DE60227387D1 - HYDROTHERMISCH STABILER, METALL DOTIERTER ZEOLITH BETA ZUR REDUKTION VON NOx - Google Patents
HYDROTHERMISCH STABILER, METALL DOTIERTER ZEOLITH BETA ZUR REDUKTION VON NOxInfo
- Publication number
- DE60227387D1 DE60227387D1 DE60227387T DE60227387T DE60227387D1 DE 60227387 D1 DE60227387 D1 DE 60227387D1 DE 60227387 T DE60227387 T DE 60227387T DE 60227387 T DE60227387 T DE 60227387T DE 60227387 D1 DE60227387 D1 DE 60227387D1
- Authority
- DE
- Germany
- Prior art keywords
- iron
- zeolite beta
- promoted
- hydrothermic
- dotted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 7
- 229910021536 Zeolite Inorganic materials 0.000 abstract 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 5
- 239000010457 zeolite Substances 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000010531 catalytic reduction reaction Methods 0.000 abstract 1
- 238000005341 cation exchange Methods 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- -1 hydrogen cations Chemical class 0.000 abstract 1
- 150000002505 iron Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/7615—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/24—After treatment, characterised by the effect to be obtained to stabilize the molecular sieve structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/10—Infrared [IR]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7057—Zeolite Beta
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/948,236 US6914026B2 (en) | 2001-09-07 | 2001-09-07 | Hydrothermally stable metal promoted zeolite beta for NOx reduction |
PCT/US2002/026308 WO2003022430A2 (en) | 2001-09-07 | 2002-08-16 | HYDROTHERMALLY STABLE METAL PROMOTED ZEOLITE BETA FOR NOx REDUCTION |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60227387D1 true DE60227387D1 (de) | 2008-08-14 |
Family
ID=25487519
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60227387T Expired - Lifetime DE60227387D1 (de) | 2001-09-07 | 2002-08-16 | HYDROTHERMISCH STABILER, METALL DOTIERTER ZEOLITH BETA ZUR REDUKTION VON NOx |
Country Status (7)
Country | Link |
---|---|
US (2) | US6914026B2 (de) |
EP (3) | EP1425099B2 (de) |
JP (1) | JP2005502451A (de) |
KR (1) | KR20040034701A (de) |
AT (1) | ATE399592T1 (de) |
DE (1) | DE60227387D1 (de) |
WO (1) | WO2003022430A2 (de) |
Families Citing this family (81)
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US7229597B2 (en) * | 2003-08-05 | 2007-06-12 | Basfd Catalysts Llc | Catalyzed SCR filter and emission treatment system |
US7501105B2 (en) * | 2004-07-29 | 2009-03-10 | N.E. Chemcat Corporation | NOx reduction catalyst having excellent low-temperature characteristics |
JP2006136776A (ja) * | 2004-11-10 | 2006-06-01 | Toyota Central Res & Dev Lab Inc | NOx選択還元触媒 |
US7585490B2 (en) * | 2005-04-15 | 2009-09-08 | University Of Iowa Research Foundation | Synthesis and use of nanocrystalline zeolites |
RU2008128363A (ru) * | 2005-12-14 | 2010-01-20 | Басф Каталистс Ллк (Us) | ЦЕОЛИТНЫЙ КАТАЛИЗАТОР С УЛУЧШЕННЫМ ВОССТАНОВЛЕНИЕМ NOх В SCR |
JP4617253B2 (ja) * | 2005-12-26 | 2011-01-19 | エヌ・イーケムキャット株式会社 | 脱硝触媒、ハニカム構造型脱硝触媒、及びそれを用いた脱硝方法 |
US8568678B2 (en) * | 2006-07-08 | 2013-10-29 | Umicore Ag & Co. Kg | Structured SCR catalyst for the reduction of nitrogen oxides in the exhaust gas from lean-burn engines using ammonia as reducing agent |
DE102006031724B3 (de) * | 2006-07-08 | 2008-04-30 | Umicore Ag & Co. Kg | Strukturierter SCR-Katalysator zur Reduktion von Stickoxiden im Abgas von Magermotoren unter Verwendung von Ammoniak als Reduktionsmittel |
DE102006037314A1 (de) * | 2006-08-08 | 2008-02-14 | Süd-Chemie AG | Verwendung eines Katalysators auf Basis von Zeolithen bei der Umsetzung von Oxygenaten zu niederen Olefinen sowie Verfahren hierzu |
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JP4957176B2 (ja) * | 2006-10-24 | 2012-06-20 | 東ソー株式会社 | 窒素酸化物浄化触媒及び窒素酸化物浄化方法 |
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US10384162B2 (en) | 2007-03-26 | 2019-08-20 | Pq Corporation | High silica chabazite for selective catalytic reduction, methods of making and using same |
EP3626329B1 (de) * | 2007-04-26 | 2021-10-27 | Johnson Matthey Public Limited Company | Abgassystem mit scr-kupfer/zsm-34-zeolithkatalysator und verfahren zur stickoxidumwandlung |
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BR112022001106A2 (pt) * | 2019-08-29 | 2022-05-03 | Basf Corp | Método para formar um catalisador de redução catalítica seletiva (scr), zeólito promovido por ferro, composição do catalisador de redução catalítica seletiva (scr), sistema de tratamento de gases de exaustão de motor e método de remoção de óxidos de nitrogênio |
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-
2001
- 2001-09-07 US US09/948,236 patent/US6914026B2/en not_active Expired - Lifetime
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2002
- 2002-08-16 EP EP02757214.8A patent/EP1425099B2/de not_active Expired - Lifetime
- 2002-08-16 EP EP20165581.8A patent/EP3708252A1/de active Pending
- 2002-08-16 KR KR10-2004-7003350A patent/KR20040034701A/ko not_active Application Discontinuation
- 2002-08-16 AT AT02757214T patent/ATE399592T1/de active
- 2002-08-16 JP JP2003526550A patent/JP2005502451A/ja active Pending
- 2002-08-16 EP EP06076601.1A patent/EP1754527B1/de not_active Expired - Lifetime
- 2002-08-16 WO PCT/US2002/026308 patent/WO2003022430A2/en active Application Filing
- 2002-08-16 DE DE60227387T patent/DE60227387D1/de not_active Expired - Lifetime
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EP3708252A1 (de) | 2020-09-16 |
US20050124486A1 (en) | 2005-06-09 |
ATE399592T1 (de) | 2008-07-15 |
EP1425099B2 (de) | 2013-11-27 |
EP1754527A3 (de) | 2007-08-08 |
KR20040034701A (ko) | 2004-04-28 |
WO2003022430A2 (en) | 2003-03-20 |
US7182927B2 (en) | 2007-02-27 |
WO2003022430A3 (en) | 2003-08-21 |
EP1425099A2 (de) | 2004-06-09 |
EP1754527A2 (de) | 2007-02-21 |
US6914026B2 (en) | 2005-07-05 |
US20030050182A1 (en) | 2003-03-13 |
EP1425099B1 (de) | 2008-07-02 |
JP2005502451A (ja) | 2005-01-27 |
EP1754527B1 (de) | 2020-04-01 |
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