DE69331531T2 - Enzymatische verfahren und verwendung von enzymen zur erzeugung von stonewash-aussehen auf indigo-gefärbtem gewebe - Google Patents
Enzymatische verfahren und verwendung von enzymen zur erzeugung von stonewash-aussehen auf indigo-gefärbtem gewebeInfo
- Publication number
- DE69331531T2 DE69331531T2 DE69331531T DE69331531T DE69331531T2 DE 69331531 T2 DE69331531 T2 DE 69331531T2 DE 69331531 T DE69331531 T DE 69331531T DE 69331531 T DE69331531 T DE 69331531T DE 69331531 T2 DE69331531 T2 DE 69331531T2
- Authority
- DE
- Germany
- Prior art keywords
- cellulase
- protease
- redeposition
- added
- denim
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 102000004190 Enzymes Human genes 0.000 title claims description 30
- 108090000790 Enzymes Proteins 0.000 title claims description 30
- 239000004744 fabric Substances 0.000 title abstract description 13
- 238000006911 enzymatic reaction Methods 0.000 title 1
- 108091005804 Peptidases Proteins 0.000 claims abstract description 161
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims abstract description 150
- 239000004365 Protease Substances 0.000 claims abstract description 147
- 239000000203 mixture Substances 0.000 claims abstract description 73
- 238000000034 method Methods 0.000 claims abstract description 42
- 108010084185 Cellulases Proteins 0.000 claims abstract description 26
- 102000005575 Cellulases Human genes 0.000 claims abstract description 26
- 239000004575 stone Substances 0.000 claims abstract description 15
- 108010059892 Cellulase Proteins 0.000 claims description 169
- 229940106157 cellulase Drugs 0.000 claims description 156
- 108090000623 proteins and genes Proteins 0.000 claims description 70
- 102000004169 proteins and genes Human genes 0.000 claims description 68
- 229940088598 enzyme Drugs 0.000 claims description 29
- 230000000694 effects Effects 0.000 claims description 25
- 239000004094 surface-active agent Substances 0.000 claims description 22
- 241000223259 Trichoderma Species 0.000 claims description 13
- 102000013142 Amylases Human genes 0.000 claims description 8
- 108010065511 Amylases Proteins 0.000 claims description 8
- 235000019418 amylase Nutrition 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 108010022999 Serine Proteases Proteins 0.000 claims description 7
- 239000008262 pumice Substances 0.000 claims description 7
- 102000012479 Serine Proteases Human genes 0.000 claims description 6
- 229940025131 amylases Drugs 0.000 claims description 6
- 108090000787 Subtilisin Proteins 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims description 5
- 108010006035 Metalloproteases Proteins 0.000 claims description 4
- COHYTHOBJLSHDF-BUHFOSPRSA-N indigo dye Chemical compound N\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-BUHFOSPRSA-N 0.000 claims description 4
- 102000005741 Metalloproteases Human genes 0.000 claims description 3
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 claims description 3
- 241001136494 Talaromyces funiculosus Species 0.000 claims description 2
- 241000228212 Aspergillus Species 0.000 claims 2
- 241000193830 Bacillus <bacterium> Species 0.000 claims 2
- 238000005516 engineering process Methods 0.000 claims 2
- 238000010353 genetic engineering Methods 0.000 claims 2
- 230000002950 deficient Effects 0.000 claims 1
- 230000002401 inhibitory effect Effects 0.000 abstract description 13
- 238000009990 desizing Methods 0.000 abstract description 3
- 230000002255 enzymatic effect Effects 0.000 abstract description 3
- 239000001045 blue dye Substances 0.000 abstract 1
- 238000011282 treatment Methods 0.000 description 32
- 239000000047 product Substances 0.000 description 25
- 239000007788 liquid Substances 0.000 description 19
- 239000000975 dye Substances 0.000 description 14
- 238000010186 staining Methods 0.000 description 13
- 238000005299 abrasion Methods 0.000 description 12
- 244000005700 microbiome Species 0.000 description 12
- 102000035195 Peptidases Human genes 0.000 description 11
- 239000000872 buffer Substances 0.000 description 8
- 239000012530 fluid Substances 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 239000003599 detergent Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 230000002797 proteolythic effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 241000223198 Humicola Species 0.000 description 4
- 230000000007 visual effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 244000063299 Bacillus subtilis Species 0.000 description 3
- 235000014469 Bacillus subtilis Nutrition 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000011179 visual inspection Methods 0.000 description 3
- 239000004382 Amylase Substances 0.000 description 2
- 240000006439 Aspergillus oryzae Species 0.000 description 2
- 235000002247 Aspergillus oryzae Nutrition 0.000 description 2
- 241000194108 Bacillus licheniformis Species 0.000 description 2
- 108091003079 Bovine Serum Albumin Proteins 0.000 description 2
- 241000231281 Burmannia Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 108010091443 Exopeptidases Proteins 0.000 description 2
- 241000228143 Penicillium Species 0.000 description 2
- 101710118538 Protease Proteins 0.000 description 2
- 229920004890 Triton X-100 Polymers 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 229940098773 bovine serum albumin Drugs 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003248 enzyme activator Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000002538 fungal effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 239000012669 liquid formulation Substances 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- -1 ny Species 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000001717 pathogenic effect Effects 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical class [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- IIBCXMVHDVUGFI-UHFFFAOYSA-N 2-(2-phenoxyethoxy)decan-2-ol Chemical compound CCCCCCCCC(C)(O)OCCOC1=CC=CC=C1 IIBCXMVHDVUGFI-UHFFFAOYSA-N 0.000 description 1
- 108091005508 Acid proteases Proteins 0.000 description 1
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 101710112457 Exoglucanase Proteins 0.000 description 1
- 102000018389 Exopeptidases Human genes 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 238000003231 Lowry assay Methods 0.000 description 1
- 238000009013 Lowry's assay Methods 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 108090000083 Serine Endopeptidases Proteins 0.000 description 1
- 102000003667 Serine Endopeptidases Human genes 0.000 description 1
- 108010056079 Subtilisins Proteins 0.000 description 1
- 102000005158 Subtilisins Human genes 0.000 description 1
- 241001557886 Trichoderma sp. Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- PXXJHWLDUBFPOL-UHFFFAOYSA-N benzamidine Chemical compound NC(=N)C1=CC=CC=C1 PXXJHWLDUBFPOL-UHFFFAOYSA-N 0.000 description 1
- 108010047754 beta-Glucosidase Proteins 0.000 description 1
- 102000006995 beta-Glucosidase Human genes 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 101150048033 cbh gene Proteins 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 230000013595 glycosylation Effects 0.000 description 1
- 238000006206 glycosylation reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000002018 overexpression Effects 0.000 description 1
- 229940023462 paste product Drugs 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/14—Hydrolases (3)
- C12N9/48—Hydrolases (3) acting on peptide bonds (3.4)
- C12N9/50—Proteinases, e.g. Endopeptidases (3.4.21-3.4.25)
- C12N9/52—Proteinases, e.g. Endopeptidases (3.4.21-3.4.25) derived from bacteria or Archaea
- C12N9/54—Proteinases, e.g. Endopeptidases (3.4.21-3.4.25) derived from bacteria or Archaea bacteria being Bacillus
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/158—Locally discharging the dyes with other compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P7/00—Dyeing or printing processes combined with mechanical treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Genetics & Genomics (AREA)
- Textile Engineering (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Zoology (AREA)
- Molecular Biology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biotechnology (AREA)
- Biomedical Technology (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Microbiology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Coloring (AREA)
- Detergent Compositions (AREA)
- Enzymes And Modification Thereof (AREA)
- Treatment Of Fiber Materials (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7565793A | 1993-06-11 | 1993-06-11 | |
| PCT/US1993/011555 WO1994029426A1 (en) | 1993-06-11 | 1993-11-30 | Enzymatic compositions and methods for producing stonewashed look on indigo-dyed denim fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69331531D1 DE69331531D1 (de) | 2002-03-14 |
| DE69331531T2 true DE69331531T2 (de) | 2002-07-11 |
Family
ID=22127178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69331531T Expired - Lifetime DE69331531T2 (de) | 1993-06-11 | 1993-11-30 | Enzymatische verfahren und verwendung von enzymen zur erzeugung von stonewash-aussehen auf indigo-gefärbtem gewebe |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP0702713B1 (https=) |
| JP (2) | JP4000193B2 (https=) |
| KR (1) | KR960703166A (https=) |
| AT (1) | ATE212659T1 (https=) |
| BR (1) | BR9307862A (https=) |
| CA (1) | CA2164849C (https=) |
| DE (1) | DE69331531T2 (https=) |
| DK (1) | DK0702713T3 (https=) |
| ES (1) | ES2170092T3 (https=) |
| FI (1) | FI115840B (https=) |
| PT (1) | PT702713E (https=) |
| WO (1) | WO1994029426A1 (https=) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6251144B1 (en) | 1992-06-12 | 2001-06-26 | Genencor International, Inc. | Enzymatic compositions and methods for producing stonewashed look on indigo-dyed denim fabric and garments |
| DE19502514A1 (de) * | 1994-02-03 | 1995-08-10 | Sandoz Ag | Textilveredlungsmittel |
| US5700686A (en) * | 1995-06-06 | 1997-12-23 | Iogen Corporation | Protease-treated and purified cellulase compositions and methods for reducing backstaining during enzymatic stonewashing |
| US5958083A (en) * | 1995-09-08 | 1999-09-28 | Novo Nordisk A/A | Prevention of back-staining in stone washing |
| DE69628311T3 (de) * | 1995-09-08 | 2012-05-16 | Novozymes A/S | Verhütung des verschmierens beim stone-washing |
| NZ320821A (en) * | 1995-09-20 | 1999-11-29 | Genencor Int | Protease modified cellulase compositions |
| US6294366B1 (en) | 1997-09-19 | 2001-09-25 | Clariant Finance (Bvi) Limited | Compositions and methods for treating cellulose containing fabrics using truncated cellulase enzyme compositions |
| AU3464199A (en) * | 1999-04-01 | 2000-10-23 | Procter & Gamble Company, The | A detergent composition containing a metallo-protease |
| US6337313B1 (en) | 1999-11-16 | 2002-01-08 | National Starch And Chemical Investment Company | Textile manufacturing and treating processes comprising a hydrophobically modified polymer |
| AU2001263777A1 (en) | 2000-06-02 | 2001-12-11 | Novozymes A/S | Redeposition or backstain inhibition during stonewashing process |
| DE10162727A1 (de) | 2001-12-20 | 2003-07-10 | Henkel Kgaa | Neue Alkalische Protease aus Bacillus gibsonii (DSM 14391) und Wasch-und Reinigungsmittel enthaltend diese neue Alkalische Protease |
| DE10162728A1 (de) | 2001-12-20 | 2003-07-10 | Henkel Kgaa | Neue Alkalische Protease aus Bacillus gibsonii (DSM 14393) und Wasch-und Reinigungsmittel enthaltend diese neue Alkalische Protease |
| DE10163884A1 (de) | 2001-12-22 | 2003-07-10 | Henkel Kgaa | Neue Alkalische Protease aus Bacillus sp. (DSM 14392) und Wasch- und Reinigungsmittel enthaltend diese neue Alkalische Protease |
| DE10358097A1 (de) | 2003-12-10 | 2005-07-14 | Sasol Germany Gmbh | Verfahren zum Verhindern bzw. Minimieren der Farbredeposition unter Verwendung von Polyestern |
| DE10360805A1 (de) | 2003-12-23 | 2005-07-28 | Henkel Kgaa | Neue Alkalische Protease und Wasch- und Reinigungsmittel, enthaltend diese neue Alkalische Protease |
| DE102004019751A1 (de) | 2004-04-23 | 2005-11-17 | Henkel Kgaa | Neue Alkalische Proteasen und Wasch- und Reinigungsmittel, enthaltend diese neuen Alkalischen Proteasen |
| CN107938308A (zh) * | 2017-12-01 | 2018-04-20 | 武汉新华扬生物股份有限公司 | 改善牛仔酶洗中染料沾色的方法以及洗涤牛仔制品的方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2094826B (en) * | 1981-03-05 | 1985-06-12 | Kao Corp | Cellulase enzyme detergent composition |
| JPS57147599A (en) * | 1981-03-09 | 1982-09-11 | Kao Corp | Detergent composition |
| US4760025A (en) * | 1984-05-29 | 1988-07-26 | Genencor, Inc. | Modified enzymes and methods for making same |
| US4566985A (en) * | 1984-09-19 | 1986-01-28 | Applied Biochemists, Inc. | Method of cleaning using liquid compositions comprising stabilized mixtures of enzymes |
| US4832864A (en) * | 1987-09-15 | 1989-05-23 | Ecolab Inc. | Compositions and methods that introduce variations in color density into cellulosic fabrics, particularly indigo dyed denim |
| FR2641555B1 (fr) * | 1989-01-09 | 1992-03-27 | Cayla | Procede de delavage heterogene d'articles a base de coton teint utilisant en milieu aqueux des cellulases |
| EP0496783B1 (en) * | 1989-10-19 | 1995-12-27 | Genencor International, Inc. | Degradation resistant detergent compositions |
| JPH03167378A (ja) * | 1989-11-24 | 1991-07-19 | Nagase Seikagaku Kogyo Kk | セルロース系繊維生地の処理方法 |
| DK0531372T4 (da) * | 1990-05-09 | 2004-08-09 | Novozymes As | Cellulasepræparat omfattende et endoglucanaseenzym |
| WO1992006183A1 (en) * | 1990-10-05 | 1992-04-16 | Genencor International, Inc. | Methods for treating cotton-containing fabrics with cellulase |
| JPH04241165A (ja) * | 1991-01-07 | 1992-08-28 | Rakutou Kasei Kogyo Kk | 染色天然繊維材料にストーン・ウオッシュ様外観を付与する処理方法 |
| DE59305892D1 (de) * | 1992-07-29 | 1997-04-24 | Henkel Kgaa | Enzymhaltiges waschmittel |
-
1993
- 1993-11-30 WO PCT/US1993/011555 patent/WO1994029426A1/en not_active Ceased
- 1993-11-30 DE DE69331531T patent/DE69331531T2/de not_active Expired - Lifetime
- 1993-11-30 AT AT94903334T patent/ATE212659T1/de active
- 1993-11-30 KR KR1019950705618A patent/KR960703166A/ko not_active Ceased
- 1993-11-30 CA CA002164849A patent/CA2164849C/en not_active Expired - Lifetime
- 1993-11-30 DK DK94903334T patent/DK0702713T3/da active
- 1993-11-30 ES ES94903334T patent/ES2170092T3/es not_active Expired - Lifetime
- 1993-11-30 PT PT94903334T patent/PT702713E/pt unknown
- 1993-11-30 BR BR9307862A patent/BR9307862A/pt not_active Application Discontinuation
- 1993-11-30 JP JP51253394A patent/JP4000193B2/ja not_active Expired - Lifetime
- 1993-11-30 EP EP94903334A patent/EP0702713B1/en not_active Expired - Lifetime
-
1995
- 1995-12-08 FI FI955909A patent/FI115840B/fi not_active IP Right Cessation
-
2007
- 2007-05-15 JP JP2007129320A patent/JP4790662B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69331531D1 (de) | 2002-03-14 |
| JPH08511307A (ja) | 1996-11-26 |
| FI955909L (fi) | 1995-12-08 |
| JP4790662B2 (ja) | 2011-10-12 |
| DK0702713T3 (da) | 2002-05-06 |
| BR9307862A (pt) | 1996-02-06 |
| ES2170092T3 (es) | 2002-08-01 |
| CA2164849A1 (en) | 1994-12-22 |
| JP4000193B2 (ja) | 2007-10-31 |
| EP0702713B1 (en) | 2002-01-30 |
| PT702713E (pt) | 2002-06-28 |
| FI115840B (fi) | 2005-07-29 |
| KR960703166A (ko) | 1996-06-19 |
| CA2164849C (en) | 2006-01-03 |
| WO1994029426A1 (en) | 1994-12-22 |
| EP0702713A1 (en) | 1996-03-27 |
| FI955909A0 (fi) | 1995-12-08 |
| JP2007231506A (ja) | 2007-09-13 |
| ATE212659T1 (de) | 2002-02-15 |
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