DE60211381T2 - Kern-schale-fluorpolymer-dispersionen - Google Patents
Kern-schale-fluorpolymer-dispersionen Download PDFInfo
- Publication number
- DE60211381T2 DE60211381T2 DE2002611381 DE60211381T DE60211381T2 DE 60211381 T2 DE60211381 T2 DE 60211381T2 DE 2002611381 DE2002611381 DE 2002611381 DE 60211381 T DE60211381 T DE 60211381T DE 60211381 T2 DE60211381 T2 DE 60211381T2
- Authority
- DE
- Germany
- Prior art keywords
- polytetrafluoroethylene
- dispersion
- particles
- creep viscosity
- shell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 144
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 61
- 239000004811 fluoropolymer Substances 0.000 title claims abstract description 61
- 239000011258 core-shell material Substances 0.000 title description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 135
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 135
- 239000002245 particle Substances 0.000 claims abstract description 107
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 79
- 239000012736 aqueous medium Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 49
- 239000003999 initiator Substances 0.000 claims description 47
- 239000004094 surface-active agent Substances 0.000 claims description 35
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 32
- 239000004744 fabric Substances 0.000 claims description 29
- 239000011521 glass Substances 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 18
- 239000000155 melt Substances 0.000 claims description 17
- 239000008199 coating composition Substances 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 15
- 238000001879 gelation Methods 0.000 claims description 14
- 239000002270 dispersing agent Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 238000011049 filling Methods 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000010923 batch production Methods 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 description 37
- 238000000576 coating method Methods 0.000 description 31
- 239000007787 solid Substances 0.000 description 28
- 238000006116 polymerization reaction Methods 0.000 description 25
- 229920005989 resin Polymers 0.000 description 23
- 239000011347 resin Substances 0.000 description 23
- 238000012360 testing method Methods 0.000 description 20
- 239000011248 coating agent Substances 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 11
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 11
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 description 9
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 8
- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- 229920006362 Teflon® Polymers 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 4
- GVEUEBXMTMZVSD-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,6-nonafluorohex-1-ene Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C GVEUEBXMTMZVSD-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 4
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 4
- 230000001427 coherent effect Effects 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000012674 dispersion polymerization Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 4
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000007766 curtain coating Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 230000003797 telogen phase Effects 0.000 description 3
- JYCQQPHGFMYQCF-UHFFFAOYSA-N 4-tert-Octylphenol monoethoxylate Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCO)C=C1 JYCQQPHGFMYQCF-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910001347 Stellite Inorganic materials 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920002113 octoxynol Polymers 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000467686 Eschscholzia lobbii Species 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010022998 Irritability Diseases 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 239000013504 Triton X-100 Substances 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000002547 anomalous effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- AHICWQREWHDHHF-UHFFFAOYSA-N chromium;cobalt;iron;manganese;methane;molybdenum;nickel;silicon;tungsten Chemical compound C.[Si].[Cr].[Mn].[Fe].[Co].[Ni].[Mo].[W] AHICWQREWHDHHF-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007771 core particle Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 230000002600 fibrillogenic effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007719 peel strength test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34529902P | 2002-01-04 | 2002-01-04 | |
| US345299P | 2002-01-04 | ||
| PCT/US2002/009018 WO2003062291A1 (en) | 2002-01-04 | 2002-03-13 | Core-shell fluoropolymer dispersions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60211381D1 DE60211381D1 (de) | 2006-06-14 |
| DE60211381T2 true DE60211381T2 (de) | 2007-05-24 |
Family
ID=27613219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2002611381 Expired - Lifetime DE60211381T2 (de) | 2002-01-04 | 2002-03-13 | Kern-schale-fluorpolymer-dispersionen |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6841594B2 (https=) |
| EP (1) | EP1470171B1 (https=) |
| JP (1) | JP4384913B2 (https=) |
| CN (1) | CN1315898C (https=) |
| AT (1) | ATE325825T1 (https=) |
| BR (1) | BR0215427B1 (https=) |
| CA (1) | CA2472135A1 (https=) |
| DE (1) | DE60211381T2 (https=) |
| ES (1) | ES2264480T3 (https=) |
| MX (1) | MXPA04006499A (https=) |
| WO (1) | WO2003062291A1 (https=) |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR0208247A (pt) * | 2001-03-13 | 2004-03-02 | Du Pont | Dispersão, pó de fluoropolìmero, composição de revestimento, substrato revestido, filme auto-sustentável e processo em batelada |
| JP5135658B2 (ja) * | 2001-08-02 | 2013-02-06 | ダイキン工業株式会社 | ポリテトラフルオロエチレンファインパウダー、それから得られるポリテトラフルオロエチレン成形体およびその製造方法 |
| US6956078B2 (en) * | 2002-01-04 | 2005-10-18 | E.I. Du Pont De Nemours And Company | Concentrated fluoropolymer dispersions |
| US7361708B2 (en) | 2002-05-20 | 2008-04-22 | Daikin Industries, Ltd. | Fluorinated resin water dispersion composition and fluorinated water base coating composition |
| US7247690B2 (en) * | 2003-04-17 | 2007-07-24 | E. I. Du Pont De Nemours And Company | Melt-fabricable tetrafluoroethylene/fluorinated vinyl ether copolymer prepared by suspension polymerization |
| US20070122698A1 (en) | 2004-04-02 | 2007-05-31 | Maxwell Technologies, Inc. | Dry-particle based adhesive and dry film and methods of making same |
| US20050266298A1 (en) * | 2003-07-09 | 2005-12-01 | Maxwell Technologies, Inc. | Dry particle based electro-chemical device and methods of making same |
| US7342770B2 (en) * | 2003-07-09 | 2008-03-11 | Maxwell Technologies, Inc. | Recyclable dry particle based adhesive electrode and methods of making same |
| US7295423B1 (en) | 2003-07-09 | 2007-11-13 | Maxwell Technologies, Inc. | Dry particle based adhesive electrode and methods of making same |
| US7791860B2 (en) | 2003-07-09 | 2010-09-07 | Maxwell Technologies, Inc. | Particle based electrodes and methods of making same |
| US20110165318A9 (en) * | 2004-04-02 | 2011-07-07 | Maxwell Technologies, Inc. | Electrode formation by lamination of particles onto a current collector |
| US7352558B2 (en) * | 2003-07-09 | 2008-04-01 | Maxwell Technologies, Inc. | Dry particle based capacitor and methods of making same |
| US7508651B2 (en) | 2003-07-09 | 2009-03-24 | Maxwell Technologies, Inc. | Dry particle based adhesive and dry film and methods of making same |
| US20050250011A1 (en) * | 2004-04-02 | 2005-11-10 | Maxwell Technologies, Inc. | Particle packaging systems and methods |
| US7920371B2 (en) | 2003-09-12 | 2011-04-05 | Maxwell Technologies, Inc. | Electrical energy storage devices with separator between electrodes and methods for fabricating the devices |
| US7495349B2 (en) | 2003-10-20 | 2009-02-24 | Maxwell Technologies, Inc. | Self aligning electrode |
| EP1533325B1 (en) * | 2003-11-17 | 2011-10-19 | 3M Innovative Properties Company | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
| US7347960B2 (en) * | 2003-12-31 | 2008-03-25 | E. I. Du Pont De Nemours And Company | Dispersion spinning core-shell fluoropolymers |
| US7384433B2 (en) | 2004-02-19 | 2008-06-10 | Maxwell Technologies, Inc. | Densification of compressible layers during electrode lamination |
| US7090946B2 (en) | 2004-02-19 | 2006-08-15 | Maxwell Technologies, Inc. | Composite electrode and method for fabricating same |
| US7227737B2 (en) | 2004-04-02 | 2007-06-05 | Maxwell Technologies, Inc. | Electrode design |
| US20060246343A1 (en) * | 2004-04-02 | 2006-11-02 | Maxwell Technologies, Inc. | Dry particle packaging systems and methods of making same |
| EP1614731B1 (en) * | 2004-07-05 | 2008-08-27 | 3M Innovative Properties Company | Primer coating of PTFE for metal substrates |
| US7245478B2 (en) | 2004-08-16 | 2007-07-17 | Maxwell Technologies, Inc. | Enhanced breakdown voltage electrode |
| US7440258B2 (en) | 2005-03-14 | 2008-10-21 | Maxwell Technologies, Inc. | Thermal interconnects for coupling energy storage devices |
| US7492574B2 (en) | 2005-03-14 | 2009-02-17 | Maxwell Technologies, Inc. | Coupling of cell to housing |
| US7147634B2 (en) | 2005-05-12 | 2006-12-12 | Orion Industries, Ltd. | Electrosurgical electrode and method of manufacturing same |
| US8814861B2 (en) | 2005-05-12 | 2014-08-26 | Innovatech, Llc | Electrosurgical electrode and method of manufacturing same |
| US7612139B2 (en) | 2005-05-20 | 2009-11-03 | E.I. Du Pont De Nemours And Company | Core/shell fluoropolymer dispersions with low fluorosurfactant content |
| US20070117929A1 (en) | 2005-11-18 | 2007-05-24 | Burch Heidi E | Fluoropolymer composition |
| WO2007061914A1 (en) * | 2005-11-18 | 2007-05-31 | E.I. Du Pont De Nemours And Company | Core/shell polymer |
| CN101309951B (zh) * | 2005-11-18 | 2011-09-07 | 纳幕尔杜邦公司 | 含氟聚合物共混方法 |
| JP4853081B2 (ja) * | 2006-03-30 | 2012-01-11 | ダイキン工業株式会社 | プライマー用水性分散組成物 |
| EP2325219A3 (en) | 2006-07-06 | 2011-07-20 | Daikin Industries, Limited | Aqueous fluorine-containing polymer dispersion |
| US8518573B2 (en) * | 2006-09-29 | 2013-08-27 | Maxwell Technologies, Inc. | Low-inductive impedance, thermally decoupled, radii-modulated electrode core |
| US7964274B2 (en) * | 2006-11-16 | 2011-06-21 | E. I. Du Pont De Nemours And Company | Heat aged perfluoropolymer |
| US20080201925A1 (en) | 2007-02-28 | 2008-08-28 | Maxwell Technologies, Inc. | Ultracapacitor electrode with controlled sulfur content |
| US20080204973A1 (en) * | 2007-02-28 | 2008-08-28 | Maxwell Technologies, Inc. | Ultracapacitor electrode with controlled iron content |
| US9040646B2 (en) | 2007-10-04 | 2015-05-26 | W. L. Gore & Associates, Inc. | Expandable TFE copolymers, methods of making, and porous, expanded articles thereof |
| US9650479B2 (en) | 2007-10-04 | 2017-05-16 | W. L. Gore & Associates, Inc. | Dense articles formed from tetrafluoroethylene core shell copolymers and methods of making the same |
| US8637144B2 (en) * | 2007-10-04 | 2014-01-28 | W. L. Gore & Associates, Inc. | Expandable TFE copolymers, method of making, and porous, expended articles thereof |
| US8192677B2 (en) | 2007-12-12 | 2012-06-05 | E. I. Du Pont De Nemours And Company | Core/shell polymer and fluoropolymer blending blow molding and blown film process |
| JP2011527717A (ja) * | 2008-07-10 | 2011-11-04 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | エチレン／テトラフルオロエチレンコポリマーの水分散液重合方法 |
| US20110092614A1 (en) * | 2008-07-10 | 2011-04-21 | E. I. Dupont Denemours And Company | Applications of ethylene/terafluoroethylene copolymer |
| US8889779B2 (en) | 2010-05-25 | 2014-11-18 | E I Du Pont De Nemours And Company | Fluoropolymer non-stick coatings |
| CN102558721B (zh) | 2010-12-31 | 2014-08-20 | 杜邦公司 | 聚四氟乙烯水分散体 |
| JP2015518438A (ja) * | 2012-04-19 | 2015-07-02 | スターン・アンド・スターン・インダストリーズ・インコーポレイテッドＳｔｅｒｎ ＆ Ｓｔｅｒｎ Ｉｎｄｕｓｔｒｉｅｓ， Ｉｎｃ． | 可撓性貼合わせ構造物 |
| WO2014007397A1 (ja) | 2012-07-06 | 2014-01-09 | ダイキン工業株式会社 | シート、電極及び燃料電池 |
| US9656203B2 (en) | 2012-10-04 | 2017-05-23 | Phillips 66 Company | Fluorinated surfactants and stabilization of polytetrafluoroethylene (PTFE) particles in hollow fiber spin solutions |
| EP2902424B1 (en) * | 2014-01-31 | 2020-04-08 | 3M Innovative Properties Company | Tetrafluoroethene polymer dispersions stabilized with aliphatic non-ionic surfactants |
| ES2755124T3 (es) | 2014-05-06 | 2020-04-21 | Italmatch Chemicals Spa | Composiciones de moldeo retardantes de la llama respetuosas con el medio ambiente basadas en polímeros estirénicos termoplásticos modificados por impacto |
| US9644054B2 (en) | 2014-12-19 | 2017-05-09 | W. L. Gore & Associates, Inc. | Dense articles formed from tetrafluoroethylene core shell copolymers and methods of making the same |
| WO2016161271A2 (en) * | 2015-04-01 | 2016-10-06 | 3M Innovative Properties Company | Multilayer articles comprising a release surface and methods thereof |
| WO2016161264A2 (en) * | 2015-04-01 | 2016-10-06 | 3M Innovative Properties Company | Multilayer articles comprising a release surface and methods thereof |
| CN107531010A (zh) * | 2015-04-01 | 2018-01-02 | 3M创新有限公司 | 包括防粘表面的多层制品以及其方法 |
| EP3103836A1 (en) * | 2015-06-12 | 2016-12-14 | 3M Innovative Properties Company | Fluoropolymer with improved transparency |
| US11859075B2 (en) | 2017-12-20 | 2024-01-02 | Daikin Industries, Ltd. | Core-shell type particle, dispersion and powder |
| CN112739728B (zh) | 2018-10-03 | 2023-03-10 | 大金工业株式会社 | 聚四氟乙烯的制造方法 |
| JP7277799B2 (ja) | 2018-10-03 | 2023-05-19 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法 |
| CN117417612A (zh) | 2018-11-19 | 2024-01-19 | 大金工业株式会社 | 组合物和拉伸体 |
| JP7174272B2 (ja) | 2018-11-19 | 2022-11-17 | ダイキン工業株式会社 | 変性ポリテトラフルオロエチレンの製造方法及び組成物 |
| WO2020213691A1 (ja) | 2019-04-16 | 2020-10-22 | ダイキン工業株式会社 | フルオロポリマー粉末の製造方法 |
| EP4006063A4 (en) | 2019-07-23 | 2023-10-25 | Daikin Industries, Ltd. | METHOD FOR PRODUCING A FLUROPOLYMER, POLYTETRAFLUORETHYLENE COMPOSITION AND POLYTETRAFLUORETHYLENE POWDER |
| JP6838627B2 (ja) | 2019-07-25 | 2021-03-03 | ダイキン工業株式会社 | 樹脂組成物、成型品及びオートマチックトランスミッション |
| EP4063405A4 (en) | 2019-11-19 | 2024-01-10 | Daikin Industries, Ltd. | PROCESS FOR PRODUCING POLYTETRAFLUOROETHYLENE |
| JP7698180B2 (ja) * | 2020-11-16 | 2025-06-25 | ダイキン工業株式会社 | 学習モデル生成方法、プログラム、記憶媒体、学習済みモデル |
| WO2022107894A1 (ja) | 2020-11-19 | 2022-05-27 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物 |
| KR102530988B1 (ko) | 2022-06-29 | 2023-05-11 | 주식회사 엘엑스엠엠에이 | 흐름성과 응집성이 개선된 코어쉘형 불소계 수지 입자 및 제조 방법 |
| TW202415742A (zh) * | 2022-09-30 | 2024-04-16 | 美商科慕Ｆｃ有限責任公司 | 用作鋰離子二次電池組電極中之黏合劑之乾燥易碎氟聚合物黏聚物組成物 |
| CN120718302B (zh) * | 2025-08-22 | 2026-03-17 | 山东东岳高分子材料有限公司 | 一种低分子量聚四氟乙烯超细粉的制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3142665A (en) | 1960-07-26 | 1964-07-28 | Du Pont | Novel tetrafluoroethylene resins and their preparation |
| US3037953A (en) | 1961-04-26 | 1962-06-05 | Du Pont | Concentration of aqueous colloidal dispersions of polytetrafluoroethylene |
| US3819594A (en) | 1972-05-17 | 1974-06-25 | Du Pont | Tetrafluoroethylene fine powder resin of a copolymer of tetrafluoroethylene and perfluoro(alkyl vinyl ether) |
| CA1339337C (en) * | 1987-12-31 | 1997-08-19 | Charles Winfield Stewart | Modified polytetrafluoroethylene resins and blends thereof |
| US4837267A (en) * | 1988-03-21 | 1989-06-06 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene copolymers |
| JP3000654B2 (ja) * | 1990-10-19 | 2000-01-17 | ダイキン工業株式会社 | ポリテトラフルオロエチレン微粒子および粉末 |
| EP0758010A4 (en) | 1994-04-28 | 1998-04-15 | Daikin Ind Ltd | FLAME RETARDANT RESIN COMPOSITION WITH DRIP INHIBITOR |
| DE4424466A1 (de) * | 1994-07-12 | 1996-01-18 | Hoechst Ag | Copolymeres vom Typ Tetrafluorethylen-Ethylen mit einer Kern-Hülle-Teilchenstruktur |
| KR100201056B1 (ko) * | 1994-10-19 | 1999-06-15 | 이노우에 노리유끼 | 전지용 결착제 및 이를 사용한 전극용 조성물 및 전지 |
-
2002
- 2002-03-13 AT AT02728547T patent/ATE325825T1/de not_active IP Right Cessation
- 2002-03-13 ES ES02728547T patent/ES2264480T3/es not_active Expired - Lifetime
- 2002-03-13 CN CNB028267397A patent/CN1315898C/zh not_active Expired - Fee Related
- 2002-03-13 MX MXPA04006499A patent/MXPA04006499A/es active IP Right Grant
- 2002-03-13 EP EP20020728547 patent/EP1470171B1/en not_active Expired - Lifetime
- 2002-03-13 WO PCT/US2002/009018 patent/WO2003062291A1/en not_active Ceased
- 2002-03-13 JP JP2003562168A patent/JP4384913B2/ja not_active Expired - Fee Related
- 2002-03-13 US US10/098,803 patent/US6841594B2/en not_active Expired - Lifetime
- 2002-03-13 CA CA 2472135 patent/CA2472135A1/en not_active Abandoned
- 2002-03-13 BR BRPI0215427-7A patent/BR0215427B1/pt not_active IP Right Cessation
- 2002-03-13 DE DE2002611381 patent/DE60211381T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005515279A (ja) | 2005-05-26 |
| EP1470171A1 (en) | 2004-10-27 |
| US20030129400A1 (en) | 2003-07-10 |
| ATE325825T1 (de) | 2006-06-15 |
| EP1470171B1 (en) | 2006-05-10 |
| WO2003062291A1 (en) | 2003-07-31 |
| DE60211381D1 (de) | 2006-06-14 |
| CN1612904A (zh) | 2005-05-04 |
| ES2264480T3 (es) | 2007-01-01 |
| CN1315898C (zh) | 2007-05-16 |
| BR0215427B1 (pt) | 2012-02-22 |
| MXPA04006499A (es) | 2004-10-04 |
| JP4384913B2 (ja) | 2009-12-16 |
| BR0215427A (pt) | 2004-12-14 |
| US6841594B2 (en) | 2005-01-11 |
| CA2472135A1 (en) | 2003-07-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE60211381T2 (de) | Kern-schale-fluorpolymer-dispersionen | |
| DE60201523T2 (de) | Dichtsichtige dispersionen | |
| JP4291157B2 (ja) | 濃縮フルオロポリマー分散液 | |
| DE69513392T2 (de) | Abkreide- und verschleissfeste trennbeschichtung | |
| DE69910909T2 (de) | Fluorpolymerdispersionen | |
| DE69933545T2 (de) | Wässrige Polytetrafluorethylendispersionszusammensetzung | |
| DE19726802C1 (de) | Wäßrige Dispersion von Fluorpolymeren unterschiedlicher Teilchengröße | |
| US7612139B2 (en) | Core/shell fluoropolymer dispersions with low fluorosurfactant content | |
| DE69003155T2 (de) | Wässerige Dispersion, Verbundpulver und Organosol aus fluorhaltigem Polymer. | |
| DE2803241A1 (de) | Verfahren zur herstellung eines beschichteten gegenstandes sowie ein danach hergestellter gegenstand | |
| DE69830368T2 (de) | Laminate aus Fluorpolymer und Metall | |
| DE4340943A1 (de) | Wäßrige Dispersion von Fluorpolymerisaten, ihre Herstellung und Verwendung für Beschichtungen | |
| WO2000078865A1 (de) | Bimodale poly(meth)acrylatplastisole und verfahren zu ihrer herstellung | |
| DE60210152T2 (de) | Wässrige Dispersionen von Fluorpolymeren | |
| DD154823A1 (de) | Verfahren zur herstellung von pulverfoermigen ethylen-vinylalkohol-copolymerisaten |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |