DE60305743T2 - Härtungsmittel für kationisch härtbare zusammensetzungen - Google Patents
Härtungsmittel für kationisch härtbare zusammensetzungen Download PDFInfo
- Publication number
- DE60305743T2 DE60305743T2 DE60305743T DE60305743T DE60305743T2 DE 60305743 T2 DE60305743 T2 DE 60305743T2 DE 60305743 T DE60305743 T DE 60305743T DE 60305743 T DE60305743 T DE 60305743T DE 60305743 T2 DE60305743 T2 DE 60305743T2
- Authority
- DE
- Germany
- Prior art keywords
- photochemically active
- anion
- accelerating
- inhibiting
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 150000003839 salts Chemical class 0.000 claims abstract description 137
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- 239000000178 monomer Substances 0.000 claims abstract description 35
- 150000001768 cations Chemical class 0.000 claims abstract description 34
- 238000000113 differential scanning calorimetry Methods 0.000 claims abstract description 7
- -1 tetraphenylborates Chemical class 0.000 claims description 66
- 238000000016 photochemical curing Methods 0.000 claims description 47
- 125000005409 triarylsulfonium group Chemical group 0.000 claims description 30
- 125000002091 cationic group Chemical group 0.000 claims description 24
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- 238000000034 method Methods 0.000 claims description 23
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- 125000004122 cyclic group Chemical group 0.000 claims description 7
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- 230000000694 effects Effects 0.000 claims description 6
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- 229910017008 AsF 6 Inorganic materials 0.000 claims description 5
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims description 5
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- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 claims description 4
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- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 6
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/687—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/681—Metal alcoholates, phenolates or carboxylates
- C08G59/685—Carboxylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyethers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (3)
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|---|---|---|---|
| US328520 | 1994-10-25 | ||
| US10/328,520 US6777460B2 (en) | 2002-12-23 | 2002-12-23 | Curing agents for cationically curable compositions |
| PCT/US2003/039810 WO2004060959A1 (en) | 2002-12-23 | 2003-12-15 | Curing agents for cationically curable compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60305743D1 DE60305743D1 (de) | 2006-07-06 |
| DE60305743T2 true DE60305743T2 (de) | 2007-05-16 |
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| DE60305743T Expired - Lifetime DE60305743T2 (de) | 2002-12-23 | 2003-12-15 | Härtungsmittel für kationisch härtbare zusammensetzungen |
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| US (2) | US6777460B2 (https=) |
| EP (1) | EP1587850B1 (https=) |
| JP (1) | JP5138870B2 (https=) |
| KR (1) | KR100994024B1 (https=) |
| AT (1) | ATE328022T1 (https=) |
| AU (1) | AU2003297082A1 (https=) |
| DE (1) | DE60305743T2 (https=) |
| WO (1) | WO2004060959A1 (https=) |
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| US20060108710A1 (en) * | 2004-11-24 | 2006-05-25 | Molecular Imprints, Inc. | Method to reduce adhesion between a conformable region and a mold |
| US7064152B2 (en) * | 2003-09-26 | 2006-06-20 | 3M Innovative Properties Company | Arylsulfinate salts in photoinitiator systems for polymerization reactions |
| US7030169B2 (en) * | 2003-09-26 | 2006-04-18 | 3M Innovative Properties Company | Arylsulfinate salts in initiator systems for polymeric reactions |
| US7026367B2 (en) * | 2003-09-26 | 2006-04-11 | 3M Innovative Properties Company | Photoiniators having triarylsulfonium and arylsulfinate ions |
| US20060088674A1 (en) * | 2004-10-27 | 2006-04-27 | Hladik Molly L | Ultraviolet curable barrier layers |
| US20080206478A1 (en) * | 2005-04-22 | 2008-08-28 | Sun Chemical Corporation | Ink Jet Ink |
| US7429800B2 (en) * | 2005-06-30 | 2008-09-30 | Sabic Innovative Plastics Ip B.V. | Molding composition and method, and molded article |
| US20070004871A1 (en) * | 2005-06-30 | 2007-01-04 | Qiwei Lu | Curable composition and method |
| US7378455B2 (en) * | 2005-06-30 | 2008-05-27 | General Electric Company | Molding composition and method, and molded article |
| US20070092733A1 (en) * | 2005-10-26 | 2007-04-26 | 3M Innovative Properties Company | Concurrently curable hybrid adhesive composition |
| JP2007148208A (ja) * | 2005-11-30 | 2007-06-14 | Sumitomo Chemical Co Ltd | 感放射線性樹脂組成物 |
| WO2007070976A1 (en) * | 2005-12-21 | 2007-06-28 | Carl Zeiss Vision Australia Holdings Limited | Coatings for optical elements |
| AU2013203003B2 (en) * | 2005-12-21 | 2014-10-02 | Carl Zeiss Vision Australia Holdings Limited | Coatings for optical elements |
| US7491287B2 (en) * | 2006-06-09 | 2009-02-17 | 3M Innovative Properties Company | Bonding method with flowable adhesive composition |
| US7714037B1 (en) | 2006-12-15 | 2010-05-11 | Henkel Corporation | Photoinitiated cationic epoxy compositions and articles exhibiting low color |
| US9456655B2 (en) * | 2008-09-26 | 2016-10-04 | Nike, Inc. | Systems and methods for stabilization of a phylon article |
| CN102224583B (zh) * | 2008-11-25 | 2014-09-10 | 洛德公司 | 使用光固化性材料保护晶片表面的方法 |
| US9093448B2 (en) | 2008-11-25 | 2015-07-28 | Lord Corporation | Methods for protecting a die surface with photocurable materials |
| US20110089839A1 (en) * | 2009-10-21 | 2011-04-21 | Chung-Chia Chen | System and method of indoor solar illumination |
| JP5684275B2 (ja) * | 2010-09-24 | 2015-03-11 | 電気化学工業株式会社 | エネルギー線硬化性樹脂組成物とそれを用いた接着剤及び硬化体 |
| WO2013084708A1 (ja) * | 2011-12-05 | 2013-06-13 | 協立化学産業株式会社 | ハードディスク装置組み立て用カチオン硬化型樹脂組成物 |
| CN108026444B (zh) | 2015-09-15 | 2020-08-04 | 3M创新有限公司 | 添加剂稳定的复合纳米粒子 |
| JP2018529832A (ja) | 2015-09-15 | 2018-10-11 | スリーエム イノベイティブ プロパティズ カンパニー | 添加剤安定化複合ナノ粒子 |
| EP3377591A1 (en) | 2015-11-18 | 2018-09-26 | 3M Innovative Properties Company | Copolymeric stabilizing carrier fluid for nanoparticles |
| WO2017142782A1 (en) | 2016-02-17 | 2017-08-24 | 3M Innovative Properties Company | Quantum dots with stabilizing fluorochemical copolymers |
| KR20180128956A (ko) | 2016-04-01 | 2018-12-04 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 플루오로케미칼 안정화제를 갖는 양자점 |
| KR20190009763A (ko) | 2016-05-20 | 2019-01-29 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 혼합 아민 및 티올 리간드를 갖는 양자점 |
| US11345849B2 (en) | 2016-07-20 | 2022-05-31 | 3M Innovative Properties Company | Stabilizing styrenic polymer for quantum dots |
| CN109476987A (zh) | 2016-07-20 | 2019-03-15 | 3M创新有限公司 | 用于量子点的稳定苯乙烯系聚合物 |
| WO2018167645A1 (en) | 2017-03-14 | 2018-09-20 | 3M Innovative Properties Company | Additive stabilized composite nanoparticles |
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| US3347676A (en) * | 1964-04-30 | 1967-10-17 | Du Pont | Photopolymerizable compositions and process |
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| GB1495746A (en) | 1974-07-05 | 1977-12-21 | Ciba Geigy Ag | Polymerisation of unsaturated amides |
| US4216288A (en) * | 1978-09-08 | 1980-08-05 | General Electric Company | Heat curable cationically polymerizable compositions and method of curing same with onium salts and reducing agents |
| US5089536A (en) * | 1982-11-22 | 1992-02-18 | Minnesota Mining And Manufacturing Company | Energy polmerizable compositions containing organometallic initiators |
| US4503211A (en) * | 1984-05-31 | 1985-03-05 | Minnesota Mining And Manufacturing Co. | Epoxy resin curing agent, process and composition |
| US4642126A (en) * | 1985-02-11 | 1987-02-10 | Norton Company | Coated abrasives with rapidly curable adhesives and controllable curvature |
| US4652274A (en) * | 1985-08-07 | 1987-03-24 | Minnesota Mining And Manufacturing Company | Coated abrasive product having radiation curable binder |
| US4707432A (en) * | 1985-09-23 | 1987-11-17 | Ciba-Geigy Corporation | Ferrocenium/alpha-cleavage photoinitiator systems for free radical polymerizable compositions |
| CA1323949C (en) * | 1987-04-02 | 1993-11-02 | Michael C. Palazzotto | Ternary photoinitiator system for addition polymerization |
| US4889792A (en) * | 1987-12-09 | 1989-12-26 | Minnesota Mining And Manufacturing Company | Ternary photoinitiator system for addition polymerization |
| US4985340A (en) * | 1988-06-01 | 1991-01-15 | Minnesota Mining And Manufacturing Company | Energy curable compositions: two component curing agents |
| US5084586A (en) * | 1990-02-12 | 1992-01-28 | Minnesota Mining And Manufacturing Company | Novel initiators for cationic polymerization |
| US5124417A (en) * | 1990-02-12 | 1992-06-23 | Minnesota Mining And Manufacturing Company | Initiators for cationic polymerization |
| JP3309419B2 (ja) * | 1992-02-25 | 2002-07-29 | 日本曹達株式会社 | 含窒素カチオン重合触媒及び含硫黄カチオン重合触媒を含有する硬化性組成物 |
| JPH07179511A (ja) * | 1993-12-22 | 1995-07-18 | Japan Carlit Co Ltd:The | 光重合性樹脂組成物 |
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| US5554664A (en) * | 1995-03-06 | 1996-09-10 | Minnesota Mining And Manufacturing Company | Energy-activatable salts with fluorocarbon anions |
| US5962546A (en) * | 1996-03-26 | 1999-10-05 | 3M Innovative Properties Company | Cationically polymerizable compositions capable of being coated by electrostatic assistance |
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| US6025406A (en) * | 1997-04-11 | 2000-02-15 | 3M Innovative Properties Company | Ternary photoinitiator system for curing of epoxy resins |
| US6265459B1 (en) * | 1998-12-31 | 2001-07-24 | 3M Innovative Properties Company | Accelerators useful for energy polymerizable compositions |
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| JP4907821B2 (ja) * | 1999-12-07 | 2012-04-04 | スリーエム イノベイティブ プロパティズ カンパニー | 加水分解性ハロゲン化物および他の高分子量材料を含有する材料をエピハロヒドリン誘導エポキシ樹脂から除去する方法 |
| US6635689B1 (en) * | 2000-06-26 | 2003-10-21 | 3M Innovative Properties Company | Accelerators for cationic polymerization catalyzed by iron-based catalysts |
-
2002
- 2002-12-23 US US10/328,520 patent/US6777460B2/en not_active Expired - Lifetime
-
2003
- 2003-12-15 AT AT03814786T patent/ATE328022T1/de not_active IP Right Cessation
- 2003-12-15 DE DE60305743T patent/DE60305743T2/de not_active Expired - Lifetime
- 2003-12-15 JP JP2004565473A patent/JP5138870B2/ja not_active Expired - Fee Related
- 2003-12-15 KR KR1020057011773A patent/KR100994024B1/ko not_active Expired - Fee Related
- 2003-12-15 WO PCT/US2003/039810 patent/WO2004060959A1/en not_active Ceased
- 2003-12-15 AU AU2003297082A patent/AU2003297082A1/en not_active Abandoned
- 2003-12-15 EP EP03814786A patent/EP1587850B1/en not_active Expired - Lifetime
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2004
- 2004-07-16 US US10/893,444 patent/US20050004246A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US6777460B2 (en) | 2004-08-17 |
| US20040122122A1 (en) | 2004-06-24 |
| KR100994024B1 (ko) | 2010-11-11 |
| JP5138870B2 (ja) | 2013-02-06 |
| US20050004246A1 (en) | 2005-01-06 |
| JP2006511670A (ja) | 2006-04-06 |
| AU2003297082A1 (en) | 2004-07-29 |
| EP1587850B1 (en) | 2006-05-31 |
| ATE328022T1 (de) | 2006-06-15 |
| DE60305743D1 (de) | 2006-07-06 |
| EP1587850A1 (en) | 2005-10-26 |
| KR20050087849A (ko) | 2005-08-31 |
| WO2004060959A1 (en) | 2004-07-22 |
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