DE69737516D1 - Katalysatorzusammensetzung und Verfahren zur Direktoxidation von Propen zu Propenoxid - Google Patents

Katalysatorzusammensetzung und Verfahren zur Direktoxidation von Propen zu Propenoxid

Info

Publication number
DE69737516D1
DE69737516D1 DE69737516T DE69737516T DE69737516D1 DE 69737516 D1 DE69737516 D1 DE 69737516D1 DE 69737516 T DE69737516 T DE 69737516T DE 69737516 T DE69737516 T DE 69737516T DE 69737516 D1 DE69737516 D1 DE 69737516D1
Authority
DE
Germany
Prior art keywords
propene
catalyst composition
direct oxidation
oxide
propene oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69737516T
Other languages
English (en)
Other versions
DE69737516T2 (de
Inventor
Robert G Bowman
Howard W Clark
Alex Kuperman
Garmt R Meima
George E Hartwell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US1997/011414 external-priority patent/WO1998000413A1/en
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Application granted granted Critical
Publication of DE69737516D1 publication Critical patent/DE69737516D1/de
Publication of DE69737516T2 publication Critical patent/DE69737516T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/50Silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69737516T 1997-06-30 1997-12-18 Katalysatorzusammensetzung und Verfahren zur Direktoxidation von Propen zu Propenoxid Expired - Lifetime DE69737516T2 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
WOPCT/US97/14414 1997-06-30
PCT/US1997/011414 WO1998000413A1 (en) 1996-07-01 1997-06-30 Process for the direct oxidation of olefins to olefin oxides
WOPCT/US97/14415 1997-06-30
PCT/US1997/011415 WO1998000414A1 (en) 1996-07-01 1997-06-30 Process for the direct oxidation of olefins to olefin oxides
WOPCT/US97/14417 1997-06-30
PCT/US1997/011417 WO1998000415A1 (en) 1996-07-01 1997-06-30 Process for the direct oxidation of olefins to olefin oxides

Publications (2)

Publication Number Publication Date
DE69737516D1 true DE69737516D1 (de) 2007-05-03
DE69737516T2 DE69737516T2 (de) 2007-11-29

Family

ID=27378304

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69737516T Expired - Lifetime DE69737516T2 (de) 1997-06-30 1997-12-18 Katalysatorzusammensetzung und Verfahren zur Direktoxidation von Propen zu Propenoxid
DE69734787T Expired - Lifetime DE69734787T2 (de) 1997-06-30 1997-12-18 Verfahren zur herstellung von olefinoxiden durch direktoxidation von olefinen

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69734787T Expired - Lifetime DE69734787T2 (de) 1997-06-30 1997-12-18 Verfahren zur herstellung von olefinoxiden durch direktoxidation von olefinen

Country Status (9)

Country Link
EP (3) EP1479437A1 (de)
JP (1) JP4282096B2 (de)
KR (1) KR100553466B1 (de)
CN (1) CN1116107C (de)
BR (1) BR9714951A (de)
DE (2) DE69737516T2 (de)
ES (2) ES2249807T3 (de)
ID (1) ID23423A (de)
WO (1) WO1999000188A1 (de)

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KR100449422B1 (ko) 1996-07-01 2005-02-23 다우 글로벌 테크놀로지스 인크. 티타노실리케이트상의금을포함하는촉매조성물및이를사용하는올레핀옥사이드의제조방법
DE69911195T2 (de) 1998-04-15 2004-07-15 Dow Global Technologies, Inc., Midland Verfahren zur direktoxidation von olefinen zu olefinoxiden
DE19835481A1 (de) * 1998-08-07 2000-02-17 Bayer Ag Verfahren zur Oxidation von Kohlenwasserstoffen
BR9917025B1 (pt) * 1998-12-16 2010-10-19 processo para preparar um óxido de olefina, composição de catalisador e processo para regenerá-la.
AU4335100A (en) * 1999-04-08 2000-10-23 Dow Chemical Company, The Process for the hydro-oxidation of olefins to olefin oxides using oxidized gold catalyst
WO2000059633A1 (en) * 1999-04-08 2000-10-12 The Dow Chemical Company Method of preparing a catalyst containing gold and titanium
US6821923B1 (en) 1999-04-08 2004-11-23 Dow Global Technologies Inc. Method of preparing a catalyst containing gold and titanium
DE19920753A1 (de) * 1999-04-23 2000-10-26 Bayer Ag Verfahren zur Herstellung von amorphen, edelmetallhaltigen Titan-Silizium-Mischoxiden
EP1086743B1 (de) 1999-09-21 2006-08-16 Nippon Shokubai Co., Ltd. Katalysator für die Herstellung von Epoxiden und Verfahren für die Bereitung derselben und die Herstellung von Epoxiden
AU770334B2 (en) 1999-12-09 2004-02-19 Dow Global Technologies Inc. Activation and regeneration of a hydro-oxidation catalyst
US6534621B2 (en) 2000-05-18 2003-03-18 Dow Global Technologies Inc. Process for manufacturing a hydroxyester derivative intermediate and epoxy resins prepared therefrom
US6509485B2 (en) * 2001-02-22 2003-01-21 Sri International Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts
BR0211796A (pt) 2001-08-01 2004-08-03 Dow Global Technologies Inc Método para aumentar a vida útil de um catalisador de hidro-oxidação
JP4572551B2 (ja) * 2003-03-25 2010-11-04 住友化学株式会社 酸化オレフィンの製造法
JP4917549B2 (ja) 2005-01-14 2012-04-18 ダウ グローバル テクノロジーズ エルエルシー チタノシリケートの再生、及び活性な酸化触媒の再構成
US8357812B2 (en) 2005-12-22 2013-01-22 Shell Oil Company Process for preparing a rejuvenated epoxidation catalyst
US7704908B2 (en) 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
JP5006855B2 (ja) * 2008-09-24 2012-08-22 本田技研工業株式会社 排ガス浄化触媒及びこれを用いた排ガス浄化フィルタ
WO2011145485A1 (en) 2010-05-17 2011-11-24 Sumitomo Chemical Company, Limited Method for producing propylene oxide
WO2011145487A1 (en) 2010-05-17 2011-11-24 Sumitomo Chemical Company, Limited Method for producing olefin oxide
CN104069893B (zh) * 2013-03-27 2016-05-25 中国石油化工股份有限公司 生产环氧乙烷用银催化剂载体、制备方法及其应用
JP6054790B2 (ja) * 2013-03-28 2016-12-27 三菱スペース・ソフトウエア株式会社 遺伝子情報記憶装置、遺伝子情報検索装置、遺伝子情報記憶プログラム、遺伝子情報検索プログラム、遺伝子情報記憶方法、遺伝子情報検索方法及び遺伝子情報検索システム
CN106927483B (zh) * 2015-12-29 2019-09-03 中国石油天然气股份有限公司 一种改性y型分子筛的制备方法
TW202045484A (zh) * 2019-02-08 2020-12-16 德商贏創運營有限公司 有機化合物的氧化
KR20220092567A (ko) * 2019-11-04 2022-07-01 라이온델 케미칼 테크놀로지, 엘.피. 티탄화 촉매, 티탄화 촉매의 제조 방법, 및 에폭시화 방법
CN113912568B (zh) * 2020-07-10 2023-12-29 中国石油化工股份有限公司 可提高极限氧含量的制环氧丙烷的方法
CN113912569B (zh) * 2020-07-10 2024-04-26 中国石油化工股份有限公司 可降低稀释气用量的丙烯直接环氧化的方法
CN113912573B (zh) * 2020-07-10 2023-07-04 中国石油化工股份有限公司 丙烯直接环氧化制备环氧丙烷的方法
US20230339875A1 (en) * 2020-07-10 2023-10-26 China Petroleum & Chemical Corporation Method for preparing propylene oxide by means of direct epoxidation of propylene
CN113912570B (zh) * 2020-07-10 2023-09-29 中国石油化工股份有限公司 以降低稀释气为目的的丙烯直接环氧化反应以制备环氧丙烷的方法
CN114522719A (zh) * 2022-02-18 2022-05-24 广西科学院 钛硅分子筛催化剂制备方法以及应用

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Also Published As

Publication number Publication date
DE69737516T2 (de) 2007-11-29
EP1314473B1 (de) 2007-03-21
EP1314473A3 (de) 2003-07-09
WO1999000188A1 (en) 1999-01-07
KR20010014404A (ko) 2001-02-26
CN1268072A (zh) 2000-09-27
EP1024895B1 (de) 2005-11-30
EP1479437A1 (de) 2004-11-24
DE69734787D1 (de) 2006-01-05
CN1116107C (zh) 2003-07-30
EP1314473A2 (de) 2003-05-28
KR100553466B1 (ko) 2006-02-22
ES2280636T3 (es) 2007-09-16
JP4282096B2 (ja) 2009-06-17
WO1999000188A8 (en) 1999-10-28
ID23423A (id) 2000-04-20
EP1024895A1 (de) 2000-08-09
DE69734787T2 (de) 2006-08-24
JP2002516591A (ja) 2002-06-04
ES2249807T3 (es) 2006-04-01
BR9714951A (pt) 2000-10-17

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