DE69521826T2 - Verfahren zur Herstellung von cyclischen Olefincopolymeren und danach hergestellte Copolymere - Google Patents

Verfahren zur Herstellung von cyclischen Olefincopolymeren und danach hergestellte Copolymere

Info

Publication number
DE69521826T2
DE69521826T2 DE69521826T DE69521826T DE69521826T2 DE 69521826 T2 DE69521826 T2 DE 69521826T2 DE 69521826 T DE69521826 T DE 69521826T DE 69521826 T DE69521826 T DE 69521826T DE 69521826 T2 DE69521826 T2 DE 69521826T2
Authority
DE
Germany
Prior art keywords
group
carbon atoms
zirconium dichloride
cyclopentadienyl
indenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69521826T
Other languages
German (de)
English (en)
Other versions
DE69521826D1 (de
Inventor
Yoshiharu Abe
Toshihiro Sagane
Akinori Toyota
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ticona GmbH
Mitsui Chemicals Inc
Original Assignee
Ticona GmbH
Mitsui Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ticona GmbH, Mitsui Chemicals Inc filed Critical Ticona GmbH
Application granted granted Critical
Publication of DE69521826D1 publication Critical patent/DE69521826D1/de
Publication of DE69521826T2 publication Critical patent/DE69521826T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Printing Methods (AREA)
DE69521826T 1994-04-22 1995-04-21 Verfahren zur Herstellung von cyclischen Olefincopolymeren und danach hergestellte Copolymere Expired - Fee Related DE69521826T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8472594 1994-04-22

Publications (2)

Publication Number Publication Date
DE69521826D1 DE69521826D1 (de) 2001-08-30
DE69521826T2 true DE69521826T2 (de) 2002-04-11

Family

ID=13838669

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69521826T Expired - Fee Related DE69521826T2 (de) 1994-04-22 1995-04-21 Verfahren zur Herstellung von cyclischen Olefincopolymeren und danach hergestellte Copolymere

Country Status (7)

Country Link
US (1) US5559199A (enExample)
EP (1) EP0678530B1 (enExample)
KR (1) KR100231173B1 (enExample)
CN (1) CN1067087C (enExample)
CA (1) CA2147589C (enExample)
DE (1) DE69521826T2 (enExample)
TW (1) TW312696B (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
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DE69525057T2 (de) * 1994-09-30 2002-08-29 Nippon Zeon Co., Ltd. Hydrogeniertes, durch ringöffnung erhaltenes polymer
JP3517471B2 (ja) * 1994-12-28 2004-04-12 三井化学株式会社 環状オレフィン共重合体の製造方法
JPH08239426A (ja) * 1995-03-01 1996-09-17 Mitsui Petrochem Ind Ltd 環状オレフィン共重合体の製造方法
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
FI105196B (fi) * 1995-05-08 2000-06-30 Optatech Oy Amorfiset olefiini-ko/terpolymeerit
DE69702506T2 (de) * 1996-03-27 2001-03-08 The Dow Chemical Co., Midland Hochlösliches aktivierungsmittel für olefinpolymerisationskatalysator
DE19623707A1 (de) * 1996-06-14 1997-12-18 Hoechst Ag Übergangsmetallverbindung
JP3817015B2 (ja) * 1997-04-14 2006-08-30 三井化学株式会社 環状オレフィン系共重合体およびその用途
FR2787113B1 (fr) * 1998-12-11 2003-10-17 Sumitomo Chemical Co Copolymere, son procede de preparation et produit moule obtenu avec ce copolymere
US6562918B1 (en) * 1999-02-04 2003-05-13 Idemitsu Petrochemical Co., Ltd. Olefin polymerization catalyst, method for producing the same and method for producing olefinic polymer
US6150478A (en) * 1999-06-04 2000-11-21 Union Carbide Chemicals & Plastics Technology Corporation Ultrasonic catalyst feed for fluid bed olefin polymerization
US6875719B2 (en) 2000-04-27 2005-04-05 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
EP1179554A1 (en) * 2000-08-08 2002-02-13 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
CA2364756A1 (en) * 2001-12-10 2003-06-10 Nova Chemicals Corporation Catalyst activator
US20050176890A1 (en) * 2003-01-23 2005-08-11 Sadahiko Matsuura Process for producing ethylene /alpha-olefin/unconjugated polyene copolymer, and ethylene/alpha-olefin/unconjugated polyene copolymer
TWI255370B (en) * 2003-02-27 2006-05-21 Hon Hai Prec Ind Co Ltd Light guide plate used for liquid crystal display
US7022787B2 (en) * 2003-09-25 2006-04-04 E. I. Du Pont De Nemours And Company Olefin polymerization catalyst
US8168292B2 (en) * 2006-06-15 2012-05-01 Innegra Technologies, Llc Composite materials including amorphous thermoplastic fibers
KR101414347B1 (ko) * 2006-07-28 2014-07-02 후지필름 가부시키가이샤 노르보르넨계 중합체, 필름, 편광판 및 액정 표시 장치
JP4074879B1 (ja) 2006-10-18 2008-04-16 株式会社コナミデジタルエンタテインメント ゲーム装置、メッセージ表示方法、および、プログラム
DE102007015707A1 (de) 2007-04-02 2008-10-09 Topas Advanced Polymers Gmbh Cycloolefin-Copolymere, Verfahren zu ihrer Herstellung, deren Verwendung und Katalysatoren
JP2020516695A (ja) 2017-04-12 2020-06-11 ウリゲン ファーマシューティカルズ、インコーポレイテッド 改善された安定性を備えた注射器中に局所麻酔薬、緩衝液、およびグルコサミノグリカンを含む製品
CN111777702B (zh) * 2020-05-13 2022-07-01 拓烯科技(衢州)有限公司 一种改性环烯烃型无规共聚物及其制备方法
CN116194492A (zh) * 2020-07-17 2023-05-30 陶氏环球技术有限责任公司 用于限制几何构型主催化剂的烃基改性的甲基铝氧烷助催化剂
CN115894757B (zh) * 2021-09-30 2024-06-04 中国石油化工股份有限公司 乙烯-烯醇共聚物及其制备方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4614778A (en) * 1984-02-03 1986-09-30 Hirokazu Kajiura Random copolymer
JPS6198780A (ja) * 1984-10-22 1986-05-17 Mitsui Petrochem Ind Ltd 新規合成ワツクス
JPS61115916A (ja) * 1984-11-12 1986-06-03 Mitsui Petrochem Ind Ltd 新重合体
JPS61120816A (ja) * 1984-11-19 1986-06-07 Mitsui Petrochem Ind Ltd 新規な付加共重合体
JPH0713084B2 (ja) * 1985-03-26 1995-02-15 三井石油化学工業株式会社 環状オレフイン系共重合体の製法
US5179171A (en) * 1985-05-24 1993-01-12 Mitsui Petrochemical Industries, Ltd. Random copolymer, and process for production thereof
US5003019A (en) * 1987-03-02 1991-03-26 Mitsui Petrochemical Industries, Ltd. Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
US5128446A (en) * 1988-09-07 1992-07-07 Mitsui Petrochemical Industries, Ltd. Process for producing cycloolefin random copolymer
US5008359A (en) * 1988-11-25 1991-04-16 Weyerhaeuser Company Isocyanate modified cellulose products and method for their manufacture
JP2730940B2 (ja) * 1988-12-27 1998-03-25 三井化学株式会社 環状オレフィン系共重合体の製造方法
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
JP2868569B2 (ja) * 1990-02-13 1999-03-10 三井化学株式会社 環状オレフィン系ランダム共重合体の製造方法
ATE212042T1 (de) * 1990-03-06 2002-02-15 Mitsui Chemicals Inc Statistische cycloolefincopolymere und verfahren zu ihrer herstellung
DE69129405T3 (de) * 1990-10-05 2001-10-04 Idemitsu Kosan Co. Ltd., Tokio/Tokyo Verfahren zur herstellung von cycloolefinpolymeren und cycloolefincopolymeren
ES2127199T3 (es) * 1991-02-27 1999-04-16 Ticona Gmbh Proceso para la preparacion de (co)polimeros de cicloolefinas con distribucion estrecha de pesos moleculares.
ATE166895T1 (de) * 1991-03-09 1998-06-15 Targor Gmbh Verfahren zur herstellung chemisch einheitlicher cycloolefincopolymere
EP0542488B1 (en) * 1991-11-11 1994-07-06 Mitsui Petrochemical Industries, Ltd. Process for preparing cycloolefin random copolymer
JPH05320258A (ja) * 1992-05-15 1993-12-03 Mitsui Petrochem Ind Ltd 環状オレフィン共重合用触媒および環状オレフィンの共重合方法
DE59402624D1 (de) * 1993-02-12 1997-06-12 Hoechst Ag Verfahren zur Herstellung von Cycloolefincopolymeren

Also Published As

Publication number Publication date
CN1112570A (zh) 1995-11-29
KR950032326A (ko) 1995-12-20
TW312696B (enExample) 1997-08-11
EP0678530B1 (en) 2001-07-25
KR100231173B1 (ko) 1999-11-15
DE69521826D1 (de) 2001-08-30
EP0678530A1 (en) 1995-10-25
CA2147589C (en) 2006-04-18
CN1067087C (zh) 2001-06-13
CA2147589A1 (en) 1995-10-23
US5559199A (en) 1996-09-24

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Legal Events

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8339 Ceased/non-payment of the annual fee