DE60315262T2 - Pvb folie mit geringer verfärbung und verfahren zu ihrer herstellung - Google Patents
Pvb folie mit geringer verfärbung und verfahren zu ihrer herstellung Download PDFInfo
- Publication number
- DE60315262T2 DE60315262T2 DE60315262T DE60315262T DE60315262T2 DE 60315262 T2 DE60315262 T2 DE 60315262T2 DE 60315262 T DE60315262 T DE 60315262T DE 60315262 T DE60315262 T DE 60315262T DE 60315262 T2 DE60315262 T2 DE 60315262T2
- Authority
- DE
- Germany
- Prior art keywords
- polyvinyl butyral
- pvb
- surfactant
- resin
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 37
- 238000004519 manufacturing process Methods 0.000 title description 16
- 238000010186 staining Methods 0.000 title 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 108
- 239000000203 mixture Substances 0.000 claims description 51
- 150000001875 compounds Chemical class 0.000 claims description 48
- 239000004014 plasticizer Substances 0.000 claims description 43
- 229920005989 resin Polymers 0.000 claims description 36
- 239000011347 resin Substances 0.000 claims description 36
- 239000004094 surface-active agent Substances 0.000 claims description 30
- 239000003963 antioxidant agent Substances 0.000 claims description 24
- 238000004061 bleaching Methods 0.000 claims description 21
- 239000007844 bleaching agent Substances 0.000 claims description 20
- 230000003078 antioxidant effect Effects 0.000 claims description 17
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 16
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 16
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 15
- 239000011342 resin composition Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 12
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 11
- 239000013036 UV Light Stabilizer Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- SSKNCQWPZQCABD-UHFFFAOYSA-N 2-[2-[2-(2-heptanoyloxyethoxy)ethoxy]ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOCCOC(=O)CCCCCC SSKNCQWPZQCABD-UHFFFAOYSA-N 0.000 claims description 7
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 claims description 7
- -1 compound Sodium dioctylsulfosuccinate Chemical class 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 239000004611 light stabiliser Substances 0.000 claims description 6
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 claims description 6
- FRQDZJMEHSJOPU-UHFFFAOYSA-N Triethylene glycol bis(2-ethylhexanoate) Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CCCC FRQDZJMEHSJOPU-UHFFFAOYSA-N 0.000 claims description 5
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 4
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 claims description 4
- 230000009477 glass transition Effects 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 description 13
- 229960000878 docusate sodium Drugs 0.000 description 8
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002845 discoloration Methods 0.000 description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- DXCHWXWXYPEZKM-UHFFFAOYSA-N 2,4-ditert-butyl-6-[1-(3,5-ditert-butyl-2-hydroxyphenyl)ethyl]phenol Chemical compound C=1C(C(C)(C)C)=CC(C(C)(C)C)=C(O)C=1C(C)C1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1O DXCHWXWXYPEZKM-UHFFFAOYSA-N 0.000 description 1
- SZAQZZKNQILGPU-UHFFFAOYSA-N 2-[1-(2-hydroxy-3,5-dimethylphenyl)-2-methylpropyl]-4,6-dimethylphenol Chemical compound C=1C(C)=CC(C)=C(O)C=1C(C(C)C)C1=CC(C)=CC(C)=C1O SZAQZZKNQILGPU-UHFFFAOYSA-N 0.000 description 1
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical class C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HXOSOIUOLGXZFL-UHFFFAOYSA-L disodium;2-decyl-6-(2-sulfonatophenoxy)benzenesulfonate Chemical compound [Na+].[Na+].CCCCCCCCCCC1=CC=CC(OC=2C(=CC=CC=2)S([O-])(=O)=O)=C1S([O-])(=O)=O HXOSOIUOLGXZFL-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- BSPCDVNIYGDPPA-UHFFFAOYSA-M hydrogen sulfite;tetramethylazanium Chemical compound OS([O-])=O.C[N+](C)(C)C BSPCDVNIYGDPPA-UHFFFAOYSA-M 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000005340 laminated glass Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
- 229940099427 potassium bisulfite Drugs 0.000 description 1
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 description 1
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- KKDONKAYVYTWGY-UHFFFAOYSA-M sodium;2-(methylamino)ethanesulfonate Chemical compound [Na+].CNCCS([O-])(=O)=O KKDONKAYVYTWGY-UHFFFAOYSA-M 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/48—Isomerisation; Cyclisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31627—Next to aldehyde or ketone condensation product
- Y10T428/3163—Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36394302P | 2002-03-12 | 2002-03-12 | |
| US363943P | 2002-03-12 | ||
| PCT/US2003/007354 WO2004018378A2 (en) | 2002-03-12 | 2003-03-11 | Low-color pvb sheet and a process for making same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60315262D1 DE60315262D1 (de) | 2007-09-13 |
| DE60315262T2 true DE60315262T2 (de) | 2008-04-17 |
Family
ID=31946659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60315262T Expired - Lifetime DE60315262T2 (de) | 2002-03-12 | 2003-03-11 | Pvb folie mit geringer verfärbung und verfahren zu ihrer herstellung |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7687560B2 (enExample) |
| EP (1) | EP1483319B1 (enExample) |
| JP (1) | JP4912591B2 (enExample) |
| CN (1) | CN1280342C (enExample) |
| AU (1) | AU2003286997A1 (enExample) |
| CA (1) | CA2478095A1 (enExample) |
| DE (1) | DE60315262T2 (enExample) |
| MX (1) | MXPA04008764A (enExample) |
| WO (1) | WO2004018378A2 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050131133A1 (en) * | 2002-03-12 | 2005-06-16 | Wong Bert C. | Low-color stiff pvb laminates |
| US7642307B2 (en) | 2002-03-12 | 2010-01-05 | E.I. Du Pont De Nemours And Company | Low-color stiff PVB laminates |
| EP1503895A1 (en) * | 2002-05-16 | 2005-02-09 | E.I. Du Pont De Nemours And Company | Laminated structures with superior impact resistance and process for making same |
| US7960503B2 (en) * | 2009-05-26 | 2011-06-14 | Solutia, Inc. | Continuous washing of poly(vinyl butyral) |
| CN102942758B (zh) * | 2012-11-09 | 2015-04-22 | 浙江德斯泰塑胶有限公司 | 应用于太阳能组件的高反光率pvb封装膜及制备方法 |
| US11014340B2 (en) * | 2013-09-30 | 2021-05-25 | Sekisui Chemical Co., Ltd. | Intermediate film for laminated glass, and laminated glass |
| WO2015115627A1 (ja) | 2014-01-31 | 2015-08-06 | 積水化学工業株式会社 | 合わせガラス及び合わせガラスの取り付け方法 |
| CN105939979B (zh) * | 2014-03-28 | 2019-06-28 | 积水化学工业株式会社 | 夹层玻璃用中间膜及夹层玻璃 |
| CN105585805A (zh) * | 2016-02-24 | 2016-05-18 | 苏州常德新科膜材料有限公司 | 一种降低紫外线伤害的pvb膜及其生产工艺 |
| FR3061074B1 (fr) | 2016-12-23 | 2021-05-28 | Saint Gobain | Vitrage feuillete colore |
| FR3064529A1 (fr) | 2017-03-29 | 2018-10-05 | Saint-Gobain Glass France | Procede de fabrication d'un miroir feuillete colore. |
| KR102097205B1 (ko) * | 2018-05-08 | 2020-04-03 | 에스케이씨 주식회사 | 폴리비닐아세탈 수지 조성물 및 이를 포함하는 접합용 중간막 |
| FR3103807A1 (fr) * | 2019-11-29 | 2021-06-04 | Saint-Gobain Glass France | Vitrage feuillete pour camera |
| CN111533832B (zh) * | 2020-04-09 | 2021-01-22 | 建滔(佛冈)特种树脂有限公司 | 一种耐黄变的聚乙烯醇缩丁醛树脂及其制备方法和应用 |
| CN111499780B (zh) * | 2020-05-26 | 2023-01-24 | 河南省科学院化学研究所有限公司 | 一种聚乙烯醇缩丁醛树脂的合成方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1247663C2 (de) * | 1961-02-24 | 1975-11-27 | E.I. Du Pont De Nemours And Company, Wilmington, Del. (V.St.A.) | Verfahren zur herstellung von polyvinylacetalen |
| US4035549A (en) * | 1975-05-19 | 1977-07-12 | Monsanto Company | Interlayer for laminated safety glass |
| FR2401941A1 (fr) * | 1977-08-31 | 1979-03-30 | Saint Gobain | Procede de fabrication de polyvinyl butyral et polyvinyl butyral obtenu par ce procede |
| DE3228076A1 (de) | 1982-07-28 | 1984-02-02 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstelltung eines polyvinylbutyral-formkoerpers |
| FR2547589B1 (fr) * | 1983-06-14 | 1986-03-21 | Saint Gobain Vitrage | Procede de fabrication de polyvinylbutyral et produits obtenus |
| EP0185796A1 (en) | 1984-12-27 | 1986-07-02 | Mitsubishi Kasei Polytec Company | Fan-shaped interlayer for a curved laminate sheet glass |
| US5187217A (en) * | 1987-04-02 | 1993-02-16 | Saint-Gobain Vitrage | Process for the production of a plasticized polyvinyl butyral for gluing a base onto a glazing |
| US5322875A (en) * | 1988-06-07 | 1994-06-21 | Saint-Gobain Vitrage | Polyvinylbutyral-based thermoplastic composition, useful for fixing bases on a glazing |
| US4937147A (en) * | 1989-04-10 | 1990-06-26 | Monsanto Company | Transparent polymeric laminate |
| MX171193B (es) * | 1989-12-08 | 1993-10-06 | Monsanto Co | Composicion plastificante, polivinil butiral plastificado y entrecapa del mismo |
| US5013779A (en) * | 1989-12-08 | 1991-05-07 | Monsanto Company | Plasticized polyvinyl butyral and interlayer thereof |
| FR2680364B1 (fr) * | 1991-08-14 | 1994-02-25 | Saint Gobain Vitrage Internal | Vitrage feuillete de securite pour avion. |
| JPH0551505A (ja) | 1991-08-27 | 1993-03-02 | Denki Kagaku Kogyo Kk | ポリビニルアセタール組成物 |
| DE4324167A1 (de) * | 1993-07-19 | 1995-01-26 | Hoechst Ag | Polyvinylbutyralfolien mit verbesserten optischen Eigenschaften |
| KR100342803B1 (ko) * | 1995-03-14 | 2003-01-24 | 이.아이,듀우판드네모아앤드캄파니 | 폴리비닐부티랄시이트의제조방법 |
| JPH08337446A (ja) * | 1995-06-09 | 1996-12-24 | Sekisui Chem Co Ltd | 合わせガラス用中間膜及び合わせガラス |
| AU7594298A (en) | 1998-05-22 | 1999-12-13 | E.I. Du Pont De Nemours And Company | Eliminating adhesion difference due to glass orientation in laminated safety glass |
| JPH11349769A (ja) | 1998-06-05 | 1999-12-21 | Denki Kagaku Kogyo Kk | ポリビニルアセタール組成物及び合わせガラス用中間膜 |
| US6383647B1 (en) * | 1998-09-30 | 2002-05-07 | Sekisui Chemical Co., Ltd. | Intermediate film for laminated glass and laminated glass |
| AU772350C (en) * | 1999-10-01 | 2004-09-23 | Sekisui Chemical Co., Ltd. | Intermediate film for laminated glass and laminated glass |
| EP1379577B1 (en) * | 2001-03-23 | 2004-08-25 | Solutia Inc. | Controlling solar radiation in safety glass laminates |
| CN1638959A (zh) * | 2002-03-12 | 2005-07-13 | 纳幕尔杜邦公司 | 飞机挡风屏用低色泽硬pvb层压材料 |
| US20050131133A1 (en) * | 2002-03-12 | 2005-06-16 | Wong Bert C. | Low-color stiff pvb laminates |
-
2003
- 2003-03-11 AU AU2003286997A patent/AU2003286997A1/en not_active Abandoned
- 2003-03-11 DE DE60315262T patent/DE60315262T2/de not_active Expired - Lifetime
- 2003-03-11 CA CA002478095A patent/CA2478095A1/en not_active Abandoned
- 2003-03-11 EP EP03777515A patent/EP1483319B1/en not_active Expired - Lifetime
- 2003-03-11 US US10/501,598 patent/US7687560B2/en not_active Expired - Lifetime
- 2003-03-11 MX MXPA04008764A patent/MXPA04008764A/es active IP Right Grant
- 2003-03-11 JP JP2004530769A patent/JP4912591B2/ja not_active Expired - Lifetime
- 2003-03-11 CN CNB038058367A patent/CN1280342C/zh not_active Expired - Lifetime
- 2003-03-11 WO PCT/US2003/007354 patent/WO2004018378A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JP4912591B2 (ja) | 2012-04-11 |
| EP1483319A2 (en) | 2004-12-08 |
| AU2003286997A1 (en) | 2004-03-11 |
| MXPA04008764A (es) | 2004-12-06 |
| WO2004018378A2 (en) | 2004-03-04 |
| WO2004018378A3 (en) | 2004-07-01 |
| US7687560B2 (en) | 2010-03-30 |
| DE60315262D1 (de) | 2007-09-13 |
| EP1483319B1 (en) | 2007-08-01 |
| CN1280342C (zh) | 2006-10-18 |
| JP2005526900A (ja) | 2005-09-08 |
| CA2478095A1 (en) | 2004-03-04 |
| CN1643049A (zh) | 2005-07-20 |
| US20050019536A1 (en) | 2005-01-27 |
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| 8364 | No opposition during term of opposition |