DE60238851D1 - Hydrogenolyse von c-5-zuckern und c-5-zuckeralkoholen - Google Patents

Hydrogenolyse von c-5-zuckern und c-5-zuckeralkoholen

Info

Publication number
DE60238851D1
DE60238851D1 DE60238851T DE60238851T DE60238851D1 DE 60238851 D1 DE60238851 D1 DE 60238851D1 DE 60238851 T DE60238851 T DE 60238851T DE 60238851 T DE60238851 T DE 60238851T DE 60238851 D1 DE60238851 D1 DE 60238851D1
Authority
DE
Germany
Prior art keywords
sugar
hydrogenolysis
alcohols
lactate
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60238851T
Other languages
English (en)
Inventor
Todd A Werpy
John G Frye
Alan H Zacher
Dennis J Miller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Battelle Memorial Institute Inc
Original Assignee
Battelle Memorial Institute Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Battelle Memorial Institute Inc filed Critical Battelle Memorial Institute Inc
Application granted granted Critical
Publication of DE60238851D1 publication Critical patent/DE60238851D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Saccharide Compounds (AREA)
  • Catalysts (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
DE60238851T 2001-10-23 2002-10-23 Hydrogenolyse von c-5-zuckern und c-5-zuckeralkoholen Expired - Lifetime DE60238851D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/012,890 US6479713B1 (en) 2001-10-23 2001-10-23 Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen
PCT/US2002/033983 WO2003035593A1 (en) 2001-10-23 2002-10-23 Hydrogenolysis of 5-carbon sugars and alcohols

Publications (1)

Publication Number Publication Date
DE60238851D1 true DE60238851D1 (de) 2011-02-17

Family

ID=21757243

Family Applications (2)

Application Number Title Priority Date Filing Date
DE60238726T Expired - Lifetime DE60238726D1 (de) 2001-10-23 2002-10-23 Zusammensetzung enthaltend Zucker oder Zuckeralkohole
DE60238851T Expired - Lifetime DE60238851D1 (de) 2001-10-23 2002-10-23 Hydrogenolyse von c-5-zuckern und c-5-zuckeralkoholen

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE60238726T Expired - Lifetime DE60238726D1 (de) 2001-10-23 2002-10-23 Zusammensetzung enthaltend Zucker oder Zuckeralkohole

Country Status (6)

Country Link
US (3) US6479713B1 (de)
EP (4) EP1935487B1 (de)
AT (2) ATE494270T1 (de)
DE (2) DE60238726D1 (de)
ES (2) ES2386002T3 (de)
WO (1) WO2003035593A1 (de)

Families Citing this family (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6670300B2 (en) * 2001-06-18 2003-12-30 Battelle Memorial Institute Textured catalysts, methods of making textured catalysts, and methods of catalyzing reactions conducted in hydrothermal conditions
US6479713B1 (en) * 2001-10-23 2002-11-12 Battelle Memorial Institute Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen
US6841085B2 (en) * 2001-10-23 2005-01-11 Battelle Memorial Institute Hydrogenolysis of 6-carbon sugars and other organic compounds
BR0214560A (pt) * 2001-11-29 2004-11-09 Wisconsin Alumni Res Found Produção de hidrogênio à baixa temperatura a partir de hidrocarbonetos oxigenados
GB0325386D0 (en) * 2003-10-30 2003-12-03 Davy Process Techn Ltd Process
US7131446B2 (en) * 2004-03-25 2006-11-07 Tang Kenneth Y Light-triggered tattoo process
US7678950B2 (en) * 2005-12-16 2010-03-16 Conocophillips Company Process for converting carbohydrates to hydrocarbons
US8450542B2 (en) * 2005-12-16 2013-05-28 Phillips 66 Company Integrated process for converting carbohydrates to hydrocarbons
KR101364280B1 (ko) 2005-12-21 2014-02-18 바이렌트, 아이엔씨. 산소화 화합물의 개질을 위한 촉매 및 방법
UA95628C2 (ru) 2006-05-08 2011-08-25 Вайрент Энерджи Системз, Инк. Способы получения оксигенированного соединения и пропиленгликоля, реакторная система для получения оксигенированных соединений (варианты)
US7619118B2 (en) 2006-06-07 2009-11-17 The Procter & Gamble Company Process for the conversion of glycerol to propylene glycol and amino alcohols
US7619119B2 (en) * 2006-06-07 2009-11-17 The Procter & Gamble Company Processes for converting glycerol to amino alcohols
EP2024319B1 (de) * 2006-06-07 2013-10-23 The Procter and Gamble Company Verfahren zur umwandlung von glycerol in propylenglycol und aminoalkohole
DE102007027374A1 (de) 2007-06-11 2008-12-18 Cognis Oleochemicals Gmbh Verfahren zur Herstellung von 1,2-Propandiol
WO2008051540A2 (en) * 2006-10-23 2008-05-02 Archer-Daniels-Midland Company Hydrogenolysis of glycerol and products produced therefrom
WO2008049440A1 (en) * 2006-10-26 2008-05-02 Oü Nordbiochem Production of organic solvents, monomers and polymers from fermentable carbohydrate materials
US20080103340A1 (en) * 2006-10-27 2008-05-01 Archer-Daniels-Midland Company Applications of biobased glycol compositions
EP2038243A1 (de) * 2006-10-27 2009-03-25 Archer-Daniels-Midland Company Verfahren zur isolierung oder reinigung von propylenglycol, ethylenglcyol und daraus hergestellten produkten
JP5231786B2 (ja) * 2006-12-05 2013-07-10 花王株式会社 多価アルコールの水素化分解物の製造方法
WO2008071641A1 (de) * 2006-12-15 2008-06-19 Basf Se Verfahren zur herstellung von 1,2-ethylenglycol und 1,2-propylenglycol durch heterogen katalysierte hydrogenolyse eines polyols
WO2008071642A1 (de) * 2006-12-15 2008-06-19 Basf Se Verfahren zur herstellung von 1,2-ethylenglycol und 1,2-propylenglycol durch heterogen katalysierte hydrogenolyse eines polyols
WO2008071616A1 (de) * 2006-12-15 2008-06-19 Basf Se Verfahren zur herstellung von 1,2-ethylenglycol und 1,2-propylenglycol durch heterogen katalysierte hydrogenolyse eines polyols
AU2007353527B2 (en) * 2006-12-20 2012-12-20 Virent, Inc. Reactor system for producing gaseous products
NZ579525A (en) * 2007-03-08 2011-12-22 Virent Inc Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
RU2472840C2 (ru) 2007-03-08 2013-01-20 Вайрент, Инк. Синтез жидкого топлива и химических реактивов из кислородсодержащих углеводородов
US20090088317A1 (en) * 2007-09-28 2009-04-02 Frye Jr John G Multi-metal reduction catalysts and methods of producing reduction catalysts
AR072446A1 (es) * 2008-03-02 2010-09-01 Dow Global Technologies Inc Proceso de hidrogenacion mejorado
US20090246430A1 (en) 2008-03-28 2009-10-01 The Coca-Cola Company Bio-based polyethylene terephthalate polymer and method of making same
CN101255098B (zh) * 2008-04-11 2010-04-14 清华大学 一种从丙三醇直接加氢制备丙二醇的方法
US20090264686A1 (en) * 2008-04-16 2009-10-22 Holladay Johnathan E Hydrogenolysis processes and hydrogenolysis catalyst preparation methods
US20090264687A1 (en) 2008-04-16 2009-10-22 Battelle Memorial Institute Chemical Production Processes and Systems
CA2736800A1 (en) 2008-08-27 2010-03-04 Randy D. Cortright Synthesis of liquid fuels from biomass
US8697924B2 (en) * 2008-09-05 2014-04-15 Shell Oil Company Liquid fuel compositions
US8101807B2 (en) * 2008-12-23 2012-01-24 Uop Llc Methods for converting glycerol to propanol
BRPI1009218A2 (pt) * 2009-03-02 2016-03-15 Süd Chemie Inc conversão de açúcar, álcool de açúcar ou glicerina em produtos químicos valiosos usando um catalisador sobre suporte de óxido de zircônio promovido
LT2403894T (lt) 2009-03-03 2016-09-26 The Coca-Cola Company Biologinės kilmės polietileno tereftalamo pakuotė ir jos gamybos būdas
PT2419393E (pt) 2009-04-16 2013-10-21 Biochemtex Spa Método para a hidrogenólise de álcoois derivados de açúcar
US20110009614A1 (en) 2009-06-30 2011-01-13 Paul George Blommel Processes and reactor systems for converting sugars and sugar alcohols
WO2011025632A1 (en) 2009-08-24 2011-03-03 Conocophillips Company Hydrotreating carbohydrates
EE200900073A (et) 2009-09-22 2011-06-15 Nordbiochem O� Katalsaator ja meetod hdrokskarbokslhapete estrite kataltiliseks hdrogeenimiseks glkoolideks
CA2779140C (en) * 2009-12-22 2017-11-21 Jianhua Yao Conversion of carbohydrates to hydrocarbons
KR20120124427A (ko) 2009-12-30 2012-11-13 바이렌트, 아이엔씨. 폴리올의 산소환원 수소처리를 위한 개선된 촉매
US9447347B2 (en) 2009-12-31 2016-09-20 Shell Oil Company Biofuels via hydrogenolysis-condensation
US9303226B2 (en) * 2009-12-31 2016-04-05 Shell Oil Company Direct aqueous phase reforming of bio-based feedstocks
US8937202B2 (en) * 2010-02-23 2015-01-20 Battelle Memorial Institute Processes and systems for the production of propylene glycol from glycerol
US20110207972A1 (en) * 2010-02-23 2011-08-25 Battelle Memorial Institute Catalysts and processes for the hydrogenolysis of glycerol and other organic compounds for producing polyols and propylene glycol
JP2013521221A (ja) * 2010-03-03 2013-06-10 ズードケミー インコーポレイテッド 活性酸化ジルコニウム支持触媒を用いた、糖、糖アルコール、又はグリセロールの、価値のある化学物質への変換
CA2798492A1 (en) 2010-05-12 2011-11-17 Juben Nemchand Chheda Process including hydrogenolysis of biomass followed by dehydrogenation and aldol condensation for producing alkanes
CA2798491A1 (en) 2010-05-12 2011-11-17 Juben Nemchand Chheda Process including hydrogenolysis of biomass followed by dehydrogenation and aldol condensation to produce alkanes
IL207945A0 (en) 2010-09-02 2010-12-30 Robert Jansen Method for the production of carbohydrates
US8809607B2 (en) 2010-10-07 2014-08-19 Phillips 66 Company Co-production of renewable diesel and renewable gasoline
KR20140004733A (ko) * 2011-01-24 2014-01-13 바스프 에스이 탄소상 니켈을 포함하는 수소화 촉매
WO2012125276A2 (en) 2011-03-14 2012-09-20 Archer Daniels Midland Company Improved methods for producing bioderived propylene glycol
AU2012253913B2 (en) * 2011-05-11 2017-03-02 Archer Daniels Midland Company Processes for making acrylic-type monomers and products made therefrom
JP5827925B2 (ja) * 2011-06-06 2015-12-02 株式会社ダイセル エリスリトールの水素化分解物の製造方法
US9617608B2 (en) 2011-10-10 2017-04-11 Virdia, Inc. Sugar compositions
AT511965B1 (de) * 2011-10-11 2013-04-15 Amitava Dipl Ing Dr Kundu Verfahren zur herstellung von milchsäure
US8946458B2 (en) 2012-08-15 2015-02-03 Virent, Inc. Catalysts for hydrodeoxygenation of oxygenated hydrocarbons
US10131604B2 (en) 2012-08-15 2018-11-20 Virent, Inc. Catalysts for hydrodeoxygenation of oxygenated hydrocarbons
US9205412B2 (en) 2013-03-01 2015-12-08 Clariant Corporation Catalyst for polyol hydrogenolysis
US20140275638A1 (en) * 2013-03-15 2014-09-18 Wisconsin Alumni Research Foundation Method for preparing triols and diols from biomass-derived reactants
CN104275181A (zh) * 2013-07-10 2015-01-14 清华大学 一种用于丙三醇氢解制丙二醇的Pd-Re催化剂及其制备方法
CN105873885B (zh) 2014-02-03 2018-07-13 巴特尔纪念研究院 2,3-丁二醇到丁二烯的转化
EP3110780A1 (de) * 2014-02-24 2017-01-04 Biochemtex S.p.A. Integriertes verfahren zur herstellung von cellulosepulpe und polyolenstrom
CN106232562B (zh) 2014-04-22 2019-01-15 阿彻丹尼尔斯米德兰德公司 制造生物衍生的丙二醇的改进的方法
US11253839B2 (en) 2014-04-29 2022-02-22 Archer-Daniels-Midland Company Shaped porous carbon products
WO2016081187A1 (en) 2014-11-18 2016-05-26 Archer Daniels Midland Co Process for making biobased propylene glycol from lactic acid esters
ES2764499T3 (es) 2015-01-07 2020-06-03 Virdia Inc Métodos para extraer y convertir azúcares de hemicelulosa
US9597667B2 (en) 2015-03-26 2017-03-21 North Carolina State University Palladium, rhenium and alumina catalysts for the selective hydrogenation of carbonyls, their synthesis, and methods of using the same
JP6651196B2 (ja) * 2015-06-17 2020-02-19 出光興産株式会社 Ｃ５＋化合物の製造方法
WO2017011615A1 (en) 2015-07-15 2017-01-19 Archer Daniels Midland Company Improved copper-containing multimetallic catalysts, and method for using the same to make biobased 1,2-propanediol
US20190367436A1 (en) * 2017-01-13 2019-12-05 Archer Daniels Midland Company Improved process of making bioderived propylene glycol
DE102017204322A1 (de) 2017-03-15 2018-09-20 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zur chemischen Umsetzung von Zuckern oder Zuckeralkoholen zu Glykolen
DE102018215394A1 (de) 2018-09-11 2020-03-12 Rheinisch-Westfälische Technische Hochschule Aachen Verfahren zur chemischen Umsetzung von Zuckern oder Zuckeralkoholen zu Glykolen
DE102019113135A1 (de) 2019-05-17 2020-11-19 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zur Herstellung von Glycolen aus Zuckern und Zuckeralkoholen
BR112022005612A2 (pt) 2019-09-24 2022-07-19 Iowa Corn Promotion Board Processo contínuo
CN110813297B (zh) * 2019-10-15 2021-04-30 厦门大学 一种糖醇的合成方法
EP4153550A1 (de) 2020-05-18 2023-03-29 Archer Daniels Midland Company Verfahren zur hydrogenolyse von glycerol
US11319269B2 (en) 2020-09-24 2022-05-03 Iowa Corn Promotion Board Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
US11680031B2 (en) 2020-09-24 2023-06-20 T. EN Process Technology, Inc. Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2852570A (en) 1958-09-16 Process for preparing polyhydric
US3030429A (en) 1962-04-17 Process for the direct hydrogenation splitting of
US2852270A (en) 1956-01-03 1958-09-16 Hunt Russell Garnsey Safety belt apparatus for vehicles
US4104478A (en) * 1977-11-23 1978-08-01 Ashland Oil, Inc. Catalytic hydrogenation of fatty acids
US4366332A (en) 1981-01-21 1982-12-28 Hydrocarbon Research, Inc. Catalytic hydrogenolysis of alditols to product glycerol and polyols
US4338472A (en) 1981-01-21 1982-07-06 Hydrocarbon Research, Inc. Catalytic hydrogenolysis of alditols to produce polyols
US4401823A (en) 1981-05-18 1983-08-30 Uop Inc. Hydrogenolysis of polyhydroxylated compounds
US4404411A (en) 1982-02-01 1983-09-13 E. I. Du Pont De Nemours And Company Hydrogenolysis of polyols to ethylene glycol in nonaqueous solvents
US4476331A (en) 1982-02-11 1984-10-09 Ethyl Corporation Two stage hydrogenolysis of carbohydrate to glycols using sulfide modified ruthenium catalyst in second stage
JPS58193735A (ja) * 1982-05-06 1983-11-11 Ube Ind Ltd 低級ヒドロキシカルボン酸エステルの水素添加用触媒の製法
US4496780A (en) 1983-06-22 1985-01-29 Uop Inc. Hydrocracking of polyols
CA2004040A1 (en) 1988-12-15 1990-06-15 Jerry A. Broussard Formaldehyde resistant catalyst for hydrogenation and hydrogenolysis of aldehydes, acetals, and esters
IT1256800B (it) 1992-01-31 1995-12-15 Novamont Spa Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento.
IT1256802B (it) 1992-01-31 1995-12-15 Novamont Spa Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'drogenazione e/o idrogenolisi di carboidrati e polioli.
IT1256801B (it) 1992-01-31 1995-12-15 Novamont Spa Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'idrogenazione e/o idrogenolisi di carboidrati e polioli.
US5401645A (en) * 1992-03-16 1995-03-28 Monsanto Company Process for producing n-substituted polyhydroxy nitrogen-containing heterocycles utilizing acetobacteraceae and corynebacterium
US5695261A (en) * 1996-04-12 1997-12-09 Slesinger; Bruce M. Integrally powered modular furniture
US5856261A (en) * 1997-04-22 1999-01-05 Exxon Research And Engineering Company Preparation of high activity catalysts; the catalysts and their use
US6455742B1 (en) * 1999-09-02 2002-09-24 Wisconsin Alumni Research Foundation Method for catalytically reducing carboxylic acid groups to hydroxyl groups in hydroxycarboxylic acids
US6291725B1 (en) 2000-03-03 2001-09-18 Board Of Trustees Operating Michigan State University Catalysts and process for hydrogenolysis of sugar alcohols to polyols
US6479713B1 (en) * 2001-10-23 2002-11-12 Battelle Memorial Institute Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen

Also Published As

Publication number Publication date
US7038094B2 (en) 2006-05-02
EP1939161A1 (de) 2008-07-02
ATE492340T1 (de) 2011-01-15
EP1440048B1 (de) 2011-01-05
DE60238726D1 (de) 2011-02-03
EP1942092A1 (de) 2008-07-09
ATE494270T1 (de) 2011-01-15
US20030130545A1 (en) 2003-07-10
US6479713B1 (en) 2002-11-12
WO2003035593A1 (en) 2003-05-01
ES2386002T3 (es) 2012-08-07
WO2003035593B1 (en) 2003-11-13
ES2384214T3 (es) 2012-07-02
EP1935487A1 (de) 2008-06-25
EP1935487B1 (de) 2010-12-22
EP1440048A1 (de) 2004-07-28
US6677385B2 (en) 2004-01-13
US20040064003A1 (en) 2004-04-01

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