DE69314845T2 - Hitzehärtbare, grundierungslose harte Silikonüberzugzusammensetzungen und thermoplastische Verbundwerkstoffe - Google Patents
Hitzehärtbare, grundierungslose harte Silikonüberzugzusammensetzungen und thermoplastische VerbundwerkstoffeInfo
- Publication number
- DE69314845T2 DE69314845T2 DE1993614845 DE69314845T DE69314845T2 DE 69314845 T2 DE69314845 T2 DE 69314845T2 DE 1993614845 DE1993614845 DE 1993614845 DE 69314845 T DE69314845 T DE 69314845T DE 69314845 T2 DE69314845 T2 DE 69314845T2
- Authority
- DE
- Germany
- Prior art keywords
- thermosetting
- weight
- adhesion promoter
- primerless
- silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 33
- 229920001169 thermoplastic Polymers 0.000 title claims description 13
- 229920001187 thermosetting polymer Polymers 0.000 title claims description 13
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 13
- 239000002131 composite material Substances 0.000 title claims description 11
- 239000004447 silicone coating Substances 0.000 title 1
- 229920001296 polysiloxane Polymers 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- 239000006185 dispersion Substances 0.000 claims description 24
- 239000002318 adhesion promoter Substances 0.000 claims description 20
- 239000003960 organic solvent Substances 0.000 claims description 17
- 239000003125 aqueous solvent Substances 0.000 claims description 16
- 239000004814 polyurethane Substances 0.000 claims description 15
- 229920002635 polyurethane Polymers 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 11
- 229920006243 acrylic copolymer Polymers 0.000 claims description 10
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical group CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 8
- 229920000515 polycarbonate Polymers 0.000 claims description 8
- 239000004417 polycarbonate Substances 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 5
- 230000002452 interceptive effect Effects 0.000 claims description 4
- 229940075614 colloidal silicon dioxide Drugs 0.000 claims description 3
- XUIMIQQOPSSXEZ-NJFSPNSNSA-N silicon-30 atom Chemical compound [30Si] XUIMIQQOPSSXEZ-NJFSPNSNSA-N 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- -1 acrylic polyol Chemical class 0.000 description 12
- 239000008119 colloidal silica Substances 0.000 description 11
- 239000000758 substrate Substances 0.000 description 11
- 229920005862 polyol Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- MCZDHTKJGDCTAE-UHFFFAOYSA-M tetrabutylazanium;acetate Chemical compound CC([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC MCZDHTKJGDCTAE-UHFFFAOYSA-M 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 3
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- 229920004142 LEXAN™ Polymers 0.000 description 2
- 239000004418 Lexan Substances 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 238000006748 scratching Methods 0.000 description 2
- 230000002393 scratching effect Effects 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 150000003673 urethanes Chemical class 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- FEWFXBUNENSNBQ-UHFFFAOYSA-N 2-hydroxyacrylic acid Chemical class OC(=C)C(O)=O FEWFXBUNENSNBQ-UHFFFAOYSA-N 0.000 description 1
- ISDGWTZFJKFKMO-UHFFFAOYSA-N 2-phenyl-1,3-dioxane-4,6-dione Chemical class O1C(=O)CC(=O)OC1C1=CC=CC=C1 ISDGWTZFJKFKMO-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- NLCKLZIHJQEMCU-UHFFFAOYSA-N cyano prop-2-enoate Chemical class C=CC(=O)OC#N NLCKLZIHJQEMCU-UHFFFAOYSA-N 0.000 description 1
- ZMAPKOCENOWQRE-UHFFFAOYSA-N diethoxy(diethyl)silane Chemical compound CCO[Si](CC)(CC)OCC ZMAPKOCENOWQRE-UHFFFAOYSA-N 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 1
- ZJBHFQKJEBGFNL-UHFFFAOYSA-N methylsilanetriol Chemical compound C[Si](O)(O)O ZJBHFQKJEBGFNL-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 239000012056 semi-solid material Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US88077792A | 1992-05-11 | 1992-05-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69314845D1 DE69314845D1 (de) | 1997-12-04 |
| DE69314845T2 true DE69314845T2 (de) | 1998-05-14 |
Family
ID=25377060
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1993614845 Expired - Lifetime DE69314845T2 (de) | 1992-05-11 | 1993-05-07 | Hitzehärtbare, grundierungslose harte Silikonüberzugzusammensetzungen und thermoplastische Verbundwerkstoffe |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0570165B1 (enExample) |
| JP (1) | JPH0633013A (enExample) |
| CA (1) | CA2093686A1 (enExample) |
| DE (1) | DE69314845T2 (enExample) |
| ES (1) | ES2108218T3 (enExample) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63148315A (ja) * | 1986-12-12 | 1988-06-21 | Fanuc Ltd | サ−ボモ−タ制御装置 |
| EP0877068A3 (en) * | 1997-05-05 | 2000-01-12 | General Electric Company | A primerless silicone hardcoat composition for plastic substrates, and related articles |
| US6342097B1 (en) | 1999-04-23 | 2002-01-29 | Sdc Coatings, Inc. | Composition for providing an abrasion resistant coating on a substrate with a matched refractive index and controlled tintability |
| EP1087001B1 (en) * | 1999-09-24 | 2004-12-01 | General Electric Company | Curable abrasion-resistant coating compositions |
| US7097704B1 (en) | 2002-09-16 | 2006-08-29 | Sdc Technologies, Inc. | Tintable abrasion resistant coating composition and methods of making and using same |
| EP1632540A1 (de) * | 2004-09-03 | 2006-03-08 | Sika Technology AG | Zum Verkleben geeignete thermisch gehärtete Silikonbeschichtung |
| KR20080076953A (ko) * | 2005-12-13 | 2008-08-20 | 블루스타 실리콘즈 프랑스 | 중합체로 안정화시킨 광물 입자 분산액의 재분산성 분말을함유하는 규소 수지 코팅 조성물 |
| EP1829917A1 (de) | 2006-03-02 | 2007-09-05 | Sika Technology AG | Ohne Primer verklebbare thermisch gehärtete Silikonbeschichtung |
| CN101579672A (zh) | 2008-05-16 | 2009-11-18 | 3M创新有限公司 | 用于提高亲水性/透射率的二氧化硅涂层 |
| US9206335B2 (en) | 2008-10-10 | 2015-12-08 | 3M Innovation Properties Company | Silica coating for enhanced hydrophilicity |
| US20100092765A1 (en) * | 2008-10-10 | 2010-04-15 | 3M Innovative Properties Company | Silica coating for enhanced hydrophilicity |
| DE102009019493B4 (de) | 2009-05-04 | 2013-02-07 | Bayer Materialscience Aktiengesellschaft | Polar lösliche UV-Absorber |
| DE102009020938A1 (de) | 2009-05-12 | 2010-11-18 | Bayer Materialscience Ag | Witterungsstabile Mehrschichtsysteme |
| CN101941001B (zh) | 2009-07-03 | 2014-04-02 | 3M创新有限公司 | 亲水涂层、制品、涂料组合物和方法 |
| JP5316300B2 (ja) * | 2009-08-07 | 2013-10-16 | 信越化学工業株式会社 | 耐摩耗性シリコーンコーティング組成物並びに被覆物品及びその製造方法 |
| DE102009042307A1 (de) | 2009-09-19 | 2011-05-12 | Bayer Materialscience Ag | Kombination zweier Triazin UV Absorber für Lack auf PC |
| DE102009058200A1 (de) | 2009-12-15 | 2011-06-16 | Bayer Materialscience Ag | Polymer-Zusammensetzung mit Wärme-absorbierenden Eigenschaften und hoher Stabilität |
| JP5805656B2 (ja) | 2009-12-21 | 2015-11-04 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＢａｙｅｒ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ ＧｍｂＨ | 基層、プライマー層および耐引掻性層を有する多層系 |
| MX2012008467A (es) | 2010-01-22 | 2012-08-15 | Bayer Ip Gmbh | Articulos ignifugos con alta transmision. |
| JP5745036B2 (ja) | 2010-04-28 | 2015-07-08 | スリーエム イノベイティブ プロパティズ カンパニー | シリコーン系材料 |
| EP2563865B1 (en) | 2010-04-28 | 2016-06-01 | 3M Innovative Properties Company | Articles including nanosilica-based primers for polymer coatings and methods |
| ITRM20100225A1 (it) | 2010-05-10 | 2011-11-10 | Bayer Materialscience Ag | Composizione di polimeri con caratteristiche di assorbimento del calore e migliorate caratteristiche di colore. |
| ITRM20100228A1 (it) | 2010-05-10 | 2011-11-10 | Bayer Materialscience Ag | Composizione polimerica con caratteristiche di assorbimento del calore e migliorate caratteristiche di colore. |
| ITRM20100227A1 (it) | 2010-05-10 | 2011-11-10 | Bayer Materialscience Ag | Composizione polimerica con caratteristiche di assorbimento di calore ad alta stabilità. |
| ITRM20100226A1 (it) | 2010-05-10 | 2011-11-10 | Bayer Materialscience Ag | Composizioni stabilizzanti. |
| CN102241899B (zh) | 2010-05-11 | 2014-05-14 | 3M创新有限公司 | 涂料组合物，改性基体表面的方法和制品 |
| KR20170137207A (ko) | 2010-10-06 | 2017-12-12 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 나노실리카계 코팅 및 배리어층을 갖는 반사방지 물품 |
| EP2447236A1 (de) | 2010-10-12 | 2012-05-02 | Bayer MaterialScience AG | Spezielle UV-Absorber für härtbare UV-Schutz Beschichtungen |
| BR112013009979A2 (pt) | 2010-10-25 | 2017-10-24 | Bayer Ip Gmbh | estrutura plástica de camadas múltiplas tendo baixa transmissão de energia |
| DE102010042939A1 (de) | 2010-10-26 | 2012-04-26 | Bayer Materialscience Aktiengesellschaft | Fugenlose Heckklappe |
| ITRM20100668A1 (it) | 2010-12-17 | 2012-06-18 | Bayer Materialscience Ag | Substrato-led a colorazione stabile. |
| IT1403380B1 (it) | 2010-12-17 | 2013-10-17 | Bayer Materialscience Ag | Composizione di polimeri con caratteristiche di assorbimento di calore ad alta stabilità agli agenti atmosferici. |
| ITRM20100670A1 (it) | 2010-12-17 | 2012-06-18 | Bayer Materialscience Ag | Colorante organico e composizioni polimeriche colorate ad alta stabilità agli agenti atmosferici. |
| ITRM20100667A1 (it) | 2010-12-17 | 2012-06-18 | Bayer Materialscience Ag | Composizione di polimeri con caratteristiche di assorbimento di calore ad alta stabilità agli agenti atmosferici. |
| EP2543695A1 (de) | 2011-07-08 | 2013-01-09 | Bayer MaterialScience AG | Matte, flammgeschützte Artikel mit hoher Transmission |
| US9651712B2 (en) | 2011-10-18 | 2017-05-16 | Covestro Deutschland Ag | Polymer composition with heat-absorbing properties |
| BR112014012642A2 (pt) | 2011-11-30 | 2017-06-13 | Bayer Ip Gmbh | objetos de camada múltipla feitos de policarbonato com efeito de brilho intenso |
| EP2785795B1 (de) | 2011-11-30 | 2017-06-07 | Covestro Deutschland AG | Mehrschichtkörper aus polycarbonat mit tiefenglanzeffekt |
| EP2700455A1 (de) | 2012-08-23 | 2014-02-26 | Bayer MaterialScience AG | Nasslackapplikation auf Kunststoffsubstraten mit Plasmahärtung |
| US20150210651A1 (en) | 2012-08-23 | 2015-07-30 | Bayer Materialscience Ag | Vapour deposition of organic uv absorbers onto plastic substrates |
| CN105008446A (zh) | 2012-12-20 | 2015-10-28 | 拜耳材料科技股份有限公司 | 含有ir反射颜料的涂盖着色的聚碳酸酯模塑料 |
| ITRM20120656A1 (it) | 2012-12-20 | 2014-06-21 | Bayer Materialscience Ag | Articolo multistrato a base di policarbonato con forte resistenza agli agenti atmosferici. |
| US9713915B2 (en) | 2013-01-18 | 2017-07-25 | Covestro Deutschland Ag | Bird protection glazing |
| WO2018060081A1 (de) | 2016-09-27 | 2018-04-05 | Covestro Deutschland Ag | Frontscheibe für kraftfahrzeug |
| US11351764B2 (en) | 2016-11-17 | 2022-06-07 | Covestro Deutschland Ag | Opaque multi-layer body of polycarbonate for heat management |
| WO2018091556A1 (de) | 2016-11-17 | 2018-05-24 | Covestro Deutschland Ag | Transparenter mehrschichtkörper zum wärmemanagement |
| EP3395875B2 (de) | 2017-04-24 | 2023-01-25 | Covestro Deutschland AG | Laserstrahl-durchlässiges substratmaterial für sensoranwendungen |
| EP3658613A1 (de) | 2017-07-24 | 2020-06-03 | Covestro Deutschland AG | Led-beleuchtungselemente mit formteilen aus transluzenten polycarbonat-zusammensetzungen mit tiefenglanzeffekt |
| CN111448473B (zh) | 2017-12-21 | 2024-12-03 | 科思创德国股份有限公司 | 包括多层体和lidar传感器的装置 |
| EP3802121B1 (de) | 2018-05-29 | 2022-07-20 | Covestro Intellectual Property GmbH & Co. KG | Opaker mehrschichtkörper aus polycarbonat mit hoher bewitterungsstabilität |
| DE202020101944U1 (de) | 2019-09-30 | 2021-01-15 | Covestro Deutschland Ag | LED-Beleuchtungselemente auf Basis von Mehrschichtkörpern mit Steinoptik |
| DE202020101945U1 (de) | 2019-09-30 | 2021-01-15 | Covestro Deutschland Ag | LED-Beleuchtungselemente auf Basis von Mehrschichtkörpern mit Massivsteinoptik |
| US12007093B2 (en) | 2019-10-15 | 2024-06-11 | Covestro Llc | Three part headlamp assembly |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2328751A1 (fr) * | 1975-10-24 | 1977-05-20 | Sumitomo Chemical Co | Compositions de revetement, a base de composes de silicium hydrolyses, de copolymere acrylique et de methylolmelamine etheree |
| US4310600A (en) * | 1980-08-29 | 1982-01-12 | American Hoechst Corp. | Polyester film having abrasion resistant radiation curable silicone coating |
| US4439494A (en) * | 1982-03-01 | 1984-03-27 | General Electric Company | Silyl-polyacrylates for polycarbonate substrates |
| US4957818A (en) * | 1987-08-14 | 1990-09-18 | Mitsubishi Kasei Vinyl Company | Molded synthetic resin product |
| JP2559598B2 (ja) * | 1987-09-09 | 1996-12-04 | 大阪有機化学工業株式会社 | 被覆組成物 |
-
1993
- 1993-04-08 CA CA 2093686 patent/CA2093686A1/en not_active Abandoned
- 1993-05-07 ES ES93303556T patent/ES2108218T3/es not_active Expired - Lifetime
- 1993-05-07 DE DE1993614845 patent/DE69314845T2/de not_active Expired - Lifetime
- 1993-05-07 EP EP19930303556 patent/EP0570165B1/en not_active Expired - Lifetime
- 1993-05-10 JP JP5107784A patent/JPH0633013A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0570165A3 (enExample) | 1994-03-23 |
| ES2108218T3 (es) | 1997-12-16 |
| EP0570165B1 (en) | 1997-10-29 |
| DE69314845D1 (de) | 1997-12-04 |
| CA2093686A1 (en) | 1993-11-12 |
| EP0570165A2 (en) | 1993-11-18 |
| JPH0633013A (ja) | 1994-02-08 |
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