DE60202135T2 - Schwach glänzende biaxial orientierte Folien, die vinylaromatische Verbindungen und im wesentlichen nicht-kuglige Kautschukpartikel enthalten - Google Patents
Schwach glänzende biaxial orientierte Folien, die vinylaromatische Verbindungen und im wesentlichen nicht-kuglige Kautschukpartikel enthalten Download PDFInfo
- Publication number
- DE60202135T2 DE60202135T2 DE60202135T DE60202135T DE60202135T2 DE 60202135 T2 DE60202135 T2 DE 60202135T2 DE 60202135 T DE60202135 T DE 60202135T DE 60202135 T DE60202135 T DE 60202135T DE 60202135 T2 DE60202135 T2 DE 60202135T2
- Authority
- DE
- Germany
- Prior art keywords
- film
- less
- rubber particles
- gloss
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002245 particle Substances 0.000 title claims abstract description 69
- 229920001971 elastomer Polymers 0.000 title claims abstract description 57
- 239000005060 rubber Substances 0.000 title claims abstract description 57
- 229920002554 vinyl polymer Polymers 0.000 title claims abstract description 9
- -1 vinyl aromatic compounds Chemical class 0.000 title 1
- 229920006254 polymer film Polymers 0.000 claims abstract description 12
- 239000004793 Polystyrene Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 229920002223 polystyrene Polymers 0.000 claims description 12
- 239000011888 foil Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 5
- 238000010998 test method Methods 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000005062 Polybutadiene Substances 0.000 claims 1
- 229920002857 polybutadiene Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 8
- 229920005669 high impact polystyrene Polymers 0.000 description 9
- 239000004797 high-impact polystyrene Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 7
- 238000012015 optical character recognition Methods 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 150000001993 dienes Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 238000007664 blowing Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229920002959 polymer blend Polymers 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical class COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26613201P | 2001-02-02 | 2001-02-02 | |
| US266132P | 2001-02-02 | ||
| PCT/US2002/000778 WO2002062876A2 (en) | 2001-02-02 | 2002-01-11 | Low-gloss biaxially oriented films comprising vinyl aromatic polymers and substantially non-spherical rubber particles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60202135D1 DE60202135D1 (de) | 2005-01-05 |
| DE60202135T2 true DE60202135T2 (de) | 2005-12-29 |
Family
ID=23013303
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60202135T Expired - Lifetime DE60202135T2 (de) | 2001-02-02 | 2002-01-11 | Schwach glänzende biaxial orientierte Folien, die vinylaromatische Verbindungen und im wesentlichen nicht-kuglige Kautschukpartikel enthalten |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6579946B2 (enExample) |
| EP (1) | EP1368416B1 (enExample) |
| JP (1) | JP4261187B2 (enExample) |
| KR (1) | KR100787689B1 (enExample) |
| CN (1) | CN1262577C (enExample) |
| AT (1) | ATE283887T1 (enExample) |
| BR (1) | BR0207065A (enExample) |
| CA (1) | CA2437316C (enExample) |
| CZ (1) | CZ20032069A3 (enExample) |
| DE (1) | DE60202135T2 (enExample) |
| ES (1) | ES2229122T3 (enExample) |
| HU (1) | HUP0302994A3 (enExample) |
| MX (1) | MXPA03006907A (enExample) |
| PL (1) | PL363479A1 (enExample) |
| WO (1) | WO2002062876A2 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008040821A3 (de) * | 2007-02-28 | 2008-09-18 | Basf Se | Hohlkörper aus polystyrol durch spritzstreckblasen |
| US8545953B2 (en) | 2007-02-28 | 2013-10-01 | Styrolution GmbH | Hollow polystyrene body obtained by injection stretch blow moulding |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2529386A1 (en) * | 2003-07-11 | 2005-01-27 | Ferro Corporation | Low glow olefin |
| EP1907290B1 (en) * | 2005-06-27 | 2014-04-16 | Dow Global Technologies LLC | Window envelopes with optical character readable window film patches |
| GB0514785D0 (en) * | 2005-07-19 | 2005-08-24 | Innovia Films Ltd | Sealed ream wrap package and films suitable for forming such packages |
| KR20090087868A (ko) * | 2006-09-15 | 2009-08-18 | 엠지시 휠시트 가부시키가이샤 | 위상차 필름 |
| DE102008016436A1 (de) * | 2008-03-31 | 2009-10-01 | Ems-Patent Ag | Polyamidformmasse für lackfreie, zähe Gehäuse mit Hochglanz-Oberfläche |
| US20090325440A1 (en) * | 2008-06-30 | 2009-12-31 | Thomas Oomman P | Films and film laminates with relatively high machine direction modulus |
| US20100140835A1 (en) * | 2008-12-09 | 2010-06-10 | Fina Technology, Inc. | Styrenic polymers for injection stretch blow molding and methods of making and using same |
| KR20120075724A (ko) * | 2010-12-29 | 2012-07-09 | 제일모직주식회사 | 내충격성이 우수한 저광성의 난연 ａｂｓ 수지 조성물 |
| WO2020027082A1 (ja) * | 2018-07-31 | 2020-02-06 | コニカミノルタ株式会社 | 光学フィルム、偏光板保護フィルム、光学フィルムのロール体、および光学フィルムの製造方法 |
| CN111303549B (zh) * | 2020-04-07 | 2021-10-08 | 四川大学 | 一种增强增韧聚苯乙烯的制备方法及拉伸薄膜 |
| JP7558508B2 (ja) * | 2020-08-21 | 2024-10-01 | 高砂熱学工業株式会社 | 木質燃料製造システム及び方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4097549A (en) | 1975-12-29 | 1978-06-27 | Monsanto Company | Polymer polyblend composition |
| US4214056A (en) | 1978-05-19 | 1980-07-22 | Monsanto Company | Method for preparing a monoalkenyl aromatic polyblend having a dispersed rubber phase as particles with a bimodal particle size distribution |
| US4334039A (en) | 1981-03-23 | 1982-06-08 | Monsanto Company | Process for preparing polymeric polyblends having a rubber phase as particles with a bimodal particle size distribution |
| JPS5852239A (ja) | 1981-09-22 | 1983-03-28 | Nippon Kayaku Co Ltd | 酸化反応生成ガスの処理法 |
| NL8202281A (nl) | 1982-06-04 | 1984-01-02 | Dow Chemical Nederland | Met rubber versterkte polymeren van aromatische monovinylideenverbindingen en werkwijze voor de bereiding daarvan. |
| NL8304029A (nl) | 1983-11-23 | 1985-06-17 | Dow Chemical Nederland | Met rubber versterkte polymeren van monovinylideen-aromatische verbindingen met een zeer goede verhouding tussen glans en sterkteeigenschappen en een werkwijze voor hun bereiding. |
| JPS62143957A (ja) | 1985-12-18 | 1987-06-27 | Sumitomo Chem Co Ltd | スチレン系樹脂組成物 |
| US5237004A (en) | 1986-11-18 | 1993-08-17 | Rohm And Haas Company | Thermoplastic and thermoset polymer compositions |
| ATE85804T1 (de) | 1988-05-18 | 1993-03-15 | Rohm & Haas | Thermoplastische und waermehaertbare zusammensetzungen. |
| DE3907968A1 (de) | 1989-03-11 | 1990-09-13 | Swf Auto Electric Gmbh | Scheibenreinigungsanlage |
| GB8920574D0 (en) | 1989-09-12 | 1989-10-25 | Dow Benelux | Monovinylidene aromatic polymers with improved properties and a process for their preparation |
| US5270386A (en) | 1992-03-10 | 1993-12-14 | The Dow Chemical Company | Styrenic copolymers modified with poly (phenylene ether) |
| JP3219485B2 (ja) | 1992-10-02 | 2001-10-15 | 電気化学工業株式会社 | スチレン系樹脂二軸延伸シート |
| CA2123828C (en) * | 1993-05-20 | 2001-03-20 | Shingo Midorikawa | Pneumatic vehicle tire |
| US5643664A (en) | 1994-08-23 | 1997-07-01 | Packaging Corporation Of America | Biaxially oriented polystyrene film |
| EP0863936A1 (en) | 1995-09-01 | 1998-09-16 | The Dow Chemical Company | Thin polystyrene films containing post-consumer recycled polystyrene |
| JPH09208717A (ja) | 1996-02-01 | 1997-08-12 | Daicel Chem Ind Ltd | ２軸延伸ポリスチレン系樹脂シート |
| US5981047A (en) | 1996-06-25 | 1999-11-09 | Applied Extrusion Technologies, Inc. | Matte finish biaxially oriented polypropylene film for cold seal release applications |
| US5852124A (en) | 1996-08-06 | 1998-12-22 | Chi Mei Corporation | Rubber-modified styrenic resin composition |
| DE19715821A1 (de) | 1997-04-16 | 1998-10-22 | Basf Ag | Thermoplastische Formmasse |
| WO1999043740A1 (en) | 1998-02-27 | 1999-09-02 | The Dow Chemical Company | Films having improved scratch resistance |
| KR100302128B1 (ko) | 1998-11-24 | 2001-10-29 | 전주범 | 사출성형용폴리스티렌계수지조성물 |
-
2002
- 2002-01-10 US US10/043,619 patent/US6579946B2/en not_active Expired - Lifetime
- 2002-01-11 JP JP2002563222A patent/JP4261187B2/ja not_active Expired - Fee Related
- 2002-01-11 CA CA002437316A patent/CA2437316C/en not_active Expired - Fee Related
- 2002-01-11 ES ES02720780T patent/ES2229122T3/es not_active Expired - Lifetime
- 2002-01-11 WO PCT/US2002/000778 patent/WO2002062876A2/en not_active Ceased
- 2002-01-11 EP EP02720780A patent/EP1368416B1/en not_active Expired - Lifetime
- 2002-01-11 DE DE60202135T patent/DE60202135T2/de not_active Expired - Lifetime
- 2002-01-11 MX MXPA03006907A patent/MXPA03006907A/es not_active Application Discontinuation
- 2002-01-11 AT AT02720780T patent/ATE283887T1/de not_active IP Right Cessation
- 2002-01-11 CN CNB028044215A patent/CN1262577C/zh not_active Expired - Fee Related
- 2002-01-11 BR BR0207065-0A patent/BR0207065A/pt not_active Application Discontinuation
- 2002-01-11 KR KR1020037010207A patent/KR100787689B1/ko not_active Expired - Fee Related
- 2002-01-11 PL PL02363479A patent/PL363479A1/xx not_active Application Discontinuation
- 2002-01-11 HU HU0302994A patent/HUP0302994A3/hu unknown
- 2002-01-11 CZ CZ20032069A patent/CZ20032069A3/cs unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008040821A3 (de) * | 2007-02-28 | 2008-09-18 | Basf Se | Hohlkörper aus polystyrol durch spritzstreckblasen |
| US8545953B2 (en) | 2007-02-28 | 2013-10-01 | Styrolution GmbH | Hollow polystyrene body obtained by injection stretch blow moulding |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030076648A (ko) | 2003-09-26 |
| ES2229122T3 (es) | 2005-04-16 |
| WO2002062876A3 (en) | 2003-06-12 |
| US20020143107A1 (en) | 2002-10-03 |
| JP4261187B2 (ja) | 2009-04-30 |
| BR0207065A (pt) | 2004-03-30 |
| CA2437316A1 (en) | 2002-08-15 |
| HUP0302994A3 (en) | 2005-08-29 |
| CZ20032069A3 (cs) | 2003-11-12 |
| WO2002062876A2 (en) | 2002-08-15 |
| CA2437316C (en) | 2009-10-27 |
| JP2004518792A (ja) | 2004-06-24 |
| PL363479A1 (en) | 2004-11-15 |
| US6579946B2 (en) | 2003-06-17 |
| CN1262577C (zh) | 2006-07-05 |
| MXPA03006907A (es) | 2004-05-05 |
| EP1368416B1 (en) | 2004-12-01 |
| HUP0302994A2 (hu) | 2003-11-28 |
| ATE283887T1 (de) | 2004-12-15 |
| KR100787689B1 (ko) | 2007-12-21 |
| DE60202135D1 (de) | 2005-01-05 |
| CN1494566A (zh) | 2004-05-05 |
| EP1368416A2 (en) | 2003-12-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |