DE656524C - Photoelektrische Zelle mit aeusserem lichtelektrischem Effekt - Google Patents
Photoelektrische Zelle mit aeusserem lichtelektrischem EffektInfo
- Publication number
- DE656524C DE656524C DE1930656524D DE656524DD DE656524C DE 656524 C DE656524 C DE 656524C DE 1930656524 D DE1930656524 D DE 1930656524D DE 656524D D DE656524D D DE 656524DD DE 656524 C DE656524 C DE 656524C
- Authority
- DE
- Germany
- Prior art keywords
- cell
- photoelectric
- intermediate layer
- photoactive
- substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000000694 effects Effects 0.000 title claims description 5
- 239000000126 substance Substances 0.000 claims description 41
- 150000001875 compounds Chemical class 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 13
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 7
- 239000003638 chemical reducing agent Substances 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 5
- BROHICCPQMHYFY-UHFFFAOYSA-N caesium chromate Chemical compound [Cs+].[Cs+].[O-][Cr]([O-])(=O)=O BROHICCPQMHYFY-UHFFFAOYSA-N 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229910052792 caesium Inorganic materials 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- 238000010025 steaming Methods 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 46
- 239000010410 layer Substances 0.000 description 34
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 10
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 6
- 210000002421 cell wall Anatomy 0.000 description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 6
- 229910052721 tungsten Inorganic materials 0.000 description 6
- 239000010937 tungsten Substances 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 229910001634 calcium fluoride Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000011775 sodium fluoride Substances 0.000 description 5
- 235000013024 sodium fluoride Nutrition 0.000 description 5
- 239000011575 calcium Substances 0.000 description 4
- 229910004261 CaF 2 Inorganic materials 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- NXHILIPIEUBEPD-UHFFFAOYSA-H tungsten hexafluoride Chemical compound F[W](F)(F)(F)(F)F NXHILIPIEUBEPD-UHFFFAOYSA-H 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 241000723368 Conium Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- XNHWVNMBVKUKMM-UHFFFAOYSA-N [Cs].[Zr] Chemical compound [Cs].[Zr] XNHWVNMBVKUKMM-UHFFFAOYSA-N 0.000 description 1
- -1 calcium fluoride Chemical class 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000002923 metal particle Chemical class 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- YYDCXBWHICKRII-UHFFFAOYSA-L sodium zirconium(4+) difluoride Chemical compound [F-].[Zr+4].[F-].[Na+] YYDCXBWHICKRII-UHFFFAOYSA-L 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J40/00—Photoelectric discharge tubes not involving the ionisation of a gas
- H01J40/02—Details
- H01J40/04—Electrodes
- H01J40/06—Photo-emissive cathodes
Landscapes
- Hybrid Cells (AREA)
- Glass Compositions (AREA)
- Photovoltaic Devices (AREA)
- Luminescent Compositions (AREA)
- Discharge Lamp (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL46329A NL27115C (enrdf_load_stackoverflow) | 1929-05-16 | 1929-05-16 | |
DE1930N0140630 DE680108C (de) | 1930-12-07 | 1930-12-07 | Photoelektrische Vorrichtung |
DE147067X | 1931-11-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE656524C true DE656524C (de) | 1938-02-15 |
Family
ID=34108259
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1930656524D Expired DE656524C (de) | 1929-05-16 | 1930-03-29 | Photoelektrische Zelle mit aeusserem lichtelektrischem Effekt |
Country Status (6)
Country | Link |
---|---|
AT (3) | AT136262B (enrdf_load_stackoverflow) |
CH (1) | CH151489A (enrdf_load_stackoverflow) |
DE (1) | DE656524C (enrdf_load_stackoverflow) |
DK (2) | DK45331C (enrdf_load_stackoverflow) |
GB (3) | GB343930A (enrdf_load_stackoverflow) |
NL (1) | NL27115C (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE967684C (de) * | 1938-12-15 | 1957-12-05 | Cinema Television Ltd | Verfahren zur Herstellung einer photoempfindlichen Schicht aus einem Alkalimetall und einem mit diesem eine Legierung bildenden Metall |
-
1929
- 1929-05-16 NL NL46329A patent/NL27115C/xx active
- 1929-11-25 GB GB36072/29A patent/GB343930A/en not_active Expired
-
1930
- 1930-03-07 DK DK45331D patent/DK45331C/da active
- 1930-03-29 AT AT136262D patent/AT136262B/de active
- 1930-03-29 DE DE1930656524D patent/DE656524C/de not_active Expired
- 1930-05-07 CH CH151489D patent/CH151489A/de unknown
-
1931
- 1931-08-25 GB GB23883/31A patent/GB373867A/en not_active Expired
- 1931-11-12 DK DK46213D patent/DK46213C/da active
-
1932
- 1932-03-19 AT AT147067D patent/AT147067B/de active
- 1932-06-14 GB GB16830/32A patent/GB393418A/en not_active Expired
-
1933
- 1933-07-20 AT AT158211D patent/AT158211B/de active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE967684C (de) * | 1938-12-15 | 1957-12-05 | Cinema Television Ltd | Verfahren zur Herstellung einer photoempfindlichen Schicht aus einem Alkalimetall und einem mit diesem eine Legierung bildenden Metall |
Also Published As
Publication number | Publication date |
---|---|
NL27115C (enrdf_load_stackoverflow) | 1932-07-15 |
AT158211B (de) | 1940-03-26 |
CH151489A (de) | 1931-12-15 |
GB393418A (en) | 1933-06-08 |
GB373867A (en) | 1932-06-02 |
DK46213C (da) | 1932-09-19 |
GB343930A (en) | 1931-02-25 |
DK45331C (da) | 1932-02-29 |
AT136262B (de) | 1934-01-25 |
AT147067B (de) | 1936-09-25 |
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