number
DE69801837D1
DE69801837D1 DE69801837T DE69801837T DE69801837D1 DE 69801837 D1 DE69801837 D1 DE 69801837D1 DE 69801837 T DE69801837 T DE 69801837T DE 69801837 T DE69801837 T DE 69801837T DE 69801837 D1 DE69801837 D1 DE 69801837D1
Authority
DE
Germany
Prior art keywords
nanocomposites
hydrogen storage
mechanical grinding
interface areas
activated interface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69801837T
Other languages
English (en)
Other versions
DE69801837T2 (de
Inventor
Robert Schulz
Guoxiang Liang
Guy Lalande
Jacques Huot
Sabin Boily
Neste Andre Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hydro Quebec
Original Assignee
Hydro Quebec
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hydro Quebec filed Critical Hydro Quebec
Application granted granted Critical
Publication of DE69801837D1 publication Critical patent/DE69801837D1/de
Publication of DE69801837T2 publication Critical patent/DE69801837T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/02—Making metallic powder or suspensions thereof using physical processes
    • B22F9/023—Hydrogen absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/02—Making metallic powder or suspensions thereof using physical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • C01B3/0047—Intermetallic compounds; Metal alloys; Treatment thereof containing a rare earth metal; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0078—Composite solid storage mediums, i.e. coherent or loose mixtures of different solid constituents, chemically or structurally heterogeneous solid masses, coated solids or solids having a chemically modified surface region
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/383—Hydrogen absorbing alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029—Heat exchange using liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/065—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by dissolution of metals or alloys; by dehydriding metallic substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/34—Gastight accumulators
    • H01M10/345—Gastight metal hydride accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Powder Metallurgy (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
DE69801837T 1997-10-22 1998-10-21 Nanokomposite mit aktivierten grenzflächen hergestellt durch mechanische zermahlung von magnesiumhydriden und deren verwendung zur wasserstoffspeicherung Expired - Fee Related DE69801837T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA002217095A CA2217095A1 (fr) 1997-10-22 1997-10-22 Nanocomposites a interfaces activees prepares par broyage mecanique d'hydrures de magnesium et usage de ceux-ci pour le stockage d'hydrogene
PCT/CA1998/000987 WO1999020422A1 (fr) 1997-10-22 1998-10-21 Nanocomposites a interfaces activees prepares par broyage mecanique d'hydrures de magnesium et usage de ceux-ci pour le stockage d'hydrogene

Publications (2)

Publication Number Publication Date
DE69801837D1 true DE69801837D1 (de) 2001-10-31
DE69801837T2 DE69801837T2 (de) 2002-06-13

Family

ID=4161556

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69801837T Expired - Fee Related DE69801837T2 (de) 1997-10-22 1998-10-21 Nanokomposite mit aktivierten grenzflächen hergestellt durch mechanische zermahlung von magnesiumhydriden und deren verwendung zur wasserstoffspeicherung

Country Status (10)

Country Link
US (1) US7201789B1 (de)
EP (1) EP1024918B1 (de)
JP (1) JP2001520316A (de)
KR (1) KR100567426B1 (de)
CN (1) CN1223423C (de)
AU (1) AU9617098A (de)
BR (1) BR9812984A (de)
CA (1) CA2217095A1 (de)
DE (1) DE69801837T2 (de)
WO (1) WO1999020422A1 (de)

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SG106032A1 (en) * 1998-10-02 2004-09-30 Univ Singapore Method for the production of ultrafine particles and nanocomposites
US6328821B1 (en) * 1999-11-22 2001-12-11 Energy Conversion Devices, Inc. Modified magnesium based hydrogen storage alloys
CA2301252A1 (en) * 2000-03-17 2001-09-17 Hydro-Quebec Method for producing gaseous hydrogen by chemical reaction of metals or metal hydrides subjected to intense mechanical deformations
JP4717257B2 (ja) * 2000-05-31 2011-07-06 本田技研工業株式会社 水素吸蔵合金粉末および車載用水素貯蔵タンク
WO2004036664A2 (en) 2002-10-21 2004-04-29 Koninklijke Philips Electronics N.V. Hydrogen storage material with high storage capacity
DE10337970B4 (de) * 2003-08-19 2009-04-23 Gkss-Forschungszentrum Geesthacht Gmbh Metallhaltiger, wasserstoffspeichernder Werkstoff und Verfahren zu seiner Herstellung
DE10339198B4 (de) * 2003-08-22 2009-04-23 Gkss-Forschungszentrum Geesthacht Gmbh Metallhaltiger, wasserstoffspeichernder Werkstoff und Verfahren zu seiner Herstellung
JP4691649B2 (ja) * 2004-10-29 2011-06-01 国立大学法人大阪大学 水素貯蔵材料
DE102005003623A1 (de) * 2005-01-26 2006-07-27 Studiengesellschaft Kohle Mbh Verfahren zur reversiblen Speicherung von Wasserstoff
JP4986101B2 (ja) * 2005-01-27 2012-07-25 太平洋セメント株式会社 水素貯蔵材料およびその製造方法
FR2881731B1 (fr) 2005-02-07 2009-02-20 Inst Francais Du Petrole Nouveaux materiaux pour le stockage de l'hydrogene comprenant un systeme equilibre entre un alliage de magnesium et de palladium et l'hydrure correspondant
JP2008538798A (ja) * 2005-04-25 2008-11-06 コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ 水素吸蔵材料およびそのような材料を調製する方法
DE102005019108B4 (de) * 2005-04-25 2008-11-06 Gkss-Forschungszentrum Geesthacht Gmbh Verwendung von Diamantpulver zur Herstellung von Metallhydriden
JP2009525940A (ja) * 2006-02-08 2009-07-16 ロス アラモス ナショナル セキュリティ，リミテッド ライアビリテイ カンパニー 水素を貯蔵し、放出させるための組成物及び方法
FR2900401B1 (fr) * 2006-04-26 2008-07-18 Centre Nat Rech Scient Composite nanocristallin pour le stockage de l'hydrogene
WO2008026333A1 (fr) * 2006-09-01 2008-03-06 National Institute Of Advanced Industrial Science And Technology Alliage de magnésium ignifuge à haute résistance
KR100811116B1 (ko) * 2006-11-14 2008-03-06 한국과학기술연구원 마그네슘계 수소저장재료의 제조방법
JP2008239367A (ja) * 2007-03-26 2008-10-09 Taiheiyo Cement Corp 水素貯蔵材料の製造方法
CN101293630B (zh) * 2007-04-24 2011-06-08 北京有色金属研究总院 一种纳米催化复合氮化物储氢材料及其制备方法
JP4462301B2 (ja) * 2007-07-27 2010-05-12 トヨタ自動車株式会社 水素吸蔵材料の製造方法
DE102007054843B4 (de) * 2007-11-16 2012-04-12 Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH Wasserstoff speichernde Kompositmaterialien
KR101062476B1 (ko) 2009-10-28 2011-09-06 한국기계연구원 마그네슘계 수소발생용 분말 및 이의 제조방법
JP5206758B2 (ja) * 2010-07-15 2013-06-12 トヨタ自動車株式会社 負極材料、金属二次電池、および負極材料の製造方法
CN103003988A (zh) * 2010-07-15 2013-03-27 丰田自动车株式会社 负极材料的制造方法、负极材料、锂二次电池的制造方法、锂二次电池
CN102593437B (zh) * 2012-02-29 2014-08-06 上海交通大学 一次性镍氢电池负极材料、负极片、电池及其制备方法
CN104445070A (zh) * 2014-12-02 2015-03-25 安徽工业大学 一种含镍和稀土金属氢化物纳米粒子的镁基双金属氢化物的制备方法
EP3133614B1 (de) 2015-08-18 2019-11-20 Delta Electronics (Thailand) Public Co., Ltd. Integriertes magnetisches bauteil
RU2675882C2 (ru) * 2016-12-21 2018-12-25 Федеральное государственное бюджетное учреждение науки Институт проблем химической физики Российской академии наук (ИПХФ РАН) Водород-аккумулирующие материалы и способ их получения
CN111252733A (zh) * 2018-11-30 2020-06-09 中国科学院大连化学物理研究所 一种多元金属氢化物的制备方法
CN110155940B (zh) * 2019-04-16 2020-11-03 浙江大学 一种室温吸氢的镁基储氢材料及其制备方法
CN110039042B (zh) * 2019-05-06 2021-04-13 安徽工业大学 一种碳纳米管增强钛镁合金复合材料的制备方法
CN111533086B (zh) * 2020-05-11 2023-12-01 中国科学院长春应用化学研究所 一种利用含氢化合物快速活化储氢合金的短流程制备方法
CN111498801A (zh) * 2020-06-09 2020-08-07 世能氢电科技有限公司 MgH2-Ni-金属氧化物-Ti-Fe复合储氢材料及其制备方法
CN112265957B (zh) * 2020-09-21 2022-07-29 武汉船用电力推进装置研究所（中国船舶重工集团公司第七一二研究所） 一种高储氢密度镁基储氢材料的制备方法
KR102389205B1 (ko) * 2020-11-13 2022-04-21 한국과학기술원 마그네슘 나노시트, 및 이를 포함하는 수소 저장 장치
CN112408328A (zh) * 2020-11-18 2021-02-26 安徽工业大学 一种新型锂离子电池ZrMn基氢化物复合负极材料及制备方法
CN114160784B (zh) * 2021-11-22 2024-08-20 上海大学 一种含有Nd4Mg80Ni8合金与纯Mg的水解制氢复合材料、其制备方法及其应用
CN115367700B (zh) * 2022-08-31 2024-04-05 理工清科(重庆)先进材料研究院有限公司 锌铜双金属MOF催化的MgH2储氢材料、其制备方法和应用

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Also Published As

Publication number Publication date
WO1999020422B1 (fr) 1999-06-03
DE69801837T2 (de) 2002-06-13
KR100567426B1 (ko) 2006-04-04
CA2217095A1 (fr) 1999-04-22
CN1223423C (zh) 2005-10-19
AU9617098A (en) 1999-05-10
KR20010031351A (ko) 2001-04-16
BR9812984A (pt) 2000-08-08
WO1999020422A1 (fr) 1999-04-29
JP2001520316A (ja) 2001-10-30
CN1280527A (zh) 2001-01-17
US7201789B1 (en) 2007-04-10
EP1024918B1 (de) 2001-09-26
EP1024918A1 (de) 2000-08-09

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