DE69721305T2 - Retroreflektierender gegenstand mit waschfestem bindemittel für kügelchen - Google Patents
Retroreflektierender gegenstand mit waschfestem bindemittel für kügelchen Download PDFInfo
- Publication number
- DE69721305T2 DE69721305T2 DE1997621305 DE69721305T DE69721305T2 DE 69721305 T2 DE69721305 T2 DE 69721305T2 DE 1997621305 DE1997621305 DE 1997621305 DE 69721305 T DE69721305 T DE 69721305T DE 69721305 T2 DE69721305 T2 DE 69721305T2
- Authority
- DE
- Germany
- Prior art keywords
- polyurethane
- segments
- weight
- retroreflective
- hard
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/61—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/71—Monoisocyanates or monoisothiocyanates
- C08G18/718—Monoisocyanates or monoisothiocyanates containing silicon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/913—Material designed to be responsive to temperature, light, moisture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31598—Next to silicon-containing [silicone, cement, etc.] layer
- Y10T428/31601—Quartz or glass
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Polyurethanes Or Polyureas (AREA)
- Optical Elements Other Than Lenses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/777,718 US5976669A (en) | 1996-12-20 | 1996-12-20 | Retroreflective article having launderably durable bead-bond |
| US777718 | 1996-12-20 | ||
| PCT/US1997/023040 WO1998028642A1 (en) | 1996-12-20 | 1997-12-04 | Retroreflective article having launderably durable bead-bond |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69721305D1 DE69721305D1 (de) | 2003-05-28 |
| DE69721305T2 true DE69721305T2 (de) | 2004-02-12 |
Family
ID=25111044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1997621305 Expired - Lifetime DE69721305T2 (de) | 1996-12-20 | 1997-12-04 | Retroreflektierender gegenstand mit waschfestem bindemittel für kügelchen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5976669A (enExample) |
| EP (1) | EP0946889B1 (enExample) |
| JP (1) | JP4344865B2 (enExample) |
| KR (1) | KR100519884B1 (enExample) |
| CN (1) | CN1113252C (enExample) |
| CA (1) | CA2274541C (enExample) |
| DE (1) | DE69721305T2 (enExample) |
| TW (1) | TW386092B (enExample) |
| WO (1) | WO1998028642A1 (enExample) |
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| US6159537A (en) * | 1997-08-01 | 2000-12-12 | 3M Innovative Properties Company | Method of making a retroreflective article that has a binder layer containing an epoxy resin and silicone crosslinked polymer |
| AU1992600A (en) | 1999-01-14 | 2000-08-01 | Reflec Plc | Retroreflective inks |
| GB2347366A (en) * | 1999-03-05 | 2000-09-06 | Reflective Technology Ind Ltd | Reflective tape |
| USD475814S1 (en) | 1999-03-25 | 2003-06-10 | Head Lites Corporation | High visibility, load bearing tactical vest |
| USD440716S1 (en) | 1999-03-25 | 2001-04-17 | Head Lites Corporation | Enhanced visibility safety garment |
| CN1179219C (zh) | 1999-06-17 | 2004-12-08 | 3M创新有限公司 | 带有含逆向反射薄片和与聚合物共价键合的染料的着色层的逆向反射制品 |
| US6361850B1 (en) | 1999-06-17 | 2002-03-26 | 3M Innovative Properties Company | Retroreflective article having a colored layer containing a dye covalently bonded to a polymer |
| FR2803724B1 (fr) * | 2000-01-18 | 2002-04-12 | T 2 S | Materiau complexe retroreflechissant la lumiere et/ou fluorescent |
| US6676754B1 (en) * | 2000-06-30 | 2004-01-13 | 3M Innovative Properties Company | Coating apparatus and methods of applying a polymer coating |
| US6953624B2 (en) * | 2001-03-02 | 2005-10-11 | 3M Innovative Properties Company | Printable film and coating composition exhibiting stain resistance |
| US6723433B2 (en) * | 2001-03-02 | 2004-04-20 | 3M Innovative Properties Company | Printable film and coating composition exhibiting stain resistance |
| ITMO20010126A1 (it) * | 2001-06-21 | 2002-12-21 | Autoadesivi S R L | Tessuto o termoadesivo rinfrangente o retroriflettente |
| US6820280B1 (en) * | 2002-06-18 | 2004-11-23 | Blaver Manufacturing Company, Inc. | Rip-off, high-visibility, safety vest |
| DE10355318A1 (de) * | 2003-11-27 | 2005-06-23 | Wacker-Chemie Gmbh | Verfahren zur Herstellung von organyloxysilylterminierten Polymeren |
| WO2005066667A1 (en) * | 2003-12-30 | 2005-07-21 | 3M Innovative Properties Company | Color shifting retroreflector and method of making same |
| CA2554743A1 (en) * | 2004-01-30 | 2005-08-11 | Kaneka Corporation | Pressure sensitive adhesive composition |
| US9198156B2 (en) * | 2004-08-23 | 2015-11-24 | Telefonaktiebolaget L M Ericsson (Publ) | Paging mobile stations in a hybrid network |
| BRPI0515661A (pt) * | 2004-10-15 | 2008-07-29 | Dow Global Technologies Inc | composição de pré-polìmero terminado por isocianato, composição de poliuretano e sistema bi-componente adequado para uso na manufatura de elastÈmeros de poliuretano |
| US8232362B2 (en) * | 2005-09-15 | 2012-07-31 | Momentive Performance Materials Inc. | Preparation of amino-silane terminated polymer by using organic bismuth catalyst and cured polymer therefrom by using non-tin catalyst |
| US9248470B2 (en) | 2006-07-31 | 2016-02-02 | Safe Reflections, Inc. | Colorized retroreflective material and method |
| DE102006055739A1 (de) * | 2006-11-25 | 2008-05-29 | Bayer Materialscience Ag | Abformmassen |
| US8292539B2 (en) * | 2007-04-10 | 2012-10-23 | Stoncor Group, Inc. | Agglomerated retroreflective beads for highway marking and methods for fabrication and use thereof |
| US9207373B2 (en) | 2007-04-10 | 2015-12-08 | Stoncor Group, Inc. | Methods for fabrication and highway marking usage of agglomerated retroreflective beads |
| USD588752S1 (en) | 2007-12-21 | 2009-03-17 | Advanced Tactical Fabrication, Inc. | Enhanced visibility safety garment |
| USD590545S1 (en) | 2007-12-21 | 2009-04-14 | Advanced Tactical Fabrication, Inc. | Enhanced visibility safety garment |
| EP2237081A4 (en) * | 2008-01-10 | 2014-07-16 | Kolon Inc | OPTICAL FOILS |
| JP2010131817A (ja) * | 2008-12-03 | 2010-06-17 | Ito Kosan Kk | 再帰反射性シート |
| EP2577365B1 (en) | 2010-05-25 | 2021-02-17 | 3M Innovative Properties Company | Exposed lens retroreflective article |
| EP2591688A1 (en) | 2011-11-11 | 2013-05-15 | Kinco LLC | High visibility hand covering |
| TW201315598A (zh) * | 2012-10-18 | 2013-04-16 | Cing Wai Kung Mau Company | 反光物品製程 |
| CN103792604B (zh) | 2012-10-26 | 2016-12-21 | 3M创新有限公司 | 回归反射制品和附饰物 |
| CN103792603B (zh) | 2012-10-26 | 2016-07-06 | 3M创新有限公司 | 回归反射材料及制品 |
| DE212013000307U1 (de) | 2013-08-29 | 2016-08-10 | Safe Reflections, Inc. | Kolorisiertes, retroreflektierendes Material |
| EP3968063A1 (en) | 2014-01-31 | 2022-03-16 | 3M Innovative Properties Company | Colored retroreflective articles |
| US10239277B2 (en) | 2014-02-13 | 2019-03-26 | 3M Innovative Properties Company | Flexible microsphere articles having high temperature stability |
| EP3105048B1 (en) | 2014-02-13 | 2021-06-16 | 3M Innovative Properties Company | Dual cure stain resistant microsphere articles |
| US10545268B2 (en) * | 2014-05-09 | 2020-01-28 | 3M Innovative Properties Company | Retroreflective articles |
| EP3155462B1 (en) * | 2014-06-16 | 2019-10-23 | 3M Innovative Properties Company | Retroreflective articles with wash durable bead bond layers |
| JP6454096B2 (ja) * | 2014-06-27 | 2019-01-16 | 株式会社松井色素化学工業所 | 画像形成方法及び布状繊維製品 |
| US10845514B2 (en) | 2014-09-30 | 2020-11-24 | 3M Innovative Properties Company | Retroreflective colored articles |
| CN104354352A (zh) * | 2014-10-14 | 2015-02-18 | 陈国顺 | 一种带彩色印花型反光织物及制作方法 |
| US10345495B2 (en) | 2014-12-30 | 2019-07-09 | 3M Innovative Properties Company | Stain resistant retroreflective articles |
| CN105891924B (zh) | 2015-02-13 | 2019-07-09 | 3M创新有限公司 | 具有高温稳定性的柔性微球制品 |
| JP6972006B2 (ja) | 2016-03-30 | 2021-11-24 | スリーエム イノベイティブ プロパティズ カンパニー | ランダムに分散された微小球の所定のパターンを主とする物品及びその製造方法 |
| ITUA20164500A1 (it) * | 2016-06-20 | 2017-12-20 | Giorgio Corradi | Inserto retro riflettente |
| US20180055124A1 (en) * | 2016-08-26 | 2018-03-01 | Chieh-Yu Chen | Hat |
| US11415731B2 (en) | 2017-10-27 | 2022-08-16 | 3M Innovative Properties Company | Retroreflective article comprising retroreflective elements comprising primary reflective layers and secondary reflective layers |
| CN111263902A (zh) | 2017-10-27 | 2020-06-09 | 3M创新有限公司 | 包括嵌入反射层的回射制品 |
| CN111279227B (zh) | 2017-10-27 | 2023-01-17 | 3M创新有限公司 | 包括局部层压反射层的回射制品 |
| CN113785226B (zh) * | 2019-05-24 | 2025-03-11 | 3M创新有限公司 | 雷达回射制品 |
| US20230099542A1 (en) * | 2021-09-29 | 2023-03-30 | Douglas Bradshaw | Traffic Control Safety Gloves |
| DE102024112160A1 (de) * | 2024-04-30 | 2025-10-30 | Valkental Gmbh | Reflektierendes Textilmaterial |
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| DE1745526B2 (de) * | 1967-03-16 | 1980-04-10 | Union Carbide Corp., New York, N.Y. (V.St.A.) | Verfahren zur Herstellung vulkanisierbarer, unter wasserfreien Bedingungen beständiger Polymerisate |
| US3758192A (en) * | 1970-08-20 | 1973-09-11 | Minnesota Mining & Mfg | Reflex-reflective structures including fabric and transfer foils |
| US3700305A (en) * | 1970-12-14 | 1972-10-24 | Minnesota Mining & Mfg | Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres |
| US3979344A (en) * | 1974-11-19 | 1976-09-07 | Inmont Corporation | Vulcanizable silicon terminated polyurethane polymer composition having improved cure speed |
| US4576850A (en) * | 1978-07-20 | 1986-03-18 | Minnesota Mining And Manufacturing Company | Shaped plastic articles having replicated microstructure surfaces |
| US4222925A (en) * | 1978-08-02 | 1980-09-16 | Inmont Corporation | Vulcanizable silicon terminated polyurethane polymer compositions having improved cure speed |
| US4495061A (en) * | 1980-06-16 | 1985-01-22 | Chevron Research Company | Hydrocarbon conversion catalyst and process using said catalyst |
| US4396681A (en) * | 1981-06-10 | 1983-08-02 | Essex Chemical Corporation | Process for coating one pot moisture curable coating composition onto non-porous substrate and article |
| US4345053A (en) * | 1981-07-17 | 1982-08-17 | Essex Chemical Corp. | Silicon-terminated polyurethane polymer |
| US4725494A (en) * | 1982-09-02 | 1988-02-16 | Minnesota Mining And Manufacturing Co. | Retroreflective sheeting |
| US4533592A (en) * | 1984-08-02 | 1985-08-06 | Minnesota Mining And Manufacturing Company | Thermally stable flame retardant reflective and retroreflective trim |
| US4763985A (en) * | 1986-08-01 | 1988-08-16 | Minnesota Mining And Manufacturing Company | Retroreflective sheet with enhanced brightness |
| US4916199A (en) * | 1988-07-14 | 1990-04-10 | The B. F. Goodrich Company | Polyurethanes made from blends of polypropyleneoxide polyol and organic-silicone block copolymer based polyol intermediates |
| US4889903A (en) * | 1988-08-03 | 1989-12-26 | Basf Corporation | Fast-cure polyurethane sealant composition containing titanium ester accelerators |
| JPH0254922A (ja) * | 1988-08-19 | 1990-02-23 | Fuji Electric Co Ltd | プラズマｃｖｄ装置 |
| US5128804A (en) * | 1991-02-06 | 1992-07-07 | Minnesota Mining And Manufacturing Company | Permeable retroreflective sheeting |
| CA2066503A1 (en) * | 1991-04-22 | 1992-10-23 | Joseph S. Sollers | Polyurethane foam based on combination of polyester resin and polyether polyol |
| CA2061708C (en) * | 1991-05-08 | 2002-04-23 | Wu-Shyong Li | Launderable retroreflective applique with colorant |
| ITMI913213A1 (it) * | 1991-11-29 | 1993-05-30 | Minnesota Mining & Mfg | Nastro altamente conformabile per segnaletica stradale sottoposta ad intense condizioni di traffico |
| US5200262A (en) * | 1992-04-01 | 1993-04-06 | Minnesota Mining And Manufacturing Company | Launderable retroreflective applique with improved retention of retroreflective elements |
| US5378520A (en) * | 1992-12-16 | 1995-01-03 | Minnesota Mining And Manufacturing Company | Supported encapsulated-lens retroreflective sheeting |
| US5474827A (en) * | 1994-03-23 | 1995-12-12 | Minnesota Mining And Manufacturing Company | Retroreflective article and method of making the same |
| US5478596A (en) * | 1994-05-13 | 1995-12-26 | Gurney; Richard S. | Stripping composition and method for stripping a road or highway surface |
| CN1119672C (zh) * | 1994-11-23 | 2003-08-27 | 美国3M公司 | 含有聚醚聚氨酯粘合剂层的反光制品及其制造方法和用途 |
| US5587448A (en) * | 1994-12-29 | 1996-12-24 | Minnesota Mining And Manufacturing | Reaction system for producing a polyurethane and method of using same to seal a surface |
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| US5645938A (en) * | 1995-09-15 | 1997-07-08 | Minnesota Mining And Manufacturing Company | Retroreflective article containing a polyester polyurethane binder layer |
-
1996
- 1996-12-20 US US08/777,718 patent/US5976669A/en not_active Expired - Lifetime
-
1997
- 1997-12-04 EP EP19970950958 patent/EP0946889B1/en not_active Expired - Lifetime
- 1997-12-04 CA CA 2274541 patent/CA2274541C/en not_active Expired - Fee Related
- 1997-12-04 KR KR10-1999-7005594A patent/KR100519884B1/ko not_active Expired - Fee Related
- 1997-12-04 WO PCT/US1997/023040 patent/WO1998028642A1/en not_active Ceased
- 1997-12-04 CN CN97180730A patent/CN1113252C/zh not_active Expired - Lifetime
- 1997-12-04 JP JP52887298A patent/JP4344865B2/ja not_active Expired - Lifetime
- 1997-12-04 DE DE1997621305 patent/DE69721305T2/de not_active Expired - Lifetime
- 1997-12-11 TW TW086118692A patent/TW386092B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1113252C (zh) | 2003-07-02 |
| CA2274541A1 (en) | 1998-07-02 |
| KR20000062254A (ko) | 2000-10-25 |
| TW386092B (en) | 2000-04-01 |
| HK1023408A1 (en) | 2000-09-08 |
| KR100519884B1 (ko) | 2005-10-12 |
| WO1998028642A1 (en) | 1998-07-02 |
| US5976669A (en) | 1999-11-02 |
| JP4344865B2 (ja) | 2009-10-14 |
| CA2274541C (en) | 2007-02-06 |
| DE69721305D1 (de) | 2003-05-28 |
| EP0946889B1 (en) | 2003-04-23 |
| CN1240516A (zh) | 2000-01-05 |
| EP0946889A1 (en) | 1999-10-06 |
| JP2001507138A (ja) | 2001-05-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |