DE60202975T2 - Kohlendioxid-geschäumte biegsame mikrozellulare Elastomere niedriger Dichte für die Herstellung von Schuhkomponenten - Google Patents

Kohlendioxid-geschäumte biegsame mikrozellulare Elastomere niedriger Dichte für die Herstellung von Schuhkomponenten Download PDF

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Publication number
DE60202975T2
DE60202975T2 DE60202975T DE60202975T DE60202975T2 DE 60202975 T2 DE60202975 T2 DE 60202975T2 DE 60202975 T DE60202975 T DE 60202975T DE 60202975 T DE60202975 T DE 60202975T DE 60202975 T2 DE60202975 T2 DE 60202975T2
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Prior art keywords
isocyanate
microcellular
density
water
component
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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DE60202975T
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German (de)
English (en)
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DE60202975D1 (de
Inventor
Usama E. Younes
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Bayer Antwerpen NV
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Bayer Antwerpen NV
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4866—Polyethers having a low unsaturation value
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6552—Compounds of group C08G18/63
    • C08G18/6558—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6564—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0066—≥ 150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2410/00—Soles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/06—Flexible foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
DE60202975T 2001-01-18 2002-01-15 Kohlendioxid-geschäumte biegsame mikrozellulare Elastomere niedriger Dichte für die Herstellung von Schuhkomponenten Expired - Lifetime DE60202975T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/764,682 US6458861B1 (en) 2001-01-18 2001-01-18 Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components
US764682 2001-01-18

Publications (2)

Publication Number Publication Date
DE60202975D1 DE60202975D1 (de) 2005-03-24
DE60202975T2 true DE60202975T2 (de) 2006-04-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE60202975T Expired - Lifetime DE60202975T2 (de) 2001-01-18 2002-01-15 Kohlendioxid-geschäumte biegsame mikrozellulare Elastomere niedriger Dichte für die Herstellung von Schuhkomponenten

Country Status (15)

Country Link
US (1) US6458861B1 (cg-RX-API-DMAC10.html)
EP (1) EP1225199B1 (cg-RX-API-DMAC10.html)
JP (1) JP2002241462A (cg-RX-API-DMAC10.html)
KR (1) KR100803856B1 (cg-RX-API-DMAC10.html)
AR (1) AR038656A1 (cg-RX-API-DMAC10.html)
AT (1) ATE289329T1 (cg-RX-API-DMAC10.html)
AU (1) AU1021802A (cg-RX-API-DMAC10.html)
BR (1) BR0200091A (cg-RX-API-DMAC10.html)
CA (1) CA2367077C (cg-RX-API-DMAC10.html)
DE (1) DE60202975T2 (cg-RX-API-DMAC10.html)
HU (1) HUP0200183A3 (cg-RX-API-DMAC10.html)
MX (1) MXPA02000493A (cg-RX-API-DMAC10.html)
PL (1) PL351735A1 (cg-RX-API-DMAC10.html)
RU (1) RU2002100702A (cg-RX-API-DMAC10.html)
SK (1) SK422002A3 (cg-RX-API-DMAC10.html)

Families Citing this family (32)

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KR101071099B1 (ko) * 2002-06-21 2011-10-10 바스프 에스이 빛에 안정한 미공질 또는 비-다공질 폴리우레탄 재료 및이의 제조방법
DE10319393A1 (de) * 2003-04-30 2004-11-18 Bayer Materialscience Ag Flexible Formteile aus geschäumten Polyurethan und ihre Verwendung
FR2858623B1 (fr) * 2003-08-08 2006-01-13 Rhodia Polyamide Intermediates Mousses polyurethannes, procede de fabrication et utilisation de ces mousses
FR2858622B1 (fr) * 2003-08-08 2007-03-30 Rhodia Polyamide Intermediates Mousses polyurethane, polyester-polyols pour l'obtention des mousses et utilisation de ces mousses
DE102004010809A1 (de) * 2004-03-05 2005-09-22 Bayer Materialscience Ag Flexible Formteile aus geschäumtem Polyurethan und ihre Verwendung
EP1817357A1 (en) * 2004-10-15 2007-08-15 Danisco A/S A foamed isocyanate-based polymer, a mix and process for production thereof
US7465757B2 (en) * 2004-10-15 2008-12-16 Danisco A/S Foamed isocyanate-based polymer, a mix and process for production thereof
US7670501B2 (en) * 2005-05-27 2010-03-02 Bayer Materialscience Llc Carbon dioxide blown low density, flexible microcellular polyurethane elastomers
ITMI20052257A1 (it) 2005-11-25 2007-05-26 Basf Ag Suole intermedie per scarpe dio sicurezza da espanso poliuretano di bassa densita'
US20080058468A1 (en) * 2006-08-31 2008-03-06 Bayer Materialscience Llc Low density rigid reinforced polyurethanes and a process for their production
DE102006042338A1 (de) * 2006-09-08 2008-03-27 Evonik Goldschmidt Gmbh Verwendung von Urethan- oder Harnstoffgruppen enthaltenden Polyethern zur Stabilisierung von Polyurethanschäumen
EP2195363B1 (de) * 2007-10-02 2017-08-30 Basf Se Niederdichte polyurethanschaumstoffe und deren verwendung in schuhsohlen
DE102007050100A1 (de) * 2007-10-19 2009-04-23 Entwicklungsgesellschaft für Akustik (EfA) mit beschränkter Haftung Schallisolierung mit CO2-beladener Kompakt-Polyurethan-Schaumstoff (RIM)-Schicht
CA2716792C (en) * 2008-03-14 2017-04-18 Basf Se Coarse-cell polyurethane elastomers
CN101486788B (zh) * 2008-12-30 2011-09-14 浙江华峰新材料股份有限公司 一种低密度高硬度聚氨酯微孔弹性体及其制备方法
TWI404739B (zh) * 2009-04-02 2013-08-11 Chung Hsien Tu 軟質聚氨酯低回彈發泡體及其製備方法
JP5597380B2 (ja) * 2009-10-09 2014-10-01 株式会社ダイフレックス 手塗り施工用塗工剤
ITMI20110062A1 (it) * 2011-01-24 2012-07-25 Dow Chemical Co Poliuretani polieteri con migliore resistenza allo scivolo in condizioni umide
CN104066763A (zh) 2012-01-18 2014-09-24 巴斯夫欧洲公司 具有高回弹性和低压缩形变的低密度聚氨酯鞋底或鞋底部分
US9023910B2 (en) 2012-01-18 2015-05-05 Basf Se Low-density polyurethane shoe soles or sole parts with high rebound resilience and low compression set
US9695266B2 (en) * 2013-03-06 2017-07-04 Foamtec International Co., Ltd. Wettable, high strength foam especially for ink holders
CN103419371B (zh) * 2013-08-01 2015-06-03 四川大学 一种具有开孔结构的橡胶泡沫材料的制备方法
CN103627310B (zh) * 2013-11-01 2016-01-06 华南理工大学 一种环保型聚氨酯塑胶跑道的喷涂面层的制备方法
CN107383322B (zh) * 2017-08-30 2020-12-18 中车青岛四方车辆研究所有限公司 城轨用低动静刚度比聚氨酯微孔弹性体组合料及制备方法
US20200231740A1 (en) * 2017-09-21 2020-07-23 Basf Se Composition and method to produce microcellular polyurethane foam systems
KR101939205B1 (ko) * 2018-02-22 2019-01-17 정순구 미드솔로 이루어진 기능성 신발 밑창
CN112020534B (zh) * 2018-03-12 2023-02-17 耐克创新有限合伙公司 用于制造热塑性泡沫物品的方法
EP3986960A1 (en) 2019-09-12 2022-04-27 Nike Innovate C.V. A cushioning element for an article of footwear
US11447615B2 (en) 2019-09-12 2022-09-20 Nike, Inc. Foam compositions and uses thereof
US20230250220A1 (en) * 2020-07-10 2023-08-10 Basf Se Process for preparing a crosslinked thermoplastic polyurethane and articles thereof
WO2022195398A1 (en) * 2021-03-15 2022-09-22 Toscana Gomma S.P.A. Process for making a polyurethane gel
CN114395105A (zh) * 2021-12-31 2022-04-26 广东粤港澳大湾区黄埔材料研究院 一种聚氨酯微孔弹性体及应用该弹性体的鞋底材料、减震材料

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US4906672A (en) * 1988-07-29 1990-03-06 Pmc, Inc. Blowing agents for polyurethane foam
US5120770A (en) 1989-11-29 1992-06-09 Doyle Earl N Use of liquid carbon dioxide as a blowing agent in the production of open-cell polyurethane foam
US5403088A (en) * 1993-06-18 1995-04-04 The Dow Chemical Company Apparatus and method for the dispersion of minute bubbles in liquid materials for the production of polymer foams
US5500450A (en) * 1995-04-05 1996-03-19 The United States Of America As Represented By The Department Of Energy Ultra-low density microcellular polymer foam and method
DE19622742C1 (de) 1996-06-07 1998-03-12 Hennecke Gmbh Verfahren zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid
US6022903A (en) * 1998-07-09 2000-02-08 Arco Chemical Technology L.P. Permanent gas blown microcellular polyurethane elastomers
US6100310A (en) * 1998-09-25 2000-08-08 Bayer Antwerp N.V. Process for making microcellular polyurethane elastomers
SK11902001A3 (sk) * 1999-02-26 2002-01-07 Bayer Antwerpen N. V. Spôsob výroby mikrobunkových polyuretánových elastomérov so zlepšenou spracovateľnosťou a elastoméry vyrobené týmto spôsobom

Also Published As

Publication number Publication date
BR0200091A (pt) 2002-10-22
HUP0200183A2 (hu) 2002-11-28
EP1225199B1 (en) 2005-02-16
EP1225199A1 (en) 2002-07-24
KR20020062180A (ko) 2002-07-25
ATE289329T1 (de) 2005-03-15
CA2367077C (en) 2011-03-22
US20020132870A1 (en) 2002-09-19
CA2367077A1 (en) 2002-07-18
JP2002241462A (ja) 2002-08-28
MXPA02000493A (es) 2004-05-21
AU1021802A (en) 2002-07-25
HUP0200183A3 (en) 2003-12-29
HU0200183D0 (en) 2002-03-28
US6458861B1 (en) 2002-10-01
KR100803856B1 (ko) 2008-02-14
AR038656A1 (es) 2005-01-26
DE60202975D1 (de) 2005-03-24
PL351735A1 (en) 2002-07-29
SK422002A3 (en) 2003-07-01
RU2002100702A (ru) 2003-07-20

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